WO2010074370A1 - 고강도 고연신 강판 및 열연강판, 냉연강판, 아연도금강판 및 아연도금합금화강판의 제조방법 - Google Patents
고강도 고연신 강판 및 열연강판, 냉연강판, 아연도금강판 및 아연도금합금화강판의 제조방법 Download PDFInfo
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- WO2010074370A1 WO2010074370A1 PCT/KR2009/002098 KR2009002098W WO2010074370A1 WO 2010074370 A1 WO2010074370 A1 WO 2010074370A1 KR 2009002098 W KR2009002098 W KR 2009002098W WO 2010074370 A1 WO2010074370 A1 WO 2010074370A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
Definitions
- the present invention relates to a steel sheet and a method for manufacturing the same that can be used for the inner plate and structural members of automobiles, and more particularly, to a method for manufacturing high strength, high stretched steel sheet and hot rolled steel sheet, cold rolled steel sheet, galvanized steel sheet and galvanized alloy steel sheet. It is about.
- the steel of a certain component is homogenized and then air-cooled, and the steel is heated again and then transformed to constant temperature to have at least 50% of bainite tissue or at least 65% of bainite tissue, and the rest of the tissue is retained in austenite.
- Korean Patent 2007-0126202 proposes a method of obtaining a tensile strength of at least 1000MPa and an elongation of at least 10% by austenitizing a steel material consisting of a certain component and then performing constant temperature transformation at a temperature between directly below Bs temperature and Bs-100 ° C.
- the manufacturing cost is very expensive and limited to the hot rolled steel sheet by the addition of expensive alloy elements such as Cr, Ni, Mo.
- the present invention is to solve the above problems, to control the component of the steel and the lath width of bainite and residual austenite to provide a high strength, high elongation steel sheet, and another object of the present invention is to To provide a method for manufacturing high-stretched hot rolled steel sheet, cold rolled steel sheet, galvanized steel sheet and galvanized alloyed steel sheet.
- One embodiment of the present invention by weight C: 0.5 ⁇ 1.0%, Mn: 0.01 ⁇ 2.0%, Si: 1.0 ⁇ 2.0%, Al: 0.01 ⁇ 2.0%, S: 0.012% or less, balance Fe and other unavoidable
- the steel plate which contains an impurity the internal structure consists of bainite and residual austenite, the average lath width of bainite: 0.3 micrometer or less, and the average lath width of residual austenite: 0.3 micrometer or less.
- the steel sheet may have a yield strength of 700 MPa or more, a tensile strength of 980 MPa or more, and an elongation of 20% or more.
- the steel sheet may further include one or two of 0.5% or less of Mo and 1.0% or less of Cr in weight%.
- the steel sheet may further include 0.005% or less of B and 0.06% or less of Ti in weight%.
- the present invention relates to a method for manufacturing a high strength hot drawn hot rolled steel sheet including hot rolling a slab containing other unavoidable impurities to finish hot rolling at an Ar3 transformation point or higher, and winding in a range of Ms (martensite transformation start temperature) to 450 ° C. .
- C 0.5 ⁇ 1.0%, Mn: 0.01 ⁇ 2.0%, Si: 1.0 ⁇ 2.0%, Al: 0.01 ⁇ 1.0%, S: 0.012% or less, balance Fe and Hot rolling step of hot rolling the steel containing other unavoidable impurities to finish the hot rolling at the Ar3 transformation point or more, winding step of winding the hot rolled hot rolled steel sheet below 650 ° C, and cold rolling the hot rolled steel sheet Ac3 After annealing at a temperature or higher, and the aging treatment step of overaging the cold rolled steel sheet in the range of Ms (Martensitic transformation start temperature) to 450 ° C.
- Ms Martensitic transformation start temperature
- C 0.5 ⁇ 1.0%, Mn: 0.01 ⁇ 2.0%, Si: 1.0 ⁇ 2.0%, Al: 0.01 ⁇ 1.0%, S: 0.012% or less, balance Fe and
- the aging treatment step of overaging the cold rolled steel sheet in the range of Ms (Martensitic transformation start temperature) to 450 ° C. and the cold rolled steel sheet subjected to the aging treatment through a plating bath are coated on a plated layer. It relates to a method of manufacturing a high strength high-strength galvanized steel sheet comprising forming a.
- C 0.5 ⁇ 1.0%
- Mn 0.01 ⁇ 2.0%
- Si 0.01 ⁇ 2.0%
- Al 0.01 ⁇ 1.0%
- S 0.012% or less
- balance Fe balance Fe
- the step of cooling After annealing above the temperature, the step of cooling, the aging treatment step of overaging the cold rolled steel sheet in the range of Ms (Martensitic transformation start temperature) ⁇ 450 ° C, and the plated layer on the surface of the steel sheet by passing the aged cold rolled steel sheet through a plating bath It relates to a method of manufacturing a high strength high-strength galvanized alloy steel sheet comprising the step of forming a galvanized alloyed steel sheet by the step of alloying heat-treated galvanized steel sheet formed with the plating layer.
- Ms Martensitic transformation start temperature
- the present invention provides a steel sheet having a yield strength of 700MPa or more, a tensile strength of 980MPa or more, an elongation of 20% or more, a hot rolled steel sheet, a cold rolled steel sheet, a galvanized steel sheet, and a galvanized alloy steel sheet, which may contribute to the weight reduction of the automobile steel sheet and the improvement of the collision stability.
- Figure 1 is a microstructure photograph of Inventive Example 13 according to the present invention
- Figure 1 (B) is an enlarged photograph of Figure 1 (A);
- Figure 2 is a microstructure photograph of Comparative Example 18, Figure 2 (B) is an enlarged photograph of Figure 2 (A).
- the content of C is less than 0.5% by weight, it is possible to secure the strength, but it may be difficult to secure an elongation of 20% or more due to the inferior stability of the stable residual austenite.
- the content of C exceeds 1.0% by weight, the physical properties may be deteriorated due to the retardation of bainite transformation significantly and the production of pearlite. Therefore, the content of C is preferably limited to 0.5 to 1.0% by weight.
- Mn is added to prevent redness brittleness due to the formation of FeS in which S and Fe are inevitably contained during the manufacturing process of steel. If the content of Mn is less than 0.01% by weight, the content of Mn may be too small to cause redness brittleness. . On the other hand, when the Mn content exceeds 2.0% by weight, the bainite transformation rate may be slowed to inhibit productivity of the annealing process. Therefore, the content of Mn is preferably limited to 0.01 to 2.0% by weight.
- Si is an element that requires active addition in steel as it promotes ferrite transformation and increases the content of C in untransformed austenite to improve the residual austenite fraction of the final product.
- Si must be added as essential for the formation of the metamorphic tissue steel containing residual austenite as in the present invention.
- the content of Si is less than 1.0% by weight, the stabilization effect of the residual austenite may not be large.
- the content of Si exceeds 2.0% by weight, the rolling property may be degraded, such as cracks during hot rolling and cold rolling. Therefore, the content of Si is preferably limited to 1.0 to 2.0% by weight.
- Al is added for two purposes, one of which removes the oxygen present in the steel to prevent the formation of non-metallic inclusions during solidification, and the other is austenite of C to stabilize residual austenite as in the present invention. This is to promote the spread of.
- the content of Al is less than 0.01% by weight can not achieve the purpose of the addition, if the content of more than 2.0% by weight can be a problem of the increase in the steelmaking raw unit. Therefore, the content of Al is preferably limited to 0.01 to 2.0% by weight.
- the upper limit is preferably limited to 1.0% by weight.
- the S is limited to less than 0.012% by weight because it is necessary to manage the amount of S low because it causes a problem of red brittle due to FeS formation.
- the lower limit was not limited because the lower the amount of S, for the same reason as described above, is advantageous.
- Mo and Cr are components which are selectively added as needed.
- the Mo is added to suppress the production of the pearlite phase, but when it exceeds 0.5% by weight, the production cost rises rapidly due to the expensive Mo. Therefore, the content of Mo is preferably limited to the range of 0.5% by weight or less.
- the Cr may be added to suppress ferrite production and promote bainite transformation, and when it exceeds 1.0 wt%, the amount of solid solution C may be reduced by promoting the formation of Cr carbide. Therefore, the content of Cr is preferably limited to the range of 1.0% by weight or less.
- B and Ti may be selectively added as needed, and in order to maximize the effect of B, Ti may be added at the same time to suppress the binding of N and B present as impurities.
- the B is additionally added to suppress the ferrite production, when the Fe exceeds 0.005% by weight Fe 23 (C, B) 6 compound production is promoted can be rather promoted ferrite production. Therefore, the content of B is preferably limited to the range of 0.005% by weight or less.
- the content of Ti exceeds 0.06% by weight, even if N (usually present as an impurity at a concentration of 0.01% or less) is sufficiently removed, a large amount of excess Ti remains and there is a problem of bonding with C. Therefore, the content of Ti is preferably limited to the range of 0.06% by weight or less.
- the internal structure is composed of bainite and residual austenite, and the bainite is a structure without polygonal ferrite of equiaxed crystal, and bainite without carbide is preferable.
- the microstructure of the TRIP steel should contain residual austenite, and technically it means a steel in which residual austenite plays a substantial role in ductility improvement by containing a fraction exceeding 0%. Therefore, as an embodiment of the present invention, in the case of TRIP steel, the microstructure has a residual austenite fraction of more than 0% and the balance is bainite. However, the microstructure of the present invention has a residual austenite fraction in the range of 10 to 40%, the balance is more preferably bainite. If the residual austenite fraction is less than 10%, the level is generally similar to that of the known TRIP steel, and if it exceeds 40%, the stability of the retained austenite is degraded.
- the average lath width of bainite and residual austenite is respectively limited to 0.3 ⁇ m or less. If the average width is less than 0.3 ⁇ m microstructure is difficult to secure strength. Therefore, the average lath width of the bainite and residual austenite is preferably limited to 0.3 ⁇ m or less.
- the steel sheet has a yield strength of 700 MPa or more, a tensile strength of 980 MPa or more, and an elongation of 20% or more. If the yield strength is less than 700 MPa, it is not suitable for use as a structural member of a vehicle, and the case where the tensile strength is 980 MPa or more is called ultra high strength steel. In addition, when the elongation is 20% or more, the elongation becomes a certain level, which can be expected to improve the workability.
- the steel sheet is one of a hot rolled steel sheet, a cold rolled steel sheet, a galvanized steel sheet and a galvanized alloy steel sheet.
- the slab according to the method for producing a hot rolled steel sheet according to the present invention is reheated by a conventional method to perform hot rolling.
- hot rolling is finished at an Ar3 transformation point or more, and wound in a range of Ms (Martensitic transformation start temperature) to 450 ° C.
- the limit of the finish temperature of hot rolling to Ar3 transformation point or more is to prevent abnormal reverse rolling. If it is less than the Ar3 transformation point, abnormal reverse rolling may occur, resulting in uneven grain structure. Therefore, it is preferable to limit the finishing temperature of hot rolling to more than Ar3 transformation point.
- the coiling temperature is preferably limited to the range of Ms ⁇ 450 °C.
- the limit of the finish temperature of hot rolling to Ar3 transformation point or more is to prevent abnormal reverse rolling. If it is less than the Ar3 transformation point, abnormal reverse rolling may occur, resulting in uneven grain structure. Therefore, it is preferable to limit the finishing temperature of hot rolling to more than Ar3 transformation point.
- the coiling temperature exceeds 650 °C surface decarburization can occur very severely.
- the lower limit is not limited because the microstructure before cold rolling does not have a significant effect on the final structure because the new structure is realized by annealing after cold rolling.
- the aging treatment temperature is preferably limited to the range of Ms ⁇ 450 °C.
- the cold rolled steel sheet may be passed through a plating bath to manufacture a galvanized steel sheet, and the galvanized steel sheet may be alloyed with heat to produce a galvanized alloyed steel sheet.
- a steel ingot having a component system shown in Table 1 below was manufactured to a thickness of 90 mm and a width of 175 mm, and reheated at 1200 ° C. for 1 hour, and then hot rolled to have a hot roll thickness of 3 mm. Some were used as samples of hot-rolled steel sheets, and others were samples for cold-rolled steel sheets, which were subjected to annealing heat treatment after cold rolling.
- the hot rolling finish temperature of the sample for hot rolled steel sheet was above the Ar3 transformation point, and after cooling, it was charged into a furnace preheated to 400 ° C. and maintained for 1 hour, followed by cooling by hot rolling.
- the cold rolled steel sample was loaded into a furnace preheated to 600 ° C. and held for 1 hour, followed by hot rolling.
- the hot rolled sheet was cold rolled to 60% to 1.2 mm. After making annealing at 840 ⁇ 900 °C and bainite transformation at 400 °C.
- the steel grades of the component systems shown in Table 1 were measured at 400 and 600 ° C., and then the yield strength, tensile strength, and elongation of the hot rolled steel sheets were measured, and the results are shown in Table 2 below. After annealing and annealing and aging treatment, the yield strength, tensile strength and elongation of the cold rolled steel sheet were measured and the results are shown in Table 3 below.
- Inventive Examples 9 to 17 were subjected to austenitic single-phase heat treatment at 840 ⁇ 900 °C, yield strength is 700MPa or more, tensile strength is 980MPa or more, elongation is 20% or more have.
- Figure 1 is a microstructure photograph of Inventive Example 13
- Figure 1 (B) is an enlarged photograph of Figure 1 (A), where the darker portions are bainite and the brighter portions are austenite. It can be seen that each average lath width is 0.3 micrometers or less and is a very fine structure.
- Figure 2 is a microstructure photograph of Comparative Example 18
- Figure 2 (B) is an enlarged photograph of Figure 2 (A)
- the relatively dark portion is bainite and the bright portion is austenite. It can also be seen that polygonal ferrite is present and the tissue is relatively coarse.
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Abstract
Description
구분 | C | Si | Mn | Al | S | Mo | B | Cr | Ti |
강종1 | 0.833 | 1.51 | 1.03 | 0.53 | 0.0016 | - | - | - | - |
강종2 | 0.831 | 1.49 | 0.52 | 0.54 | 0.0016 | - | - | - | - |
강종3 | 0.827 | 1.46 | 0.11 | 0.52 | 0.0017 | - | - | - | - |
강종4 | 0.616 | 1.49 | 1.49 | 0.54 | 0.0016 | - | - | - | - |
강종5 | 0.708 | 1.49 | 0.72 | 0.52 | 0.0016 | - | - | - | - |
강종6 | 0.712 | 1.47 | 0.70 | 0.52 | 0.0016 | - | 0.0019 | - | 0.011 |
강종7 | 0.713 | 1.61 | 0.68 | 0.55 | 0.0018 | 0.25 | - | - | - |
강종8 | 0.705 | 1.56 | 0.81 | 0.62 | 0.0023 | - | - | 0.71 | - |
강종9 | 0.191 | 1.49 | 1.97 | 1.04 | 0.0056 | 0.24 | - | - | - |
강종10 | 0.318 | 1.47 | 1.98 | 1.07 | 0.0052 | 0.25 | - | - | - |
강종11 | 0.449 | 1.48 | 1.96 | 1.08 | 0.0054 | 0.24 | - | - | - |
구분 | 권취온도(℃) | 항복강도(MPa) | 인장강도(MPa) | 연신율(%) | 비고 |
강종1 | 400 | 763 | 1342 | 41.5 | 발명예1 |
600 | 766 | 1227 | 13.2 | 비교예1 | |
강종2 | 400 | 836 | 1245 | 36.8 | 발명예2 |
600 | 697 | 1166 | 14.2 | 비교예2 | |
강종3 | 400 | 886 | 1254 | 26.1 | 발명예3 |
600 | 636 | 1084 | 15.9 | 비교예3 | |
강종4 | 400 | 825 | 1210 | 38.2 | 발명예4 |
600 | 672 | 1054 | 16.2 | 비교예4 | |
강종5 | 400 | 912 | 1193 | 42.0 | 발명예5 |
600 | 650 | 1069 | 15.7 | 비교예5 | |
강종6 | 400 | 916 | 1210 | 43.1 | 발명예6 |
600 | 672 | 1075 | 15.3 | 비교예6 | |
강종7 | 400 | 886 | 1209 | 39.2 | 발명예7 |
600 | 712 | 1108 | 15.8 | 비교예7 | |
강종8 | 400 | 948 | 1213 | 38.1 | 발명예8 |
강종9 | 400 | 487 | 947 | 17.4 | 비교예8 |
600 | 631 | 751 | 22.2 | 비교예9 | |
강종10 | 400 | 770 | 1122 | 15.7 | 비교예10 |
600 | 668 | 840 | 19.4 | 비교예11 | |
강종11 | 400 | 741 | 1284 | 13.5 | 비교예12 |
600 | 715 | 953 | 16.0 | 비교예13 |
구분 | 권취온도(℃) | 소둔온도(℃) | 변태온도(℃) | 항복강도(MPa) | 인장강도(MPa) | 연신율(%) | 비고 |
강종1 | 600 | 900 | 400 | 732 | 1313 | 39.7 | 발명예9 |
강종2 | 600 | 900 | 400 | 875 | 1222 | 35.4 | 발명예10 |
강종3 | 600 | 900 | 400 | 917 | 1250 | 23.1 | 발명예11 |
500 | 859 | 1241 | 14.6 | 비교예14 | |||
강종4 | 600 | 900 | 400 | 807 | 1220 | 37.4 | 발명예12 |
강종5 | 600 | 900 | 400 | 899 | 1187 | 39.0 | 발명예13 |
840 | 400 | 952 | 1173 | 36.7 | 발명예14 | ||
강종6 | 600 | 900 | 400 | 900 | 1185 | 39.6 | 발명예15 |
강종7 | 600 | 900 | 400 | 874 | 1194 | 38.6 | 발명예16 |
강종8 | 600 | 840 | 400 | 923 | 1189 | 37.4 | 발명예17 |
강종9 | 600 | 900 | 400 | 450 | 945 | 20.6 | 비교예15 |
840 | 400 | 435 | 967 | 16.6 | 비교예16 | ||
강종10 | 600 | 900 | 400 | 646 | 1117 | 18.3 | 비교예17 |
840 | 400 | 529 | 1169 | 18.4 | 비교예18 | ||
강종11 | 600 | 900 | 400 | 717 | 1314 | 14.9 | 비교예19 |
840 | 400 | 693 | 1291 | 17.1 | 비교예20 |
Claims (15)
- 중량%로, C: 0.5~1.0%, Mn: 0.01~2.0%, Si: 1.0~2.0%, Al: 0.01~2.0%, S: 0.012%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하고, 내부조직은 베이나이트와 잔류오스테나이트로 이루어져 있으며, 베이나이트의 평균 레스(lath) 폭: 0.3㎛ 이하, 잔류오스테나이트의 평균 레스 폭: 0.3㎛ 이하인 것을 포함하는 고강도 고연신 강판.
- 제 1항에 있어서,상기 강판은 A그룹 및 B그룹 중 적어도 하나의 그룹을 추가로 포함하는 고강도 고연신 강판.A그룹:중량%로, 0.5%이하의 Mo 및 1.0%이하의 Cr 중 선택된 1종 또는 2종,B그룹:중량%로, 0.005%이하의 B 및 0.06%이하의 Ti 중 선택된 1종 또는 2종.
- 제 1항 또는 제 2항에 있어서,상기 강판은 항복강도가 700MPa 이상이고, 인장강도가 980MPa 이상이며, 연신율이 20% 이상인 것을 특징으로 하는 고강도 고연신 강판.
- 제 1항 또는 제 2항에 있어서,상기 강판은 열연강판, 냉연강판, 아연도금강판 및 아연도금합금화강판 중 1종인 고강도 고연신 강판.
- 제 3항에 있어서,상기 강판은 열연강판, 냉연강판, 아연도금강판 및 아연도금합금화강판 중 1종인 고강도 고연신 강판.
- 제 1항 또는 제 2항에 있어서,상기 강판은 냉연강판, 아연도금강판 및 아연도금합금화강판 중 1종이고, 상기 강판의 Al의 함량은 0.01~1.0중량%인 고강도 고연신 강판.
- 제 3항에 있어서,상기 강판은 냉연강판, 아연도금강판 및 아연도금합금화강판 중 1종이고, 상기 강판의 Al의 함량은 0.01~1.0중량%인 고강도 고연신 강판.
- 중량%로, C: 0.5~1.0%, Mn: 0.01~2.0%, Si: 1.0~2.0%, Al: 0.01~2.0%, S: 0.012%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 슬라브를 열간압연하여 Ar3 변태점 이상에서 열간압연을 마무리하고, Ms(마르텐사이트 변태 시작온도)~450℃ 범위에서 권취하는 것을 포함하는 고강도 고연신 열연강판의 제조방법.
- 제 8항에 있어서,상기 열연강판은 A그룹 및 B그룹 중 적어도 하나의 그룹을 추가로 포함하는 고강도 고연신 열연강판의 제조방법.A그룹:중량%로, 0.5%이하의 Mo 및 1.0%이하의 Cr 중 선택된 1종 또는 2종,B그룹:중량%로, 0.005%이하의 B 및 0.06%이하의 Ti 중 선택된 1종 또는 2종.
- 중량%로, C: 0.5~1.0%, Mn: 0.01~2.0%, Si: 1.0~2.0%, Al: 0.01~1.0%, S: 0.012%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 슬라브를 열간압연하여 Ar3 변태점 이상에서 열간압연을 마무리하는 열간압연단계;상기와 같이 열간압연된 열연강판을 650℃이하에서 권취하는 권취단계;상기 열연강판을 냉간압연후 Ac3 온도이상에서 소둔후 냉각하는 단계; 및상기 냉연강판을 Ms(마르텐사이트 변태 시작온도)~450℃ 범위에서 과시효처리하는 시효처리단계를 포함하는 고강도 고연신 냉연강판의 제조방법.
- 제 10항에 있어서,상기 냉연강판은 A그룹 및 B그룹 중 적어도 하나의 그룹을 추가로 포함하는 고강도 고연신 냉연강판의 제조방법.A그룹:중량%로, 0.5%이하의 Mo 및 1.0%이하의 Cr 중 선택된 1종 또는 2종,B그룹:중량%로, 0.005%이하의 B 및 0.06%이하의 Ti 중 선택된 1종 또는 2종.
- 중량%로, C: 0.5~1.0%, Mn: 0.01~2.0%, Si: 1.0~2.0%, Al: 0.01~1.0%, S: 0.012%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 슬라브를 열간압연하여 Ar3 변태점 이상에서 열간압연을 마무리하는 열간압연단계;상기와 같이 열간압연된 열연강판을 650℃이하에서 권취하는 권취단계;상기 열연강판을 냉간압연후 Ac3 온도이상에서 소둔후 냉각하는 단계;상기 냉연강판을 Ms(마르텐사이트 변태 시작온도)~450℃ 범위에서 과시효처리하는 시효처리단계; 및상기 시효처리한 냉연강판을 도금욕을 통과시켜 강판표면에 도금층을 형성시키는 단계를 포함하는 고강도 고연신 아연도금강판의 제조방법.
- 제 12항에 있어서,상기 아연도금강판은 A그룹 및 B그룹 중 적어도 하나의 그룹을 추가로 포함하는 고강도 고연신 아연도금강판의 제조방법.A그룹:중량%로, 0.5%이하의 Mo 및 1.0%이하의 Cr 중 선택된 1종 또는 2종,B그룹:중량%로, 0.005%이하의 B 및 0.06%이하의 Ti 중 선택된 1종 또는 2종.
- 중량%로, C: 0.5~1.0%, Mn: 0.01~2.0%, Si: 1.0~2.0%, Al: 0.01~1.0%, S: 0.012%이하, 잔부 Fe 및 기타 불가피한 불순물을 포함하는 슬라브를 열간압연하여 Ar3 변태점 이상에서 열간압연을 마무리하는 열간압연단계;상기와 같이 열간압연된 열연강판을 650℃이하에서 권취하는 권취단계;상기 열연강판을 냉간압연후 Ac3 온도이상에서 소둔후 냉각하는 단계;상기 냉연강판을 Ms(마르텐사이트 변태 시작온도)~450℃ 범위에서 과시효처리하는 시효처리단계;상기 시효처리한 냉연강판을 도금욕을 통과시켜 강판표면에 도금층을 형성시키는 단계; 및상기 도금층을 형성한 아연도금강판을 합금화 열처리하여 아연도금합금화강판을 제조하는 단계를 포함하는 고강도 고연신 아연도금합금화강판의 제조방법.
- 제 14항에 있어서,상기 아연도금합금화강판은 A그룹 및 B그룹 중 적어도 하나의 그룹을 추가로 포함하는 고강도 고연신 아연도금합금화강판의 제조방법.A그룹:중량%로, 0.5%이하의 Mo 및 1.0%이하의 Cr 중 선택된 1종 또는 2종,B그룹:중량%로, 0.005%이하의 B 및 0.06%이하의 Ti 중 선택된 1종 또는 2종.
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JP5756774B2 (ja) * | 2012-03-09 | 2015-07-29 | 株式会社神戸製鋼所 | 熱間プレス用鋼板およびプレス成形品、並びにプレス成形品の製造方法 |
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WO2016108443A1 (ko) * | 2014-12-30 | 2016-07-07 | 한국기계연구원 | 강도와 연성의 조합이 우수한 고강도 강판, 및 그 제조 방법 |
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