WO2011138366A1 - Composition fibreuse pour la fabrication de papier et de carton - Google Patents

Composition fibreuse pour la fabrication de papier et de carton Download PDF

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Publication number
WO2011138366A1
WO2011138366A1 PCT/EP2011/057134 EP2011057134W WO2011138366A1 WO 2011138366 A1 WO2011138366 A1 WO 2011138366A1 EP 2011057134 W EP2011057134 W EP 2011057134W WO 2011138366 A1 WO2011138366 A1 WO 2011138366A1
Authority
WO
WIPO (PCT)
Prior art keywords
pulp
paper
oxidized
waste paper
oxidation
Prior art date
Application number
PCT/EP2011/057134
Other languages
German (de)
English (en)
Inventor
Christian Jehn-Rendu
Hans-Georg Lemaire
Oliver Koch
Tilo Habicher
Sylke Haremza
Markus Hoffmann
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Priority to BR112012027210A priority Critical patent/BR112012027210A2/pt
Priority to CN2011800224242A priority patent/CN102869830A/zh
Priority to CA2795834A priority patent/CA2795834A1/fr
Priority to EP11716963A priority patent/EP2567024A1/fr
Publication of WO2011138366A1 publication Critical patent/WO2011138366A1/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/02—Oxycellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
    • D21H11/20—Chemically or biochemically modified fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/10—Retention agents or drainage improvers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents

Definitions

  • waste paper pulp ie a pulp obtained by recycling waste paper, or using mechanical pulp. Since the cost of waste paper pulp or of mechanical material is substantially lower than for fresh pulp, an increase in the proportion of waste paper pulp or of mechanical pulp in the paper pulp or paper pulp. Paperboard production used a great economic advantage for the paper manufacturer. Frequently, however, the quality of the waste paper pulp leaves much to be desired if the structure of the fibers is damaged in the recycling of paper and cardboard or in the mechanical pulping of wood, which leads to lower strength values in the paper. Therefore, the amount of waste paper pulp or mechanical pulp in the pulp used to make the paper or paperboard is limited. However, an increase in the content of waste paper pulp and / or mechanical pulp is desirable for the reasons mentioned above. It has been reported on various occasions to use a stock for papermaking in which the cellulose fibers have previously been subjected to oxidation.
  • WO 01/29309 likewise describes a process for the production of paper in which a pulp is used whose cellulose fibers have been previously treated with an oxidizing agent in the presence of a mediator. Again, the oxidation leads to an improvement in the wet strength properties of the paper.
  • a further problem in the production of paper or board is the often unsatisfactory retention properties of the pulp compositions used for paper or board production, in particular those pulp compositions with a high content of waste paper and / or mechanical or thermomechanical material, so that larger quantities must be used on retention aids. Often, the drainage properties of the compositions are unsatisfactory.
  • the present invention relates to the use of an oxidized pulp B in which by oxidation of at least one conventional pulp selected from waste paper pulp, mechanical pulp and blends thereof 1 to 500 mmol, especially 5 to 200 mmol, especially 10 to 150 mmol carboxyl groups per kg of conventional pulp and from 1 to 200 mmol, in particular from 2 to 150 mmol and especially from 5 to 100 mmol aldehyde groups per kg of conventional pulp were used to improve the retention properties or to improve the drainage properties of the pulp compositions defined herein and below and / or to improve the dry strength properties, in particular dry tensile strength, tensile strength, tear propagation strength and bursting pressure of paper or board, particularly paper or board, using the fibrous material defined herein and hereinafter fuses arrangementen is produced.
  • the total amount of the components A and B account for 30 to 80 wt .-% of the total pulp in the pulp composition and the ingredients A, B and C at least 70 wt .-%, in particular at least 80 wt .-% and especially at least 90 wt. % or 100% by weight of the total mass of pulp in the pulp composition, the stated amounts of constituents A, B and C each being calculated as oven-dry pulp.
  • the amount of oxidized fibers B namely oxidized waste paper pulp and / or oxidized mechanical pulp, is typically 10 to 79 wt .-%, often 20 to 68 wt .-% and in particular 30 to 55 wt .-%, based on total mass in the pulp composition.
  • the amount of chemical pulp A and oxidized pulp B is according to the invention 20 to 80 wt .-%, often 30 to 70 wt .-% and in particular 40 to 60 wt .-%, based on the total mass of matter in the pulp composition.
  • oxidized waste paper pulp and mixtures of oxidized waste paper pulp with oxidized mechanical pulp in which the proportion of oxidised waste paper pulp is at least 30% by weight, in particular at least 50% by weight, based on the total mass of constituents B.
  • the oxidation of the conventional pulp can be carried out in a conventional manner.
  • the amount of aldehyde groups and carboxyl groups introduced by oxidation can be controlled by those skilled in the art by choosing appropriate reaction conditions, reagent amounts, and by determining the necessary reaction conditions and reagent levels by routine experimentation.
  • mixed bales (1.02), Kaufhausaltpapier (1.04), corrugated board Il (4.03), multi-pressure (3.10), white rotary waste (3.14 / 3.15) and white envelope chips (3.18.01) may include.
  • the numbers in parentheses indicate the number assigned to EN 643, respectively. It may also be equivalent waste or packaging of cardboard or paperboard, including paper, cardboard or paperboard composites with other materials, such as plastic coatings or liners.
  • the essential aspect of the waste paper pulp used in accordance with the invention is that, in contrast to fresh fiber material which has hitherto not undergone any disruption or which has not yet been processed into paper or paperboard products, it is recycled waste paper material.
  • the conventional waste paper pulp is treated with atmospheric oxygen in the presence of an oxidase or with hydrogen peroxide in the presence of a suitable peroxidase.
  • Oxidases such as catechol oxidase (EC 1 .10.3.1), laccases (EC 1 .10.3.2), bilirubin oxidases (EC 1.3.3.5) are preferred.
  • the oxidation-mediating enzyme is a laccase. Basically, all laccases are suitable.
  • M. thermophila Rhizoctonia sp., In particular Rhizoctonia praticola or Rhizoctonia solani , from Scytotidium sp., in particular S. thermophilium, from Pyricularia sp., in particular Pyricularia oryzae or Coprinus sp. be derived as C. cinereus.
  • the oxidation time depends in a conventional manner on the type and amount of each selected oxidant and the other reaction conditions such as temperature and pH, in the case of enzymatic oxidation of activity and
  • the oxidation time is in the range of 5 minutes to 24 hours, more preferably in the range of 10 minutes to 18 hours and more preferably in the range of 20 minutes to 12 hours.
  • the oxidation of the conventional pulp takes place in the presence of at least one mediator compound, hereinafter also referred to as redox mediator.
  • Suitable mediator compounds are in principle all compounds described in the prior art for this purpose, for example those described in US Pat
  • Phenoxazine compounds such as 10-phenoxazine-propionic acid (POP), 10-methylphenoxazine, or 10- (2-hydroxyethyl) phenoxazine;
  • Biphenylamines such as N-benzylidene-4-biphenylamine or 4,4'-dimethoxy-N-methyldiphenylamine;
  • atmospheric oxygen for enzymatic oxidation using atmospheric oxygen, it is usually necessary to atmospheric oxygen in the aqueous suspension of the fibrous material to be oxidized contribute. This is usually achieved by moving the suspension, for example by stirring in suitable vessels, preferably vessels, which are provided with internals to improve the mixing. Optionally, it is also possible to inject atmospheric oxygen into the reaction mixture.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Microbiology (AREA)
  • Paper (AREA)

Abstract

L'invention concerne une nouvelle composition fibreuse pour la fabrication de papier ou de carton contenant une pâte de fibre recyclée oxydée et/ou une matière mécanique oxydée dans laquelle 1 à 500 mmol de groupes carboxyle par kg et 1 à 200 mmol de groupes aldéhyde par kg ont été introduits par oxydation. L'invention concerne également du papier et du carton à base d'une telle composition fibreuse ainsi qu'un procédé de fabrication d'un tel papier ou carton. L'invention concerne également l'utilisation de pâte de fibre recyclée oxydée et/ou de matière mécanique oxydée destinée à améliorer la rétention et les propriétés de déshydratation d'une matière appropriée pour la fabrication de papier ou de carton. L'invention concerne en outre l'utilisation de pâte de fibre recyclée oxydée et/ou de matière mécanique oxydée pour améliorer, c'est-à-dire augmenter, la résistance à sec du papier et du carton.
PCT/EP2011/057134 2010-05-05 2011-05-04 Composition fibreuse pour la fabrication de papier et de carton WO2011138366A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BR112012027210A BR112012027210A2 (pt) 2010-05-05 2011-05-04 composição de polpa para a produção de papel ou de cartolina, material de papel, papel ou cartolina, processo para produzir papel ou cartolina, e, uso
CN2011800224242A CN102869830A (zh) 2010-05-05 2011-05-04 纸张和纸板生产用纤维状组合物
CA2795834A CA2795834A1 (fr) 2010-05-05 2011-05-04 Composition fibreuse pour la fabrication de papier et de carton
EP11716963A EP2567024A1 (fr) 2010-05-05 2011-05-04 Composition fibreuse pour la fabrication de papier et de carton

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10162028 2010-05-05
EP10162028.4 2010-05-05

Publications (1)

Publication Number Publication Date
WO2011138366A1 true WO2011138366A1 (fr) 2011-11-10

Family

ID=44318338

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/057134 WO2011138366A1 (fr) 2010-05-05 2011-05-04 Composition fibreuse pour la fabrication de papier et de carton

Country Status (5)

Country Link
EP (1) EP2567024A1 (fr)
CN (1) CN102869830A (fr)
BR (1) BR112012027210A2 (fr)
CA (1) CA2795834A1 (fr)
WO (1) WO2011138366A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102677496A (zh) * 2012-05-29 2012-09-19 宜宾长毅浆粕有限责任公司 一种漂白竹木复合纸浆改性制备溶解浆的备料工艺

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103556517B (zh) * 2013-10-31 2016-11-23 昆明理工大学 一种漆酶预处理提高氧碱制浆效果的方法
CN104213448A (zh) * 2014-08-28 2014-12-17 华南理工大学 一种基于漆酶/谷氨酸用于抑制再生纤维强度下降的生物处理方法
CN105064133B (zh) * 2015-07-07 2017-04-19 浙江华川实业集团有限公司 一种高韧耐磨纸板及其制备方法

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02238885A (ja) 1989-03-13 1990-09-21 Oji Paper Co Ltd フェノールオキシダーゼ遺伝子組換えｄｎａ、該組換えｄｎａにより形質転換された微生物、その培養物及びフェノールオキシダーゼの製造方法
EP0462365A1 (fr) 1990-06-18 1991-12-27 Cytec Technology Corp. Microbilles chargées en polymères organiques pour la fabrication du papier
WO1992001046A1 (fr) 1990-07-06 1992-01-23 Valtion Teknillinen Tutkimuskeskus Production de laccase au moyen d'organismes recombines
WO1995001426A1 (fr) 1993-06-29 1995-01-12 Novo Nordisk A/S Renforcement de reactions aux laccases
WO1996010079A1 (fr) 1994-09-27 1996-04-04 Novo Nordisk A/S Activateurs tels que l'acetosyringone
WO1999023117A1 (fr) 1997-11-04 1999-05-14 Valtion Teknillinen Tutkimuskeskus Procede de modification de la cellulose
WO2000068500A1 (fr) 1999-05-06 2000-11-16 Novozymes A/S Procede de production de materiaux de type papier presentant une resistance a l'humidite amelioree
EP1077286A1 (fr) 1999-08-17 2001-02-21 National Starch and Chemical Investment Holding Corporation Pâte cellulosique modifiée à l'aldéhyde destinée à la fabrication de produits de papier à haute résistance
WO2001029309A1 (fr) 1999-10-15 2001-04-26 Weyerhaeuser Company Procede de fabrication de fibres de cellulose carboxylees et produits fabriques selon ledit procede
WO2001034908A1 (fr) 1999-11-08 2001-05-17 Ciba Specialty Chemicals Water Treatments Limited Fabrication de papier ou de carton
WO2001034910A1 (fr) 1999-11-08 2001-05-17 Ciba Specialty Chemicals Water Treatments Limited Fabrication de papier et de carton
EP1106732A2 (fr) 1999-08-17 2001-06-13 National Starch and Chemical Investment Holding Corporation Papier fabriqué à partir de pâte de cellulose modifiée avec des aldéhydes
WO2002033171A1 (fr) 2000-10-16 2002-04-25 Ciba Speciality Chemicals Water Treatments Limited Fabrication du papier et du carton
US20030192664A1 (en) 1995-01-30 2003-10-16 Kulick Russell J. Use of vinylamine polymers with ionic, organic, cross-linked polymeric microbeads in paper-making
EP1505208A2 (fr) * 2003-08-05 2005-02-09 Weyerhaeuser Company Procédé de préparation de produits papier tissu contanant des fibres cellulosiques carboxylées

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MXPA01008545A (es) * 1999-02-24 2003-06-06 Sca Hygiene Prod Gmbh Materiales fibrosos que contienen celulosa oxidada y productos preparados a partir de estos.
US6695950B1 (en) * 1999-08-17 2004-02-24 National Starch And Chemical Investment Holding Corporation Aldehyde modified cellulose pulp for the preparation of high strength paper products

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02238885A (ja) 1989-03-13 1990-09-21 Oji Paper Co Ltd フェノールオキシダーゼ遺伝子組換えｄｎａ、該組換えｄｎａにより形質転換された微生物、その培養物及びフェノールオキシダーゼの製造方法
EP0462365A1 (fr) 1990-06-18 1991-12-27 Cytec Technology Corp. Microbilles chargées en polymères organiques pour la fabrication du papier
WO1992001046A1 (fr) 1990-07-06 1992-01-23 Valtion Teknillinen Tutkimuskeskus Production de laccase au moyen d'organismes recombines
WO1995001426A1 (fr) 1993-06-29 1995-01-12 Novo Nordisk A/S Renforcement de reactions aux laccases
WO1996010079A1 (fr) 1994-09-27 1996-04-04 Novo Nordisk A/S Activateurs tels que l'acetosyringone
US20030192664A1 (en) 1995-01-30 2003-10-16 Kulick Russell J. Use of vinylamine polymers with ionic, organic, cross-linked polymeric microbeads in paper-making
WO1999023117A1 (fr) 1997-11-04 1999-05-14 Valtion Teknillinen Tutkimuskeskus Procede de modification de la cellulose
WO2000068500A1 (fr) 1999-05-06 2000-11-16 Novozymes A/S Procede de production de materiaux de type papier presentant une resistance a l'humidite amelioree
EP1106732A2 (fr) 1999-08-17 2001-06-13 National Starch and Chemical Investment Holding Corporation Papier fabriqué à partir de pâte de cellulose modifiée avec des aldéhydes
EP1077286A1 (fr) 1999-08-17 2001-02-21 National Starch and Chemical Investment Holding Corporation Pâte cellulosique modifiée à l'aldéhyde destinée à la fabrication de produits de papier à haute résistance
WO2001029309A1 (fr) 1999-10-15 2001-04-26 Weyerhaeuser Company Procede de fabrication de fibres de cellulose carboxylees et produits fabriques selon ledit procede
WO2001034908A1 (fr) 1999-11-08 2001-05-17 Ciba Specialty Chemicals Water Treatments Limited Fabrication de papier ou de carton
WO2001034910A1 (fr) 1999-11-08 2001-05-17 Ciba Specialty Chemicals Water Treatments Limited Fabrication de papier et de carton
WO2002033171A1 (fr) 2000-10-16 2002-04-25 Ciba Speciality Chemicals Water Treatments Limited Fabrication du papier et du carton
EP1505208A2 (fr) * 2003-08-05 2005-02-09 Weyerhaeuser Company Procédé de préparation de produits papier tissu contanant des fibres cellulosiques carboxylées

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"Ulmann's Encyclopedia of Industrial Chemistry", 1997, WILEY-VCH
ROEMPP: "Lexikon Chemie", 1998, THIEME VERLAG, pages: 3110 - 3115

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102677496A (zh) * 2012-05-29 2012-09-19 宜宾长毅浆粕有限责任公司 一种漂白竹木复合纸浆改性制备溶解浆的备料工艺

Also Published As

Publication number Publication date
CA2795834A1 (fr) 2011-11-10
CN102869830A (zh) 2013-01-09
BR112012027210A2 (pt) 2016-07-26
EP2567024A1 (fr) 2013-03-13

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