WO2010029876A1 - 固体撮像装置の製造方法 - Google Patents
固体撮像装置の製造方法 Download PDFInfo
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- WO2010029876A1 WO2010029876A1 PCT/JP2009/065302 JP2009065302W WO2010029876A1 WO 2010029876 A1 WO2010029876 A1 WO 2010029876A1 JP 2009065302 W JP2009065302 W JP 2009065302W WO 2010029876 A1 WO2010029876 A1 WO 2010029876A1
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- transparent substrate
- solid
- state imaging
- wafer
- cover glass
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Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14683—Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
- H01L27/14687—Wafer level processing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/14618—Containers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/14625—Optical elements or arrangements associated with the device
- H01L27/14627—Microlenses
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04N—PICTORIAL COMMUNICATION, e.g. TELEVISION
- H04N23/00—Cameras or camera modules comprising electronic image sensors; Control thereof
- H04N23/50—Constructional details
- H04N23/55—Optical parts specially adapted for electronic image sensors; Mounting thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/161—Cap
- H01L2924/162—Disposition
- H01L2924/16235—Connecting to a semiconductor or solid-state bodies, i.e. cap-to-chip
Definitions
- the present invention relates to a method for manufacturing a solid-state imaging device, and more particularly to a method for manufacturing a thin solid-state imaging device.
- the solid-state imaging device composed of CCD and CMOS used in digital cameras and mobile phones is increasingly required to be miniaturized. For this reason, the conventional large package in which the entire solid-state image sensor chip is hermetically sealed in a ceramic package or the like has recently been shifted to a chip size package (CSP) type having a size substantially equal to the size of the solid-state image sensor chip. .
- CSP chip size package
- Patent Document 1 discloses a method of manufacturing CSP type solid-state imaging devices collectively at the wafer level.
- a plurality of solid-state imaging elements constituting a light receiving portion are formed on a silicon wafer, and a cover glass wafer made of a transparent material is bonded to the silicon wafer via a spacer formed so as to correspond to the light receiving portion.
- a method of manufacturing a solid-state imaging device collectively by cutting a cover glass wafer and a silicon wafer into individual pieces is described.
- both the cover glass wafer and the silicon wafer have an outer diameter of 8 inches
- the substrate begins to have a large deflection of several millimeters only by its own weight.
- the shape of the base cover glass wafer itself is unstable, the spacers are formed. Process construction becomes difficult.
- the present invention has been made in view of such circumstances, and an object thereof is to provide a manufacturing method of a solid-state imaging device capable of easily manufacturing a thin solid-state imaging device at a wafer level.
- a first manufacturing method of a solid-state imaging device includes a plurality of frame spacers and the frame spacers on one surface of a transparent substrate serving as a base material of a cover glass, Forming a ring-shaped spacer along the outer periphery of the transparent substrate, applying a mask material on one side of the transparent substrate so as to cover the frame-shaped spacer and the ring-shaped spacer, Removing the transparent substrate so as to have a thickness within a predetermined range from the other surface side, removing the mask material from the transparent substrate, attaching the first support wafer to the other surface of the transparent substrate, Forming a plurality of solid-state imaging elements on one side of the semiconductor substrate; removing the semiconductor substrate to a thickness within a predetermined range from the other side; and a second support window on the other side of the semiconductor substrate.
- a second manufacturing method of a solid-state imaging device includes a plurality of frame spacers and the frame spacers on one surface of a transparent substrate serving as a base material of a cover glass, Forming a ring-shaped spacer along the outer periphery of the transparent substrate, applying a mask material on one side of the transparent substrate so as to cover the frame-shaped spacer and the ring-shaped spacer, Removing the transparent substrate so as to have a thickness within a predetermined range from the other surface side, removing the mask material from the transparent substrate, attaching the first support wafer to the other surface of the transparent substrate, A step of separating the transparent substrate into a cover glass, a step of forming a plurality of solid-state imaging elements on one side of the semiconductor substrate, and a step of removing the semiconductor substrate from the other side so as to have a thickness within a predetermined range.
- a step of bonding a second support wafer to the other surface of the semiconductor substrate, a step of bonding the semiconductor substrate and the cover glass via the spacer, the first support wafer, and the second support wafer A step of peeling the support wafer from the transparent substrate and the semiconductor substrate; and a step of separating the semiconductor substrate into individual pieces.
- the spacer is formed on the transparent substrate having sufficient rigidity, it is not necessary to bond the support wafer for forming the spacer.
- the transparent substrate is thinned by applying the mask material after forming the spacer, the spacer side surface of the transparent substrate can be protected by the mask material.
- the transparent substrate is possible to prevent the transparent substrate from being damaged by the mask material during handling after thinning.
- the ring-shaped spacer formed so that it may follow along the outer periphery of a transparent substrate prevents the penetration
- the support wafer is attached to both the thinned transparent substrate and the thinned semiconductor substrate, rigidity and flatness can be ensured. Thereby, it is possible to easily handle the transparent substrate and the semiconductor substrate and to join them together.
- the step of removing the transparent substrate so as to have a thickness within a predetermined range from the other surface side includes the step of removing the transparent substrate from the other surface side, and hydrofluoric acid as a main component. It is preferable that the etching process is performed using a chemical solution.
- the mask material has resistance to hydrofluoric acid.
- the step of removing the transparent substrate so as to have a thickness within a predetermined range from the other surface side is performed by lapping and / or polishing from the other surface side.
- a polishing step is preferred.
- the mask material is preferably a single-sided tape or a coating liquid whose adhesive strength is reduced by applying external energy.
- the member for bonding the transparent substrate and the first support wafer is preferably a double-sided tape or an adhesive having self-peeling properties.
- the member for bonding the semiconductor substrate and the second support wafer is preferably a double-sided tape or an adhesive having self-peeling properties.
- the bonded member Since the bonded member has a self-peeling function, it can be easily peeled without applying a load to the transparent substrate or the semiconductor substrate.
- a thin solid-state imaging device can be easily manufactured at the wafer level.
- FIG. 1 is a perspective view of a solid-state imaging device manufactured by the method according to the present embodiment
- FIG. 2 is a cross-sectional view of a solid-state imaging device manufactured by the method according to the present embodiment
- FIG. 3A is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3B is an explanatory diagram illustrating the method for manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3C is an explanatory diagram illustrating the method for manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3D is an explanatory view showing the method for manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3A is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3B is an explanatory diagram illustrating the method for manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3C is an explanatory diagram illustrating the method for manufacturing the solid-state imaging device
- FIG. 3E is an explanatory view showing the method of manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3F is an explanatory diagram illustrating the manufacturing method of the solid-state imaging device according to the first embodiment
- FIG. 3G is an explanatory view showing the method for manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3H is an explanatory view showing the method of manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3I is an explanatory view showing the method of manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3J is an explanatory view showing the method of manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3K is an explanatory view showing the method of manufacturing the solid-state imaging device according to the first embodiment
- FIG. 3L is an explanatory view showing the method of manufacturing the solid-state imaging device according to the first embodiment
- FIG. 4A is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4B is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4C is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4D is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4E is an explanatory view showing the method of manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4A is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4B is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4C is an explanatory diagram illustrating a method for manufacturing the
- FIG. 4F is an explanatory view showing the method of manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4G is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4H is an explanatory view showing the method of manufacturing the solid-state imaging device according to the second embodiment
- FIG. 4I is an explanatory diagram illustrating a method for manufacturing the solid-state imaging device according to the second embodiment
- FIG. 5 is a diagram illustrating a state in which a cover glass wafer is ground and cut with a grindstone.
- FIG. 1 and FIG. 2 are a perspective view and a cross-sectional view showing an external shape of a solid-state imaging device manufactured by the method according to the present invention.
- the solid-state imaging device 1 includes a solid-state imaging element chip 2 provided with a plurality of solid-state imaging elements 3, a frame-like spacer 5 attached to the solid-state imaging element chip 2 and surrounding the plurality of solid-state imaging elements 3, And a cover glass 4 that seals the plurality of solid-state imaging devices 3.
- the solid-state image sensor chip 2 is obtained by dividing a semiconductor substrate on which a solid-state image sensor described later is manufactured, and the cover glass 4 is obtained by dividing a transparent substrate described later.
- the solid-state image sensor chip 2 includes a rectangular chip substrate 2A, a solid-state image sensor 3 formed on the chip substrate 2A, and a plurality of solid-state image sensor chips 2 arranged outside the solid-state image sensor 3. And a pad (electrode) 6 for performing wiring.
- the material of the chip substrate 2A is, for example, a silicon single crystal, and the thickness thereof is, for example, about 0.15 mm.
- the solid-state imaging device 3 includes a photodiode that is a light-receiving element formed on a wafer (solid-state imaging device chip 2), a transfer electrode that transfers excitation voltage to the outside, a light shielding film having an opening, and an interlayer insulating film. . Further, in the solid-state imaging device 3, an inner lens is formed on the interlayer insulating film, a color filter is provided on the upper portion of the inner lens via an intermediate layer, and a microlens or the like is provided on the upper portion of the color filter via the intermediate layer. Is provided.
- the solid-state imaging device 3 Since the solid-state imaging device 3 is configured in this way, light incident from the outside is condensed by the microlens and the inner lens and irradiated to the photodiode, so that the effective aperture ratio is increased.
- the cover glass 4 is made of transparent glass having a thermal expansion coefficient close to that of silicon, such as “Pyrex (registered trademark) glass”, and the thickness thereof is, for example, about 0.1 mm.
- the frame spacer 5 is an inorganic material and is preferably made of a material having similar physical properties such as a thermal expansion coefficient to the chip substrate 2A and the cover glass 4, for example, polycrystalline silicon is used. Further, when a part of the frame-shaped frame spacer 5 is viewed in cross section, the width of the cross section is, for example, about 0.15 mm, and the thickness is, for example, about 0.05 mm.
- the frame-like spacer 5 is bonded to the chip substrate 2 ⁇ / b> A using an adhesive 7 at one end surface, and bonded to the cover glass 4 using the adhesive 8 at the other end surface.
- a cover glass wafer having an outer diameter ⁇ 8 inch ⁇ thickness t0.3 mm and a silicon wafer having an outer diameter ⁇ 8 inch ⁇ thickness t0.3 mm are used as the original material.
- a case will be described in which a solid-state imaging device having a solid-state imaging element chip thickness of t0.15 mm, a frame spacer thickness of t0.05 mm, and a cover glass thickness of t0.1 mm is manufactured collectively at the wafer level. .
- Low alpha ray glass was used for the cover glass wafer in consideration of damage to the solid-state imaging device.
- a frame-shaped spacer 5 having a width of four sides of 0.1 to 0.15 mm and a height of t0.05 mm is provided in the surface of the cover glass wafer 10 which is a transparent substrate of ⁇ 8 inch ⁇ t 0.3 mm. A large number (hundreds to thousands) is formed.
- a ring-shaped spacer 20 having a width of 150 mm and a height of t0.05 mm is formed on the outer periphery of the cover glass wafer 10.
- the frame-shaped spacer 5 and the ring-shaped spacer 20 can be manufactured by using, for example, the following method.
- a permanent resist for MEMS is spin-coated on the cover glass wafer 10 to a thickness of 0.05 mm, and the frame-shaped spacer 5 and the ring-shaped spacer 20 having the required dimensions are formed by photolithography.
- the permanent resist for MEMS for example, SU-83000 series manufactured by Kayaku Microchem Corporation, TMMR S2000 manufactured by Tokyo Ohka Kogyo Co., Ltd., or the like can be used.
- the liquid resist was mentioned, it is not necessarily this limitation, You may use a similar thing and a sheet-like thing (Drye film resist type).
- a photosensitive adhesive or an adhesive sheet is spin-coated or laminated to a thickness of 0.05 mm on the cover glass wafer 10, and the frame-shaped spacer 5 and the ring-shaped spacer 20 having the required dimensions are formed by photolithography.
- the photosensitive adhesive / adhesive sheet for example, an adhesive sheet manufactured by Nitto Denko Corporation, MA-1000 series manufactured by Hitachi Chemical Co., Ltd., U-100 series manufactured by Taiyo Ink Manufacturing Co., Ltd., etc. can be used.
- a frame-like spacer and a ring-like spacer are formed of an inorganic material, and in the second and third methods, an organic material.
- an organic material When the final solid-state imaging device requires environmental resistance such as strict sealing (moisture resistance), it is preferable to form the frame spacer and the ring spacer by the first method.
- the means is not limited as long as a similar structure can be obtained with high accuracy and efficiency, such as a screen printing technique or a dispensing method.
- the frame spacer 5 and the ring spacer 20 are formed with the cover glass wafer 10 having a thickness of t0.3 mm. Even a wafer with an outer diameter of 8 inches and a large area has a sufficient rigidity and little deflection itself if the thickness is t0.3 mm. Therefore, the frame spacer 5 and the ring spacer 20 can be formed relatively easily and with high accuracy.
- a functional film such as an antireflection film can be easily provided on the cover glass wafer 10.
- a mask material 12 is applied to the frame spacer 5 side of the cover glass wafer 10 so as to cover the frame spacer 5 and the ring spacer 20.
- a mask material 12 a single-sided tape type or a coating liquid type can be used.
- the cover glass wafer 10 is thinned with a chemical solution mainly containing hydrofluoric acid
- a chemical solution mainly containing hydrofluoric acid if it is a single-sided tape type, at least the base material of the base material and the adhesive layer constituting the tape is in addition, if it is a coating solution type, it is preferable that the coating solution is resistant to a chemical solution such as hydrofluoric acid.
- the mask material 12 is a single-sided tape type
- the single-sided tape can be attached to the frame-shaped spacer 5 and the ring-shaped spacer 20 with a roller or the like.
- the coating liquid is applied by spin coating, bar coating, spray coating, or the like, and then cured (dried), whereby the coating liquid becomes the frame spacer 5 and the ring spacer 20. Can be coated to fill.
- the mask material 12 is supplied to the cover glass wafer 10 so as to cover the frame spacer 5 and the ring spacer 20.
- ELEGRIP U-3083D manufactured by Nitto Denko Corporation has a tape base material which is PET and has hydrofluoric acid resistance. It can be easily peeled off. Therefore, the spacer can be suitably used because it hardly adheres to the adherend surface.
- the tape base material is PET, it has IPA resistance, or after washing with pure water after wet etching, it is possible to select a drying method that suppresses drying spots such as IPA drying (solvent vapor drying). it can.
- an Intellimer tape manufactured by Nitta Corporation can be used.
- the tape base material is PET and has hydrofluoric acid resistance, and its adhesive strength is reduced by heating or cooling after bonding, and it can be easily peeled off, and there is little adhesion to the adherend surface. it can.
- the peeling can be performed in an atmosphere of 50 ° C. or higher, and in the type in which the adhesive strength is reduced by cooling, for example, in an atmosphere of 40 ° C. or lower.
- UV curable temporary fixing adhesive Templock series manufactured by Denki Kagaku Kogyo Co., Ltd. can be used as the mask material 12. After coating and UV curing, it can be easily peeled off by dipping in warm water of about 60 to 80 ° C. for several minutes to swell and reduce the adhesive strength. Further, it is also resistant to hydrofluoric acid, and furthermore, it is suitable with less adhesion to the adherend surface of the frame spacer 5 after peeling.
- a UV curable adhesive LC-3000 series manufactured by Sumitomo 3M Co., Ltd. can be used as the mask material 12.
- any member having the same function is not limited to the present embodiment.
- all of the above members are mainly composed of a resin.
- a non-resin material for example, silicon sufficiently thicker than the glass wafer 10.
- An inorganic material such as a wafer or a glass wafer may be attached.
- the cover glass wafer 10 provided with the mask material 12 is immersed in a chemical solution such as hydrofluoric acid, and the surface opposite to the spacer formation surface is chemically treated until the thickness is changed from t0.3 mm to t0.1 mm. Thinned by processing. At this time, it is necessary to pay attention to the etching rate so that the surface of the cover glass wafer 10 does not become a rough surface due to a chemical reaction.
- a chemical solution such as hydrofluoric acid
- the glass surface on the spacer side of the cover glass wafer 10 (the surface that finally becomes the inside of the cover glass of the solid-state imaging device) is sealed with the mask material 12 and the ring-shaped spacer 20. There is no entry. Thereby, the glass surface on the spacer side of the cover glass wafer 10 is protected from damage by the chemical solution.
- Thinning by wet etching is non-load processing. Further, since the mask material 12 affixed to the spacer side also acts as a support, it can be processed without damaging the cover glass wafer 10 during the etching process, or during subsequent pure water cleaning and drying.
- a means by wet etching with a low load on the object to be processed and a low risk of breakage during the process has been described.
- a method by mechanical polishing such as lapping or polishing may be used.
- the mask material 12 plays a role of protecting the spacer side of the cover glass wafer 10 from polishing dust and abrasive.
- the mask material 12 is peeled from the cover glass wafer 10. Since the cover glass wafer 10 is in an extremely thin state when the mask material 12 is peeled off, a flat vacuum suction table (not shown) is used to prevent the glass surface side from being damaged by the pulling force at the time of peeling. ) It is preferable to carry out in a state of being adsorbed and fixed on top.
- the mask material 12 when a member whose adhesive strength is reduced by external energy (for example, UV light or temperature) is used as the mask material 12, it is peeled after external energy is applied or in a state where external energy is applied. It is preferable to carry out.
- external energy for example, UV light or temperature
- the glass surface side subjected to the etching process is vacuumed after irradiating the mask material 12 side with UV light of about 30 sec at an illuminance of 30 mW.
- a vacuum is fixed to the suction table, and the mask material 12 is slowly peeled off. Since the adhesive strength is reduced by UV light irradiation and the cover glass wafer 10 is firmly fixed to the vacuum suction table, the mask material 12 can be easily peeled off without being damaged.
- the vacuum suction table As the vacuum suction table, a porous structure is suitable because the suction force acts on the entire surface of the table.
- the flatness is preferably 5 ⁇ m or less in order to prevent damage due to adsorption force.
- the peeling of the mask material 12 is performed by applying desired peeling conditions according to the material used as the mask material 12.
- the first support wafer 14 is attached to the glass surface opposite to the spacer side of the cover glass wafer 10 on which the frame-like spacer 5 is formed via the bonding member 16.
- the purpose of the first support wafer 14 is simply to ensure rigidity during handling.
- the bonding member 16 is preferably a double-sided tape, an adhesive, or the like having self-peeling properties and low adhesion to the glass surface. In the state where the first support wafer 14 is attached to the cover glass wafer 10, these are not subjected to semiconductor process processing such as formation of the frame spacer 5. Therefore, the bonding member 16 does not need to withstand severe process environments such as chemical resistance, water resistance, vacuum resistance, plasma resistance, and high temperature resistance. Therefore, the options of members applicable as the bonding member 16 are expanded.
- the attachment of the first support wafer 14 to the cover glass wafer 10 is performed as follows.
- a vacuum suction table having a porous structure and a flatness of 5 ⁇ m or less.
- the Pyrex (registered trademark) glass having the same outer diameter ( ⁇ 8 inch) and the thickness of t0.5 mm is bonded to the cover glass wafer 10 side as the first support wafer 14 while being fixed to the vacuum suction table.
- Selfa BG has a function of generating a self-peeling action when UV irradiation is performed on one surface.
- adhesion is released by outgas generation by UV irradiation. It is useful when peeling the first support wafer 14 from the cover glass wafer 10 after that, and is designed so that the remaining adhesive layer is small, and can be suitably used.
- candidates for the following methods / members are also applicable.
- ⁇ Double-sided tape type> a heat-releasable double-sided tape such as Riba Alpha manufactured by Nitto Denko Corporation or ELEGrip manufactured by Electrochemical Industry Co., Ltd. can be suitably used.
- a self-peeling function that reduces the adhesion area and expands adhesion by expansion of the microcapsules contained in the adhesion layer by heating, and there is little adhesion to the adherend surface.
- WSS Wafer-Support-System
- Zero-Newton system manufactured by Tokyo Ohka Kogyo Co., Ltd.
- a dedicated bonding / peeling device and stripper are necessary, it is useful as a method for temporarily applying a support wafer.
- the present embodiment is not limited to the present embodiment as long as it is a method / member having a similar function.
- a silicon wafer is prepared in a process different from that shown in FIGS. 3A to 3E in which the cover glass wafer 10 is thinned and the cover glass wafer 10 and the first support wafer 14 are attached.
- a general semiconductor element manufacturing process is applied to the surface of a silicon wafer 18 ( ⁇ 8 inch ⁇ t 0.3 mm), which is a semiconductor substrate, to form a plurality of solid-state imaging elements 3 and pads 6. .
- the back surface of the silicon wafer 18 is polished by back grinding or the like to reduce the thickness to t 0.15 mm.
- the back side may be thinned by wet etching.
- the second support wafer 22 is bonded to the back surface of the silicon wafer 18 via the bonding member 24.
- the bonding member 24 preferably has self-peeling properties.
- the second support wafer 22 is attached to the back surface of the silicon wafer 18, unlike the bonding member 16, if there is no influence on the electrical characteristics and the assembly to the module or the like, the adhesive layer remains somewhat. There are few problems.
- the attachment of the second support wafer 22 to the silicon wafer 18 is performed as follows. Pyrex (registered trademark) glass t0.5 mm having the same outer diameter ( ⁇ 8 inch) was bonded to the polished surface of the silicon wafer 18 as a second support wafer with a self-peeling double-sided tape (Selfa BG).
- the bonding member / system as described in FIG. 3E can be used.
- the cover glass wafer 10 and the silicon wafer 18 have the light receiving area of the solid-state imaging device 3 in a frame shape with the time-curing type adhesive transferred to the bonding surface of the frame spacer 5. It is positioned and joined three-dimensionally so as to be surrounded by the spacer 5. After bonding, pressure is applied from the first and second support wafers 14 and 22 side, and the adhesive is completely aged until the adhesive is completely cured.
- first and second support wafers 14 and 22 are attached to the cover glass wafer 10 and the silicon wafer 18, damage due to handling can be prevented. In addition, since the flatness of each other is maintained, alignment and joining can be easily performed with high accuracy.
- the self-peeling action of the bonding members 16 and 24 is applied to peel the cover glass wafer 10 and the first support wafer 14, the silicon wafer 18 and the second support wafer 22.
- the first and second support wafers 14 and 22 can be used repeatedly.
- the bonding members 16 and 24 are double-sided tape (Selfa BG), specifically, the cover glass wafer 10 and the first support wafer 14 are separated from the silicon wafer 18 and the second support wafer 22 by the following procedure. Is done.
- UV light is irradiated from the first support wafer 14 side at an illuminance of 30 mW for about 100 seconds. Since the first support wafer 14 is a transparent substrate, the UV light is transmitted and is applied to the double-sided tape (Selfa BG) which is the bonding member 16. The self-peeling action (opening of adhesion due to outgas generation) occurs in the bonding member 16 by UV irradiation. Even when the rigid wafers are bonded to each other, the first support wafer 14 can be easily peeled from the cover glass wafer 10.
- UV light is irradiated from the second support wafer 22 side for about 100 seconds with an illuminance of 30 mW.
- the second support wafer 22 can be easily peeled from the silicon wafer 18.
- Either peeling of the cover glass wafer 10 and the first support wafer 14 or peeling of the silicon wafer 18 and the second support wafer 22 may be performed first.
- the first and second supports are provided by giving appropriate peeling conditions (heating conditions, swelling conditions, etc.), respectively.
- the wafers 14 and 22 are peeled off.
- the disc-shaped grindstone (dicing blade) 26 is used to grind and cut only the cover glass wafer 10 to separate the cover glass 4 into individual pieces.
- the lowest point of the grindstone 26 is the silicon wafer 18.
- the height of the grindstone 26 is set so as to pass a height of 0.02 to 0.03 mm from the surface, and grinding and cutting are performed in both the X axis direction and the Y axis direction perpendicular to each other on the plane of the cover glass wafer 10.
- the grindstone 26 is selected to have a fineness of about abrasive grains # 600 to 1200. Furthermore, in order to reduce the grinding resistance, it is preferable to select a resin bond having a small abrasive grain holding force, a self-generated blade action, and elasticity.
- the processing speed is set in a relatively low range of 0.5 to 2 mm / sec.
- the silicon wafer 18 is ground and cut in both the X-axis direction and the Y-axis direction in accordance with the dicing street with a thin grindstone (about t0.04 mm). Tidy up. As a result, a large number of thin solid-state imaging devices 1 having a total thickness t of 0.30 mm can be manufactured simultaneously at the wafer level.
- a second embodiment according to the method for manufacturing a solid-state imaging device of the present invention will be described.
- symbol may be attached
- the manufacturing process of the silicon wafer 18 corresponding to FIGS. 3F to 3H is omitted.
- the method of the second embodiment is different from the method of the first embodiment with respect to the method of individualizing the cover glass wafer into the cover glass.
- FIGS. 4A to 4E The process of FIGS. 4A to 4E is exactly the same as the process of FIGS. 3A to 3E.
- the cover glass wafer 10 can be singulated into the cover glass 4 while the first support wafer 14 is bonded to the cover glass wafer 10 via the bonding member 16.
- the cover glass wafer 10 can be separated into the cover glass 4 with the grindstone 26 in a state where the cover glass wafer 10 and the silicon wafer 18 are bonded together.
- the height of the frame spacer 5 is lowered, the distance between the lowest point of the grindstone 26 and the silicon wafer 18 is reduced. Thereby, the clearance for discharging the grinding waste of the cover glass wafer 10 is reduced. The possibility that the grinding scraps damage the silicon wafer 18 is increased.
- the first support wafer 14 is bonded to the cover glass wafer 10 via the bonding member 16.
- the cover glass wafer 10 is separated into the cover glass 4. Therefore, the grinding waste of the cover glass wafer 10 does not damage the silicon wafer 18.
- FIG. 5 shows a state where the cover glass wafer 10 is ground and cut by the grindstone 26.
- the grindstone is slightly cut from the frame spacer 5 side to the bonding member 16 of the first support wafer 14.
- the height of 26 is set, and the cover glass 4 is divided into individual pieces (full cut).
- the thickness of the bonding member 16 is set to t0.08 mm or more, and the amount of the grindstone 26 cut into the bonding member 16 is set to be in the range of 0.04 to 0.07 mm. Since the roundness 30 at the tip of the grindstone 26 cuts and advances halfway through the bonding member 16, the influence of the roundness 30 on the edge of the grindstone 26 can be avoided.
- the processing speed can be set to 2 to 5 mm / sec. Thereby, grinding and cutting can be performed at a higher speed than the separation of the cover glass 4 from the cover glass wafer 10 in FIG. 3K.
- the grindstone 26 is set so as not to cut into the first support wafer 14. Therefore, the bonding member 16 is not singulated. After the first support wafer 14 is peeled off from the plurality of cover glasses 4, the bonding member 16 can be peeled off from the first support wafer 14 as an integrated body. Thereby, the reproduction
- the cover glass wafer 10 and the silicon wafer 18 have the light receiving area of the solid-state imaging device 3 in the state where the time-curing adhesive is transferred to the bonding surface of the frame spacer 5. Are three-dimensionally positioned and joined so as to be surrounded by the spacer 5. After bonding, pressure is applied from the first and second support wafers 14 and 22 side, and the adhesive is completely aged until the adhesive is completely cured.
- the self-peeling action of the bonding members 16 and 24 is applied to peel the cover glass wafer 10 and the first support wafer 14, the silicon wafer 18 and the second support wafer 22.
- the first and second support wafers 14 and 22 can be used repeatedly.
- the silicon wafer 18 is ground and cut into pieces by thin grinding stones (about t0.04 mm) in the X-axis direction and the Y-axis direction in accordance with the dicing street.
- thin grinding stones about t0.04 mm
- a large number of thin solid-state imaging devices having a total thickness t of 0.30 mm can be simultaneously manufactured at the wafer level.
- SYMBOLS 1 Solid-state imaging device, 2 ... Solid-state image sensor chip, 3 ... Solid-state image sensor, 4 ... Cover glass, 5 ... Frame spacer, 6 ... Pad, 10 ... Cover glass wafer, 12 ... Mask material, 16, 24 ... Paste Alignment member, 14 ... first support wafer, 18 ... silicon wafer, 20 ... ring spacer, 22 ... second support wafer, 26, 28 ... grinding stone
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Abstract
Description
カバーガラスウエハ10にまず接着剤を塗布して、そこにスペーサ用部材として同外径(φ8inch×t0.73mm)のシリコンウエハ(不図示)を両者の外径を合わせて接着する。次いで、砥石による平面研削加工を施して、シリコンウエハのみを厚さt0.05mmまで薄板化する。次いで薄板化したシリコンウエハに対し、フォトリソグラフィ技術によるレジストのパターニング、ドライエッチング技術によって、シリコンウエハの不要部分除去する。最後に、ドライ、及びウェット洗浄によって、レジストと接着剤の除去を順次行い、必要寸法の枠状スペーサ5及びリング状スペーサ20を形成する。
MEMS(Micro Electro Mechanical Systems)用永久レジストをカバーガラスウエハ10上に厚さt0.05mmでスピンコート塗布し、フォトリソグラフィ技術によって、必要寸法の枠状スペーサ5及びリング状スペーサ20が形成される。MEMS用永久レジストとしては例えば化薬マイクロケム株式会社製のSU-8 3000シリーズ、東京応化工業株式会社製のTMMR S2000などを用いることができる。なお、液状のレジストを挙げたが、必ずしもこの限りではなく、類似品でシート状のもの(ドライフイルムレジストタイプ)を用いてもよい。
感光性接着剤あるいは接着シートをカバーガラスウエハ10上に厚みt0.05mmにスピンコート塗布あるいはラミネートし、フォトリソグラフィ技術によって、必要寸法の枠状スペーサ5及びリング状スペーサ20が形成される。感光性接着剤/接着シートとしては例えば日東電工株式会社製の接着シート、日立化成工業株式会社製のMA-1000シリーズ、太陽インキ製造株式会製のU-100シリーズなどを用いることができる。
(1)テープタイプであれば日東電工株式会社製のエレグリップ(UB-3083D)はテープ基材がPETで耐フッ酸性があり、さらには接着後もUV照射により接着力を低下(接着層が硬化)させることができるため簡単に剥離することができる。したがって、スペーサの被着面への付着も少ないので好適に使用することができる。また、テープ基材がPETであるため、耐IPA性もあることかウエットエッチングング後の純水洗浄後には、例えばIPA乾燥(溶剤蒸気乾燥)など乾燥シミを抑制した乾燥手法を選択することができる。
(2)別のテープタイプとして、例えば株式会社ニッタ製のインテリマーテープなどを使用することができる。テープ基材がPETで耐フッ酸性があり、かつ接着後も加温あるいは冷却によりその接着力が低下し簡単に剥離可能で、かつ被着面への付着も少ないので、好適に使用することができる。加温により接着力が低下するタイプでは、例えば50℃以上、冷却により接着力が低下するタイプでは例えば40℃以下の雰囲気下にて剥離を行うことができる。
(1)例えば、電気化学工業株式会社製のUV硬化型仮固定用接着剤テンプロックシリーズがマスク材12として使用できる。塗布・UV硬化後に、60~80℃程度の温水に数分間浸漬することで、膨潤し接着力が低下するため容易に剥離することができる。また耐フッ酸性もあり、さらには剥離後の枠状スペーサ5の被着面への付着も少なく好適である。
(2)例えば住友3M株式会社製のUV硬化型接着剤LC-3000シリーズなどがマスク材12として使用できる。塗布硬化(接着)後に、外的エネルギーの付与による接着力の低下機能はないものの元来剥離性はよく、耐フッ酸性があり、枠状スペーサ5の被着面への付着も少ないので、好適に使用することができる。
この他にも下記の方式・部材が候補も適用可能である。
例えば日東電工株式会社製のリバアルファや電気化学工業株式会社製のエレグリップなどの熱剥離両面テープを好適に使用することができる。加熱により接着層中に含まれるマイクロカプセルの膨張により接着面積を低減し密着を開放する自己剥離機能があり、被着面への付着も少ない。
例えば化研テック株式会社製の仮着剤エコセパラや電気化学工業株式会社製テンプロックなどの仮止め接着剤などを好適に使用することができる。これらは温水への浸漬で自己剥離性あるいは接着力が低下する機能がある。この際、温水に溶解(分解)するのではなく、塗布された形態を留めたまま一体形成された物として剥離することができ作業性もよく有用である。ただし、これらは接着部(=ウエハ全面)を効率よく温水膨順させるために第1のサポートウエハ14には多数の微小穴を開けておくなど、温水の経路を設けることが必要となる。
例えば住友3M株式会社製のWSS(Wafer-Support-System)や東京応化工業株式会社製のZero-Newtonシステムなどを好適に使用することができる。専用の貼り合わせ/剥離装置や剥離液が必要ではあるが、サポートウエハを一時的に付与する方法として有用である。上記以外にも類似の機能を有する方式・部材であれば、本実施の形態に限定されない。
図4Fに示すように、カバーガラスウエハ10に貼り合わせ部材16を介して第1のサポートウエハ14を貼り合せ状態で、カバーガラスウエハ10をカバーガラス4に個片化することができる。
Claims (8)
- カバーガラスの基材となる透明基板の一方面に、複数の枠状スペーサと、前記枠状スペーサを囲み、前記透明基板の外周に沿うようなリング状スペーサとを形成する工程と、
前記透明基板の一方面側に、前記枠状スペーサ及び前記リング状スペーサを覆うようにマスク材を付与する工程と、
前記透明基板を他方面側から所定範囲の厚さとなるよう除去する工程と、
前記透明基板から前記マスク材を除去する工程と、
前記透明基板の他方面に第1のサポートウエハを貼り合せる工程と、
半導体基板の一方面に複数の固体撮像素子を形成する工程と、
前記半導体基板を他方面側から所定範囲の厚さとなるよう除去する工程と、
前記半導体基板の他方面に第2のサポートウエハを貼り合せる工程と、
前記半導体基板と前記透明基板とを前記スペーサを介して接合する工程と、
前記第1のサポートウエハ及び前記第2のサポートウエハを前記透明基板および前記半導体基板から剥離する工程と、
前記透明基板を個片化する工程と、
前記半導体基板を個片化する工程と、
を備える固体撮像装置の製造方法。 - カバーガラスの基材となる透明基板の一方面に、複数の枠状スペーサと、前記枠状スペーサを囲み、前記透明基板の外周に沿うようなリング状スペーサとを形成する工程と、
前記透明基板の一方面側に、前記枠状スペーサ及び前記リング状スペーサを覆うようにマスク材を付与する工程と、
前記透明基板を他方面側から所定範囲の厚さとなるよう除去する工程と、
前記透明基板から前記マスク材を除去する工程と、
前記透明基板の他方面に第1のサポートウエハを貼り合せる工程と、
前記透明基板をカバーガラスに個片化する工程と、
半導体基板の一方面に複数の固体撮像素子を形成する工程と、
前記半導体基板を他方面側から所定範囲の厚さとなるよう除去する工程と、
前記半導体基板の他方面に第2のサポートウエハを貼り合せる工程と、
前記半導体基板と前記カバーガラスとを前記スペーサを介して接合する工程と、
前記第1のサポートウエハ及び前記第2のサポートウエハを前記透明基板および前記半導体基板から剥離する工程と、
前記半導体基板を個片化する工程と、
を備えることを特徴とする固体撮像装置の製造方法。 - 前記透明基板を他方面側から所定範囲の厚さとなるよう除去する工程は、前記透明基板を他方面側から、フッ酸を主成分とする薬液によりエッチングする工程である請求項1又は2記載の固体撮像装置の製造方法。
- 前記マスク材が、フッ酸に対して耐性を有する材料で構成された請求項3記載の固体撮像装置の製造方法。
- 前記透明基板を他方面側から所定範囲の厚さとなるよう除去する工程は、前記透明基板を他方面側から、ラッピング及び/又はポリッシングにより研磨する工程である請求項1又は2記載の固体撮像装置の製造方法。
- 前記マスク材は外的なエネルギーの付与でその接着力が低下する片面テープもしくは塗布液である請求項1~5に何れか1記載の固体撮像装置の製造方法。
- 前記透明基板と第1のサポートウエハを貼り合わせる部材は自己剥離性を有する両面テープもしくは接着剤である請求項1~6に何れか1記載の固体撮像装置の製造方法。
- 前記半導体基板と第2のサポートウエハを貼り合わせる部材は自己剥離性を有する両面テープもしくは接着剤である請求項1~7に何れか1記載の固体撮像装置の製造方法。
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- 2009-09-02 KR KR1020117005689A patent/KR20110056290A/ko not_active Application Discontinuation
- 2009-09-02 CN CN2009801357028A patent/CN102150269B/zh not_active Expired - Fee Related
- 2009-09-02 WO PCT/JP2009/065302 patent/WO2010029876A1/ja active Application Filing
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US20130168703A1 (en) * | 2011-12-28 | 2013-07-04 | Ledengin, Inc. | Deposition of phosphor on die top by stencil printing |
US8993358B2 (en) * | 2011-12-28 | 2015-03-31 | Ledengin, Inc. | Deposition of phosphor on die top by stencil printing |
Also Published As
Publication number | Publication date |
---|---|
CN102150269A (zh) | 2011-08-10 |
JP5091066B2 (ja) | 2012-12-05 |
KR20110056290A (ko) | 2011-05-26 |
US8772070B2 (en) | 2014-07-08 |
EP2325886A1 (en) | 2011-05-25 |
EP2325886A4 (en) | 2013-05-29 |
EP2325886B1 (en) | 2013-12-25 |
US20110189808A1 (en) | 2011-08-04 |
JP2010067836A (ja) | 2010-03-25 |
CN102150269B (zh) | 2013-08-28 |
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