WO2011046308A3 - 4,4'-비스(알킬아미노)디페닐아민의 제조방법 - Google Patents

4,4'-비스(알킬아미노)디페닐아민의 제조방법 Download PDF

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Publication number
WO2011046308A3
WO2011046308A3 PCT/KR2010/006674 KR2010006674W WO2011046308A3 WO 2011046308 A3 WO2011046308 A3 WO 2011046308A3 KR 2010006674 W KR2010006674 W KR 2010006674W WO 2011046308 A3 WO2011046308 A3 WO 2011046308A3
Authority
WO
WIPO (PCT)
Prior art keywords
diphenylamine
alkylamino
bis
production method
dndpa
Prior art date
Application number
PCT/KR2010/006674
Other languages
English (en)
French (fr)
Other versions
WO2011046308A2 (ko
Inventor
김진억
김승일
장정희
곽한진
Original Assignee
금호석유화학 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 금호석유화학 주식회사 filed Critical 금호석유화학 주식회사
Priority to US13/502,052 priority Critical patent/US20120197044A1/en
Priority to CN2010800451472A priority patent/CN102686553A/zh
Publication of WO2011046308A2 publication Critical patent/WO2011046308A2/ko
Publication of WO2011046308A3 publication Critical patent/WO2011046308A3/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/54—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 4,4'-비스(알킬아미노)디페닐아민의 제조방법에 관한 것으로서, 더욱 상세하게는 요소와 니트로벤젠을 극성 유기용매와 염기 촉매 존재 하에서 반응시켜 4,4'-디니트로디페닐아민(4,4'-dinitrodiphenylamine, 4,4'-DNDPA)을 제조한 다음, 상기 4,4'-DNDPA와 케톤류를 수첨촉매 존재 하에서 수첨반응시켜 4,4'-비스(알킬아미노)디페닐아민(4,4'-bis(alkylamino)diphenylamine, 4,4'-BAADA)을 제조하는 방법에 관한 것이다.
PCT/KR2010/006674 2009-10-15 2010-09-30 4,4'-비스(알킬아미노)디페닐아민의 제조방법 WO2011046308A2 (ko)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US13/502,052 US20120197044A1 (en) 2009-10-15 2010-09-30 Production method for 4,4'-bis(alkylamino) diphenylamine
CN2010800451472A CN102686553A (zh) 2009-10-15 2010-09-30 4,4′-双(烷基氨基)二苯胺的生产方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2009-0098371 2009-10-15
KR1020090098371A KR20110041279A (ko) 2009-10-15 2009-10-15 4,4’-비스(알킬아미노)디페닐아민의 제조방법

Publications (2)

Publication Number Publication Date
WO2011046308A2 WO2011046308A2 (ko) 2011-04-21
WO2011046308A3 true WO2011046308A3 (ko) 2011-09-09

Family

ID=43876665

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/006674 WO2011046308A2 (ko) 2009-10-15 2010-09-30 4,4'-비스(알킬아미노)디페닐아민의 제조방법

Country Status (4)

Country Link
US (1) US20120197044A1 (ko)
KR (1) KR20110041279A (ko)
CN (1) CN102686553A (ko)
WO (1) WO2011046308A2 (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101358605B1 (ko) * 2010-12-21 2014-02-04 금호석유화학 주식회사 4-니트로아닐린을　이용한 4,4'-디니트로디페닐아민 및 4,4'-비스(알킬아미노)디페닐아민의 제조방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100331490B1 (ko) * 1999-12-03 2002-04-09 박찬구 요소와 니트로벤젠으로 부터 4,4'-디니트로디페닐아민을제조하는 방법
JP2005270910A (ja) * 2004-03-26 2005-10-06 Sumitomo Chemical Co Ltd 還元触媒の再生方法及び（アルキルアミノ）ジフェニルアミン類の製造方法。
JP2008133196A (ja) * 2006-11-27 2008-06-12 Sumitomo Chemical Co Ltd ４−（アルキルアミノ）ジフェニルアミン類の製造方法
US20090156864A1 (en) * 2005-09-28 2009-06-18 Appleton Papers Inc. Process for manufacturing diphenylamines

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3137828B2 (ja) * 1993-12-03 2001-02-26 三井化学株式会社 アミノジフェニルアミンの製造法
JPH10168038A (ja) * 1996-12-04 1998-06-23 Takashi Watanabe 劣化防止剤ジアミノジフェニルアミン誘導体の製造方法
US6156932A (en) * 2000-02-23 2000-12-05 Korea Kumho Petrochemical Co., Ltd. Preparation of 4,4'-dinitrodiphenylamine from urea and nitrobenzene
CN1177802C (zh) * 2001-12-16 2004-12-01 辽宁天合精细化工股份有限公司 N，n'－二仲烷基对苯二胺的合成方法
KR101358519B1 (ko) * 2010-12-21 2014-02-05 금호석유화학 주식회사 복합염기촉매를　이용한 4,4'-디니트로디페닐아민 및 4,4'-비스(알킬아미노)디페닐아민의 제조방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100331490B1 (ko) * 1999-12-03 2002-04-09 박찬구 요소와 니트로벤젠으로 부터 4,4'-디니트로디페닐아민을제조하는 방법
JP2005270910A (ja) * 2004-03-26 2005-10-06 Sumitomo Chemical Co Ltd 還元触媒の再生方法及び（アルキルアミノ）ジフェニルアミン類の製造方法。
US20090156864A1 (en) * 2005-09-28 2009-06-18 Appleton Papers Inc. Process for manufacturing diphenylamines
JP2008133196A (ja) * 2006-11-27 2008-06-12 Sumitomo Chemical Co Ltd ４−（アルキルアミノ）ジフェニルアミン類の製造方法

Also Published As

Publication number Publication date
WO2011046308A2 (ko) 2011-04-21
CN102686553A (zh) 2012-09-19
KR20110041279A (ko) 2011-04-21
US20120197044A1 (en) 2012-08-02

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