WO2010092970A1 - 低温焼結セラミック焼結体および多層セラミック基板 - Google Patents
低温焼結セラミック焼結体および多層セラミック基板 Download PDFInfo
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- WO2010092970A1 WO2010092970A1 PCT/JP2010/051929 JP2010051929W WO2010092970A1 WO 2010092970 A1 WO2010092970 A1 WO 2010092970A1 JP 2010051929 W JP2010051929 W JP 2010051929W WO 2010092970 A1 WO2010092970 A1 WO 2010092970A1
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- ceramic
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- H—ELECTRICITY
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- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
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- C04B2237/32—Ceramic
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
- H05K3/4626—Manufacturing multilayer circuits by laminating two or more circuit boards characterised by the insulating layers or materials
- H05K3/4629—Manufacturing multilayer circuits by laminating two or more circuit boards characterised by the insulating layers or materials laminating inorganic sheets comprising printed circuits, e.g. green ceramic sheets
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24926—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including ceramic, glass, porcelain or quartz layer
Definitions
- the present invention relates to a low-temperature sintered ceramic sintered body obtained by firing a non-glass-based low-temperature sintered ceramic material, and a multilayer ceramic substrate formed using the low-temperature sintered ceramic sintered body. .
- a low temperature sintered ceramic (LTCC: Low Temperature Ceramics) sintered body is formed by forming a low temperature sintered ceramic material into a predetermined shape and sintering it.
- Low temperature sintered ceramic materials can be fired simultaneously with low melting point metal materials such as silver and copper having a relatively small specific resistance, so that a multilayer ceramic substrate having excellent high frequency characteristics can be formed.
- high frequency modules in information communication terminals It is widely used as a substrate material for use.
- a so-called glass ceramic composite system in which a B 2 O 3 —SiO 2 glass material is mixed with a ceramic material such as Al 2 O 3 is generally used. It is necessary to use an expensive glass material, and since boron that easily volatilizes during baking is included, the composition of the resulting substrate tends to vary, so a special setter for controlling the volatilization amount of boron is required. The manufacturing process is complicated, such as having to use it.
- low-temperature sintered ceramic materials described in JP-A-2002-173362 Patent Document 1
- JP-A-2008-044829 Patent Document 2
- JP-A-2008-053525 Patent Document 3
- the low-temperature sintered ceramic materials described in these documents do not contain glass as a starting material, and are non-glass-based low-temperature sintered ceramic materials that do not contain boron. I do not encounter.
- the low-temperature sintered ceramic sintered body obtained by sintering the low-temperature sintered ceramic material described in these documents may not have sufficient bonding strength with the conductor film formed on this surface, Since the fracture toughness value of the sintered body itself is small, desired strength characteristics may not be obtained.
- the present invention has been made in view of the above-mentioned circumstances, and the object thereof is a non-glass-based low-temperature sintered ceramic sintered body that can be manufactured inexpensively and easily without using glass as a starting material. Another object of the present invention is to provide a low-temperature sintered ceramic sintered body having a high bonding strength with a conductor film and a large fracture toughness value.
- Another object of the present invention is to provide a highly reliable multilayer ceramic substrate including a plurality of ceramic layers made of the above-mentioned low-temperature sintered ceramic sintered body.
- the low-temperature sintered ceramic sintered body according to the present invention is formed by sintering a non-glass-based low-temperature sintered ceramic material, and each crystal phase of Quartz, Alumina, and Fresnoite is obtained. It is characterized by precipitation.
- the present invention also provides a multilayer ceramic substrate comprising a laminate formed by laminating a plurality of ceramic layers, and a conductor pattern mainly composed of gold, silver, or copper provided on a surface layer and an inner layer of the laminate. Also directed to.
- the ceramic layer is formed by sintering a non-glass low-temperature sintered ceramic material, and crystal phases of quartz, alumina and fresnoite are precipitated. It is characterized by comprising a sintered body.
- the low-temperature sintered ceramic sintered body of the present invention is formed by sintering a non-glass low-temperature sintered ceramic material, there is little composition variation, it is inexpensive, and a special setter is not used. Can also be fired, the manufacturing process is easy. Furthermore, since each crystal phase of quartz, alumina, and fresnoite is precipitated, the bonding strength with the conductor film formed on the surface is high, and the fracture toughness value of the sintered body itself is large, so the strength characteristics are improved. Are better.
- the ceramic layer constituting the multilayer ceramic substrate is formed by sintering a non-glass-based low-temperature sintered ceramic material. Since it can be baked without using a special setter, it can be manufactured easily. Furthermore, because the ceramic layer has precipitated quartz, alumina, and Fresnoite crystal phases, the bonding strength with the external conductor film formed on the surface is high, and the fracture toughness value of the sintered body itself is large.
- the multilayer ceramic substrate provided with this ceramic layer can have excellent strength characteristics and high reliability.
- FIG. 1 is a cross-sectional view schematically showing a multilayer ceramic substrate 1 configured using a low-temperature sintered ceramic sintered body according to the present invention.
- the low-temperature sintered ceramic sintered body of the present invention is obtained by sintering a non-glass-based low-temperature sintered ceramic material. Quartz (SiO 2 ), alumina (Alumina: Al 2 O 3 ), and fresnoite ( Each crystal phase of Fresnoite: Ba 2 TiSi 2 O 8 ) is precipitated.
- the “low-temperature sintered ceramic sintered body” is a low-temperature sintered ceramic material that can be fired simultaneously with a low-melting-point metal material such as gold, silver, or copper having a small specific resistance at a firing temperature of, for example, 1050 ° C. It is a thing.
- the starting material does not substantially contain a glass component, but the sintered body itself has an amorphous portion in addition to the above-described crystal phases. This is because when a non-glass low-temperature sintered ceramic material is fired, a part of the starting material is vitrified.
- the low-temperature sintered ceramic sintered body of the present invention has the above-mentioned crystal phase as the main crystal phase, the low dielectric constant ⁇ r is as small as 10 or less, and the low-temperature sintered ceramic suitable for the ceramic layer constituting the high-frequency substrate A sintered body can be obtained. Moreover, as described above, since the bonding strength with the external conductor film is high, the electrode peel strength is improved, and problems such as dropping of the surface-mounted components to be mounted are less likely to occur. Furthermore, since a ceramic layer having a large fracture toughness value can be formed, a multilayer ceramic substrate having excellent reliability can be obtained.
- the low-temperature sintered ceramic sintered body of the present invention preferably further precipitates at least one crystal phase of Sanbornite (BaSi 2 O 5 ) or Celsian (Celsian: BaAl 2 Si 2 O 8 ).
- Sanbornite BaSi 2 O 5
- Celsian Celsian: BaAl 2 Si 2 O 8
- the crystalline phase of sambourite or celsian is precipitated, a large number of various crystalline phases exist, and as a result, the crystalline structure of the sintered body becomes non-uniform, even if the sintered body is cracked. Even if it enters, the elongation can be suppressed. More preferably, both the crystalline phases of sambourite and celsian are precipitated.
- the Fresnoite crystal phase is contained at a ratio of 1 to 20% by weight.
- the amount of precipitation of the Fresnoite crystal phase segregation of the crystal phase can be suppressed, the bonding strength of the external conductor film can be further improved, and the electrode peel strength can be further increased.
- the average crystal grain size of the Fresnoite crystal phase is preferably 5 ⁇ m or less. That is, when such fine crystal phases are present at a predetermined ratio, the crystal grain boundaries increase, and even if cracks are generated in the sintered body, the elongation can be suppressed.
- the non-glass low-temperature sintered ceramic material constituting the low-temperature sintered ceramic sintered body of the present invention includes a main component ceramic material containing Si oxide, Ba oxide and Al oxide, Mn oxide and Ti. And a subcomponent ceramic material containing an oxide, and preferably substantially free of either Cr oxide or B oxide.
- substantially means that Cr oxide and B oxide can be contained as impurities in an amount of less than 0.1 wt%. That is, even if Cr oxide and B oxide are mixed as impurities, the effect of the present invention can be obtained as long as it is less than 0.1% by weight.
- this low-temperature sintered ceramic material comprises 48 to 75% by weight of Si converted to SiO 2 , 20 to 40% by weight of Ba converted to BaO, and Al to Al 2 O 3.
- Main component ceramic material containing 5-20% by weight in terms of Mn, and 100 parts by weight of this main component ceramic material, Mn is converted to MnO, 2-10 parts by weight, and Ti is converted to TiO 2 It is preferable that the secondary component ceramic material is contained in an amount of 0.1 to 10 parts by weight and substantially contains neither Cr oxide nor B oxide.
- this low-temperature sintered ceramic material is a non-glass low-temperature sintered ceramic material that does not use glass as a starting material and does not contain boron, the composition of the obtained sintered body is unlikely to vary, and the firing process can be managed. Easy. Moreover, the obtained sintered body has a bending strength of 230 MPa or more, and the sintered body itself has a high strength, and when this is used as a substrate, it has a high peel strength, and the outer conductor film and The bonding strength is high and the substrate is highly reliable.
- the crystallization is promoted, the environmental resistance against high temperature and high humidity can be improved, and the chemical resistance of the substrate is also improved so that the elution of the substrate components into the plating solution can be suppressed. be able to. Furthermore, since crystallization is promoted, a multilayer ceramic substrate having a small number of amorphous portions and a high Qf value can be obtained.
- Si is contained in 48 to 75 wt% in terms of SiO 2 , Ba in terms of 20 to 40 wt% in terms of BaO, and Al in an amount of 5 to 20 wt% in terms of Al 2 O 3.
- component ceramic material a basic component of the sintered body obtained, the insulation resistance is increased, the relative dielectric constant epsilon r is smaller, it has contributed greatly to the dielectric loss is obtained a small sintered body.
- Mn which is a subcomponent ceramic material, easily reacts with the SiO 2 —BaO—Al 2 O 3 main component ceramic material to form a liquid phase component and reduces the viscosity of the starting material during firing. Although acting as a sintering aid, the volatility is much less than B 2 O 3 acting as the same sintering aid. Therefore, variation in firing is reduced, management of the firing process is facilitated, and mass productivity is improved.
- the detailed mechanism of Ti which is a subcomponent ceramic material, is unknown, but the reaction between a ceramic layer made of a low-temperature sintered ceramic material and an external conductor film made of a low-melting-point metal material such as copper.
- the co-firing process can increase the bonding strength between the sintered body and the conductor film, that is, the bonding strength between the ceramic layer and the external conductor film.
- a strong solder joint is formed between the active element such as a semiconductor device mounted on the multilayer ceramic substrate, a passive element such as a chip capacitor, and the multilayer ceramic substrate, and suppresses the junction breakdown due to the impact such as dropping. be able to.
- the low-temperature sintered ceramic material may further contain Fe (particularly Fe 2 O 3 ) as a subcomponent ceramic material, instead of Ti described above or in addition to Ti.
- Fe particularly Fe 2 O 3
- the total content with the Ti oxide is preferably 0.1 to 10 parts by weight with respect to 100 parts by weight of the main component ceramic material.
- This Fe can also increase the reactivity between the ceramic layer and the outer conductor film, and the co-firing process increases the bonding strength between the sintered body and the conductor film, that is, the bonding strength between the ceramic layer and the outer conductor film. be able to.
- this low-temperature sintered ceramic material does not substantially contain B oxide (particularly B 2 O 3 ), the composition variation at the time of firing can be reduced, and a special setter is not used. The management of the baking process can be facilitated.
- Cr oxide (particularly Cr 2 O 3 ) is not substantially contained, a reduction in Qf value in a high frequency band typified by a microwave band is suppressed, and a Qf value of 1000 or more is obtained at 3 GHz, for example. be able to.
- This low-temperature sintered ceramic material preferably does not contain an alkali metal oxide such as Li 2 O or Na 2 O. This is because, like B 2 O 3 , these alkali metal oxides are also likely to volatilize during firing, and may cause variations in the composition of the obtained substrate. Furthermore, if these alkali metal oxides are not included, the environmental resistance against high temperature and high humidity is improved, and the chemical resistance can be improved such that elution into the plating solution can be suppressed.
- an alkali metal oxide such as Li 2 O or Na 2 O.
- Mg is contained in an amount of 0.1 to 5 parts by weight in terms of MgO with respect to 100 parts by weight of the main component ceramic material as a subcomponent ceramic material.
- Mg especially MgO
- crystallization of the low-temperature sintered ceramic material at the time of firing is promoted, and as a result, the volume of the liquid phase part that causes a decrease in substrate strength is reduced. And the bending strength of the obtained sintered body can be further improved.
- At least one selected from Nb, Ce, Zr and Zn as an auxiliary component ceramic material and 100 parts by weight of the main component ceramic material is Nb 2 O, respectively. 5 , 0.1 to 6 parts by weight in terms of CeO 2 , ZrO 2 and ZnO are preferably contained.
- Nb, Ce, Zr and Zn in particular, at least one oxide selected from Nb 2 O 5 , CeO 2 , ZrO 2 and ZnO
- the amount of Mn (especially MnO) that tends to remain as a quality component can be reduced, and as a result, the volume of the liquid phase part that causes a reduction in the substrate strength can be reduced, and the resulting multilayer ceramic substrate can be bent.
- the strength can be further improved.
- this low-temperature sintered ceramic material is further converted into CoO and / or V 2 O 5 as CoO and / or V 2 O 5 with respect to 100 parts by weight of the main component ceramic material as a subcomponent ceramic material. It may contain up to 5.0 parts by weight. These components can further improve the bending strength of the resulting multilayer ceramic substrate and also function as a colorant.
- MnCO 3 ceramic powder and at least one ceramic powder of TiO 2 and Fe 2 O 3 are added to each ceramic powder of SiO 2 , BaCO 3 and Al 2 O 3.
- the low-temperature sintered ceramic material added and mixed can be formed into a predetermined shape, and the formed body can be fired.
- a mixture obtained by adding at least one ceramic powder of TiO 2 and Fe 2 O 3 to each ceramic powder of SiO 2 , BaCO 3 and Al 2 O 3 is calcined, thereby producing a calcined powder And a step of adding a non-calcined MnCO 3 ceramic powder to the calcined powder.
- the ceramic green sheet containing the above-mentioned low-temperature sintered ceramic material preferably, at least one ceramic powder of TiO 2 and Fe 2 O 3 is added to each ceramic powder of SiO 2 , BaCO 3 and Al 2 O 3. And calcining the resulting mixture, adding a ceramic powder of MnCO 3 that has not been calcined to the calcined powder, and adding a binder, thereby adding a ceramic slurry.
- the ceramic slurry is manufactured through a manufacturing step and a step of forming the ceramic slurry, thereby forming a ceramic green sheet.
- a calcined powder obtained by calcining the Si component, Ba component, Al component and Ti / Fe component is obtained and calcined. If a non-Mn component is added to the calcined powder, the reaction of calcining synthesis is suppressed at the time of calcining, so that the particle size of the calcined powder can be reduced. Therefore, the pulverization step of the calcined powder can be simplified, and the ceramic green sheet produced using the calcined powder can be easily thinned. In addition, the color of the calcined powder can be prevented from changing to dark brown, and thus, when printing a conductive paste mainly composed of copper, a ceramic green sheet produced using such a calcined powder. Image recognizability can be improved.
- FIG. 1 is a cross-sectional view schematically showing a multilayer ceramic substrate 1 constituted by using a low-temperature sintered ceramic sintered body according to the present invention.
- the multilayer ceramic substrate 1 includes a laminated body 3 including a plurality of laminated ceramic layers 2.
- the ceramic layer 2 provided in the laminate 3 is composed of the low-temperature sintered ceramic sintered body according to the present invention.
- various conductor patterns are provided in association with specific ones of the ceramic layers 2.
- some outer conductor films 4 and 5 formed on the end face in the lamination direction of the laminate 3 and some inner conductors formed along a specific interface between the ceramic layers 2.
- the outer conductor film 4 provided on the surface of the multilayer body 3 is used for connection to the electronic components 8 and 9 to be mounted on the outer surface of the multilayer body 3.
- an electronic component 8 including a bump electrode 10 such as a semiconductor device and an electronic component 9 including a planar terminal electrode 11 such as a chip capacitor are illustrated.
- the external conductor film 5 provided on the back surface of the multilayer body 3 is used for connection to a mother board (not shown) on which the multilayer ceramic substrate 1 is mounted.
- the multilayer body 3 provided in such a multilayer ceramic substrate 1 includes a plurality of laminated ceramic green layers to be the ceramic layer 2, an internal conductor film 6 and a via-hole conductor 7 formed of a conductive paste.
- the raw laminated body further provided with the outer conductor films 4 and 5 formed of the conductive paste is obtained by firing.
- the laminated structure of the ceramic green layer in the raw laminate described above is typically provided by laminating a plurality of ceramic green sheets obtained by forming a ceramic slurry, and a conductor pattern, particularly an inner conductor.
- the pattern is provided on the ceramic green sheet before lamination.
- the ceramic slurry is composed of the above-mentioned low-temperature sintered ceramic material, an organic binder such as polyvinyl butyral, a solvent such as toluene and isopropyl alcohol, a plasticizer such as di-n-butyl phthalate, and the like. Then, it can be obtained by adding an additive such as a dispersant to make a slurry.
- an organic binder such as polyvinyl butyral
- a solvent such as toluene and isopropyl alcohol
- a plasticizer such as di-n-butyl phthalate
- a doctor blade method may be applied to form a ceramic slurry into a sheet on a carrier film made of an organic resin such as polyethylene terephthalate. Done.
- a conductive paste containing a low melting point metal material such as gold, silver or copper as a main component of the conductive component is used, and the through hole for the via-hole conductor 7 is provided in the ceramic green sheet.
- the conductive paste film for the internal conductor film 6 and the conductive paste film for the external conductor films 4 and 5 are formed by, for example, a screen printing method.
- the low-temperature sintered ceramic sintered body of the present invention is particularly excellent in co-sinterability with a conductive paste mainly composed of copper among low melting point metal materials such as gold, silver or copper.
- Such ceramic green sheets are laminated in a predetermined order and pressed in the lamination direction with a pressure of, for example, 1000 to 1500 kgf / cm 2 to obtain a raw laminate.
- this raw laminate may be provided with a cavity for accommodating other electronic components, and a joint portion for fixing a cover that covers the electronic components 8 and 9 and the like.
- the raw laminated body has a temperature higher than the temperature at which the ceramic material contained in the ceramic green layer can be sintered, for example, 850 ° C. Baking in the temperature range.
- the ceramic green layer is sintered and the conductive paste is also sintered, so that a circuit pattern is formed by the sintered conductor film.
- the firing is performed in a non-oxidizing atmosphere such as a nitrogen atmosphere, and for example, the binder removal is completed at a temperature of 900 ° C. or lower.
- the temperature is lowered, the oxygen partial pressure is lowered so that copper is not substantially oxidized when the firing is completed.
- the firing temperature is, for example, 980 ° C. or higher, it is difficult to use silver as the metal contained in the conductor pattern.
- it is an Ag—Pd-based alloy containing 20% by weight or more of palladium, it may be used. Is possible. In this case, calcination can be carried out in air.
- the firing temperature is, for example, 950 ° C. or lower, silver can be used as the metal contained in the conductor pattern.
- the ceramic layer 2 in the multilayer ceramic substrate 1 does not contain glass as a starting component, but glass that is an amorphous component is generated during the firing cycle. Includes glass. Therefore, the multilayer ceramic substrate 1 can be stably produced without using expensive glass.
- the low-temperature-sintered ceramic sintered body of the present invention is preferably applied to a multilayer ceramic substrate provided with a multilayer body having the above-described multilayer structure.
- the ceramic having a single-layer structure including only one ceramic layer is preferable. It can also be applied to a substrate.
- the low-temperature sintered ceramic sintered body according to the present invention is divided into a low dielectric constant ceramic layer made of the low-temperature sintered ceramic sintered body and a relatively high relative dielectric constant ⁇ r (for example, ⁇ r is 15 or more).
- the present invention can also be applied to a composite type multilayer ceramic substrate having a high dielectric constant ceramic layer made of a low-temperature sintered ceramic sintered body.
- ceramic powders of SiO 2 , BaCO 3 , Al 2 O 3 , MnCO 3 , TiO 2, and Mg (OH) 2 each having a particle size of 2.0 ⁇ m or less were prepared.
- these starting raw material powders are weighed so that the composition ratio shown in Table 1 is obtained after firing, wet-mixed and pulverized, and then dried, and the resulting mixture is calcined at 750 to 1000 ° C. for 1 to 3 hours.
- the raw material powder was obtained.
- the BaCO 3 becomes BaO after firing
- the MnCO 3 becomes MnO after firing
- the Mg (OH) 2 becomes MgO after firing.
- the main component ceramic materials of SiO 2 , BaO and Al 2 O 3 are shown in units of wt% (wt%), and the total of these is 100 wt%.
- the subcomponent ceramic material of MnO, TiO 2 and MgO the ratio with respect to 100 parts by weight of the main component ceramic is shown in units of parts by weight.
- an appropriate amount of an organic binder, a dispersant, and a plasticizer are added to the raw material powder according to each sample described above to produce a ceramic slurry, and then the average particle size (D50) of the raw material powder in the slurry is 1.
- the mixture was pulverized so as to be 5 ⁇ m or less.
- the ceramic slurry was formed into a sheet shape by a doctor blade method, dried, and cut into an appropriate size to obtain a ceramic green sheet having a thickness of 50 ⁇ m.
- a conductive paste mainly composed of copper was printed on a predetermined ceramic green sheet by a screen printing method to form a conductor pattern serving as an external conductor film.
- the obtained ceramic green sheets are cut to a predetermined size, and then a plurality of sheets are laminated, and then thermocompression bonded under conditions of a temperature of 60 to 80 ° C. and a pressure of 1000 to 1500 kg / cm 2 , and raw lamination Got the body.
- the raw laminated body is fired at a temperature of 900 to 1050 ° C. in a non-oxidizing atmosphere of nitrogen and hydrogen, and a ceramic green sheet and a conductor pattern are simultaneously sintered to form a plate-like ceramic sintered body A sample was obtained.
- an indentation with a Vickers indenter was applied to the surface of the obtained sample under the condition of 500 gf ⁇ 15 seconds, and the fracture toughness value K IC was calculated from the size and the crack length.
- an L-shaped lead wire is soldered to a square electrode with a side of 2 mm on the surface, and the bonding strength (electrode peel) between the sample and the electrode is determined by a tensile test in the direction perpendicular to the sample surface. Strength) was measured.
- the sample was pulverized, and the precipitated crystal was identified by the diffraction X-ray spectrum, and the weight ratio (precipitation amount) of the fresnoite crystal phase was calculated from the diffraction peak intensity. Moreover, the average particle diameter of the Fresnoite crystal phase was computed with the scanning microscope and the transmission microscope. Further, the relative dielectric constant ⁇ r at 3 GHz was measured by the perturbation method.
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Abstract
Description
次に、この発明による効果を確認するために実施した実験例について説明する。
2 セラミック層
3 積層体
4,5 外部導体膜
6 内部導体膜
7 ビアホール導体
Claims (6)
- 非ガラス系の低温焼結セラミック材料を焼結してなるもので、クォーツ(Quartz)、アルミナ(Alumina)およびフレスノイト(Fresnoite)の各結晶相を析出している、低温焼結セラミック焼結体。
- さらに、サンボルナイト(Sanbornite)およびセルシアン(Celsian)のうち少なくとも一方の結晶相を析出している、請求項1に記載の低温焼結セラミック焼結体。
- 前記フレスノイト結晶相が1~20重量%の割合で含まれている、請求項1または2に記載の低温焼結セラミック焼結体。
- 前記フレスノイト結晶相の平均結晶粒径が5μm以下である、請求項1ないし3のいずれかに記載の低温焼結セラミック焼結体。
- 前記非ガラス系の低温焼結セラミック材料は、Si酸化物、Ba酸化物およびAl酸化物を含む主成分セラミック材料と、Mn酸化物およびTi酸化物を含む副成分セラミック材料と含み、実質的にCr酸化物およびB酸化物のいずれをも含まない、請求項1ないし4のいずれかに記載の低温焼結セラミック焼結体。
- 複数のセラミック層を積層してなる積層体と、前記積層体の表層および内層に設けられた、金、銀または銅を主成分とする導体パターンとを備える、多層セラミック基板であって、前記セラミック層は、非ガラス系の低温焼結セラミック材料を焼結してなるもので、クォーツ(Quartz)、アルミナ(Alumina)およびフレスノイト(Fresnoite)の各結晶相を析出している低温焼結セラミック焼結体で構成されている、多層セラミック基板。
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CN201080007906.6A CN102307825B (zh) | 2009-02-16 | 2010-02-10 | 低温烧结陶瓷烧结体及多层陶瓷基板 |
KR1020117017230A KR101241256B1 (ko) | 2009-02-16 | 2010-02-10 | 저온 소결 세라믹 소결체 및 다층 세라믹 기판 |
JP2010550531A JP4883228B2 (ja) | 2009-02-16 | 2010-02-10 | 低温焼結セラミック焼結体および多層セラミック基板 |
EP10741247.0A EP2397452B1 (en) | 2009-02-16 | 2010-02-10 | Sintered body of low temperature cofired ceramic (ltcc) and multilayer ceramic substrate |
US13/205,656 US8173565B2 (en) | 2009-02-16 | 2011-08-09 | Sintered body of low temperature cofired ceramic and multilayer ceramic substrate |
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US8361918B2 (en) * | 2007-08-17 | 2013-01-29 | Murata Manufacturing Co., Ltd. | Ceramic composition, method for producing the same, ceramic substrate and method for producing ceramic green layer |
US8383533B2 (en) * | 2009-01-07 | 2013-02-26 | Murata Manufacturing Co., Ltd. | Low-temperature sintering ceramic material and ceramic substrate |
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Publication number | Publication date |
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KR20110104533A (ko) | 2011-09-22 |
EP2397452A1 (en) | 2011-12-21 |
KR101241256B1 (ko) | 2013-03-15 |
CN102307825B (zh) | 2014-07-30 |
US8173565B2 (en) | 2012-05-08 |
EP2397452A4 (en) | 2013-05-01 |
US20110300355A1 (en) | 2011-12-08 |
JPWO2010092970A1 (ja) | 2012-08-16 |
EP2397452B1 (en) | 2017-05-17 |
JP4883228B2 (ja) | 2012-02-22 |
CN102307825A (zh) | 2012-01-04 |
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