WO2009150740A1 - Liquide de travail par abrasion pour l'aluminium ou son alliage - Google Patents

Liquide de travail par abrasion pour l'aluminium ou son alliage Download PDF

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Publication number
WO2009150740A1
WO2009150740A1 PCT/JP2008/060788 JP2008060788W WO2009150740A1 WO 2009150740 A1 WO2009150740 A1 WO 2009150740A1 JP 2008060788 W JP2008060788 W JP 2008060788W WO 2009150740 A1 WO2009150740 A1 WO 2009150740A1
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WO
WIPO (PCT)
Prior art keywords
aluminum
grinding
alloy
acid
dicarboxylic acid
Prior art date
Application number
PCT/JP2008/060788
Other languages
English (en)
Japanese (ja)
Inventor
武志 北村
哲雄 鈴木
イェー ホーイ タン
シャウ ピン リー
Original Assignee
日本クエーカー・ケミカル株式会社
株式会社神戸製鋼所
コウベ・プレシジョン・テクノロジー・センドリアン・ベルハード
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日本クエーカー・ケミカル株式会社, 株式会社神戸製鋼所, コウベ・プレシジョン・テクノロジー・センドリアン・ベルハード filed Critical 日本クエーカー・ケミカル株式会社
Priority to PCT/JP2008/060788 priority Critical patent/WO2009150740A1/fr
Priority to JP2009532637A priority patent/JP4465039B2/ja
Publication of WO2009150740A1 publication Critical patent/WO2009150740A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Definitions

  • the present invention relates to a grinding fluid for aluminum or an alloy thereof, and particularly to a grinding fluid for aluminum or an alloy thereof suitable for grinding a hard disk substrate.
  • Aluminum alloys are often used for hard disk substrates as recording media.
  • an aluminum alloy plate for a hard disk is manufactured by the following method. First, the rolled aluminum coil is punched into a donut-shaped disk, and the disks are stacked. Next, pressure annealing is performed to ensure the flatness of the disk, and the inner and outer circumferences of the disk are end-cut. Thereafter, double-side grinding is performed to produce an aluminum alloy substrate.
  • a method for grinding of an aluminum alloy plate for a hard disk, a method is generally used in which a PVA grindstone is used and both surfaces are ground simultaneously by a double-sided lapping machine.
  • a grinding method has the following problems as the grinding amount increases. Clogging occurred on the entire surface of the grinding wheel that contacted the substrate, resulting in decreased grinding efficiency. Further, scratches were generated on the ground surface of the substrate due to grinding sludge and falling abrasive grains generated during grinding. Furthermore, clogging locally occurred on the substrate contact surface of the grindstone, and scratches (scratches) occurred on the substrate.
  • the present invention sufficiently suppresses the occurrence of general and local clogging on the substrate contact surface of the grindstone during grinding of aluminum or its alloy substrate, resulting from grinding sludge and falling abrasive grains on the substrate grinding surface.
  • An object of the present invention is to provide a grinding fluid for aluminum or its alloy that sufficiently suppresses the occurrence of scratches.
  • the present invention (A) 2 to 15% by weight of a monocarboxylic acid having 12 to 18 carbon atoms; (B) 3-15% by weight of an alicyclic dicarboxylic acid; (C) The water-soluble amine contains at least an equivalent amount required for neutralization of the monocarboxylic acid (A) and the alicyclic dicarboxylic acid (B); and (D) contains 15% by weight or more of a nonionic surfactant.
  • the present invention relates to a grinding fluid for aluminum or alloys thereof.
  • the grinding fluid for aluminum or its alloy it is possible to sufficiently suppress the occurrence of general and local clogging on the substrate contact surface of the grindstone when grinding a substrate made of aluminum or its alloy. And generation
  • the grinding fluid according to the present invention (hereinafter sometimes simply referred to as a machining fluid) is used after being diluted with water during grinding of aluminum or an alloy thereof (hereinafter referred to as an aluminum alloy or the like).
  • the grinding fluid of the present invention may contain water or not contain water as long as it is diluted with water at the time of use.
  • the processing oil of the present invention contains at least the following components (A) to (D), and usually further contains water as the balance.
  • Component (A) is a monocarboxylic acid having 12 to 18 carbon atoms, specifically an aliphatic hydrocarbon compound having the same carbon number and having only one carboxyl group in the molecule.
  • monocarboxylic acids include unsaturated aliphatic monocarboxylic acids and saturated aliphatic monocarboxylic acids. From the viewpoint of more effectively suppressing local clogging of the grindstone, it is preferable to use at least an unsaturated aliphatic monocarboxylic acid.
  • the unsaturated aliphatic monocarboxylic acid examples include myristoleic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, and elaidic acid.
  • the preferred number of carbons of the unsaturated aliphatic monocarboxylic acid is 14-18, especially 16-18.
  • the most preferred unsaturated aliphatic monocarboxylic acid is oleic acid.
  • saturated aliphatic monocarboxylic acid examples include myristic acid, palmitic acid, stearic acid, and the like.
  • the preferred carbon number of the saturated aliphatic monocarboxylic acid is 14-18, especially 16-18.
  • Such unsaturated aliphatic monocarboxylic acids and saturated aliphatic monocarboxylic acids are readily available as commercial products.
  • the content of component (A) is 2 to 15% by weight, preferably 2 to 10% by weight.
  • the grindstone will be clogged as a whole, and scratches will occur on the substrate.
  • the component (A) is too small, local clogging occurs in the grindstone, and scratches occur in the substrate.
  • the component (A) two or more kinds of compounds may be used, and in this case, the total content thereof may be within the above range. In the present specification, the content is expressed as a ratio to the total amount of the machining fluid.
  • Component (B) is an alicyclic dicarboxylic acid, specifically an alicyclic hydrocarbon compound having only two carboxyl groups in the molecule.
  • alicyclic dicarboxylic acid examples include cycloolefin dicarboxylic acid having an unsaturated bond in the carbocyclic ring and cycloparaffin dicarboxylic acid having a saturated carbocyclic ring structure. From the viewpoint of more effectively suppressing the overall clogging of the grindstone, it is preferable to use only cycloolefin dicarboxylic acid as the component (B). If an aliphatic dicarboxylic acid or an aromatic dicarboxylic acid is used in place of the alicyclic dicarboxylic acid, the grindstone is totally clogged, and the substrate is scratched.
  • cycloolefin dicarboxylic acid examples include general formula (b1); And a cycloolefin dicarboxylic acid (hereinafter referred to as cycloolefin dicarboxylic acid (b1)).
  • R 1 is an alkylene group having 4 to 10 carbon atoms, preferably 6 to 8 carbon atoms.
  • R 2 is a single bond (-) or an alkylene group having 1 to 3 carbon atoms, preferably a single bond.
  • R 3 is an alkyl group having 4 to 8 carbon atoms, preferably 5 to 7 carbon atoms.
  • the alkyl group may be linear or branched, and is preferably linear.
  • cycloolefin dicarboxylic acid (b1) include, for example, 8- (5-carboxy-4-hexyl-2-cyclohexen-1-yl) octanoic acid, 8- (6-carboxy-4-pentyl-2-cyclohexene) -1-yl) octanoic acid, 8- (6-carboxy-4-hexyl-2-cyclohexen-1-yl) octanoic acid, and the like.
  • the most preferred cycloolefin dicarboxylic acid is 8- (5-carboxy-4-hexyl-2-cyclohexen-1-yl) octanoic acid.
  • the cycloolefin dicarboxylic acid (b1) is available as, for example, commercially available Diacid 1550 (manufactured by Harima Chemicals Co., Ltd.).
  • cycloparaffin dicarboxylic acid examples include general formula (b2); And cycloparaffin dicarboxylic acid (hereinafter referred to as cycloparaffin dicarboxylic acid (b2)).
  • R 4 is an alkylene group having 4 to 10 carbon atoms, preferably 6 to 8 carbon atoms.
  • R 5 is a single bond (-) or an alkylene group having 1 to 3 carbon atoms, preferably a single bond.
  • R 6 is an alkyl group having 4 to 8 carbon atoms, preferably 5 to 7 carbon atoms.
  • the alkyl group may be linear or branched, and is preferably linear.
  • cycloparaffin dicarboxylic acid (b2) include, for example, 8- (6-carboxy-4-hexyl-cyclohexyl) octanoic acid, 8- (3-carboxy-4-hexyl-cyclohexyl) octanoic acid, and the like.
  • component (B) The content of component (B) is 3 to 15% by weight, preferably 3 to 10% by weight. If the component (B) is too much, the grindstone will be clogged as a whole, and scratches will occur on the substrate. If the component (B) is too small, the grindstone will be clogged as a whole and grinding efficiency will be reduced. Two or more types of compounds may be used as the component (B), and in this case, the total content thereof may be within the above range.
  • Component (C) is a water-soluble amine, for example, alkylamines such as ethylamine and propylamine; alkanolamines such as monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine and triisopropanolamine; morpholine and the like A cyclic amine; an alkyl alkanolamine such as ethyldiethanolamine; an alkyl diamine such as metaxylenediamine; and the like.
  • a preferred water-soluble amine is alkanolamine.
  • component (C) is not less than the equivalents required for neutralizing components (A) and (B), and preferably 10 to 25% by weight. When there is too little component (C), the solubility to water will fall. Two or more kinds of compounds may be used as the component (C), and in this case, the total content thereof may be within the above range.
  • Component (D) is a nonionic surfactant, and any nonionic surfactant conventionally used in the field of grinding fluids can be used.
  • nonionic surfactants include polyoxyalkylene, polyoxyalkylene alkyl ether, polyoxyalkylene alkyl phenyl ether, and polyoxyalkylene alkyl ester. From the viewpoint of suppressing clogging of the entire grindstone, it is preferable to use at least one compound selected from polyoxyalkylene, polyoxyalkylene alkyl ether, and polyoxyalkylene alkylphenyl ether. More preferably, at least polyoxyalkylene and polyoxyalkylene alkyl ether are used in combination.
  • At least polyoxyalkylene, polyoxyalkylene alkyl ether, and polyoxyalkylene alkylphenyl ether are used in combination.
  • an anionic surfactant or a cationic surfactant is used instead of the component (D)
  • the zeta potential is affected and local clogging occurs.
  • polyoxyalkylene for example, general formula (d1); HO (CH 2 CH 2 O) p 1- (CH 2 CH (CH 3 ) O) p 2- (CH 2 CH (C 2 H 5 ) O) p 3 -H (d1) And polyoxyalkylene (hereinafter referred to as polyoxyalkylene (d1)).
  • p1 + p2 + p3 is not particularly limited as long as the molecular weight falls within the range described later, and p1, p2 and p3 are each independently an integer of 0 or more (provided that p1, p2 And p3 are not simultaneously 0).
  • p1 is an integer of 1 or more, particularly 3 to 6
  • p2 and p3 are each independently an integer of 0 or more, particularly 0 to 8.
  • the ratio of p1 to p2 + p3 is 10:90 to 90:10.
  • the polyoxyalkylene (d1) may have a oxyalkylene part such as an oxyethylene part, an oxypropylene part, or an oxybutylene part in a block type or a random type, but is preferably a block type.
  • Polyoxyalkylene (d1) is available as commercially available Pluronic (manufactured by BASF Japan).
  • polyoxyalkylene alkyl ether examples include the general formula (d2); R 7 O (CH 2 CH 2 O) n1- (CH 2 CH (CH 3 ) O) n2- (CH 2 CH (C 2 H 5 ) O) n3 -H (d2) And polyoxyalkylene alkyl ethers (hereinafter referred to as polyoxyalkylene alkyl ethers (d2)).
  • R 7 is an alkyl group having 8 to 18 carbon atoms, preferably 10 to 14 carbon atoms.
  • n1 + n2 + n3 is not particularly limited as long as the molecular weight falls within the range described later, and n1, n2, and n3 are each independently an integer of 0 or more (provided that n1, n2, and n3 are not 0 at the same time) ).
  • n1 is an integer of 1 or more, particularly 3 to 9
  • n2 and n3 are each independently an integer of 0 or more, particularly 0 to 2.
  • the ratio of n1 to n2 + n3 is 10:90 to 100: 0.
  • the polyoxyalkylene alkyl ether (d2) may be a random type, even if the oxyalkylene part such as an oxyethylene part, an oxypropylene part, or an oxybutylene part is a block type In particular, a block type is preferable.
  • Polyoxyalkylene alkyl ether (d2) is available as commercially available Lutensol (manufactured by BASF Japan).
  • polyoxyalkylene alkylphenyl ether examples include the general formula (d3); R 8 -Ph-O (CH 2 CH 2 O) m1- (CH 2 CH (CH 3 ) O) m2- (CH 2 CH (C 2 H 5 ) O) m3 -H (d3) And polyoxyalkylene alkylphenyl ether (hereinafter referred to as polyoxyalkylene alkylphenyl ether (d3)).
  • R 8 is an alkyl group having 6 to 10 carbon atoms, preferably 8 to 9 carbon atoms.
  • Ph is a phenylene group, preferably a 1,4-phenylene group.
  • m1 + m2 + m3 is not particularly limited as long as the molecular weight falls within the range described below, and m1, m2, and m3 are each independently an integer of 0 or more (provided that m1, m2, and m3 are not 0 at the same time) ).
  • m1 is an integer of 1 or more, particularly 1 to 12
  • m2 and m3 are each independently an integer of 0 or more, particularly 0 to 10.
  • the ratio of m1 to m2 + m3 is 10:90 to 100: 0.
  • the polyoxyalkylene alkylphenyl ether (d3) may be a block type oxyalkylene part such as an oxyethylene part, an oxypropylene part, or an oxybutylene part, or randomly although it may be a mold, a block type is particularly preferable.
  • Polyoxyalkylene alkyl phenyl ether (d3) is available as commercially available nonipol (manufactured by Sanyo Chemical Industries).
  • the average molecular weight of the nonionic surfactant is usually 200 to 10,000 in terms of weight average molecular weight.
  • the content of the component (D) is 15% by weight or more, particularly 15 to 90% by weight, preferably 15 to 80% by weight, more preferably 30 to 50% by weight. If the component (D) is too small, the grindstone will be clogged as a whole and grinding efficiency will be reduced. Two or more kinds of compounds may be used as the component (D), and in this case, the total content thereof may be within the above range.
  • the working fluid of the present invention is diluted with water at the time of use, it does not necessarily contain water, but usually a predetermined amount of the above components are added to the remaining water and sufficient It is manufactured by mixing.
  • the processing fluid of the present invention exhibits sufficient storage stability even when it contains water.
  • the working fluid of the present invention is stored in a container and traded on the market.
  • the working fluid is diluted 20 to 1000 times, preferably 100 to 1000 times by weight, with water as an aqueous solution for grinding. used. Grinding is performed by interposing such a water dilution body (aqueous solution for grinding) of the working fluid between the aluminum alloy to be ground and the grindstone.
  • the grindstone those conventionally used for grinding aluminum alloys and the like can be used, and examples thereof include a porous grindstone represented by a PVA grindstone.
  • the working fluid of the present invention provides the effect of the present invention, particularly the effect of simultaneously suppressing both the overall and local clogging of the grindstone.
  • the details of the mechanism are not clear, but are thought to be based on the following phenomenon.
  • the absolute value of the zeta potential of the aluminum-based fine powder generated during grinding can be increased. Therefore, the dispersibility of the aluminum-based fine powder is improved, and aggregation / accumulation on the inner wall of the grindstone is suppressed. As a result, it is considered that both the overall and local clogging of the grindstone are simultaneously suppressed and the effect of the present invention can be obtained.
  • the working fluid of the present invention exhibits a zeta potential of ⁇ 50 mV or less, particularly ⁇ 60 to ⁇ 50 mV, with respect to aluminum fine powder generated when an aluminum alloy is ground by diluting with water at the aforementioned magnification.
  • Example / Comparative Example The processing liquid was prepared by mixing the components described in the table.
  • the machining fluid was evaluated for the following items.
  • % means “% by weight”.
  • Lunac OA manufactured by Kao Corporation: oleic acid 75%, palmitoleic acid 6%, linoleic acid 6%, palmitic acid 5%, myristic acid 3%, myristoleic acid 3%, stearic acid 1%, linolenic acid 1%.
  • C10 saturated aliphatic monocarboxylic acid diacid 1550 manufactured by Harima Chemicals
  • Nonionic active agent A POEO block polymer, PO (6) EO (4), weight average molecular weight 2800.
  • the working fluid of the present invention is useful as a lubricating oil and a cleaning agent used for washing a workpiece after grinding or processing aluminum or an alloy thereof.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)

Abstract

La présente invention concerne un liquide de travail par abrasion pour l'aluminium ou son alliage qui, lors d'un travail par abrasion d'un substrat d'aluminium ou son alliage, est capable d'inhiber de manière satisfaisante tout encrassement total ou local sur une surface de contact avec le substrat du fusil à affûter et également d'inhiber de manière satisfaisante tout rayage (apparition de défectuosités) d'une surface du substrat à abraser attribuées à la boue d'abrasion et aux grains abrasifs jetés. Le liquide de travail par abrasion pour l'aluminium ou son alliage est caractérisé en ce qu'il contient (A) 2 à 15 % en poids d’un acide monocarboxylique en C12 à C18, (B) 3 à 15 % en poids d'un acide dicarboxylique alicyclique, (C) une amine soluble dans l'eau présente en une quantité au moins égale à un équivalent en poids pour la neutralisation de l'acide monocarboxylique (A) et de l'acide dicarboxylique alicyclique (B), et (D) 15 % en poids ou plus de tensioactif non ionique.
PCT/JP2008/060788 2008-06-12 2008-06-12 Liquide de travail par abrasion pour l'aluminium ou son alliage WO2009150740A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/JP2008/060788 WO2009150740A1 (fr) 2008-06-12 2008-06-12 Liquide de travail par abrasion pour l'aluminium ou son alliage
JP2009532637A JP4465039B2 (ja) 2008-06-12 2008-06-12 アルミニウムまたはその合金用研削加工液

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2008/060788 WO2009150740A1 (fr) 2008-06-12 2008-06-12 Liquide de travail par abrasion pour l'aluminium ou son alliage

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Publication Number Publication Date
WO2009150740A1 true WO2009150740A1 (fr) 2009-12-17

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WO (1) WO2009150740A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010103806A1 (fr) * 2009-03-11 2010-09-16 出光興産株式会社 Fluide de traitement de métaux
JP2014080623A (ja) * 2014-01-14 2014-05-08 Idemitsu Kosan Co Ltd 金属加工油剤
WO2016125761A1 (fr) * 2015-02-06 2016-08-11 出光興産株式会社 Composition de fluide pour le travail des métaux soluble dans l'eau et son procédé d'utilisation

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Publication number Priority date Publication date Assignee Title
JPS63168493A (ja) * 1986-12-29 1988-07-12 Yushiro Chem Ind Co Ltd 難燃性切削油剤
JPH0488097A (ja) * 1990-07-31 1992-03-19 Asahi Denka Kogyo Kk 金属加工油
JP2000063863A (ja) * 1998-08-13 2000-02-29 Asahi Denka Kogyo Kk 金属加工油組成物
JP2000160186A (ja) * 1998-11-30 2000-06-13 Yushiro Chem Ind Co Ltd 水溶性金属加工用油剤
JP2003041285A (ja) * 2001-07-30 2003-02-13 Neos Co Ltd アルミニウムまたはその合金用水溶性切削研削油剤

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002241742A (ja) * 2001-02-21 2002-08-28 Daido Chem Ind Co Ltd 磁気ディスク基板に用いるアルミニウム合金板用研削加工液および研削加工方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63168493A (ja) * 1986-12-29 1988-07-12 Yushiro Chem Ind Co Ltd 難燃性切削油剤
JPH0488097A (ja) * 1990-07-31 1992-03-19 Asahi Denka Kogyo Kk 金属加工油
JP2000063863A (ja) * 1998-08-13 2000-02-29 Asahi Denka Kogyo Kk 金属加工油組成物
JP2000160186A (ja) * 1998-11-30 2000-06-13 Yushiro Chem Ind Co Ltd 水溶性金属加工用油剤
JP2003041285A (ja) * 2001-07-30 2003-02-13 Neos Co Ltd アルミニウムまたはその合金用水溶性切削研削油剤

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010103806A1 (fr) * 2009-03-11 2010-09-16 出光興産株式会社 Fluide de traitement de métaux
JP2010209246A (ja) * 2009-03-11 2010-09-24 Idemitsu Kosan Co Ltd 金属加工油剤
JP2014080623A (ja) * 2014-01-14 2014-05-08 Idemitsu Kosan Co Ltd 金属加工油剤
WO2016125761A1 (fr) * 2015-02-06 2016-08-11 出光興産株式会社 Composition de fluide pour le travail des métaux soluble dans l'eau et son procédé d'utilisation
JP2016145293A (ja) * 2015-02-06 2016-08-12 出光興産株式会社 水溶性金属加工油組成物およびその使用方法

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JPWO2009150740A1 (ja) 2011-11-10

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