JPS5553280A - Preparation of 5-hydroxymethyl-2-furfural - Google Patents

Preparation of 5-hydroxymethyl-2-furfural

Info

Publication number
JPS5553280A
JPS5553280A JP12574478A JP12574478A JPS5553280A JP S5553280 A JPS5553280 A JP S5553280A JP 12574478 A JP12574478 A JP 12574478A JP 12574478 A JP12574478 A JP 12574478A JP S5553280 A JPS5553280 A JP S5553280A
Authority
JP
Japan
Prior art keywords
solvent
hexose
furfural
hydroxymethyl
oligosaccharide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12574478A
Other languages
Japanese (ja)
Inventor
Shunichi Morikawa
Yoshio Nakamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Noguchi Institute
Original Assignee
Noguchi Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Noguchi Institute filed Critical Noguchi Institute
Priority to JP12574478A priority Critical patent/JPS5553280A/en
Publication of JPS5553280A publication Critical patent/JPS5553280A/en
Pending legal-status Critical Current

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  • Furan Compounds (AREA)

Abstract

PURPOSE: To prepare the title compound useful as a synthetic intermediate of medicines, etc., economically, by heating a naturally producing sugars in a specific solvent in the presence of an acidic catalyst, at a low temperature, for a definite time interval instead of the instantaneous heating, thereby facilitating the removal of the by-products.
CONSTITUTION: A hexose, an oligosaccharide containing hexose, or a polysaccharide containing hexose, is heated in dimethylsulfoxide as a solvent, in the presence of an acidic solvent such as oxalic acid, hydrochloric acid, ammonium alum, etc. to afford 5-hydroxymethyl-2-furfural. The dimethylsulfoxide used as the solvent can be recovered by distillation, and reused. The hexose is, e.g. glucose, fructose, etc., the oligosaccharide is, e.g. sucrose, maltose, etc., and the polysaccharide is, e.g. starch, cellulose, etc.
COPYRIGHT: (C)1980,JPO&Japio
JP12574478A 1978-10-12 1978-10-12 Preparation of 5-hydroxymethyl-2-furfural Pending JPS5553280A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12574478A JPS5553280A (en) 1978-10-12 1978-10-12 Preparation of 5-hydroxymethyl-2-furfural

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12574478A JPS5553280A (en) 1978-10-12 1978-10-12 Preparation of 5-hydroxymethyl-2-furfural

Publications (1)

Publication Number Publication Date
JPS5553280A true JPS5553280A (en) 1980-04-18

Family

ID=14917715

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12574478A Pending JPS5553280A (en) 1978-10-12 1978-10-12 Preparation of 5-hydroxymethyl-2-furfural

Country Status (1)

Country Link
JP (1) JPS5553280A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006063220A3 (en) * 2004-12-10 2007-01-11 Archer Daniels Midland Co Preparation of 2,5-(hydr0xymethyl)furaldehyde (hmf) , derivatives thereof and levulinic acid from fructose as well as preparation of 2 , 5-bis- (hydroxymethyl) furan from 2 , 5- (hydroxymethyl) furaldehyde
US7317116B2 (en) 2004-12-10 2008-01-08 Archer-Daniels-Midland-Company Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives
WO2010131844A2 (en) * 2009-05-11 2010-11-18 한국생산기술연구원 Method for producing biofuel using marine algae-derived galactan
KR101141675B1 (en) * 2009-08-12 2012-05-04 한국생산기술연구원 Method of preparing 5-hydroxymethyl-2-furfural from algal galactans
WO2013047984A1 (en) * 2011-09-29 2013-04-04 한국생산기술연구원 Method for producing 5- hydroxymethyl-2- furfural or alkyl ether derivatives thereof using an ion exchange resin in the presence of an organic solvent

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54154757A (en) * 1978-05-26 1979-12-06 Noguchi Kenkyusho Manufacture of hydroxymethylfurfural

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54154757A (en) * 1978-05-26 1979-12-06 Noguchi Kenkyusho Manufacture of hydroxymethylfurfural

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8058458B2 (en) 2004-12-10 2011-11-15 Archer Daniels Midland Company Processes for the preparation and purification of hydroxymethylfuraldehyde derivatives
US7317116B2 (en) 2004-12-10 2008-01-08 Archer-Daniels-Midland-Company Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives
US7579489B2 (en) 2004-12-10 2009-08-25 Archer-Daniels-Midland Company Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives
WO2006063220A3 (en) * 2004-12-10 2007-01-11 Archer Daniels Midland Co Preparation of 2,5-(hydr0xymethyl)furaldehyde (hmf) , derivatives thereof and levulinic acid from fructose as well as preparation of 2 , 5-bis- (hydroxymethyl) furan from 2 , 5- (hydroxymethyl) furaldehyde
CN102421877A (en) * 2009-05-11 2012-04-18 韩国生产技术研究院 Method for producing biofuel using marine algae-derived galactan
WO2010131844A3 (en) * 2009-05-11 2011-03-31 한국생산기술연구원 Method for producing biofuel using marine algae-derived galactan
WO2010131844A2 (en) * 2009-05-11 2010-11-18 한국생산기술연구원 Method for producing biofuel using marine algae-derived galactan
US8795393B2 (en) 2009-05-11 2014-08-05 Korea Institute Of Industrial Technology Method for producing biofuel using marine algae-derived galactan
KR101141675B1 (en) * 2009-08-12 2012-05-04 한국생산기술연구원 Method of preparing 5-hydroxymethyl-2-furfural from algal galactans
WO2013047984A1 (en) * 2011-09-29 2013-04-04 한국생산기술연구원 Method for producing 5- hydroxymethyl-2- furfural or alkyl ether derivatives thereof using an ion exchange resin in the presence of an organic solvent
CN103842349A (en) * 2011-09-29 2014-06-04 韩国生产技术研究院 Method for producing 5- hydroxymethyl-2- furfural or alkyl ether derivatives thereof using an ion exchange resin in the presence of an organic solvent
JP2014528407A (en) * 2011-09-29 2014-10-27 エスケー ケミカルズ カンパニー リミテッド Process for producing 5-hydroxymethyl-2-furfural or an alkyl ether derivative thereof using ion exchange resin under organic solvent
US9206147B2 (en) 2011-09-29 2015-12-08 Korea Institute Of Industrial Technology Method for producing 5-hydroxymethyl-2-furfural or alkyl ether derivatives thereof using an ion exchange resin in the presence of an organic solvent
JP2017128600A (en) * 2011-09-29 2017-07-27 エスケー ケミカルズ カンパニー リミテッド Method for producing 5-hydroxymethyl-2-furfural or alkyl ether derivatives thereof using ion exchange resin in presence of organic solvent

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