WO2011051140A1 - Lavage au moyen de corps polymères - Google Patents
Lavage au moyen de corps polymères Download PDFInfo
- Publication number
- WO2011051140A1 WO2011051140A1 PCT/EP2010/065737 EP2010065737W WO2011051140A1 WO 2011051140 A1 WO2011051140 A1 WO 2011051140A1 EP 2010065737 W EP2010065737 W EP 2010065737W WO 2011051140 A1 WO2011051140 A1 WO 2011051140A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polymer
- polymer body
- acid
- detergent composition
- hexamethylenediamine
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 98
- 238000005406 washing Methods 0.000 title description 18
- 239000000203 mixture Substances 0.000 claims abstract description 61
- 238000000034 method Methods 0.000 claims abstract description 44
- 239000003599 detergent Substances 0.000 claims abstract description 43
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000004753 textile Substances 0.000 claims abstract description 17
- 238000004140 cleaning Methods 0.000 claims abstract description 9
- 230000003750 conditioning effect Effects 0.000 claims abstract description 8
- 230000001143 conditioned effect Effects 0.000 claims abstract description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 41
- 239000004744 fabric Substances 0.000 claims description 33
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 24
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 18
- -1 polyethylenes Polymers 0.000 claims description 13
- 239000004952 Polyamide Substances 0.000 claims description 12
- 239000001361 adipic acid Substances 0.000 claims description 12
- 235000011037 adipic acid Nutrition 0.000 claims description 12
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims description 12
- 229920002647 polyamide Polymers 0.000 claims description 12
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 12
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 9
- 229920000572 Nylon 6/12 Polymers 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 9
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 8
- 238000009472 formulation Methods 0.000 claims description 8
- 229920001281 polyalkylene Polymers 0.000 claims description 8
- YLIIGKBLXUJUIG-UHFFFAOYSA-N 7-hexylazepan-2-one Chemical compound CCCCCCC1CCCCC(=O)N1 YLIIGKBLXUJUIG-UHFFFAOYSA-N 0.000 claims description 6
- 102000004190 Enzymes Human genes 0.000 claims description 6
- 108090000790 Enzymes Proteins 0.000 claims description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 6
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims description 6
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000003945 anionic surfactant Substances 0.000 description 11
- 150000002191 fatty alcohols Chemical class 0.000 description 10
- 239000002736 nonionic surfactant Substances 0.000 description 10
- 239000007844 bleaching agent Substances 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 4
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 206010020751 Hypersensitivity Diseases 0.000 description 2
- 229920001410 Microfiber Polymers 0.000 description 2
- 239000004435 Oxo alcohol Substances 0.000 description 2
- 206010070834 Sensitisation Diseases 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229940098396 barley grain Drugs 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000008313 sensitization Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 240000001890 Ribes hudsonianum Species 0.000 description 1
- 235000016954 Ribes hudsonianum Nutrition 0.000 description 1
- 235000001466 Ribes nigrum Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 235000003095 Vaccinium corymbosum Nutrition 0.000 description 1
- 235000017537 Vaccinium myrtillus Nutrition 0.000 description 1
- 244000077233 Vaccinium uliginosum Species 0.000 description 1
- 229920006102 Zytel® Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000012753 anti-shrinkage agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 235000021014 blueberries Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 235000015120 cherry juice Nutrition 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- YLQLIQIAXYRMDL-UHFFFAOYSA-N propylheptyl alcohol Chemical compound CCCCCC(CO)CCC YLQLIQIAXYRMDL-UHFFFAOYSA-N 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 235000020095 red wine Nutrition 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 235000014438 salad dressings Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/01—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using only solid or pasty agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- the invention relates to a method for cleaning and / or conditioning of textile
- the invention also relates to a kit comprising ingredients of the formulation.
- WO 2007/128962 A1 discloses a washing method which comprises the treatment of soiled laundry by contacting the laundry with a formulation comprising a multiplicity of polymer particles.
- This object is achieved by a method for cleaning and / or conditioning of textile fabrics, wherein the moist, to be cleaned and / or conditioned fabrics with a formulation containing
- Conditioning process is less heavily colored or dirty on its surface. Due to the much cleaner appearance of the polymer body, the consumer has significantly fewer inhibitions to use the polymer body multiple times.
- the polymer body is a polymer selected from the group of
- Polyalkylenes polyesters, polyurethanes, polyamides and mixtures thereof. These polymers are suitable for use in such a low-water washing process and, above all, are also compatible with H 2 O 2 .
- the polymer body contains a polyamide which is selected from the group comprising PA 6 (polymer of ⁇ -caprolactam), PA 1 1 (polymer of 1 1-aminoundecanoic acid), PA 12 (polymer of ⁇ - Laurolactam), PA 66 (polymer of hexamethylenediamine and adipic acid), PA 69 (polymer of hexamethylenediamine and azelaic acid), PA 612 (polymer of hexamethylenediamine and dodecanedioic acid), PA 46 (polymer of tetramethylenediamine and adipic acid), PA 610 (polymer of hexane) 1, 6-diamine and sebacic acid) PA 612 (polymer of hexane-1, 6-diamine and dodecanedioic acid), PA 66/610
- Polyamides are preferably used in the polymer body since they are effective on a variety of different stains.
- the polymer body contains a polyalkylene which is selected from the group of polyethylenes, polypropylenes and mixtures thereof.
- Polymer bodies of polyalkylenes are particularly suitable for the removal of oil-based stains.
- the detergent composition may be free of enzymes.
- the polymer body is in the form of a chip, a sphere, a cube, an ice, a cylinder, a disk, a cuboid or a truncated cone. It is further preferred that the maximum spatial extent of the polymer body is in the range of 1 to 10 mm. A polymer body of this size and shape has a good flow or
- the hydrogen peroxide can be incorporated separately, incorporated into the detergent composition, applied to the polymer body, and / or absorbed by the polymer body in the process.
- the detergent composition may be applied separately, applied to the polymer body and / or absorbed by the polymer body in the process.
- H 2 O 2 which is an inexpensive bleaching agent compared with other bleaching agents such as percarbonates or perborates, can be used in the process.
- hydrogen peroxide is used in aqueous solution, so that the bleaching agent does not have to dissolve during the washing process. It also distributes it more evenly in the formulation.
- the invention also relates to a kit for cleaning and / or conditioning textile
- the method according to the invention can be applied to a large number of textile fabrics. It can be used for example in all natural and synthetic
- Tissue fibers are used, although it is particularly advantageously applied to fabrics of PA 66, polyester and cotton.
- the tissues to be treated are moistened with water, in particular to improve the transport of dirt particles to the polymer body. If the H 2 0 2 and / or the detergent composition applied to the polymer body and / or absorbed by the polymer body, by wetting the fabrics also the transport of H 2 0 2 and / or the ingredients of the detergent composition of
- Fabric may be made, for example, by wetting with water or an aqueous solution of the detergent composition.
- the weight ratio of fabric to water be from 1: 0, 1 to 1: 5, and more preferably from 1: 0.2 to 1: 2.
- At least one polymer body is used in the process. However, it is preferred for reasons of process efficiency if a variety of polymer bodies are used in the process.
- the weight ratio of polymer body to textile fabrics is preferably from 30: 1 to 1: 1, more preferably from 15: 1 to 2: 1, and most preferably from 8: 1 to 3: 1.
- the polymer body may include a polymer selected from the group of polyalkylenes, polyesters, polyurethanes, polyamides, and mixtures thereof, with polyamides and polyalkylenes being preferred.
- Preferred polyalkylenes include polyethylenes, polypropylenes or mixtures thereof.
- the polymer body contains a polyamide.
- the polyamide may be selected from the group comprising PA 6 (polymer of ⁇ -caprolactam), PA 1 1 (polymer of 1 1 -aminoundecanoic acid), PA 12 (polymer of ⁇ -laurolactam), PA 66 (polymer of
- PA 69 polymer of hexamethylenediamine
- PA 612 polymer of hexamethylenediamine and dodecanedioic acid
- PA 46 polymer of tetramethylenediamine and adipic acid
- PA 610 polymer of hexane-1, 6-diamine and
- PA 612 polymer of hexane-1, 6-diamine and dodecanedioic acid
- the polymer body may be of any shape, but is preferably in the form of a chip, sphere, cube, ice, cylinder, disk, cuboid or truncated cone. These forms ensure good mobility of the
- the maximum spatial extent of the polymer body is preferably in the range of 1 to 10 mm, and more preferably in the range of 2 to 6 mm.
- maximum spatial extent of the polymer body is preferably in the range of 1 to 10 mm, and more preferably in the range of 2 to 6 mm.
- Expansion in this context refers to the distance between the two farthest points on the polymer body.
- the polymer body is in the form of a cloth, for example a microfiber cloth.
- the microfiber cloth is attached to the fabrics, and more preferably to the patches located there.
- the attachment should be such that as much as possible of the surface of the textile fabrics is in contact with the surface of the fabric. It is advantageous if the cloth used has as much surface as possible, so that
- Looped goods, velvet, terry cloth or nonwoven fabrics are preferably used.
- the cloth has a surface area (in one side) of from 40 cm 2 to 800 cm 2, and more preferably from 100 cm 2 to 400 cm 2 .
- the formulation contains, in addition to the molding, a detergent composition.
- the detergent composition contains surfactant (s) wherein anionic, nonionic, zwitterionic and / or amphoteric surfactants can be used. Preference is given to
- the total surfactant content of a liquid detergent is preferably below 40% by weight and more preferably below 35% by weight, based on the total, preferably liquid, detergent composition.
- Suitable nonionic surfactants include alkoxylated fatty alcohols, alkoxylated
- Fatty acid alkyl esters Fatty acid alkyl esters, fatty acid amides, alkoxylated fatty acid amides, polyhydroxy fatty acid amides, alkylphenol polyglycol ethers, amine oxides, alkyl polyglucosides and mixtures thereof.
- the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
- alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
- Preferred ethoxylated alcohols include, for example, C 12 -14 alcohols containing 3 EO, 7 EO or 4 EO, C 9 n-alcohol with 7 EO, C 13 -i 5 alcohols containing 3 EO, 5 EO, 7 EO or 8 EO, Ci 2 -i8 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as
- Ci 2 -i4-alcohol with 3 EO Ci 2 -i8-alcohol with 7 EO.
- Levels of ethoxylation represent statistical averages, which may be an integer or a fractional number for a particular product.
- Preferred alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
- fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
- Nonionic surfactants containing EO and PO groups together in the molecule can also be used according to the invention.
- a mixture of a (more) branched ethoxylated fatty alcohol and an unbranched ethoxylated fatty alcohol such as a mixture of a C16-18 fatty alcohol with 7 EO and 2-propylheptanol with 7 EO.
- the washing, cleaning, post-treatment or washing aid containing a C 2 -i8 fatty alcohol with 7 EO, or C-i3-i5-oxo-alcohol with 7 EO as non-ionic surfactant.
- the content of nonionic surfactants in the detergent composition is preferably 3 to 40 wt .-%, preferably 5 to 30 wt .-% and in particular 7 to 20 wt .-%, each based on the total detergent composition.
- the detergent composition may also contain anionic surfactants.
- the anionic surfactant used is preferably sulfonates, sulfates, soaps, alkyl phosphates, anionic silicone surfactants and mixtures thereof.
- Suitable surfactants of the sulfonate type are preferably C 9 .i 3 -alkylbenzenesulfonates and olefinsulfonates. Also suitable are C 2 -i 8-alkanesulfonates and the esters of a-sulfofatty acids (ester sulfonates), for example, the ⁇ -sulfonated Methylester of hydrogenated coconut, palm kernel or tallow fatty acids.
- Alk (en) ylsulfates are the alkali metal and in particular the sodium salts of
- Sulfuric acid semi-esters of Ci 2 -C 8 fatty alcohols for example from coconut fatty alcohol,
- Tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the Ci 0 -C 2 o-oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred.
- the Ci 2 -Ci 6 alkyl sulfates and Ci 2 -Ci 5 alkyl sulfates and Ci 4 -Ci 5 alkyl sulfates are preferred.
- 2,3-alkyl sulfates are also suitable anionic surfactants.
- sulfuric acid monoesters of straight-chain or branched C 7 ethoxylated with 1 to 6 moles of ethylene oxide are suitable.
- 2 i-alcohols such as 2-methyl-branched Cg-n-alcohols having on average 3.5 mol of ethylene oxide (EO) or Ci 2 _i 8 -Fettalkohole with 1 to 4 EO, are suitable.
- anionic surfactants are soaps.
- Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
- the anionic surfactants including the soaps may be in the form of their sodium, potassium or magnesium or ammonium salts.
- the anionic surfactants are in the form of their sodium salts.
- Further preferred counterions for the anionic surfactants are also the protonated forms of choline, triethylamine or methylethylamine.
- the content of anionic surfactants in a washing or cleaning agent may be from 1 to 40% by weight, preferably from 5 to 30% by weight and most preferably from 10 to 25% by weight, based in each case on the total washing or cleaning agent ,
- the detergent composition may contain other ingredients which have the performance and / or aesthetic properties of the surfactants.
- Detergent composition further improve.
- preferred detergent compositions additionally comprise one or more substances from the group of builders, bleaching agents, bleach activators, bleach catalysts, enzymes, electrolytes, nonaqueous solvents, pH adjusters, perfumes, perfume carriers, Fluorescent agents, dyes, hydrotopes, foam inhibitors, silicone oils, soil release polymers, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents,
- Color transfer inhibitors antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, thickeners, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents and UV absorbers.
- the detergent composition contain no ingredients which, when in contact with skin, contain an ingredient
- the detergent composition may be free of enzymes.
- the detergent composition itself may be solid, liquid, gel, waxy or pasty, with liquid detergents being particularly preferred due to the improved quenching properties.
- the detergent composition can be applied separately and / or on the polymer body and / or absorbed by the polymer body in the process. It may be preferred that the polymer body is coated with the detergent composition. When the detergent composition is applied to the polymer body and / or absorbed by the polymer body used in the process, this facilitates the operation of the process for the user since he does not yet have to dose the detergent composition separately.
- the formulation contains hydrogen peroxide. Hydrogen peroxide is a cheap bleaching agent and does not leave any residue on the treated textile fabrics.
- the hydrogen peroxide may be incorporated separately and / or in the detergent composition and / or applied to the polymer body and / or absorbed by the polymer body in the process. If the hydrogen peroxide is already incorporated into detergent composition or is applied to the polymer body and / or absorbed by the polymer body in the process, this avoids the user coming into direct contact with the hydrogen peroxide.
- the amount of H 2 O 2 is preferably 0.5 to 10 g, and more preferably 0.5 to 3 g per
- the process can be carried out in specially designed washing machines.
- the polymer bodies used can either be introduced separately into the washing drum by the user of the method or, in an alternative embodiment, stored in a storage chamber within the washing machine and then to the wash cycle in the washing machine Wash drum automatically dosed.
- the polymer bodies may be either removed along with the cleaned fabrics after completion of the washing process or returned to the pantry for other applications.
- a refreshing step When using a polymer body several times, it may be preferable to subject it to a refreshing step. This can be done, for example, by rinsing the
- this refreshing step may be automatically executed in a dedicated one
- the process can be carried out in a commercially available dryer.
- the moist textiles to be cleaned together with the polymer body (s), the detergent composition and the hydrogen peroxide are placed in an air, water and water vapor-tight bag and this is then placed sealed in a dryer. After completion of the drying program, the bag is removed and the cleaned fabrics are removed and dried.
- the process according to the invention is preferably carried out at a temperature of less than 100.degree
- the process is carried out. Particularly preferably, the process is carried out at temperatures between 30 and 90 ° C.
- the duration of the process is preferably between 15 and 240 minutes and more preferably between 20 and 90 minutes.
- An autoclave pouch was charged with 550 g nylon PA 66 (Zytel® 101 from DuPont) polyamide chips having a length of about 4 mm, a width of 3 mm and a weight of 30 to 40 mg per chip.
- 150 g of white barley grain towels on which standard cotton test cloths were attached with test spots were moistened with an aqueous solution of 290.7 g of water, 1 g of H 2 O 2 (active ingredient) and 11, 81 g of Detergent A.
- the bag was then closed and transferred to the drum of a dryer (Miele Novotronic T 7644 C).
- Example 2 The procedure was analogous to Example 1, with the difference that the terry towels were moistened with an aqueous solution of 290.7 g of water and 1 1, 81 g of detergent A.
- the detergent A contained 21, 1 wt .-% surfactants (nonionic and anionic surfactants), and other conventional ingredients of liquid detergents such as the sodium salt of citric acid, sodium metaborate, defoamers, Acrylatverdicker, water-miscible solvents, optical brightener, dyes, perfume and water.
- Detergent A was free of enzymes.
- Standard color value Y (DIN 5033). These were the Y values of the stained, untreated
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
Abstract
L'invention concerne un procédé de nettoyage et/ou de conditionnement de surfaces textiles, selon lequel les surfaces textiles humides à nettoyer et/ou à conditionner sont mises en contact avec une formulation contenant a) au moins un corps polymère, b) une composition détergente et c) du peroxyde d'hydrogène (H2O2).
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL10766061T PL2494020T3 (pl) | 2009-10-29 | 2010-10-19 | Zmywanie za pomocą bryłek polimerycznych |
ES10766061.5T ES2565478T3 (es) | 2009-10-29 | 2010-10-19 | Lavado con cuerpos poliméricos |
EP10766061.5A EP2494020B1 (fr) | 2009-10-29 | 2010-10-19 | Lavage au moyen de corps polymères |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009046170A DE102009046170A1 (de) | 2009-10-29 | 2009-10-29 | Waschen mit Polymerkörpern |
DE102009046170.1 | 2009-10-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2011051140A1 true WO2011051140A1 (fr) | 2011-05-05 |
Family
ID=43466500
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2010/065737 WO2011051140A1 (fr) | 2009-10-29 | 2010-10-19 | Lavage au moyen de corps polymères |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2494020B1 (fr) |
DE (1) | DE102009046170A1 (fr) |
ES (1) | ES2565478T3 (fr) |
PL (1) | PL2494020T3 (fr) |
WO (1) | WO2011051140A1 (fr) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012035342A1 (fr) * | 2010-09-14 | 2012-03-22 | Xeros Limited | Procédé de traitement de polymères |
WO2013132223A1 (fr) * | 2012-03-08 | 2013-09-12 | Reckitt & Colman (Overseas) Limited | Procédé de nettoyage avec des particules polymères |
WO2013132225A1 (fr) * | 2012-03-08 | 2013-09-12 | Reckitt & Colman (Overseas) Limited | Procédé de traitement de polymère |
WO2014006424A1 (fr) * | 2012-07-06 | 2014-01-09 | Xeros Limited | Nouvelle substance nettoyante |
DE102012222263A1 (de) | 2012-12-05 | 2014-06-05 | Henkel Ag & Co. Kgaa | Entfernung fettiger Anschmutzungen |
EP2631287A3 (fr) * | 2012-02-21 | 2014-07-02 | Henkel AG & Co. KGaA | Lavage avec fibres |
US9121000B2 (en) | 2010-09-14 | 2015-09-01 | Xeros Limited | Cleaning method |
US9127882B2 (en) | 2011-01-19 | 2015-09-08 | Xeros Limited | Drying method |
US9297107B2 (en) | 2010-04-12 | 2016-03-29 | Xeros Limited | Cleaning method |
US9523169B2 (en) | 2013-11-25 | 2016-12-20 | Xeros Limited | Cleaning apparatus and method |
WO2017017455A1 (fr) * | 2015-07-29 | 2017-02-02 | Xeros Limited | Procédé, appareil de nettoyage et utilisation |
US9803307B2 (en) | 2011-01-14 | 2017-10-31 | Xeros Limited | Cleaning method |
US10081900B2 (en) | 2013-11-08 | 2018-09-25 | Xeros Limited | Cleaning method including use of solid particles |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102817208B (zh) | 2011-06-09 | 2017-03-01 | 塞罗斯有限公司 | 洗涤用固体颗粒及其洗涤方法 |
GB201117421D0 (en) * | 2011-10-10 | 2011-11-23 | Reckitt & Colman Overseas | Product |
GB201117425D0 (en) * | 2011-10-10 | 2011-11-23 | Reckitt & Colman Overseas | Product |
DE102014213312A1 (de) * | 2014-07-09 | 2016-01-14 | Henkel Ag & Co. Kgaa | Waschmaschine mit Entfärbungseinrichtung und Reservoir für wasserunlösliche feste Teilchen |
DE102014213314A1 (de) * | 2014-07-09 | 2016-01-14 | Henkel Ag & Co. Kgaa | Neuartiges Waschverfahren |
DE102014213313A1 (de) * | 2014-07-09 | 2016-01-14 | Henkel Ag & Co. Kgaa | Waschmaschine mit Entfärbungseinrichtung und Reservoir für wasserunlösliche feste Teilchen |
DE102018133499A1 (de) * | 2018-12-21 | 2020-06-25 | Henkel Ag & Co. Kgaa | Wachswolle als Vorbehandlungsmittel zur Fleckenentfernung |
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- 2009-10-29 DE DE102009046170A patent/DE102009046170A1/de not_active Withdrawn
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- 2010-10-19 ES ES10766061.5T patent/ES2565478T3/es active Active
- 2010-10-19 WO PCT/EP2010/065737 patent/WO2011051140A1/fr active Application Filing
- 2010-10-19 EP EP10766061.5A patent/EP2494020B1/fr active Active
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Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9297107B2 (en) | 2010-04-12 | 2016-03-29 | Xeros Limited | Cleaning method |
US9121000B2 (en) | 2010-09-14 | 2015-09-01 | Xeros Limited | Cleaning method |
WO2012035342A1 (fr) * | 2010-09-14 | 2012-03-22 | Xeros Limited | Procédé de traitement de polymères |
US9550966B2 (en) | 2010-09-14 | 2017-01-24 | Xeros Limited | Cleaning method |
US9803307B2 (en) | 2011-01-14 | 2017-10-31 | Xeros Limited | Cleaning method |
US9127882B2 (en) | 2011-01-19 | 2015-09-08 | Xeros Limited | Drying method |
EP2631287A3 (fr) * | 2012-02-21 | 2014-07-02 | Henkel AG & Co. KGaA | Lavage avec fibres |
WO2013132225A1 (fr) * | 2012-03-08 | 2013-09-12 | Reckitt & Colman (Overseas) Limited | Procédé de traitement de polymère |
WO2013132223A1 (fr) * | 2012-03-08 | 2013-09-12 | Reckitt & Colman (Overseas) Limited | Procédé de nettoyage avec des particules polymères |
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WO2014006424A1 (fr) * | 2012-07-06 | 2014-01-09 | Xeros Limited | Nouvelle substance nettoyante |
US10494590B2 (en) | 2012-07-06 | 2019-12-03 | Xeros Limited | Cleaning material |
US9365807B2 (en) | 2012-12-05 | 2016-06-14 | Henkel Ag & Co. Kgaa | Removal of greasy stains comprising porous polyamide particles |
WO2014086682A1 (fr) | 2012-12-05 | 2014-06-12 | Henkel Ag & Co. Kgaa | Élimination de salissures grasses |
DE102012222263A1 (de) | 2012-12-05 | 2014-06-05 | Henkel Ag & Co. Kgaa | Entfernung fettiger Anschmutzungen |
US10081900B2 (en) | 2013-11-08 | 2018-09-25 | Xeros Limited | Cleaning method including use of solid particles |
US9523169B2 (en) | 2013-11-25 | 2016-12-20 | Xeros Limited | Cleaning apparatus and method |
CN108026484A (zh) * | 2015-07-29 | 2018-05-11 | 塞罗斯有限公司 | 清洁方法、设备及用途 |
WO2017017455A1 (fr) * | 2015-07-29 | 2017-02-02 | Xeros Limited | Procédé, appareil de nettoyage et utilisation |
CN108026484B (zh) * | 2015-07-29 | 2020-09-01 | 塞罗斯有限公司 | 清洁方法、设备及用途 |
US11414633B2 (en) | 2015-07-29 | 2022-08-16 | Xeros Limited | Cleaning method, apparatus and use |
Also Published As
Publication number | Publication date |
---|---|
ES2565478T3 (es) | 2016-04-05 |
DE102009046170A1 (de) | 2011-05-05 |
EP2494020B1 (fr) | 2016-03-02 |
EP2494020A1 (fr) | 2012-09-05 |
PL2494020T3 (pl) | 2016-08-31 |
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