WO2011125050A1 - Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same - Google Patents
Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same Download PDFInfo
- Publication number
- WO2011125050A1 WO2011125050A1 PCT/IB2011/051526 IB2011051526W WO2011125050A1 WO 2011125050 A1 WO2011125050 A1 WO 2011125050A1 IB 2011051526 W IB2011051526 W IB 2011051526W WO 2011125050 A1 WO2011125050 A1 WO 2011125050A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- zeolites
- exhaust gas
- bea
- structure type
- Prior art date
Links
- 239000010457 zeolite Substances 0.000 title claims abstract description 209
- 239000003054 catalyst Substances 0.000 title claims abstract description 192
- 238000000034 method Methods 0.000 title claims abstract description 50
- 230000008569 process Effects 0.000 title claims abstract description 37
- 229910021536 Zeolite Inorganic materials 0.000 title claims description 66
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 57
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 72
- 238000010531 catalytic reduction reaction Methods 0.000 claims abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 86
- 239000000758 substrate Substances 0.000 claims description 77
- 230000003647 oxidation Effects 0.000 claims description 45
- 238000007254 oxidation reaction Methods 0.000 claims description 45
- 229910021529 ammonia Inorganic materials 0.000 claims description 41
- 239000010410 layer Substances 0.000 claims description 32
- 238000002485 combustion reaction Methods 0.000 claims description 31
- 238000011068 loading method Methods 0.000 claims description 22
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 17
- 239000004202 carbamide Substances 0.000 claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 14
- 238000011144 upstream manufacturing Methods 0.000 claims description 14
- 239000004071 soot Substances 0.000 claims description 13
- 239000012530 fluid Substances 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 238000004891 communication Methods 0.000 claims description 7
- 239000002356 single layer Substances 0.000 claims description 6
- 229910052878 cordierite Inorganic materials 0.000 claims description 5
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 5
- 239000007789 gas Substances 0.000 description 150
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 50
- 229960000510 ammonia Drugs 0.000 description 40
- 229910052742 iron Inorganic materials 0.000 description 31
- 229910002089 NOx Inorganic materials 0.000 description 27
- 239000003638 chemical reducing agent Substances 0.000 description 25
- 239000000203 mixture Substances 0.000 description 17
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 11
- 150000002430 hydrocarbons Chemical class 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- 238000006722 reduction reaction Methods 0.000 description 9
- 230000009467 reduction Effects 0.000 description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 7
- 238000001354 calcination Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000446 fuel Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000010970 precious metal Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- 229910052845 zircon Inorganic materials 0.000 description 3
- 229910000505 Al2TiO5 Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012013 faujasite Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 2
- 239000003870 refractory metal Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 239000011232 storage material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- -1 Y-zeoiite Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- HEHRHMRHPUNLIR-UHFFFAOYSA-N aluminum;hydroxy-[hydroxy(oxo)silyl]oxy-oxosilane;lithium Chemical compound [Li].[Al].O[Si](=O)O[Si](O)=O.O[Si](=O)O[Si](O)=O HEHRHMRHPUNLIR-UHFFFAOYSA-N 0.000 description 1
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052675 erionite Inorganic materials 0.000 description 1
- 229910001657 ferrierite group Inorganic materials 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229910052670 petalite Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/7215—Zeolite Beta
-
- B01J35/56—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2067—Urea
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/92—Dimensions
- B01D2255/9205—Porosity
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MX2012011540A MX2012011540A (es) | 2010-04-08 | 2011-04-08 | Catalizador de zeolita mixta de fe-bea/fe-mfi y proceso para tratar nox en corrientes de gas usando el mismo. |
| EP11765158.8A EP2555867A4 (en) | 2010-04-08 | 2011-04-08 | FE-BEA / FE-MFI MIXED ZEOLITE CATALYST AND METHOD FOR TREATING NOX IN GASEOUS CURRENTS USING THE CATALYST |
| BR112012025744A BR112012025744A2 (pt) | 2010-04-08 | 2011-04-08 | catalisador, sistema de tratamento de gás de escape, e, processo para o tratamento de uma corrente de gás |
| CN2011800268611A CN102958610A (zh) | 2010-04-08 | 2011-04-08 | Fe-BEA/Fe-MFI混合沸石催化剂和使用其处理气流中的NOx的方法 |
| CA2795522A CA2795522A1 (en) | 2010-04-08 | 2011-04-08 | Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same |
| JP2013503212A JP2013523442A (ja) | 2010-04-08 | 2011-04-08 | Ｆｅ−ＢＥＡ／Ｆｅ−ＭＦＩ混合ゼオライト触媒及びガス流中のＮＯＸ処理方法 |
| KR1020127029118A KR20130091638A (ko) | 2010-04-08 | 2011-04-08 | Ｆｅ-ＢＥＡ/Ｆｅ-ＭＦＩ 혼합 제올라이트 촉매 및 이를 사용하여 가스 스트림 내의 ＮＯｘ를 처리하는 방법 |
| ZA2012/08258A ZA201208258B (en) | 2010-04-08 | 2012-11-05 | Fe-bea/fe-mfi mixed zeolite catalyst and process for the treatment of nox in gas streams |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10159369.7 | 2010-04-08 | ||
| EP10159369 | 2010-04-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011125050A1 true WO2011125050A1 (en) | 2011-10-13 |
Family
ID=44762074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IB2011/051526 WO2011125050A1 (en) | 2010-04-08 | 2011-04-08 | Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP2555867A4 (zh) |
| JP (1) | JP2013523442A (zh) |
| KR (1) | KR20130091638A (zh) |
| CN (1) | CN102958610A (zh) |
| BR (1) | BR112012025744A2 (zh) |
| CA (1) | CA2795522A1 (zh) |
| MX (1) | MX2012011540A (zh) |
| WO (1) | WO2011125050A1 (zh) |
| ZA (1) | ZA201208258B (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015204012A1 (de) | 2015-03-05 | 2016-09-08 | Clariant International Ltd. | SCR-Katalysator mit verbesserter Haftung |
| CN111954577A (zh) * | 2018-04-11 | 2020-11-17 | 巴斯夫公司 | 含有混合沸石的scr催化剂 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6294127B2 (ja) * | 2014-03-31 | 2018-03-14 | 株式会社キャタラー | Ｓｃｒ用触媒及び排ガス浄化触媒システム |
| EP3694643A1 (de) * | 2017-10-09 | 2020-08-19 | Umicore AG & Co. KG | Scr-aktiver katalysator |
| CN109289508B (zh) * | 2018-10-24 | 2021-09-24 | 昆山工统环保科技有限公司 | 一种高疏水性沸石材料的制备方法 |
| CN109592687B (zh) * | 2018-12-03 | 2023-06-06 | 南京理工大学 | 利用tob制备多孔二氧化硅材料的方法 |
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| CN1395501A (zh) * | 2000-01-14 | 2003-02-05 | 犹德有限公司 | 用于去除NOx和N2O的工艺 |
| CN1711135A (zh) * | 2002-11-18 | 2005-12-21 | 株式会社Ict | 废气净化用催化剂与废气净化方法 |
| CN1735451A (zh) * | 2002-11-25 | 2006-02-15 | 亚拉国际有限公司 | 多金属沸石催化剂的制备和活化方法、催化剂组合物和用于减少n2o的应用 |
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| US5676912A (en) * | 1995-02-22 | 1997-10-14 | Mobil Oil Corporation | Process for exhaust gas NOx, CO, and hydrocarbon removal |
| EP1078685A3 (en) * | 1999-08-25 | 2001-04-18 | Praxair Technology, Inc. | Novel adsorbents for preferential nitrogen adsorption from other gases |
| WO2006093802A2 (en) * | 2005-02-28 | 2006-09-08 | Catalytic Solutions, Inc. | Catalyst and method for reducing nitrogen oxides in exhaust streams with hydrocarbons or alcohols |
| DE102006020158B4 (de) * | 2006-05-02 | 2009-04-09 | Argillon Gmbh | Extrudierter Vollkatalysator sowie Verfahren zu seiner Herstellung |
| CN101134172B (zh) * | 2006-08-31 | 2010-10-27 | 中国石油化工股份有限公司 | 一种烃类转化催化剂 |
| CN101190866B (zh) * | 2006-11-21 | 2011-08-17 | 中国石油化工股份有限公司 | 低乙苯副产物的芳烃烷基转移和脱烷基反应方法 |
| JP5110954B2 (ja) * | 2007-05-09 | 2012-12-26 | エヌ・イーケムキャット株式会社 | 選択還元型触媒を用いた排気ガス浄化触媒装置並びに排気ガス浄化方法 |
| DE102007057305A1 (de) * | 2007-11-28 | 2009-06-04 | Süd-Chemie AG | Beschichtungszusammensetzung für Dieseloxidationskatalysatoren |
| JP2009262098A (ja) * | 2008-04-28 | 2009-11-12 | Ne Chemcat Corp | 選択還元触媒を用いた排気ガス浄化方法 |
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2011
- 2011-04-08 JP JP2013503212A patent/JP2013523442A/ja active Pending
- 2011-04-08 KR KR1020127029118A patent/KR20130091638A/ko not_active Application Discontinuation
- 2011-04-08 BR BR112012025744A patent/BR112012025744A2/pt not_active IP Right Cessation
- 2011-04-08 CN CN2011800268611A patent/CN102958610A/zh active Pending
- 2011-04-08 MX MX2012011540A patent/MX2012011540A/es unknown
- 2011-04-08 EP EP11765158.8A patent/EP2555867A4/en not_active Withdrawn
- 2011-04-08 CA CA2795522A patent/CA2795522A1/en not_active Abandoned
- 2011-04-08 WO PCT/IB2011/051526 patent/WO2011125050A1/en active Application Filing
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2012
- 2012-11-05 ZA ZA2012/08258A patent/ZA201208258B/en unknown
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| CN1395501A (zh) * | 2000-01-14 | 2003-02-05 | 犹德有限公司 | 用于去除NOx和N2O的工艺 |
| CN1711135A (zh) * | 2002-11-18 | 2005-12-21 | 株式会社Ict | 废气净化用催化剂与废气净化方法 |
| CN1735451A (zh) * | 2002-11-25 | 2006-02-15 | 亚拉国际有限公司 | 多金属沸石催化剂的制备和活化方法、催化剂组合物和用于减少n2o的应用 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015204012A1 (de) | 2015-03-05 | 2016-09-08 | Clariant International Ltd. | SCR-Katalysator mit verbesserter Haftung |
| WO2016139102A1 (de) * | 2015-03-05 | 2016-09-09 | Clariant International Ltd | Scr-katalysator mit verbesserter haftung der zeolithen-enthaltenden katalytischen schicht |
| US10150103B2 (en) * | 2015-03-05 | 2018-12-11 | Clariant International Ltd. | SCR catalyst having improved adhesion of the zeolite-containing catalytic layer |
| CN111954577A (zh) * | 2018-04-11 | 2020-11-17 | 巴斯夫公司 | 含有混合沸石的scr催化剂 |
| EP3774033A4 (en) * | 2018-04-11 | 2021-12-29 | BASF Corporation | Mixed zeolite-containing scr catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102958610A (zh) | 2013-03-06 |
| BR112012025744A2 (pt) | 2016-06-28 |
| JP2013523442A (ja) | 2013-06-17 |
| CA2795522A1 (en) | 2011-10-13 |
| EP2555867A4 (en) | 2014-12-10 |
| ZA201208258B (en) | 2014-01-29 |
| KR20130091638A (ko) | 2013-08-19 |
| MX2012011540A (es) | 2012-11-16 |
| EP2555867A1 (en) | 2013-02-13 |
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