WO2010074458A2 - 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판, 이를 이용한 용융아연도금강판, 합금화 용융아연도금강판 및 이들의 제조방법 - Google Patents
딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판, 이를 이용한 용융아연도금강판, 합금화 용융아연도금강판 및 이들의 제조방법 Download PDFInfo
- Publication number
- WO2010074458A2 WO2010074458A2 PCT/KR2009/007608 KR2009007608W WO2010074458A2 WO 2010074458 A2 WO2010074458 A2 WO 2010074458A2 KR 2009007608 W KR2009007608 W KR 2009007608W WO 2010074458 A2 WO2010074458 A2 WO 2010074458A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- steel sheet
- less
- steel
- value
- hot
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
- C21D8/0436—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
Definitions
- the present invention relates to a cold rolled steel sheet, a hot-dip galvanized steel sheet, an alloyed hot-dip galvanized steel sheet and a method for manufacturing the same that can be used in automobiles and exterior panels, more specifically, the yield ratio is 60% or more and the dent resistance and durability Cold rolled steel sheet using TRIP (TRansformation Induced Plasticity) phenomenon containing small amount of retained austenite having high tensile strength of 490MPa or more
- TRIP Treatment Induced Plasticity
- r value is an index indicating deep drawing property, and is generally expressed as plastic anisotropy and is known to have a different value for each direction.
- r value is represented by r0, r90, r45 with respect to r value in a rolling direction, a rolling perpendicular
- r (average) is expressed generally by r value.
- a method of imparting a high r value (plasticity anisotropy index) to a high strength steel sheet is a very low carbon steel to which carbon and nitride forming elements such as Ti and Nb are added, that is, Si, Mn, There is a method of adding a solid solution strengthening element such as P.
- Japanese Patent Application No. 55-10650 discloses a method of cold-rolling low carbon steel at a temperature between the recrystallization temperature and the Ac3 transformation point after cold rolling, and then tempering after heating at 700 to 800 ° C. for the production of composite tissue steel.
- this method has a problem that the manufacturing cost is increased by performing two times of continuous annealing after the annealing.
- Japanese Patent Application Laid-Open No. 55-100934 discloses a technique of performing annealing after cold rolling in order to obtain a high r value, making the temperature at this time a biphase of ferrite-austenite, and then performing continuous annealing.
- Mn is concentrated from a ferrite phase to austenite by an annealing step, and then a Mn thickened phase is preferentially changed into an austenite phase by subsequent annealing, thereby obtaining a composite structure in the cooling process, which is the next step.
- this method requires a long time annealing operation at a relatively high temperature for the concentration of Mn in the annealing process, and also because of the large number of processes, it is not only economical in terms of manufacturing cost, but also adhesion between steel sheets, generation of temper color, and furnace body. Problems such as deterioration of the life of the inner cover may occur.
- Japanese Unexamined Patent Application Publication No. 1-35900 discloses a technique for improving the r value by achieving proper carbon content and V content. That is, before recrystallization annealing, carbon in the steel is precipitated as V-based carbide to reduce the solid solution strengthening as much as possible to achieve a high r value, and thereafter, the V-based carbide is dissolved again by heating in the two-phase region of ferrite-austenite, thereby austenitic By increasing the carbon content to secure the martensite phase through cooling.
- V is very expensive, there is a problem that causes a significant increase in manufacturing cost.
- a high-strength steel sheet containing predetermined carbon and having an average r value of 1.3 or more and containing at least 3% of at least one of bainite, martensite, and austenite in the structure by obtaining a high strength steel sheet The production method is to develop a texture by forming a cold rolling ratio of 30 to 95%, followed by forming clusters and precipitates of Al and N.
- this method requires annealing and heat treatment to form a structure, respectively, to obtain a good r value after cold rolling, productivity is deteriorated.
- there is a limit to the application to the structural member due to the low yield ratio due to the nature of the metamorphic tissue steel.
- Korean Patent Laid-Open Publication No. 2006-0137001 also proposes a method for manufacturing a composite tissue sheet having a high r value.
- the yield strength is low and thus the application to the structural member is limited.
- the present invention improves the r value of the metamorphic tissue steel by solving the above problems and deriving the influences of the solute N and the solute C affecting the r value, and at the same time, the carbon and nitride elements to obtain a high yield ratio. It is to provide a high-strength cold-rolled steel sheet, a hot dip galvanized steel sheet using the same and a manufacturing method thereof having excellent deep drawing property and high yield ratio by fine control.
- the present invention is in weight%, C: 0.02 to 0.05%, Mn: 1.0 to 3.0%, Si: 0.5 to 2.0%, P: 0.05% or less, N: 0.006% or less, Al: 0.01 to 0.1%, S: 0.012 Less than or equal to Nb: 0.04 to 0.15% is added, and at least one selected from the group consisting of Ti, B and Zr is included, and these elements simultaneously satisfy the following Eq_N value of 0.001 or less and Eq_C value of 0.03 or less , The remainder is made of Fe and other unavoidable impurities, and relates to a high strength cold rolled steel sheet having excellent deep drawing property and having a high yield ratio containing 5% or less of retained austenite.
- Eq_C C-12 ⁇ (Nb / 92.9 + (Ti-47.9 / 14 ⁇ N) /47.9+ (Zr-91.2 / 14 ⁇ N) /91.2) ⁇ Ti, Zr added>
- a method of manufacturing a high strength cold rolled steel sheet having a high deep drawability and a high yield ratio comprising a.
- the present invention is excellent in dent resistance and durability with a yield ratio (YR) ratio of 60% or more, which contributes to the weight reduction of interior and exterior materials, and is suitable for molding requiring drawing characteristics by satisfying an r value of 1.4 or more.
- a high strength steel sheet having a strength of 490 MPa or more can be provided.
- 1 is a graph showing the relationship between Eq_C and r value.
- composition range of the present invention will be described in detail (hereinafter,% by weight).
- the content of carbon (C) is 0.02 to 0.05%.
- C is more preferable in terms of formation of metamorphic steel, that is, stabilization of retained austenite, but in terms of r-value, the amount of solid solution C is better. Therefore, if the C content is less than 0.02%, it is difficult to make the metamorphic tissue steel. If the content is more than 0.05%, the r value is inhibited as excessive amounts of the second phase, that is, residual austenite and martensite are formed. There is.
- Mn manganese
- the content of manganese (Mn) is 1.0 to 3.0%. Mn is added to prevent red brittleness due to the formation of FeS in which S and Fe are inevitably contained in the steel manufacturing process. If the amount is too small, red brittleness is generated, and if too large, segregation such as central segregation or micro segregation occurs. It gets worse.
- the primary goal is to construct a metamorphic tissue steel, which requires a large amount of Mn.
- Mn is required to form the second phase martensite and residual austenite, and when it is added in excess of 3.0%, not only does the increase in strength and the deterioration of formability occur due to the increase of the second phase fraction,
- a large amount of oxides such as MnO are generated on the surface of the steel sheet, thereby degrading the adhesion of the plate and a large amount of plating defects such as stripes, resulting in deterioration of product quality.
- Si silicon
- Si is an element that needs to be actively added in steel because it promotes ferrite transformation and increases the content of carbon in the unmodified austenite, thereby improving the residual austenite fraction of the final product.
- Si must be added essentially for the production of metamorphic steel containing residual austenite as in the present invention.
- the lower limit thereof is limited to 0.5%, and the cold rolling property is lowered.
- the upper limit is limited to 2.0%.
- the content of phosphorus (P) is made 0.05% or less (excluding 0).
- P is the alloy element with the largest solidification effect. It improves in-plane anisotropy and improves strength.
- P content exceeds 0.05%, P increases with strength and segregates at grain boundaries, resulting in secondary processing brittleness and Since the weldability is deteriorated, the addition amount is limited to 0.05% or less.
- the content of nitrogen (N) is to be 0.006% or less (excluding 0).
- N is known to deteriorate the formability of steel by being in solid solution before or after annealing, but in the range contained in ordinary steel (0.01% or less), N is not known to significantly affect the mechanical properties of the metamorphic steel.
- the upper limit is set to 0.006% because N is likely to decrease due to the increase in the steelmaking unit and increase in the total amount of precipitates as the amount of nitride forming element is increased. Is not limited.
- Al aluminum
- Al is added for two purposes, one to remove oxygen present in the steel to prevent the formation of non-metallic inclusions during solidification, and the other is to have a negligible effect when a nitride forming element is added as in the present invention, This is to refine the grain size by fixing nitrogen present in the steel with AlN.
- Al also needs to be added in an appropriate range, if the content of the component is too low can not achieve the purpose of the addition, when the nitride forming element for the stable control of N as in the present invention is added, if the addition amount is high Since the addition of the nitride forming element for the problem of the rise of the steelmaking raw unit, the content is limited to 0.01 ⁇ 0.1%.
- the content of sulfur (S) is to be 0.012% or less (excluding 0). Since S is an impurity that precipitates in the form of MnS to increase the amount of precipitates, it is necessary to manage the amount of S low, and the upper limit thereof is limited to 0.012%.
- Nb niobium
- the content of niobium (Nb) is 0.04 to 0.15%.
- Nb is added to lower the amount of solid solution carbon through carbide formation and to improve yield strength by strengthening precipitation.
- the residual austenite when utilized as in the present invention, it also contributes to stabilization of the residual austenite. If the content of Nb is less than 0.04%, the effect of precipitation strengthening is inadequate, and if it exceeds 0.15%, the upper limit is limited because there is a problem in that elongation of the steelmaking unit is increased and elongation of fine carbide is formed.
- the present invention includes at least one member selected from the group consisting of titanium (Ti), zirconium (Zr) and boron (B), wherein boron (B) is a nitride forming element, and according to the present invention, solid solution N It is an important important nitride forming element that improves the r value by scavenging.
- titanium (Ti) and zirconium (Zr) play an important role in securing r value by removing solid solution N and at the same time, it is an important element for making solid solution C below an appropriate amount (0.03%).
- the value of the parameter is set so that the Eq_C value is less than or equal to 0.03 or less simultaneously.
- Eq_C C-12 ⁇ (Nb / 92.9 + (Ti-47.9 / 14 ⁇ N) /47.9+ (Zr-91.2 / 14 ⁇ N) /91.2) ⁇ Ti, Zr added>
- the present invention defines the value of Eq_N defined in the above formula to be 0.001% or less.
- the effect of solute N on the r value is examined. The value was found to improve. However, since it is impossible to reduce N to less than 0.001% using only steelmaking technology, it is proposed to minimize the employment state by using nitride forming elements.
- the Eq_N value may be less than zero. This means that Ti, Zr and B all bind with N and remain redundant.
- the present invention defines that the value of Eq_C defined by the above formula is 0.03% or less.
- the value of r decreases and the value of r tends to increase as the amount of C decreases.
- C should be lowered to 0.01% or less in order to manufacture steel having a very high r value.
- bainite and residual austenite which are metamorphic structures, are very difficult to form, which makes it impossible to increase the strength.
- satisfactory r value can be obtained when controlling Eq_C to 0.03% or less when Eq_N satisfies 0.001% or less.
- antimony (Sb) may be added at 0.04% or less.
- the Sb has an advantage of improving wettability during zinc plating by suppressing surface concentration of surface oxides such as Mn and Si.
- surface oxides such as Mn and Si.
- the content is added in excess of 0.04%, the effect on the above-mentioned advantages is insignificant and the steelmaking unit is increased, so it is preferable to limit the upper limit.
- the remainder is composed of Fe and unavoidable impurities.
- the finish hot rolling temperature is limited to more than the Ar3 transformation point.
- the reason for limiting the finish hot rolling temperature above the Ar3 transformation point is to prevent the two-phase reverse rolling. This is because, when the two-phase reverse rolling is performed in the present invention, the r-value decreases due to the generation of non-uniform grain structure and the presence of modified ferrite.
- pickling is carried out in a conventional manner, and then cold rolling is performed at a rolling reduction of 63 to 90%. If the cold reduction rate is less than 63%, it is limited because it is difficult to maximize the development of the recrystallized texture during annealing, and if the cold reduction rate exceeds 90% it is limited because it causes a decrease in cold rolling property.
- annealing temperature is to secure the yield strength and r value required by the present invention steel at the same time below 780 °C there is a problem of incomplete development of ⁇ 111 ⁇ aggregate structure and decrease in elongation due to delayed recrystallization, 880 °C This is because the excessively dissolves the carbide and nitride due to the degradation of yield strength and deterioration of annealing operation.
- the hot-dip galvanized steel or hot-dip galvanized steel sheet is subjected to hot-dip galvanizing or alloying hot-dip galvanizing under normal manufacturing conditions. Manufacture.
- the reason for specifying the retained austenite to 5% or less in the present invention is that in order to secure the retained austenite of 5% or more, a large amount of C, that is, the Eq_C value must exceed 0.03, and the r value decreases.
- Cold rolled steel sheet or hot dip galvanized steel sheet, hot dip galvanized steel sheet produced by the present invention has a tensile strength of 490MPa or more and r value of 1.4 or more, yield ratio (YR) satisfies 60% or more.
- the steel ingot having Eq_N and Eq_C in Table 1 having the composition of Table 1 and having a thickness of 90 mm and a width of 175 mm was reheated at 1200 ° C. for 1 hour, and then hot rolled to have a hot rolled thickness of 4 mm. .
- the hot rolling finish temperature was above the Ar3 transformation point, and after cooling, charged into a furnace preheated to 500 ° C. to 700 ° C., and retained for 1 hour to simulate hot rolling.
- the hot rolled sheet was further cold rolled to 50 to 80% and then annealed at 750 to 860 ° C.
- the present inventors show the mechanical properties obtained after changing the coiling temperature, cold reduction rate, annealing temperature, etc., for steel grades of various component systems shown in Table 1 in Tables 2 and 3.
- the target mechanical properties of the invention steel are YR ratio of 60% or more, tensile strength of 490 MPa or more, and r value of 1.4 or more.
- Table 3 further shows the change in mechanical properties according to the change in winding temperature and annealing temperature for some steel grades in Table 2.
- the recrystallization is delayed when the annealing temperature is low while carbon and nitride forming elements are added as in the present invention, the elongation is sharply lowered when the annealing is performed at a low temperature and the moldability is deteriorated.
- the present invention is limited to an annealing condition of 780 °C or more, the tensile strength of the annealing temperature up to 860 °C Although there are some downwards, the mechanical properties meet the criteria of the invention.
- the role of the cold reduction rate is important, but in the case of Inventive Steel 3-Comparative 1 of Table 3 in which the cold reduction rate is less than 63%, the r value does not reach the target value.
- the r value limited in the present invention at the time of applying a low winding temperature does not satisfy 1.4 or more. This is attributed to the fact that carbide precipitation is suppressed when the coiling temperature is low, so that the amount of solid solution C in the hot rolled sheet increases, and the development of ⁇ 111 ⁇ aggregate tissue is suppressed during recrystallization annealing after subsequent cold rolling.
- Eq_C in Table 4 was calculated using the Eq_C parameter described above, and the relationship with the r value of this value is shown in FIG. 1.
- Eq_C As shown in FIG. 1, there is no particular correlation with the r value. In other words, when the value of Eq_C is 0.03 or more, the value of r shows a low value. When the value of Eq_C is less than 0.03, the value of r varies widely from a high value to a low value.
- an Eq_N value of 0.001 or less and an Eq_C value of 0.003% or less must be satisfied at the same time to satisfy an r value of 1.3 or more.
- Figure 3 is a photograph showing the microstructure of the inventive steel 4 residual austenite is observed.
- Si to secure the retained austenite
- an r value of 1.4 or more was added when Si was added. I am satisfied. It is believed that this is due to the further development of ferrite texture by lowering the C concentration in the ferrite by promoting the C migration to residual austenite by increasing the activity of C in the ferrite.
- the fraction of retained austenite is 2% or less.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Coating With Molten Metal (AREA)
Abstract
Description
강종 | C | Si | Mn | P | S | B | Mo | Al | Ti | Nb | Zr | N |
비교강1 | 0.0251 | 1.01 | 1.44 | 0.030 | 0.0003 | 0.254 | 0.411 | 0.041 | 0.0033 | |||
비교강2 | 0.0261 | 1.20 | 1.84 | 0.028 | 0.0002 | 0.251 | 0.425 | 0.040 | 0.0028 | |||
비교강3 | 0.0232 | 1.02 | 1.44 | 0.028 | 0.0003 | 0.004 | 0.097 | 0.0034 | ||||
비교강4 | 0.0242 | 1.15 | 1.66 | 0.029 | 0.0003 | 0.012 | 0.100 | 0.0034 | ||||
비교강5 | 0.0244 | 1.12 | 1.85 | 0.029 | 0.0003 | 0.018 | 0.098 | 0.0029 | ||||
비교강6 | 0.0249 | 1.17 | 2.06 | 0.029 | 0.0003 | 0.027 | 0.099 | 0.0029 | ||||
비교강7 | 0.0266 | 1.50 | 1.85 | 0.029 | 0.0004 | 0.029 | 0.095 | 0.0032 | ||||
발명강1 | 0.0257 | 0.91 | 1.27 | 0.030 | 0.0032 | 0.038 | 0.016 | 0.098 | 0.0022 | |||
발명강2 | 0.0257 | 0.91 | 1.45 | 0.030 | 0.0032 | 0.036 | 0.017 | 0.099 | 0.0023 | |||
발명강3 | 0.0258 | 0.93 | 1.63 | 0.030 | 0.0031 | 0.037 | 0.016 | 0.099 | 0.0025 | |||
발명강4 | 0.0261 | 0.93 | 1.82 | 0.031 | 0.0031 | 0.034 | 0.017 | 0.101 | 0.0026 | |||
발명강5 | 0.0257 | 0.93 | 2.00 | 0.029 | 0.0029 | 0.039 | 0.016 | 0.098 | 0.0023 | |||
발명강6 | 0.0261 | 0.93 | 2.18 | 0.030 | 0.0028 | 0.036 | 0.017 | 0.101 | 0.0026 | |||
발명강7 | 0.0289 | 0.94 | 1.81 | 0.031 | 0.0027 | 0.037 | 0.017 | 0.042 | 0.0025 | |||
발명강8 | 0.0289 | 0.95 | 1.81 | 0.032 | 0.0026 | 0.036 | 0.017 | 0.063 | 0.0026 | |||
발명강9 | 0.0336 | 0.94 | 1.81 | 0.032 | 0.0026 | 0.044 | 0.017 | 0.081 | 0.0025 | |||
발명강10 | 0.0266 | 1.17 | 1.79 | 0.032 | 0.0026 | 0.050 | 0.017 | 0.120 | 0.0026 | |||
비교강8 | 0.0253 | 0.10 | 0.030 | 0.0032 | 0.039 | 0.015 | 0.037 | 0.0010 | ||||
비교강9 | 0.0245 | 0.09 | 0.029 | 0.0027 | 0.042 | 0.015 | 0.095 | 0.0011 | ||||
비교강10 | 0.0253 | 0.11 | 0.030 | 0.0028 | 0.048 | 0.015 | 0.134 | 0.0015 | ||||
비교강11 | 0.0770 | 0.94 | 1.79 | 0.028 | 0.0024 | 0.038 | 0.017 | 0.099 | 0.0024 | |||
발명강11 | 0.0451 | 0.91 | 1.76 | 0.028 | 0.0023 | 0.032 | 0.016 | 0.156 | 0.0026 | |||
비교강12 | 0.0752 | 0.91 | 1.76 | 0.029 | 0.0023 | 0.029 | 0.017 | 0.276 | 0.0025 | |||
비교강13 | 0.0239 | 0.11 | 0.027 | 0.0019 | 0.038 | 0.036 | 0.0018 | |||||
발명강12 | 0.0305 | 0.93 | 1.82 | 0.026 | 0.0019 | 0.0020 | 0.040 | 0.033 | 0.0017 | |||
발명강13 | 0.0293 | 0.95 | 2.03 | 0.031 | 0.0007 | 0.0018 | 0.045 | 0.094 | 0.0030 | |||
비교강14 | 0.0305 | 0.11 | 0.030 | 0.0020 | 0.054 | 0.094 | 0.021 | 0.0030 | ||||
비교강15 | 0.0267 | 0.11 | 0.030 | 0.0018 | 0.054 | 0.094 | 0.017 | 0.0030 | ||||
비교강16 | 0.0261 | 0.29 | 1.79 | 0.028 | 0.0023 | 0.041 | 0.017 | 0.084 | 0.0028 | |||
발명강14 | 0.0272 | 0.57 | 1.79 | 0.029 | 0.0025 | 0.041 | 0.017 | 0.084 | 0.0027 | |||
발명강15 | 0.0263 | 0.94 | 1.80 | 0.028 | 0.0025 | 0.043 | 0.017 | 0.083 | 0.0029 | |||
발명강16 | 0.0266 | 0.58 | 1.80 | 0.028 | 0.0024 | 0.047 | 0.084 | 0.020 | 0.0024 | |||
발명강17 | 0.0251 | 0.92 | 1.80 | 0.021 | 0.0041 | 0.059 | 0.011 | 0.083 | 0.014 | 0.0031 | ||
발명강18 | 0.0263 | 1.49 | 2.52 | 0.028 | 0.0028 | 0.039 | 0.022 | 0.095 | 0.0030 |
강종 | 권취온도(℃) | 냉간압하율(%) | 소둔온도(℃) | 항복강도(MPa) | 인장강도(MPa) | 연신율(%) | r값 | YR(%) |
비교강1 | 700 | 80 | 820 | 472.2 | 548.9 | 26.88 | 1.140 | 86 |
비교강2 | 700 | 80 | 820 | 479.0 | 582.8 | 29.23 | 1.099 | 82 |
비교강3 | 700 | 80 | 820 | 505.8 | 563.4 | 23.60 | 1.132 | 90 |
비교강4 | 700 | 80 | 820 | 461.0 | 541.3 | 28.18 | 1.111 | 85 |
비교강5 | 700 | 80 | 820 | 494.3 | 576.5 | 24.72 | 1.167 | 86 |
비교강6 | 700 | 80 | 820 | 472.2 | 584.9 | 26.44 | 1.116 | 81 |
비교강7 | 700 | 80 | 820 | 517.4 | 598.9 | 25.72 | 1.105 | 86 |
발명강1 | 700 | 80 | 820 | 479.5 | 549.2 | 25.13 | 1.715 | 87 |
발명강2 | 700 | 80 | 820 | 480.3 | 554.3 | 23.12 | 1.609 | 87 |
발명강3 | 700 | 80 | 820 | 487.1 | 562.1 | 22.54 | 1.603 | 87 |
발명강4 | 700 | 80 | 820 | 476.9 | 562.7 | 22.83 | 1.682 | 85 |
발명강5 | 700 | 80 | 820 | 456.4 | 560.8 | 25.78 | 1.517 | 81 |
발명강6 | 700 | 80 | 820 | 440.6 | 571.7 | 26.07 | 1.403 | 77 |
발명강7 | 700 | 80 | 820 | 443.3 | 544.3 | 26.33 | 1.472 | 81 |
발명강8 | 700 | 80 | 820 | 452.3 | 545.9 | 24.27 | 1.511 | 83 |
발명강9 | 700 | 80 | 820 | 465.3 | 551.7 | 24.15 | 1.651 | 84 |
발명강10 | 700 | 80 | 820 | 442.9 | 544.9 | 22.99 | 1.634 | 81 |
비교강8 | 700 | 80 | 820 | 354.6 | 377.5 | 32.69 | 1.392 | 94 |
비교강9 | 700 | 80 | 820 | 339.4 | 384.1 | 31.14 | 1.467 | 88 |
비교강10 | 700 | 80 | 820 | 312.3 | 379.4 | 33.94 | 1.463 | 82 |
비교강11 | 700 | 80 | 820 | 519.2 | 652.0 | 21.26 | 0.964 | 80 |
발명강11 | 700 | 80 | 820 | 468.1 | 572.0 | 22.76 | 1.489 | 82 |
비교강12 | 700 | 80 | 820 | 481.2 | 602.6 | 22.67 | 1.139 | 80 |
비교강13 | 700 | 80 | 820 | 334.5 | 378.7 | 36.28 | 1.183 | 88 |
발명강12 | 700 | 80 | 820 | 466.4 | 565.5 | 24.96 | 1.452 | 82 |
발명강13 | 700 | 80 | 820 | 487.8 | 561.5 | 26.93 | 1.496 | 87 |
비교강14 | 700 | 80 | 820 | 355.6 | 399.8 | 32.91 | 1.361 | 89 |
비교강15 | 700 | 80 | 820 | 355.4 | 400.0 | 32.55 | 1.491 | 89 |
비교강16 | 630 | 75 | 820 | 446.1 | 505.4 | 25.41 | 1.334 | 88 |
발명강14 | 630 | 75 | 820 | 454.2 | 524.7 | 26.92 | 1.441 | 87 |
발명강15 | 630 | 75 | 820 | 485.3 | 559.4 | 25.84 | 1.472 | 87 |
발명강16 | 630 | 75 | 820 | 465.6 | 536.4 | 25.76 | 1.483 | 87 |
발명강17 | 630 | 75 | 820 | 493.1 | 562.3 | 25.21 | 1.561 | 88 |
발명강18 | 650 | 75 | 860 | 388.8 | 619.5 | 26.27 | 1.446 | 63 |
구분 | 권취온도(℃) | 냉간압하율(%) | 소둔온도(℃) | 항복강도(MPa) | 인장강도(MPa) | 연신율(%) | r값 | YR(%) |
발명강3-발명 | 700 | 80 | 820 | 487.1 | 562.1 | 22.54 | 1.603 | 87 |
발명강3-비교1 | 700 | 60 | 820 | 463.3 | 543.3 | 23.2 | 1.141 | 85 |
발명강3-비교2 | 500 | 80 | 820 | 465.2 | 565.7 | 23.12 | 1.121 | 82 |
발명강8-발명 | 700 | 80 | 820 | 452.3 | 545.9 | 24.27 | 1.511 | 83 |
발명강8-비교 | 500 | 80 | 820 | 443.1 | 551.3 | 23.54 | 1.161 | 80 |
발명강14-비교 | 630 | 75 | 750 | 531.3 | 584.6 | 16.31 | 1.423 | 91 |
발명강14-발명 | 630 | 75 | 780 | 484.1 | 551.3 | 21.61 | 1.492 | 88 |
발명강14-발명 | 630 | 75 | 800 | 483.6 | 551.8 | 25.42 | 1.454 | 88 |
발명강14-발명 | 630 | 75 | 820 | 454.2 | 524.7 | 26.92 | 1.441 | 87 |
발명강14-발명 | 630 | 75 | 840 | 441.2 | 514.4 | 28.13 | 1.493 | 86 |
발명강18-발명 | 650 | 75 | 860 | 388.8 | 619.5 | 26.27 | 1.446 | 63 |
발명강18-발명 | 650 | 65 | 860 | 379.4 | 608.1 | 27.66 | 1.422 | 62 |
발명강18-비교 | 650 | 50 | 860 | 375.0 | 602.4 | 26.26 | 1.311 | 62 |
강종 | Solute N | Solute C |
비교강1 | 0.0033 | 0.0198 |
비교강2 | 0.0028 | 0.0209 |
비교강3 | 0.0034 | 0.0107 |
비교강4 | 0.0034 | 0.0113 |
비교강5 | 0.0029 | 0.0117 |
비교강6 | 0.0029 | 0.0121 |
비교강7 | 0.0032 | 0.0143 |
발명강1 | -0.0026 | 0.0108 |
발명강2 | -0.0025 | 0.0107 |
발명강3 | -0.0023 | 0.0110 |
발명강4 | -0.0023 | 0.0112 |
발명강5 | -0.0025 | 0.0110 |
발명강6 | -0.0023 | 0.0111 |
발명강7 | -0.0024 | 0.0215 |
발명강8 | -0.0023 | 0.0188 |
발명강9 | -0.0024 | 0.0210 |
발명강10 | -0.0023 | 0.0092 |
비교강8 | -0.0032 | 0.0177 |
비교강9 | -0.0032 | 0.0095 |
비교강10 | -0.0029 | 0.0055 |
비교강11 | -0.0025 | 0.0621 |
발명강11 | -0.0021 | 0.0232 |
비교강12 | -0.0024 | 0.0374 |
비교강13 | 0.0018 | 0.0193 |
발명강12 | -0.0009 | 0.0178 |
발명강13 | 0.0006 | 0.0172 |
비교강14 | -0.0003 | 0.0182 |
비교강15 | 0.0004 | 0.0149 |
비교강16 | -0.0022 | 0.0134 |
발명강14 | -0.0023 | 0.0144 |
발명강15 | -0.0021 | 0.0138 |
발명강16 | -0.0007 | 0.0152 |
발명강17 | -0.0023 | 0.0151 |
발명강18 | -0.0035 | 0.0140 |
Claims (9)
- 중량%로, C: 0.02 ~ 0.05%, Mn: 1.0~3.0%, Si: 0.5~2.0%, P: 0.05%이하, N: 0.006%이하, Al: 0.01~0.1%, S: 0.012%이하, Nb: 0.04 ~ 0.15%가 첨가되고, Ti, B 및 Zr로 이루어진 그룹에서 선택된 1종 이상이 포함되며, 이 원소들은 아래의 Eq_N 값이 0.001 이하이고 Eq_C값이 0.03 이하를 동시에 만족하며, 나머지는 Fe 및 기타 불가피한 불순물로 이루어지고, 잔류 오스테나이트의 분율이 5%이하를 함유한 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판.Eq_N = N - 14 × (Ti/47.9 + Zr/91.2 + B/10.8)Eq_C = C - 12/92.9 × Nb <Ti, Zr 미첨가>Eq_C = C - 12 × (Nb/92.9 + (Ti - 47.9/14 ×N)/47.9+ (Zr - 91.2/14 × N)/91.2) <Ti, Zr 첨가>(여기서 Ti - 47.9/14 ×N < 0 인 경우에, Ti - 47.9/14 ×N = 0 으로 간주하며, Zr - 91.2/14 × N < 0 인 경우에, Zr - 91.2/14 × N = 0 으로 간주함)
- 제 1 항에 있어서,상기 조성에 추가적으로 Sb: 0.03%이하를 포함하는 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판.
- 제 1 항에 있어서, 상기 냉연강판은 인장강도 490MPa이상이고, r(소성이방성지수)값이 1.4이상이며, 항복비가 60%이상인 것을 특징으로 하는 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판.
- 제 1 항 내지 제 3 항 중 어느 한 항에 기재된 상기 냉연강판에 용융아연도금층을 포함하는 것을 특징으로 하는 딥드로잉성이 우수하고 고항복비를 갖는 고강도 용융아연도금강판.
- 제 4 항에 기재된 상기 아연도금강판을 열처리함으로써 합금화 아연도금층을 포함하는 것을 특징으로 하는 딥드로잉성이 우수하고 고항복비를 갖는 고강도 합금화 용융아연도금강판.
- 중량%로, C: 0.02~0.05%, Mn: 1.0~3.0%, Si: 0.5~2.0%, P: 0.05%이하, N: 0.006%이하, Al: 0.01~0.1%, S: 0.012%이하, Nb: 0.04~0.15%가 첨가되고, Ti, B 및 Zr로 이루어진 그룹에서 선택된 1종 이상이 포함되며, 이 원소들은 아래의 Eq_N 값이 0.001 이하이고 Eq_C값이 0.03 이하를 동시에 만족하며, 나머지는 Fe 및 기타 불가피한 불순물로 이루어지는 강 슬라브를 재가열하고 Ar3 변태점 이상의 온도에서 마무리 열간압연하는 단계;상기 열간압연한 열연강판을 냉각하고 600~750℃의 온도범위에서 권취하는 단계;상기 권취된 열연강판을 63~90%의 압하율로 냉간압연하는 단계; 및상기 냉간압연된 냉연강판을 780~880℃의 온도범위에서 연속소둔하는 단계를 포함하는 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판의 제조방법.Eq_N = N - 14 × (Ti/47.9 + Zr/91.2 + B/10.8)Eq_C = C - 12/92.9 × Nb <Ti, Zr 미첨가>Eq_C = C - 12 × (Nb/92.9 + (Ti - 47.9/14 ×N)/47.9+ (Zr - 91.2/14 × N)/91.2) <Ti, Zr 첨가>(여기서 Ti - 47.9/14 ×N < 0 인 경우에, Ti - 47.9/14 ×N = 0 으로 간주하며, Zr - 91.2/14 × N < 0 인 경우에, Zr - 91.2/14 × N = 0 으로 간주함)
- 제 6 항에 있어서,상기 조성에 추가적으로 Sb: 0.03%이하를 포함하는 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판의 제조방법.
- 제 6 항 또는 제 7 항에 기재된 방법에 의하여 제조된 냉연강판에 용융아연도금하여 용융아연도금층을 형성하는 단계를 포함하는 딥드로잉성이 우수하고 고항복비를 갖는 고강도 용융아연도금강판의 제조방법.
- 제 8 항에 기재된 방법에 의하여 제조된 용융아연도금강판에 열처리하여 합금화 용융아연도금층을 형성하는 단계를 포함하는 딥드로잉성이 우수하고 고항복비를 갖는 고강도 합금화 용융아연도금강판의 제조방법.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011543421A JP5764498B2 (ja) | 2008-12-24 | 2009-12-18 | 深絞り性に優れ高降伏比を有する高強度冷延鋼板、これを用いた溶融亜鉛メッキ鋼板、合金化溶融亜鉛メッキ鋼板及びこれらの製造方法 |
CN2009801560489A CN102301022B (zh) | 2008-12-24 | 2009-12-18 | 深拉性优异且具有高屈强比的高强度冷轧钢板,使用其的镀锌钢板、合金化镀锌钢板,及其制造方法 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2008-0133565 | 2008-12-24 | ||
KR20080133565 | 2008-12-24 | ||
KR1020090120367A KR101153485B1 (ko) | 2008-12-24 | 2009-12-07 | 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판, 이를 이용한 용융아연도금강판, 합금화 용융아연도금강판 및 이들의 제조방법 |
KR10-2009-0120367 | 2009-12-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010074458A2 true WO2010074458A2 (ko) | 2010-07-01 |
WO2010074458A3 WO2010074458A3 (ko) | 2010-08-26 |
Family
ID=42288260
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2009/007608 WO2010074458A2 (ko) | 2008-12-24 | 2009-12-18 | 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판, 이를 이용한 용융아연도금강판, 합금화 용융아연도금강판 및 이들의 제조방법 |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2010074458A2 (ko) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011219855A (ja) * | 2010-03-24 | 2011-11-04 | Jfe Steel Corp | 深絞り性に優れた高強度冷延鋼板およびその製造方法 |
CN102816975A (zh) * | 2012-09-04 | 2012-12-12 | 北京科技大学 | 一种高r值高强IF钢生产工艺 |
EP2767604A4 (en) * | 2011-10-13 | 2016-02-17 | Jfe Steel Corp | HIGH-RESISTANT COLD-ROLLED STEEL PLATE WITH EXCELLENT DEEP-DRAWN CAPACITY AND MATERIAL UNIFORMITY ON COIL AS WELL AS MANUFACTURING METHOD THEREFOR |
CN114836690A (zh) * | 2022-04-28 | 2022-08-02 | 鞍钢股份有限公司 | 一种均匀延伸率优良的无间隙原子冷轧钢板及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20040027981A (ko) * | 2001-08-24 | 2004-04-01 | 신닛뽄세이테쯔 카부시키카이샤 | 가공성이 우수한 강판 및 제조 방법 |
JP2007197748A (ja) * | 2006-01-25 | 2007-08-09 | Jfe Steel Kk | 深絞り用高強度複合組織型冷延鋼板の製造方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11286747A (ja) * | 1998-04-01 | 1999-10-19 | Kawasaki Steel Corp | 塗装焼付硬化型深絞り用冷延鋼板およびその製造方法 |
-
2009
- 2009-12-18 WO PCT/KR2009/007608 patent/WO2010074458A2/ko active Application Filing
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20040027981A (ko) * | 2001-08-24 | 2004-04-01 | 신닛뽄세이테쯔 카부시키카이샤 | 가공성이 우수한 강판 및 제조 방법 |
JP2007197748A (ja) * | 2006-01-25 | 2007-08-09 | Jfe Steel Kk | 深絞り用高強度複合組織型冷延鋼板の製造方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011219855A (ja) * | 2010-03-24 | 2011-11-04 | Jfe Steel Corp | 深絞り性に優れた高強度冷延鋼板およびその製造方法 |
EP2767604A4 (en) * | 2011-10-13 | 2016-02-17 | Jfe Steel Corp | HIGH-RESISTANT COLD-ROLLED STEEL PLATE WITH EXCELLENT DEEP-DRAWN CAPACITY AND MATERIAL UNIFORMITY ON COIL AS WELL AS MANUFACTURING METHOD THEREFOR |
US9297052B2 (en) | 2011-10-13 | 2016-03-29 | Jfe Steel Corporation | High strength cold rolled steel sheet with excellent deep drawability and material uniformity in coil and method for manufacturing the same |
CN102816975A (zh) * | 2012-09-04 | 2012-12-12 | 北京科技大学 | 一种高r值高强IF钢生产工艺 |
CN114836690A (zh) * | 2022-04-28 | 2022-08-02 | 鞍钢股份有限公司 | 一种均匀延伸率优良的无间隙原子冷轧钢板及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2010074458A3 (ko) | 2010-08-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2020130560A1 (ko) | 가공성이 우수한 냉연강판, 용융아연도금강판 및 이들의 제조방법 | |
KR100711475B1 (ko) | 용융아연도금특성이 우수한 고 가공성 고강도 강판의제조방법 | |
WO2012081871A2 (ko) | 항복비 및 연성이 우수한 오스테나이트계 경량 고강도 강판 및 그의 제조방법 | |
WO2009145563A2 (ko) | 열처리성이 우수한 초고강도 열간성형 가공용 강판, 열처리 경화형 부재 및 이들의 제조방법 | |
WO2020130666A1 (ko) | 열간성형 후 충격특성이 우수한 열간성형용 도금강판, 열간성형 부재 및 이들의 제조방법 | |
KR20130055021A (ko) | 딥 드로잉성 및 베이킹 경화성이 우수한 고강도 냉연 강판과 그 제조 방법 | |
KR20110119285A (ko) | 고강도 냉연강판, 아연도금강판 및 이들의 제조방법 | |
WO2010074370A1 (ko) | 고강도 고연신 강판 및 열연강판, 냉연강판, 아연도금강판 및 아연도금합금화강판의 제조방법 | |
WO2016105115A1 (ko) | 표면품질, 도금밀착성 및 성형성이 우수한 고강도 용융아연도금강판 및 그 제조방법 | |
WO2011105652A1 (ko) | 도금성이 우수한 고강도 강판 및 그 제조 방법 | |
WO2017222159A1 (ko) | 가공성이 우수한 고강도 냉연강판 및 그 제조 방법 | |
WO2021100995A1 (ko) | 고강도 및 고성형성을 가지는 강판 및 그 제조방법 | |
KR101153485B1 (ko) | 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판, 이를 이용한 용융아연도금강판, 합금화 용융아연도금강판 및 이들의 제조방법 | |
KR102200227B1 (ko) | 가공성이 우수한 냉연강판, 용융아연 도금강판 및 그 제조방법 | |
WO2010074458A2 (ko) | 딥드로잉성이 우수하고 고항복비를 갖는 고강도 냉연강판, 이를 이용한 용융아연도금강판, 합금화 용융아연도금강판 및 이들의 제조방법 | |
WO2017051998A1 (ko) | 도금 강판 및 이의 제조방법 | |
WO2016182098A1 (ko) | 굽힘 가공성이 우수한 초고강도 열연강판 및 그 제조 방법 | |
WO2013154254A1 (ko) | 재질 균일성이 우수한 고탄소 열연강판 및 이의 제조방법 | |
WO2011081236A1 (ko) | 열간 프레스 가공성이 우수한 열처리 강화형 강판 및 그 제조방법 | |
WO2022124609A1 (ko) | 연성 및 성형성이 우수한 고강도 용융아연도금강판 및 그 제조방법 | |
WO2014038759A1 (en) | Ferritic lightweight high-strength steel sheet having excelent stiffness and ductility, and method of manufacturing the same | |
WO2020130257A1 (ko) | 연성 및 가공성이 우수한 고강도 강판 및 그 제조방법 | |
WO2009157661A9 (ko) | 표면특성 및 내2차 가공취성이 우수한 소부경화강 및 그 제조방법 | |
WO2023075287A1 (ko) | 페라이트계 스테인리스강 및 그 제조방법 | |
WO2024071522A1 (ko) | 초고강도 강판 및 그 제조방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200980156048.9 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09835224 Country of ref document: EP Kind code of ref document: A2 |
|
ENP | Entry into the national phase |
Ref document number: 2011543421 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 09835224 Country of ref document: EP Kind code of ref document: A2 |