WO2010053333A2 - 고산도 원유 중의 산성분 제거를 위한 촉매 및 그 제법 - Google Patents

고산도 원유 중의 산성분 제거를 위한 촉매 및 그 제법 Download PDF

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Publication number
WO2010053333A2
WO2010053333A2 PCT/KR2009/006581 KR2009006581W WO2010053333A2 WO 2010053333 A2 WO2010053333 A2 WO 2010053333A2 KR 2009006581 W KR2009006581 W KR 2009006581W WO 2010053333 A2 WO2010053333 A2 WO 2010053333A2
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WO
WIPO (PCT)
Prior art keywords
catalyst
acidic
crude oil
decarboxylation
production method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2009/006581
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English (en)
French (fr)
Other versions
WO2010053333A3 (ko
Inventor
박종호
오현영
김종남
고창현
이광복
한상섭
조순행
노남선
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Korea Institute of Energy Research KIER
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Korea Institute of Energy Research KIER
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Institute of Energy Research KIER filed Critical Korea Institute of Energy Research KIER
Publication of WO2010053333A2 publication Critical patent/WO2010053333A2/ko
Publication of WO2010053333A3 publication Critical patent/WO2010053333A3/ko
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/14—Silica and magnesia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

본 발명은 고산도 원유(High TAN crude) 중의 산 성분을 반응을 통하여 제거하기 위한 촉매와 그 제법에 관한 것이다. 고산도 원유는 공정 부식을 일으키는 산성분이 많이 함유되어 있는데, 이러한 산성분을 탈탄산 반응을 통하여 제거한다. 기존의 탈탄산 반응을 위한 촉매로는 알칼리 토금속 산화물이나 수화물이 이용되었는데 이들 촉매들은 촉매 반응환경하에서 원유에 나프텐염의 형태로 녹아들어가 이차적인 문제를 유발한다. 본 발명은 알칼리 토금속 양이온 혹은 전이금속 양이온이 실리케이트 혹은 알루미네이트 등의 음이온과 결합한 형태의 탈탄산 촉매를 제공하며 이 촉매는 산성분위기 하에서도 안정하면서 우수한 탈탄산 활성을 보인다.
PCT/KR2009/006581 2008-11-10 2009-11-10 고산도 원유 중의 산성분 제거를 위한 촉매 및 그 제법 Ceased WO2010053333A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020080110965A KR101040966B1 (ko) 2008-11-10 2008-11-10 고산도 원유 중의 산성분 제거를 위한 촉매 및 그 제법
KR10-2008-0110965 2008-11-10

Publications (2)

Publication Number Publication Date
WO2010053333A2 true WO2010053333A2 (ko) 2010-05-14
WO2010053333A3 WO2010053333A3 (ko) 2010-08-12

Family

ID=42153419

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2009/006581 Ceased WO2010053333A2 (ko) 2008-11-10 2009-11-10 고산도 원유 중의 산성분 제거를 위한 촉매 및 그 제법

Country Status (2)

Country Link
KR (1) KR101040966B1 (ko)
WO (1) WO2010053333A2 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101691953B1 (ko) * 2015-01-05 2017-01-02 고려대학교 산학협력단 고산도 원유 또는 탄화수소 유분으로부터 유기산의 제거방법
KR101675351B1 (ko) 2015-03-25 2016-11-11 현대오일뱅크 주식회사 납센산의 탈카르복실화 반응용 불균일계 촉매
KR20160140138A (ko) 2015-05-29 2016-12-07 한국에너지기술연구원 가스 하이드레이트 억제제와 촉매를 사용한 원유 내 유기산 제거방법
KR101696773B1 (ko) * 2015-12-01 2017-01-16 한국에너지기술연구원 글리세롤 또는 그 유도체와 촉매를 사용하여 원유 내의 유기산을 제거하는 방법
KR101696376B1 (ko) 2016-03-25 2017-01-12 서울시립대학교 산학협력단 촉매를 이용한 바이오 오일의 안정화 방법
KR101954115B1 (ko) 2017-04-20 2019-03-05 현대오일뱅크 주식회사 불균일 그라피틱 카본 나이트라이드 - 코팅 산화알루미늄 촉매, 그 제조방법 및 그를 이용한 고산도 원유의 납센산 제거방법
KR101994635B1 (ko) * 2018-04-06 2019-07-02 주식회사이맥솔루션 원유 내의 산도 저감을 위한 첨가제 및 이의 응용
KR102671870B1 (ko) * 2023-09-20 2024-06-03 주식회사 에버인더스 전기화학소자용 실리콘계 다공성 음극 활물질, 이를 포함하는 전기화학소자 및 이의 제조방법

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57185224A (en) 1981-05-11 1982-11-15 Res Assoc Petroleum Alternat Dev<Rapad> Preparation of liquid hydrocarbon from oxygen- containing compound
US5052561A (en) 1987-09-16 1991-10-01 Chevron Research & Technology Company Crystalline silicate catalyst and a reforming process using the catalyst
JPH11241074A (ja) 1998-02-25 1999-09-07 Union Sekiyu Kogyo Kk ナフテン酸含有油の処理方法
US5985137A (en) * 1998-02-26 1999-11-16 Unipure Corporation Process to upgrade crude oils by destruction of naphthenic acids, removal of sulfur and removal of salts
US6547957B1 (en) * 2000-10-17 2003-04-15 Texaco, Inc. Process for upgrading a hydrocarbon oil
JP2008504409A (ja) * 2004-07-07 2008-02-14 カリフォルニア インスティテュート オブ テクノロジー 金属酸化物を使用して油を改良するプロセス

Also Published As

Publication number Publication date
WO2010053333A3 (ko) 2010-08-12
KR101040966B1 (ko) 2011-06-16
KR20100052089A (ko) 2010-05-19

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