WO2009125680A3 - 誘電体材料の製造方法 - Google Patents

誘電体材料の製造方法 Download PDF

Info

Publication number
WO2009125680A3
WO2009125680A3 PCT/JP2009/056213 JP2009056213W WO2009125680A3 WO 2009125680 A3 WO2009125680 A3 WO 2009125680A3 JP 2009056213 W JP2009056213 W JP 2009056213W WO 2009125680 A3 WO2009125680 A3 WO 2009125680A3
Authority
WO
WIPO (PCT)
Prior art keywords
heating
dielectric material
intermediate product
lactic acid
particle powder
Prior art date
Application number
PCT/JP2009/056213
Other languages
English (en)
French (fr)
Other versions
WO2009125680A2 (ja
Inventor
和田智志
近藤修平
深沢純也
Original Assignee
日本化学工業株式会社
国立大学山梨大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日本化学工業株式会社, 国立大学山梨大学 filed Critical 日本化学工業株式会社
Publication of WO2009125680A2 publication Critical patent/WO2009125680A2/ja
Publication of WO2009125680A3 publication Critical patent/WO2009125680A3/ja

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • C04B35/462Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
    • C04B35/465Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates
    • C04B35/468Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates
    • C04B35/4682Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates based on BaTiO3 perovskite phase
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • C01G23/003Titanates
    • C01G23/006Alkaline earth titanates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62645Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/62675Thermal treatment of powders or mixtures thereof other than sintering characterised by the treatment temperature
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62645Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/6268Thermal treatment of powders or mixtures thereof other than sintering characterised by the applied pressure or type of atmosphere, e.g. in vacuum, hydrogen or a specific oxygen pressure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/018Dielectrics
    • H01G4/06Solid dielectrics
    • H01G4/08Inorganic dielectrics
    • H01G4/12Ceramic dielectrics
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/018Dielectrics
    • H01G4/06Solid dielectrics
    • H01G4/08Inorganic dielectrics
    • H01G4/12Ceramic dielectrics
    • H01G4/1209Ceramic dielectrics characterised by the ceramic dielectric material
    • H01G4/1218Ceramic dielectrics characterised by the ceramic dielectric material based on titanium oxides or titanates
    • H01G4/1227Ceramic dielectrics characterised by the ceramic dielectric material based on titanium oxides or titanates based on alkaline earth titanates
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/80Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/64Nanometer sized, i.e. from 1-100 nanometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/10Solid density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/449Organic acids, e.g. EDTA, citrate, acetate, oxalate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5409Particle size related information expressed by specific surface values
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5445Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5454Particle size related information expressed by the size of the particles or aggregates thereof nanometer sized, i.e. below 100 nm
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/72Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
    • C04B2235/724Halogenide content
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/79Non-stoichiometric products, e.g. perovskites (ABO3) with an A/B-ratio other than 1
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/16Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor
    • H05K1/162Printed circuits incorporating printed electric components, e.g. printed resistor, capacitor, inductor incorporating printed capacitors

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Power Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Thermal Sciences (AREA)
  • Nanotechnology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Inorganic Insulating Materials (AREA)

Abstract

 本発明は、微粒でありながら凝集が防止されており、比誘電率が高い誘電体材料を容易に製造し得る方法を提供する。 本発明は、下記の無定形微粒子粉末を空気中230℃以上530℃未満で加熱して中間生成物を得る第1の工程と、第1の工程で得られた中間生成物を、減圧下700℃以上1000℃以下で加熱する第2の工程とを備えることを特徴とする。〔無定形微粒子粉末〕 チタン、バリウム、乳酸及び蓚酸を含み、BET比表面積が6m2/g以上で、Ba原子とTi原子のモル比(Ba/Ti)が0.98~1.02で、乳酸に由来する1120~1140cm-1及び1040~1060cm-1に赤外線吸収スペクトルピークを有することを特徴とする無定形微粒子粉末。
PCT/JP2009/056213 2008-03-19 2009-03-19 誘電体材料の製造方法 WO2009125680A2 (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2008-072408 2008-03-19
JP2008072408 2008-03-19
JP2009061689A JP5410124B2 (ja) 2008-03-19 2009-03-13 誘電体材料の製造方法
JP2009-061689 2009-03-13

Publications (2)

Publication Number Publication Date
WO2009125680A2 WO2009125680A2 (ja) 2009-10-15
WO2009125680A3 true WO2009125680A3 (ja) 2009-12-03

Family

ID=41162350

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2009/056213 WO2009125680A2 (ja) 2008-03-19 2009-03-19 誘電体材料の製造方法

Country Status (2)

Country Link
JP (1) JP5410124B2 (ja)
WO (1) WO2009125680A2 (ja)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010047428A (ja) * 2008-08-19 2010-03-04 Nippon Chem Ind Co Ltd チタン複合塩粉末、その製造方法及びそれを用いたペロブスカイト型チタン複合酸化物粉末の製造方法
JP4894908B2 (ja) * 2009-11-17 2012-03-14 Tdk株式会社 誘電体磁器組成物
KR102539617B1 (ko) * 2014-06-13 2023-06-07 도다 고교 가부시끼가이샤 티타늄산바륨 미립자 분말, 분산체 및 도막
CN114317076B (zh) * 2021-12-14 2022-10-25 菏泽学院 一种同核异壳纳米颗粒电流变液及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01294527A (ja) * 1988-05-20 1989-11-28 Mitsubishi Petrochem Co Ltd Abo↓3型ペロブスカイト型金属酸化物の製造方法
WO2005093763A1 (ja) * 2004-03-29 2005-10-06 Nippon Chemical Industrial Co., Ltd. 複合誘電体材料用無機誘電体粉末及び複合誘電体材料
WO2005094978A1 (ja) * 2004-03-18 2005-10-13 Gifu University 粒子を分散させるための組成物、粒子が分散されている組成物及びその製造方法並びにアナターゼ型酸化チタン焼結体
JP2007161502A (ja) * 2005-12-09 2007-06-28 Gifu Univ チタン含有複合酸化物形成用溶液及びその製造方法、チタン含有複合酸化物の製造方法、チタン含有複合酸化物の前駆体、誘電体材料、並びに誘電体材料の製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01294527A (ja) * 1988-05-20 1989-11-28 Mitsubishi Petrochem Co Ltd Abo↓3型ペロブスカイト型金属酸化物の製造方法
WO2005094978A1 (ja) * 2004-03-18 2005-10-13 Gifu University 粒子を分散させるための組成物、粒子が分散されている組成物及びその製造方法並びにアナターゼ型酸化チタン焼結体
WO2005093763A1 (ja) * 2004-03-29 2005-10-06 Nippon Chemical Industrial Co., Ltd. 複合誘電体材料用無機誘電体粉末及び複合誘電体材料
JP2007161502A (ja) * 2005-12-09 2007-06-28 Gifu Univ チタン含有複合酸化物形成用溶液及びその製造方法、チタン含有複合酸化物の製造方法、チタン含有複合酸化物の前駆体、誘電体材料、並びに誘電体材料の製造方法

Also Published As

Publication number Publication date
WO2009125680A2 (ja) 2009-10-15
JP2009256190A (ja) 2009-11-05
JP5410124B2 (ja) 2014-02-05

Similar Documents

Publication Publication Date Title
WO2009125681A3 (ja) チタン酸バリウムの製造方法
WO2009125680A3 (ja) 誘電体材料の製造方法
WO2010078524A3 (en) Ceramic article and process for making the same
CN101565317B (zh) 电介质粒子的制造方法
WO2008102785A1 (ja) 無定形微粒子粉末、その製造方法およびそれを用いたペロブスカイト型チタン酸バリウム粉末
WO2006012279A3 (en) High capacitance tantalum flakes and methods of producing the same
JP2010089981A5 (ja)
CN105050958A (zh) 钛酸钾的制造方法
WO2014077176A3 (ja) 被覆チタン酸バリウム微粒子及びその製造方法
CN101283692A (zh) 改善面粉品质及面制食品品质的面粉加工方法
CN103360059A (zh) 陶瓷粉末和层叠陶瓷电容器
Sundararajan et al. Combined effects of milling and calcination methods on the characteristics of nanocrystalline barium titanate
WO2016021464A1 (ja) αアルミナ成形体およびその製造方法
CN105164052A (zh) 钛酸钡的制造方法
KR101381710B1 (ko) 코크스를 이용한 전극용 활성탄의 제조방법 및 전극용 활성탄 조성물의 제조방법
Verma et al. Effect of grain size on structural and dielectric properties of barium titanate piezoceramics synthesized by high energy ball milling
CN106745214A (zh) 一种超细电子级高纯钛酸钙的生产方法
TWI541189B (zh) 熱電複合材及其製造方法
CN102167975A (zh) 一种红外防伪发光材料及其制备方法和应用
GB2534069A (en) Method for producing barium titanate powder
Kim et al. Properties of BaTiO3 synthesized from barium titanyl oxalate
TWI635067B (zh) 鈦酸鋇粉體的製造方法
US9796631B2 (en) Method of manufacturing barium titanate and electronic component of barium titanate
JP2005289788A (ja) 誘電体用酸化物粉末及び誘電体用酸化物粉末の製造方法及び積層セラミックコンデンサ
KR20120043348A (ko) 고상법을 이용한 티탄산바륨 분말의 제조방법

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 09729979

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 09729979

Country of ref document: EP

Kind code of ref document: A2