WO2011064605A3 - Procédé et appareil d'extraction d'azote présent dans du gnl - Google Patents

Procédé et appareil d'extraction d'azote présent dans du gnl Download PDF

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Publication number
WO2011064605A3
WO2011064605A3 PCT/GB2010/051997 GB2010051997W WO2011064605A3 WO 2011064605 A3 WO2011064605 A3 WO 2011064605A3 GB 2010051997 W GB2010051997 W GB 2010051997W WO 2011064605 A3 WO2011064605 A3 WO 2011064605A3
Authority
WO
WIPO (PCT)
Prior art keywords
stream
fractionation column
overhead
cooling
nitrogen
Prior art date
Application number
PCT/GB2010/051997
Other languages
English (en)
Other versions
WO2011064605A2 (fr
Inventor
Adrian Finn
Grant Johnson
Terence Tomlinson
Original Assignee
Costain Oil, Gas & Process Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Costain Oil, Gas & Process Limited filed Critical Costain Oil, Gas & Process Limited
Priority to EP10787542.9A priority Critical patent/EP2507567B1/fr
Priority to US13/511,780 priority patent/US20120285196A1/en
Priority to AU2010322827A priority patent/AU2010322827A1/en
Publication of WO2011064605A2 publication Critical patent/WO2011064605A2/fr
Publication of WO2011064605A3 publication Critical patent/WO2011064605A3/fr

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0209—Natural gas or substitute natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0257—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/02—Processes or apparatus using separation by rectification in a single pressure main column system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/40—Features relating to the provision of boil-up in the bottom of a column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/50—Processes or apparatus using separation by rectification using multiple (re-)boiler-condensers at different heights of the column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/70—Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/76—Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/04—Recovery of liquid products
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/02—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/30—Dynamic liquid or hydraulic expansion with extraction of work, e.g. single phase or two-phase turbine
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/02—Internal refrigeration with liquid vaporising loop

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

L'invention concerne des procédés et des appareils permettant d'extraire de l'azote présent dans des alimentations en gaz naturel liquéfié. Les procédés comprennent les étapes consistant : (i) à refroidir l'alimentation et faire passer l'alimentation dans une colonne de fractionnement ; (ii) à retirer de la colonne de fractionnement un courant de vapeur de tête ayant une teneur en azote enrichie, et un courant de liquide ayant une teneur en azote réduite ; (iii) à diviser le courant de vapeur de tête provenant de l'étape (ii) en au moins des premier et second courants de tête ; (iv) à comprimer, refroidir et au moins partiellement condenser au moins le premier courant de tête provenant de l'étape (iii) ; et (v) à détendre le courant provenant de l'étape (iv) et faire passer le courant détendu dans la colonne de fractionnement en tant que reflux. Un refroidissement est prévu à l'étape (iv), au moins en partie, par échange de chaleur avec un ou plusieurs courants provenant de la colonne de fractionnement.
PCT/GB2010/051997 2009-11-30 2010-11-30 Procédé et appareil d'extraction d'azote présent dans du gnl WO2011064605A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP10787542.9A EP2507567B1 (fr) 2009-11-30 2010-11-30 Procédé et appareil d'extraction d'azote présent dans du gnl
US13/511,780 US20120285196A1 (en) 2009-11-30 2010-11-30 Process and apparatus for separation of nitrogen from lng
AU2010322827A AU2010322827A1 (en) 2009-11-30 2010-11-30 Process and apparatus for separation of nitrogen from LNG

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0920947A GB2462555B (en) 2009-11-30 2009-11-30 Process and apparatus for separation of Nitrogen from LNG
GB0920947.9 2009-11-30

Publications (2)

Publication Number Publication Date
WO2011064605A2 WO2011064605A2 (fr) 2011-06-03
WO2011064605A3 true WO2011064605A3 (fr) 2013-04-04

Family

ID=41567125

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2010/051997 WO2011064605A2 (fr) 2009-11-30 2010-11-30 Procédé et appareil d'extraction d'azote présent dans du gnl

Country Status (5)

Country Link
US (1) US20120285196A1 (fr)
EP (1) EP2507567B1 (fr)
AU (3) AU2010322827A1 (fr)
GB (1) GB2462555B (fr)
WO (1) WO2011064605A2 (fr)

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US10852060B2 (en) 2011-04-08 2020-12-01 Pilot Energy Solutions, Llc Single-unit gas separation process having expanded, post-separation vent stream
EP2796818A1 (fr) * 2013-04-22 2014-10-29 Shell Internationale Research Maatschappij B.V. Procédé et appareil de production d'un flux d'hydrocarbure liquéfié
US10436505B2 (en) 2014-02-17 2019-10-08 Black & Veatch Holding Company LNG recovery from syngas using a mixed refrigerant
US9945604B2 (en) 2014-04-24 2018-04-17 Air Products And Chemicals, Inc. Integrated nitrogen removal in the production of liquefied natural gas using refrigerated heat pump
US9816754B2 (en) 2014-04-24 2017-11-14 Air Products And Chemicals, Inc. Integrated nitrogen removal in the production of liquefied natural gas using dedicated reinjection circuit
US20150308737A1 (en) * 2014-04-24 2015-10-29 Air Products And Chemicals, Inc. Integrated Nitrogen Removal in the Production of Liquefied Natural Gas Using Intermediate Feed Gas Separation
US10443930B2 (en) 2014-06-30 2019-10-15 Black & Veatch Holding Company Process and system for removing nitrogen from LNG
TWI603044B (zh) 2015-07-10 2017-10-21 艾克頌美孚上游研究公司 使用液化天然氣製造液化氮氣之系統與方法
TWI608206B (zh) 2015-07-15 2017-12-11 艾克頌美孚上游研究公司 藉由預冷卻天然氣供給流以增加效率的液化天然氣（ｌｎｇ）生產系統
TWI606221B (zh) 2015-07-15 2017-11-21 艾克頌美孚上游研究公司 一倂移除溫室氣體之液化天然氣的生產系統和方法
JP6749396B2 (ja) 2015-12-14 2020-09-02 エクソンモービル アップストリーム リサーチ カンパニー 液体窒素を貯蔵するｌｎｇ運搬船上の天然ガス液化の方法
AU2016372709B2 (en) 2015-12-14 2019-09-12 Exxonmobil Upstream Research Company Method and system for separating nitrogen from liquefied natural gas using liquefied nitrogen
EP3586057B1 (fr) 2017-02-24 2022-09-14 ExxonMobil Upstream Research Company Procédé de purge d'un réservoir de stockage lng/lin à double objectif
JP7026490B2 (ja) 2017-11-21 2022-02-28 レール・リキード－ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード Ｂｏｇ再凝縮装置およびそれを備えるｌｎｇ貯蔵システム。
CA3091930C (fr) 2018-03-14 2022-11-29 Exxonmobil Upstream Research Company Procede et systeme de liquefaction de gaz naturel par utilisation d'azote liquide
EP3803241B1 (fr) 2018-06-07 2022-09-28 ExxonMobil Upstream Research Company Pré-traitement et pré-refroidissement de gaz naturel par compression et détente à haute pression
AU2019322808B2 (en) 2018-08-14 2022-10-13 ExxonMobil Technology and Engineering Company Conserving mixed refrigerant in natural gas liquefaction facilities
SG11202101054SA (en) 2018-08-22 2021-03-30 Exxonmobil Upstream Res Co Primary loop start-up method for a high pressure expander process
CA3109750A1 (fr) 2018-08-22 2020-02-27 Exxonmobil Upstream Research Company Configuration d'echangeur de chaleur pour un procede de detente haute pression et procede de liquefaction de gaz naturel l'utilisant
JP7154385B2 (ja) 2018-08-22 2022-10-17 エクソンモービル アップストリーム リサーチ カンパニー 高圧エキスパンダプロセスのための補給ガス組成変動の管理
WO2020106394A1 (fr) 2018-11-20 2020-05-28 Exxonmobil Upstream Research Company Procédé prico utilisant des échangeurs de chaleur tolérants aux solides
US11215410B2 (en) 2018-11-20 2022-01-04 Exxonmobil Upstream Research Company Methods and apparatus for improving multi-plate scraped heat exchangers
AU2020216277B2 (en) 2019-01-30 2023-04-20 ExxonMobil Technology and Engineering Company Methods for removal of moisture from LNG refrigerant
US11668524B2 (en) 2019-01-30 2023-06-06 Exxonmobil Upstream Research Company Methods for removal of moisture from LNG refrigerant
US11465093B2 (en) 2019-08-19 2022-10-11 Exxonmobil Upstream Research Company Compliant composite heat exchangers
US20210063083A1 (en) 2019-08-29 2021-03-04 Exxonmobil Upstream Research Company Liquefaction of Production Gas
US11806639B2 (en) 2019-09-19 2023-11-07 ExxonMobil Technology and Engineering Company Pretreatment and pre-cooling of natural gas by high pressure compression and expansion
US11815308B2 (en) 2019-09-19 2023-11-14 ExxonMobil Technology and Engineering Company Pretreatment and pre-cooling of natural gas by high pressure compression and expansion
WO2021055074A1 (fr) 2019-09-20 2021-03-25 Exxonmobil Upstream Research Company Élimination des gaz acides d'un flux gazeux avec enrichissement de o2 pour la capture et la séquestration des gaz acides
US11808411B2 (en) 2019-09-24 2023-11-07 ExxonMobil Technology and Engineering Company Cargo stripping features for dual-purpose cryogenic tanks on ships or floating storage units for LNG and liquid nitrogen
US11674749B2 (en) * 2020-03-13 2023-06-13 Air Products And Chemicals, Inc. LNG production with nitrogen removal

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EP0725256A1 (fr) * 1995-02-03 1996-08-07 Air Products And Chemicals, Inc. Procédé pour éliminer l'azote à partir de gaz naturel
US5617741A (en) * 1995-02-10 1997-04-08 Air Products And Chemicals, Inc. Dual column process to remove nitrogen from natural gas
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US20040231359A1 (en) * 2003-05-22 2004-11-25 Brostow Adam Adrian Nitrogen rejection from condensed natural gas
US20080016908A1 (en) * 2006-07-24 2008-01-24 Ransbarger Weldon L Lng system with enhanced refrigeration efficiency
US20090277217A1 (en) * 2008-05-08 2009-11-12 Conocophillips Company Enhanced nitrogen removal in an lng facility

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ID24280A (id) * 1997-07-01 2000-07-13 Exxon Production Research Co Proses untuk memisahkan aliran gas multi-komponen yang mengandung paling tidak satu komponen yang dapat membeku
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GB0216537D0 (en) * 2002-07-16 2002-08-28 Boc Group Plc Nitrogen rejection method and apparatus

Patent Citations (6)

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Publication number Priority date Publication date Assignee Title
EP0725256A1 (fr) * 1995-02-03 1996-08-07 Air Products And Chemicals, Inc. Procédé pour éliminer l'azote à partir de gaz naturel
US5617741A (en) * 1995-02-10 1997-04-08 Air Products And Chemicals, Inc. Dual column process to remove nitrogen from natural gas
CN1293232A (zh) * 1999-10-15 2001-05-02 余庆发 液化天然气的生产方法
US20040231359A1 (en) * 2003-05-22 2004-11-25 Brostow Adam Adrian Nitrogen rejection from condensed natural gas
US20080016908A1 (en) * 2006-07-24 2008-01-24 Ransbarger Weldon L Lng system with enhanced refrigeration efficiency
US20090277217A1 (en) * 2008-05-08 2009-11-12 Conocophillips Company Enhanced nitrogen removal in an lng facility

Also Published As

Publication number Publication date
EP2507567B1 (fr) 2020-06-24
WO2011064605A2 (fr) 2011-06-03
GB2462555A (en) 2010-02-17
AU2010322827A1 (en) 2012-06-21
US20120285196A1 (en) 2012-11-15
GB2462555B (en) 2011-04-13
AU2016244250A1 (en) 2016-11-03
GB0920947D0 (en) 2010-01-13
EP2507567A2 (fr) 2012-10-10
AU2018204827A1 (en) 2018-07-19

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