WO2010131844A3 - 해조류 유래 갈락탄을 이용한 바이오연료의 제조방법 - Google Patents

해조류 유래 갈락탄을 이용한 바이오연료의 제조방법 Download PDF

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Publication number
WO2010131844A3
WO2010131844A3 PCT/KR2010/002360 KR2010002360W WO2010131844A3 WO 2010131844 A3 WO2010131844 A3 WO 2010131844A3 KR 2010002360 W KR2010002360 W KR 2010002360W WO 2010131844 A3 WO2010131844 A3 WO 2010131844A3
Authority
WO
WIPO (PCT)
Prior art keywords
producing biofuel
galactan
macroalgae
furfural
marine
Prior art date
Application number
PCT/KR2010/002360
Other languages
English (en)
French (fr)
Other versions
WO2010131844A2 (ko
Inventor
조진구
김상용
이도훈
김보라
정재원
Original Assignee
한국생산기술연구원
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020090040576A external-priority patent/KR101098542B1/ko
Priority claimed from KR1020090074245A external-priority patent/KR101116392B1/ko
Priority claimed from KR1020090074234A external-priority patent/KR101141675B1/ko
Application filed by 한국생산기술연구원 filed Critical 한국생산기술연구원
Priority to US13/320,058 priority Critical patent/US8795393B2/en
Priority to CN201080020561.8A priority patent/CN102421877B/zh
Publication of WO2010131844A2 publication Critical patent/WO2010131844A2/ko
Publication of WO2010131844A3 publication Critical patent/WO2010131844A3/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/20—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D233/24—Radicals substituted by nitrogen atoms not forming part of a nitro radical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C07D307/50—Preparation from natural products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/44—Solvents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

본 발명은 저비용으로 대량 공급이 가능하고, 해양계 재생자원인 거대 해조류로부터 추출이 가능한 갈락탄으로부터 촉매전환반응을 이용하여 단당화반응을 거치지 않고 단일공정으로 5-히드록시메틸-2-푸르푸랄(HMF), 5-알콕시메틸-2-푸르푸랄 및 루브리닉산 알킬 에스테르 등의 석유대체 바이오연료 물질을 제조하는 방법에 관한 것이다. 본 발명에 따르면, 해양계 바이오매스 자원인 거대 해조류를 활용함으로서 작물계 바이오매스 자원처럼 곡물가에 영향을 미치는 문제가 없고, 목질계 바이오매스 자원에 비해 손쉽게 탄소원을 추출할 수 있다.
PCT/KR2010/002360 2009-05-11 2010-04-15 해조류 유래 갈락탄을 이용한 바이오연료의 제조방법 WO2010131844A2 (ko)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US13/320,058 US8795393B2 (en) 2009-05-11 2010-04-15 Method for producing biofuel using marine algae-derived galactan
CN201080020561.8A CN102421877B (zh) 2009-05-11 2010-04-15 利用来源于海藻类的半乳聚糖的生物燃料的制造方法

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR1020090040576A KR101098542B1 (ko) 2009-05-11 2009-05-11 5-히드록시메틸푸르푸랄의 제조방법
KR10-2009-0040576 2009-05-11
KR10-2009-0074245 2009-08-12
KR1020090074245A KR101116392B1 (ko) 2009-08-12 2009-08-12 해조류 유래 갈락탄을 이용한 바이오 연료의 제조방법
KR1020090074234A KR101141675B1 (ko) 2009-08-12 2009-08-12 해조류 유래 갈락탄을 이용한 5-히드록시메틸-2-푸르푸랄의 제조방법
KR10-2009-0074234 2009-08-12

Publications (2)

Publication Number Publication Date
WO2010131844A2 WO2010131844A2 (ko) 2010-11-18
WO2010131844A3 true WO2010131844A3 (ko) 2011-03-31

Family

ID=43085416

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/002360 WO2010131844A2 (ko) 2009-05-11 2010-04-15 해조류 유래 갈락탄을 이용한 바이오연료의 제조방법

Country Status (3)

Country Link
US (1) US8795393B2 (ko)
CN (1) CN102421877B (ko)
WO (1) WO2010131844A2 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101186502B1 (ko) * 2011-02-16 2012-09-27 한국생산기술연구원 해조류 유래 갈락탄으로부터 5-클로로메틸-2-푸르푸랄을 제조하기 위한 산촉매조성물 및 이를 이용하여 이성분계 상에서 해조류 유래 갈락탄으로부터 5-클로로메틸-2-푸르푸랄을 제조하는 방법
WO2014058322A1 (en) 2012-10-11 2014-04-17 Institutt For Energiteknikk Method for the production of aqueous nutrient source for algae aquaculture farming
JP2014528407A (ja) * 2011-09-29 2014-10-27 エスケー ケミカルズ カンパニー リミテッド 有機溶媒の下でイオン交換樹脂を用いる５−ヒドロキシメチル−２−フルフラールまたはそのアルキルエーテル誘導体の製造方法
CN103508985B (zh) * 2012-06-29 2016-05-11 中国科学院宁波材料技术与工程研究所 以红藻生物质为原料生产糠醛和/或5-羟甲基糠醛的方法
CN103396825B (zh) * 2013-08-27 2015-06-17 青岛大学 一种海藻多糖液化制备碳氢液体燃油的方法

Citations (6)

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Publication number Priority date Publication date Assignee Title
GB171479A (en) * 1920-08-16 1921-11-16 William Richard Walkey Improvements in or relating to the preparation of alcohol
JPS5553280A (en) * 1978-10-12 1980-04-18 Noguchi Kenkyusho Preparation of 5-hydroxymethyl-2-furfural
JP2005521748A (ja) * 2002-04-01 2005-07-21 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー バイオマスおよびオレフィンからのレブリン酸エステルおよびギ酸エステルの製造
WO2007104514A2 (en) * 2006-03-10 2007-09-20 Furanix Technologies B.V. Method for the synthesis of 5-alkoxymethyl furfural ethers and their use
WO2008105618A1 (en) * 2007-02-26 2008-09-04 Korea Institute Of Industrial Technology Method of producing biofuel using sea algae
WO2009030511A1 (en) * 2007-09-07 2009-03-12 Furanix Technologies B.V. Mixture of furfural and 5-(alkoxymethyl)furfural derivatives from sugars and alcohols

Family Cites Families (3)

* Cited by examiner, † Cited by third party
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JP2007145736A (ja) * 2005-11-25 2007-06-14 Canon Inc ５−ヒドロキシメチルフルフラールの製造方法
KR100882462B1 (ko) 2007-06-29 2009-02-06 나현주 제주산 홍조류의 효소적 추출물을 이용한 항혈액응고성설페이티드 갈락탄조성물
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Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB171479A (en) * 1920-08-16 1921-11-16 William Richard Walkey Improvements in or relating to the preparation of alcohol
JPS5553280A (en) * 1978-10-12 1980-04-18 Noguchi Kenkyusho Preparation of 5-hydroxymethyl-2-furfural
JP2005521748A (ja) * 2002-04-01 2005-07-21 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー バイオマスおよびオレフィンからのレブリン酸エステルおよびギ酸エステルの製造
WO2007104514A2 (en) * 2006-03-10 2007-09-20 Furanix Technologies B.V. Method for the synthesis of 5-alkoxymethyl furfural ethers and their use
WO2008105618A1 (en) * 2007-02-26 2008-09-04 Korea Institute Of Industrial Technology Method of producing biofuel using sea algae
WO2009030511A1 (en) * 2007-09-07 2009-03-12 Furanix Technologies B.V. Mixture of furfural and 5-(alkoxymethyl)furfural derivatives from sugars and alcohols

Non-Patent Citations (1)

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Title
ZHAO, HAIBO ET AL.: "Metal Chlorides in Ionic Solvents Sugars to 5-Hydroxymet hylfurfural", SCIENCE, vol. 316, no. 5831, 15 June 2007 (2007-06-15), pages 1597 - 1600, Retrieved from the Internet <URL:http://www.sciencemag.org/cgi/reprint/316/5831/1597.pdf> [retrieved on 20110127] *

Also Published As

Publication number Publication date
CN102421877A (zh) 2012-04-18
WO2010131844A2 (ko) 2010-11-18
CN102421877B (zh) 2015-01-21
US20120053355A1 (en) 2012-03-01
US8795393B2 (en) 2014-08-05

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