WO2009156502A1 - Conteneur de transport pour alcoolates métalliques et procédé pour le transport d’alcoolates métalliques - Google Patents

Conteneur de transport pour alcoolates métalliques et procédé pour le transport d’alcoolates métalliques Download PDF

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Publication number
WO2009156502A1
WO2009156502A1 PCT/EP2009/058028 EP2009058028W WO2009156502A1 WO 2009156502 A1 WO2009156502 A1 WO 2009156502A1 EP 2009058028 W EP2009058028 W EP 2009058028W WO 2009156502 A1 WO2009156502 A1 WO 2009156502A1
Authority
WO
WIPO (PCT)
Prior art keywords
container
transport
transport container
measured
bulk material
Prior art date
Application number
PCT/EP2009/058028
Other languages
German (de)
English (en)
Inventor
Mathias Viandt
Claus Bauer
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Priority to US13/001,299 priority Critical patent/US20110099951A1/en
Priority to BRPI0915285A priority patent/BRPI0915285A2/pt
Priority to RU2011103009/12A priority patent/RU2011103009A/ru
Priority to CN2009801249540A priority patent/CN102076574A/zh
Priority to JP2011515398A priority patent/JP2011526231A/ja
Priority to EP09769350A priority patent/EP2303717A1/fr
Publication of WO2009156502A1 publication Critical patent/WO2009156502A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/04—Articles or materials enclosed in two or more containers disposed one within another
    • B65D77/06—Liquids or semi-liquids or other materials or articles enclosed in flexible containers disposed within rigid containers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/04—Articles or materials enclosed in two or more containers disposed one within another
    • B65D77/06—Liquids or semi-liquids or other materials or articles enclosed in flexible containers disposed within rigid containers
    • B65D77/061—Liquids or semi-liquids or other materials or articles enclosed in flexible containers disposed within rigid containers the containers being mounted on a pallet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/04—Articles or materials enclosed in two or more containers disposed one within another

Definitions

  • the invention relates to a transport container for metal alcoholates.
  • Metal alcoholates especially magnesium alcoholates, are known chemical compounds used to prepare catalysts used, for example, in polyolefin production.
  • magnesium ethanolate is highly flammable, irritating and violently reacts with water. There is a risk of spontaneous combustion under air. This also applies accordingly to other metal alcoholates.
  • a transport container for metal alcoholates comprising a rigid outer container which consists predominantly of renewable raw materials and a present in the outer container flexible bulk material container, wherein the flexible bulk material container at least one inner diffusion-tight layer with a water vapor diffusion rate WDD less than 0.3 g / ( m2 * d), measured at 38 ° C and 90% relative humidity, according to DIN 53122 and an oxygen and carbon dioxide diffusion rate of q A less than 0.3 cm 3 / (m 2 * d * bar), measured at 23 ° C and 75% relative humidity, according to DIN53380 and an outer flexible fabric layer having a maximum tensile force chain of at least 185 daV / 5 cm and a maximum tensile force of at least 150 daV / 5 cm, determined according to DIN EN-ISO 13934-1 of floor and sidewalls.
  • a rigid outer container Under a rigid outer container is a dimensionally stable container made of a material such as e.g. To understand cardboard or wood, which preferably has a strength, characterized by the puncture work according to DIN 53142, of at least 18 J, measured at 23 ° C and 50% relative humidity.
  • a flexible bulk material container is understood to mean a container whose container shape is variable, wherein the container shape is formed only by the filling material filled into the container.
  • the rigid outer container may consist of several individual parts, which are held together by metal clips, plastic adhesive sheets or similar fasteners. However, the major part, ie at least 50 wt .-%, preferably at least 70 wt .-%, particularly preferably at least 90 wt .-% of the rigid outer container consists of materials based on renewable raw materials.
  • the flexible bulk material container is inserted in the rigid outer container and is enclosed by this.
  • the inner layer and the outer layer of the flexible bulk material container can be wholly or partially connected to each other or be present separately.
  • the inner layer can consist of all film materials known to the person skilled in the art, as long as the required diffusion rates for water vapor, oxygen and carbon dioxide are maintained.
  • the inner layer is preferably a composite film, for example an aluminum composite liner consisting of polyethylene (PE), aluminum and polyethylene terephthalate (PET).
  • the outer layer of the flexible bulk material container is preferably made of a fabric, particularly preferably of a polypropylene fabric.
  • Such flexible bulk containers are also referred to as FIBC (flexible intermediate bulk containers).
  • the flexible bulk material container can be earthed to prevent a dust explosion that can be triggered by static electricity and to allow filling and draining in explosion-proof areas.
  • the inventively usable flexible bulk material container may have a filler neck and an outlet.
  • at least the inner layer of the flexible bulk goods container weldable, so that after filling and an overlay with inert gas permanently a product contamination with the atmosphere can be excluded.
  • the flexible bulk goods container can be transported on four carrying straps 3, 4, 5 and 6.
  • FIG. 1 A typical flexible bulk material container which can be used according to the invention is shown schematically in FIG.
  • the transport containers according to the present invention are intended to be used as disposable packaging, which can be disposed of after emptying. A return transport to the producer can therefore be omitted.
  • the proportion of the total weight of the packaging weight is approx. 35%. In the disposable containers according to the prior art, the proportion of the total weight of the packaging weight is about 20%. In the case of the transport container according to the invention, the proportion of the packaging weight in the total weight of transport containers filled with metal alcoholate is less than 15% and is thus significantly lower than in the containers of the prior art. Preferably, the weight of the transport container according to the invention is less than 10% of the total weight of transport containers filled with metal alcoholate.
  • the existing of predominantly renewable raw materials rigid outer container is preferably predominantly of wood, more preferably predominantly of cardboard.
  • the cardboard can consist of corrugated cardboard and have a size matched to the flexible bulk material container.
  • the carton should be such that at least two transport containers according to the invention can be stacked on top of each other.
  • the dimensions of the rigid outer container are preferably such that up to 20 transport containers each stacked on pallets can be accommodated in a known ship or rail container.
  • the rigid outer container may have the following dimensions: Internal dimensions in millimeters
  • L length 1128 (1100 + 14 + 14)
  • B width 1128 (1100 + 14 + 14)
  • H height 936 (880 + 14 + 14 + 14 + 14)
  • FIG. 1 A typical rigid outer container made of cardboard, as it can be used according to the invention, is shown schematically in FIG.
  • the transport container according to the invention preferably fulfills the criteria for a combination IBC type 11HZ2 within the meaning of the European Convention for the International Carriage of Dangerous Goods by Road (ADR) and the International Maritime Dangerous Goods Code (IMDG Code).
  • the transport container according to the invention has an approval for the transport of alkaline earth metal alkoxides and self-heating organic solids according to the Hazardous Goods Ordinance Road, Rail and Inland Navigation - GGVSEB and the Regulation on the transport of dangerous goods by seagoing vessels (Hazardous Goods Ordinance - GGVSee).
  • Chapter 3.2 List of Dangerous Goods, the ADR and the IMDG Code, e.g.
  • UN 3205 ERDALKALIMETAL ALCOHOLATE, N.A.G.
  • UN 3088 SELF-HEATABLE ORGANIC SOLID FABRIC, N.A.G.
  • Packing Group II Packing Group II, respectively, the packaging instruction IBC 06, which allows the use of a combination IBC type 11HZ2 as a bulk packaging.
  • the transport container according to the invention is characterized in that the flexible Bulk container from the transport container can be removed.
  • a removable flexible bulk material container facilitates the handling of the cargo.
  • a rigid outer container ensures good dimensional stability and stackability. By removing the flexible bulk goods container on site, handling and emptying are simplified.
  • the invention also encompasses a transport container according to the invention filled with a metal alcoholate.
  • the metal alcoholate is preferably selected from the group of magnesium ethanolate, magnesium methanolate,
  • the alkoxides may also be present in carbonated, solid form of the general formula Mg (ORi) x (OR 2 ) y (CO 2 ) z.
  • the powders or granules may also consist of mixtures of one or more of the above-mentioned materials with other materials (up to 50% by weight) (e.g., silica, titania, Mg hydroxides, Mg carbonates).
  • other materials up to 50% by weight
  • the transport container is filled with magnesium ethanolate.
  • the invention likewise encompasses a method for transporting metal alcoholates, comprising the steps of providing a transport container filling the container with metal alcoholate closing the container and subsequent transport, characterized in that the transport container comprises the following components:
  • the flexible bulk material container at least one inner diffusion-tight layer with a water vapor diffusion rate WDD less than 0.3 g / (m2 * d), preferably less than 0.1 g / (m2 * d), measured at 38 ° C and 90% relative humidity according to DIN53122 and an oxygen and carbon dioxide diffusion rate of each q a less than 0.3 cm3 / (m2 * d * bar), preferably less than 0.1 cm3 / (m2 * d * bar) measured at 23 ° C and 75% relative Humidity, according to DIN53380 and an outer flexible layer with a maximum tensile strength of at least 185 daV / 5 cm and a maximum tensile force of at least 150 daV / 5 cm measured according to DIN EN-ISO 13934-1, of the floor and side walls.
  • the flexible bulk material container for the transport of metal alcoholates, in particular of magnesium alcoholate, is preferably superimposed with nitrogen.
  • the flexible bulk material container which can be used according to the invention has a filler neck 1, an outlet neck 2 and the carrying straps 3, 4, 5 and 6.
  • a carton is arranged on a pallet 12 as a rigid outer container 11, in which the flexible bulk goods container is inserted.
  • the lid flaps IIa, IIb, 11c and Hd are still open.
  • bands for example CORDSTRAP ® -Polyester- strapping can be used.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Packages (AREA)

Abstract

L’invention concerne un conteneur pour alcoolates métalliques, comprenant un contenant extérieur (11) rigide qui est constitué principalement de matières premières renouvelables et un contenant (10)  de produit en vrac, flexible, se trouvant dans le contenant extérieur, le contenant de produit en vrac flexible présentant au moins une couche intérieure étanche à la diffusion et une couche d’étoffe extérieure flexible.
PCT/EP2009/058028 2008-06-28 2009-06-26 Conteneur de transport pour alcoolates métalliques et procédé pour le transport d’alcoolates métalliques WO2009156502A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US13/001,299 US20110099951A1 (en) 2008-06-28 2009-06-26 Transport container for metal alcoholates and method for transporting metal alcoholates
BRPI0915285A BRPI0915285A2 (pt) 2008-06-28 2009-06-26 recipiente de transporte para alcoolatos de metal e método para transporte de alcoolatos de metal
RU2011103009/12A RU2011103009A (ru) 2008-06-28 2009-06-26 Транспортный контейнер для транспортировки алкоголятов металлов и способ транспортировки алкоголятов металлов
CN2009801249540A CN102076574A (zh) 2008-06-28 2009-06-26 用于金属醇化物的运输容器及用于运输金属醇化物的方法
JP2011515398A JP2011526231A (ja) 2008-06-28 2009-06-26 金属アルコレート用の運搬容器および金属アルコレートを運搬する方法
EP09769350A EP2303717A1 (fr) 2008-06-28 2009-06-26 Conteneur de transport pour alcoolates métalliques et procédé pour le transport d'alcoolates métalliques

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008030765 2008-06-28
DE102008030765.3 2008-06-28

Publications (1)

Publication Number Publication Date
WO2009156502A1 true WO2009156502A1 (fr) 2009-12-30

Family

ID=40943849

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/058028 WO2009156502A1 (fr) 2008-06-28 2009-06-26 Conteneur de transport pour alcoolates métalliques et procédé pour le transport d’alcoolates métalliques

Country Status (8)

Country Link
US (1) US20110099951A1 (fr)
EP (1) EP2303717A1 (fr)
JP (1) JP2011526231A (fr)
KR (1) KR20110036091A (fr)
CN (1) CN102076574A (fr)
BR (1) BRPI0915285A2 (fr)
RU (1) RU2011103009A (fr)
WO (1) WO2009156502A1 (fr)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE8531565U1 (de) * 1985-11-08 1986-08-28 Bayer Ag, 5090 Leverkusen Verpackung für granulatförmiges oder kleinkörniges Gut mit hohem Reinheitsgrad
US20040251300A1 (en) * 2002-10-16 2004-12-16 Perkins David W. Interlocking container
WO2005080229A2 (fr) * 2004-02-21 2005-09-01 Abdelkader Alami Recipient flexible

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2329311A (en) * 1940-06-05 1943-09-14 Harry F Waters Method of producing liquid-containing packages
JPS6019433U (ja) * 1983-07-19 1985-02-09 カンボウプラス株式会社 防湿積層シ−ト状物
JP2926474B2 (ja) * 1996-04-26 1999-07-28 岡田紙工株式会社 粉粒体の袋容器
JP2000128277A (ja) * 1998-10-23 2000-05-09 Mitsubishi Kagaku Sanshi Corp 高気密性フレキシブルコンテナ
JP2002337981A (ja) * 2001-05-15 2002-11-27 Fujimori Kogyo Co Ltd 包装体および包装体の製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE8531565U1 (de) * 1985-11-08 1986-08-28 Bayer Ag, 5090 Leverkusen Verpackung für granulatförmiges oder kleinkörniges Gut mit hohem Reinheitsgrad
US20040251300A1 (en) * 2002-10-16 2004-12-16 Perkins David W. Interlocking container
WO2005080229A2 (fr) * 2004-02-21 2005-09-01 Abdelkader Alami Recipient flexible

Also Published As

Publication number Publication date
JP2011526231A (ja) 2011-10-06
US20110099951A1 (en) 2011-05-05
KR20110036091A (ko) 2011-04-06
RU2011103009A (ru) 2013-07-27
BRPI0915285A2 (pt) 2016-02-16
CN102076574A (zh) 2011-05-25
EP2303717A1 (fr) 2011-04-06

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