WO2011112189A1 - Production d'hydrocarbures aromatiques alkylés - Google Patents

Production d'hydrocarbures aromatiques alkylés Download PDF

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Publication number
WO2011112189A1
WO2011112189A1 PCT/US2010/026844 US2010026844W WO2011112189A1 WO 2011112189 A1 WO2011112189 A1 WO 2011112189A1 US 2010026844 W US2010026844 W US 2010026844W WO 2011112189 A1 WO2011112189 A1 WO 2011112189A1
Authority
WO
WIPO (PCT)
Prior art keywords
stream
aromatic compound
impurities
alkylated
catalyst
Prior art date
Application number
PCT/US2010/026844
Other languages
English (en)
Other versions
WO2011112189A8 (fr
Inventor
Matthew J. Vincent
Vijay Nanda
Maruti Bhandarkar
Brain Maerz
Terry E. Helton
Original Assignee
Exxonmobil Chemical Patents Inc.
Stone & Webster, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2012557019A priority Critical patent/JP5659247B2/ja
Priority to SG2012060281A priority patent/SG183322A1/en
Priority to BR112012022691A priority patent/BR112012022691A2/pt
Priority to CN201080065284.2A priority patent/CN102906054B/zh
Priority to EP10847601.1A priority patent/EP2545018A4/fr
Priority to RU2012141942/04A priority patent/RU2528825C2/ru
Application filed by Exxonmobil Chemical Patents Inc., Stone & Webster, Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to KR1020127023242A priority patent/KR101533875B1/ko
Priority to PCT/US2010/026844 priority patent/WO2011112189A1/fr
Priority to TW099144498A priority patent/TWI523831B/zh
Publication of WO2011112189A1 publication Critical patent/WO2011112189A1/fr
Publication of WO2011112189A8 publication Critical patent/WO2011112189A8/fr
Priority to US14/075,218 priority patent/US8877996B2/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/60—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the type L, as exemplified by patent document US3216789
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/085—Isopropylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

La présente invention concerne un procédé de production d'hydrocarbures aromatiques alkylés impliquant la mise en contact d'un flux d'alimentation contenant un hydrocarbure aromatique alkylable, un agent alkylant et des traces d'eau et d'impuretés avec un premier et un second catalyseurs d'alkylation, l'eau et les impuretés étant éliminées afin de rallonger la durée des cycles catalytiques desdits catalyseurs d'alkylation. L'eau et une partie des impuretés sont éliminées dans une zone de déshydratation. Une première zone d'alkylation comportant un premier catalyseur d'alkylation qui, selon certains modes de réalisation, est constitué d'un tamis moléculaire à larges pores, élimine une part importante des impuretés, par exemple les espèces azotées et d'autres espèces, et alkyle une petite partie du composé aromatique alkylable. Une seconde zone d'alkylation, qui, selon certains modes de réalisation, est constituée d'un tamis moléculaire à pores moyens, élimine une plus petite partie des impuretés et alkyle une part plus importante du composé aromatique alkylable.
PCT/US2010/026844 2010-03-10 2010-03-10 Production d'hydrocarbures aromatiques alkylés WO2011112189A1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
SG2012060281A SG183322A1 (en) 2010-03-10 2010-03-10 Alkylated aromatics production
BR112012022691A BR112012022691A2 (pt) 2010-03-10 2010-03-10 produção de aromáticos alquilados
CN201080065284.2A CN102906054B (zh) 2010-03-10 2010-03-10 烷基化的芳族化合物生产
EP10847601.1A EP2545018A4 (fr) 2010-03-10 2010-03-10 Production d'hydrocarbures aromatiques alkylés
RU2012141942/04A RU2528825C2 (ru) 2010-03-10 2010-03-10 Получение алкилированных ароматических соединений
JP2012557019A JP5659247B2 (ja) 2010-03-10 2010-03-10 アルキル化芳香族の製造
KR1020127023242A KR101533875B1 (ko) 2010-03-10 2010-03-10 알킬화 방향족 화합물의 제조 방법
PCT/US2010/026844 WO2011112189A1 (fr) 2010-03-10 2010-03-10 Production d'hydrocarbures aromatiques alkylés
TW099144498A TWI523831B (zh) 2010-03-10 2010-12-17 經烷化芳族物質的製造方法
US14/075,218 US8877996B2 (en) 2010-03-10 2013-11-08 Alkylated aromatics production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2010/026844 WO2011112189A1 (fr) 2010-03-10 2010-03-10 Production d'hydrocarbures aromatiques alkylés

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/721,326 Continuation US8629311B2 (en) 2010-03-10 2010-03-10 Alkylated aromatics production

Publications (2)

Publication Number Publication Date
WO2011112189A1 true WO2011112189A1 (fr) 2011-09-15
WO2011112189A8 WO2011112189A8 (fr) 2012-03-08

Family

ID=44563758

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/026844 WO2011112189A1 (fr) 2010-03-10 2010-03-10 Production d'hydrocarbures aromatiques alkylés

Country Status (8)

Country Link
EP (1) EP2545018A4 (fr)
JP (1) JP5659247B2 (fr)
KR (1) KR101533875B1 (fr)
CN (1) CN102906054B (fr)
BR (1) BR112012022691A2 (fr)
RU (1) RU2528825C2 (fr)
SG (1) SG183322A1 (fr)
WO (1) WO2011112189A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013175490A1 (fr) * 2012-04-03 2013-11-28 Reliance Industries Limited Flux d'hydrocarbures aromatiques c8-c12 sans oxygénats et son procédé de préparation
WO2016073543A2 (fr) 2014-11-07 2016-05-12 Uop Llc Procédé d'alkylation hautement sélectif ayant recours à une composition de catalyseur à faible teneur en zéolite
WO2018160327A1 (fr) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Compositions catalytiques et leur utilisation dans des procédés d'alkylation aromatique
CN113333014A (zh) * 2021-06-02 2021-09-03 辽宁师范大学 用于乙苯乙醇/乙烯烷基化制二乙苯的固体催化剂及制备方法
RU2769447C2 (ru) * 2017-02-28 2022-03-31 Эксонмобил Кемикэл Пейтентс Инк. Каталитические композиции и их применение в способах алкилирования ароматических соединений

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150030261A (ko) 2010-05-20 2015-03-19 엑손모빌 케미칼 패턴츠 인코포레이티드 개선된 알킬화 공정
CN105339328B (zh) * 2013-05-08 2020-08-25 巴杰许可有限责任公司 芳烃烷基化方法
SG11201908901UA (en) * 2017-03-29 2019-10-30 Exxonmobil Chemical Patents Inc Catalyst compositions and their use in aromatic alkylation processes
CN111574318B (zh) * 2020-06-04 2022-09-30 常州瑞华化工工程技术股份有限公司 一种纯乙烯生产乙苯的节能反应工艺
RU2756954C1 (ru) * 2020-12-09 2021-10-07 Акционерное общество "Газпромнефть - Омский НПЗ" (АО "Газпромнефть-ОНПЗ") Способ получения алкилпроизводных аренов

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US6995295B2 (en) * 2002-09-23 2006-02-07 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US20080287720A1 (en) * 2006-01-31 2008-11-20 Clark Michael C Alkylaromatics Production

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US6617482B1 (en) * 2000-08-16 2003-09-09 Exxonmobil Chemical Patents Inc. Removable of polar contaminants from aromatic feedstocks
CN1639089A (zh) * 2002-02-28 2005-07-13 斯东及韦伯斯特公司 烷基芳香族化合物的制备
US7645913B2 (en) * 2007-01-19 2010-01-12 Exxonmobil Chemical Patents Inc. Liquid phase alkylation with multiple catalysts

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US6995295B2 (en) * 2002-09-23 2006-02-07 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US20080287720A1 (en) * 2006-01-31 2008-11-20 Clark Michael C Alkylaromatics Production

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See also references of EP2545018A4 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013175490A1 (fr) * 2012-04-03 2013-11-28 Reliance Industries Limited Flux d'hydrocarbures aromatiques c8-c12 sans oxygénats et son procédé de préparation
US9725383B2 (en) 2012-04-03 2017-08-08 Reliance Industries Limited Oxygenates-free C8-C12 aromatic hydrocarbon stream and a process for preparing the same
WO2016073543A2 (fr) 2014-11-07 2016-05-12 Uop Llc Procédé d'alkylation hautement sélectif ayant recours à une composition de catalyseur à faible teneur en zéolite
EP3215477A4 (fr) * 2014-11-07 2018-03-07 Uop Llc Procédé d'alkylation hautement sélectif ayant recours à une composition de catalyseur à faible teneur en zéolite
WO2018160327A1 (fr) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Compositions catalytiques et leur utilisation dans des procédés d'alkylation aromatique
RU2769447C2 (ru) * 2017-02-28 2022-03-31 Эксонмобил Кемикэл Пейтентс Инк. Каталитические композиции и их применение в способах алкилирования ароматических соединений
US11654423B2 (en) 2017-02-28 2023-05-23 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in aromatic alkylation processes
US20230249167A1 (en) * 2017-02-28 2023-08-10 ExxonMobil Technology and Engineering Company Catalyst Compositions and Their Use in Aromatic Alkylation Processes
CN113333014A (zh) * 2021-06-02 2021-09-03 辽宁师范大学 用于乙苯乙醇/乙烯烷基化制二乙苯的固体催化剂及制备方法

Also Published As

Publication number Publication date
CN102906054A (zh) 2013-01-30
EP2545018A4 (fr) 2014-10-08
JP5659247B2 (ja) 2015-01-28
JP2013521336A (ja) 2013-06-10
EP2545018A1 (fr) 2013-01-16
WO2011112189A8 (fr) 2012-03-08
RU2528825C2 (ru) 2014-09-20
BR112012022691A2 (pt) 2016-08-23
CN102906054B (zh) 2015-11-25
SG183322A1 (en) 2012-09-27
KR101533875B1 (ko) 2015-07-03
RU2012141942A (ru) 2014-04-10
KR20120136357A (ko) 2012-12-18

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