WO2009117546A1 - A system and method for enhanced removal of co2 from a mixed gas stream via use of a catalyst - Google Patents

A system and method for enhanced removal of co2 from a mixed gas stream via use of a catalyst Download PDF

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Publication number
WO2009117546A1
WO2009117546A1 PCT/US2009/037608 US2009037608W WO2009117546A1 WO 2009117546 A1 WO2009117546 A1 WO 2009117546A1 US 2009037608 W US2009037608 W US 2009037608W WO 2009117546 A1 WO2009117546 A1 WO 2009117546A1
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WO
WIPO (PCT)
Prior art keywords
catalyst
flue gas
gas stream
amine
mixed gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2009/037608
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English (en)
French (fr)
Inventor
Nareshkumar B. Handagama
Zheng Liu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GE Vernova GmbH
Original Assignee
Alstom Technology AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2011500946A priority Critical patent/JP2011515210A/ja
Priority to MX2010010326A priority patent/MX2010010326A/es
Priority to EP09721367A priority patent/EP2252387A1/en
Priority to BRPI0908957-8A priority patent/BRPI0908957A2/pt
Priority to RU2010143048/05A priority patent/RU2486947C2/ru
Priority to KR1020107023323A priority patent/KR101224439B1/ko
Priority to CN2009801101685A priority patent/CN101977669A/zh
Priority to CA2718725A priority patent/CA2718725C/en
Application filed by Alstom Technology AG filed Critical Alstom Technology AG
Priority to AU2009225583A priority patent/AU2009225583B2/en
Publication of WO2009117546A1 publication Critical patent/WO2009117546A1/en
Priority to IL207982A priority patent/IL207982A0/en
Priority to ZA2010/06479A priority patent/ZA201006479B/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18—Absorbing units; Liquid distributors therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/864—Removing carbon monoxide or hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/204—Alkaline earth metals
    • B01D2255/2047—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20753—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Definitions

  • the proposed invention relates to a system and method for removing carbon dioxide (CO 2 ) from a process gas stream containing carbon dioxide and sulphur dioxide. More particularly, the proposed invention is directed to a solvent based flue gas processing system for removing CO 2 from a flue gas stream in which a catalyst is provided to increase the efficiency of the solvent in capturing CO2 from the flue gas stream or in regenerating the solvent.
  • CO 2 carbon dioxide
  • a hot process gas (or flue gas) is generated.
  • a flue gas will often contain, among other things, carbon dioxide (CO 2 )
  • CO 2 carbon dioxide
  • One such system and process has previously been disclosed and is directed to a single-stage Chilled Ammonia based system and method for removal of carbon dioxide (CO2) from a post- combustion flue gas stream.
  • CAP ammonia based systems and processes
  • FIG. 1A is a diagram generally depicting a flue gas processing system 15 for use in removing various pollutants from a flue gas stream FG emitted by the combustion chamber of a boiler system 26 used in a steam generator system of, for example, a power generation plant.
  • This system includes a CO2 rem oval system 70 that is configured to remove CO 2 from the flue gas stream FG before emitting the cleaned flue gas stream to an exhaust stack 90 (or alternatively additional processing). It is also configured to output CO 2 removed from the flue gas stream FG. Details of CO 2 removal system 70 are generally depicted in FIG. 1 B.
  • CO2 removal System 70 includes a capture system 72 for capturing/removing CO 2 from a flue gas stream FG and a regeneration system 74 for regenerating ionic ammonia solution used to remove CO 2 from the flue gas stream FG. Details of capture system 72 are generally depicted in FIG. 1 C.
  • a capture system 72 of a CO 2 capture system 70 (FIG. 1A) is generally depicted.
  • the capture system 72 is a solvent based CO 2 capture system. More particularly, in this example, the solvent used is chilled ammonia.
  • a chilled ammonia (CAP) based system/method for CO 2 removal an absorber vessel is provided in which an absorbent ionic ammonia solution (ionic ammonia solution) is contacted with a flue gas stream (FG) containing CO 2 .
  • the ionic ammonia solution is typically aqueous and may be composed of, for example, water and ammonium ions, bicarbonate ions, carbonate ions, and/or carbamate ions.
  • An example of a known CAP CO 2 removal system is generally depicted in the diagrams of FIG. 1C and FIG. 1 D.
  • an absorber vessel 170 is configured to receive a flue gas stream (FG) originating from, for example, the combustion chamber of a fossil fuel fired boiler 26 (see FIG. 1A). It is also configured to receive a lean ionic ammonia solution supply from regeneration system 74 (see FIG. 1 B). The lean ionic ammonia solution is introduced into the vessel 170 via a liquid distribution system 121 while the flue gas stream FG is also received by the absorber vessel 170 via flue gas inlet 76.
  • FG flue gas stream
  • regeneration system 74 see FIG. 1 B
  • the ionic ammonia solution is put into contact with the flue gas stream via a gas-liquid contacting device (hereinafter, mass transfer device, MTD) 111 used for contacting the flue gas stream with solvent and located in the absorber vessel 170 and within the path that the flue gas stream travels from its entrance via inlet 76 to the vessel exit 77.
  • MTD mass transfer device
  • the gas-liquid contacting device 111 may be, for example, one or more commonly known structured or random packing materials, or a combination thereof.
  • the ionic ammonia solution acts to absorb CO2 from the flue gas stream, thus making the ionic ammonia solution "rich” with CO2 (rich solution).
  • the rich ionic ammonia solution continues to flow downward through the mass transfer device and is then collected in the bottom 78 of the absorber vessel 170.
  • the rich ionic ammonia solution is then regenerated via regenerator system 74 (see FIG. 1 B) to release the CO 2 absorbed by the ionic ammonia solution from the flue gas stream.
  • the CO 2 released from the ionic ammonia solution may then be output to storage or other predetermined uses/purposes.
  • System 74 includes a regenerator vessel 195.
  • Regenerator vessel 195 is configured to receive a rich solution feed from the capture system 72 and to return a lean solution feed to the capture system 72 once CO2 has been separated from the rich solution.
  • the rich ionic ammonia solution is heated so that C02 contained in the solution separates from the chilled ammonia solution.
  • ammonia is returned to the capture system for use in capturing further CO 2 from a gas stream.
  • solvent based CO 2 capture technologies typically consume approximately 20-30% of the power generated by the power generation system in order for the CO2 capture process to work effectively.
  • these technologies often require a large portion of thermal energy generated by boiler/re-boiler functions (reboiler duty) in order to regenerate amine solution for re-use in capturing CO2 from a flue gas stream.
  • boiler/re-boiler functions reboiler duty
  • the physical size of the absorber and/or re-generator tanks in a typical system must be very large. The cost to design and implement these towers of such large scale is very high. Additionally, the physical space that is required on-site to accommodate these vessels is significant. Where on-site space is limited, additional steps must be taken to implement the vessels/system in the limited space, if possible.
  • Embodiments of the present invention provide for flue gas processing system for use with a fossil fuel fired boiler.
  • a flue gas processing system that includes an absorber tower configured to receive a mixed gas stream containing carbon dioxide and to contact it with a solvent; and the absorber tower comprises packing materials that are coated with a catalyst.
  • Embodiments of the present invention can also be viewed as providing methods for processing a mixed gas stream wherein the method includes the steps of: receiving a flue gas stream from the combustion chamber of a boiler; contacting the flue gas stream with a solvent and contacting the solvent with a catalyst.
  • FIG. 1A - FIG. 1C are diagram generally depicting a typical flue gas processing system 15 with provisions for CO2 removal.
  • FIG. 2A - FIG. 2C are diagrams generally illustrating an example of packing materials 315 on which a catalyst has been immobilized on the wall/surfaces of the packing materials.
  • FIG. 3 is a diagram generally depicting relevant portions of an amine or ammonia based CO2 capture system 70 in which absorber 110 and regenerator 330 are provided with packing materials 315 and 335, respectively that have been coated with a catalyst.
  • FIG. 4A is a diagram generally depicting relevant portions of an amine or ammonia based CO2 capture system 70 in which a catalyst 425 is added to the solvent supply 195 (FIG. 4A) or alternatively it may be added directly into the solvent supply feed.
  • the solvent is amine or ammonia.
  • FIG. 4B is a diagram generally depicting relevant portions of an amine or ammonia based CO2 capture system 70 in which a catalyst 425 is added directly into the solvent supply feed.
  • the proposed invention is directed to increasing CO 2 capture efficiency in a solvent based capture system for use in processing, for example, a flue gas stream.
  • the proposed invention is also directed to efficiently regenerating a solvent used to capture CO 2 .
  • a catalyst 425 that is coated (or immobilized) on one or more surfaces of the packing materials 315 located in the absorber tower 110 of an amine or ammonia based CO 2 capture system 70.
  • FIG. 2A - FIG. 2C are diagrams generally depicting packing materials 315 that have been coated with a catalyst 425.
  • the packing materials 315 may be composed of, for example, a series of corrugated support structures 320 arranged in close proximity to each other so as to form a series of channels 334 through which flue gas entering the absorber vessel 110 flow.
  • the catalyst 425 is coated on one or more surfaces of each corrugated support structures 320.
  • the corrugated troughs 334 form pathways for the flue gas to pass through the packing materials 315 thereby contacting the catalyst layer 425.
  • the catalyst 425 may be either a homogeneous and/or a heterogeneous catalyst.
  • Homogeneous type catalyst may include, for example, organo-metallic complex composed of transition metal and inorganic/organic ligands (such as bi- pyradine, aromatics, halogen, etc). Formation of the transition metal complex is one of the most powerful and universal ways of activating inert molecules. Coordination results in a change of reactivity of the ligands and creates favourable steric conditions for ligand interaction. This activation via coordination enables one to carry out numerous catalytic reactions under the influence of transition metal compounds.
  • Other examples of catalyst that may be used include, but are not limited to, for example, organo-metallic complex catalysts, such as, for example, halogen-type complex, Ni(bpy)sCI 2 ) [bpy: bipyridine].
  • Heterogeneous type catalyst may include, for example, metals or their compounds such as oxides (e.g. MgO), chloride MgCI 2 , etc. (Oxide preferably will not include sulphide and chloride. They are independent of each other) that are dispersed, preferably evenly, on solid materials with a high BET surface area, such as, for example, polymer, metal oxides, SiO 2 , molecular sieves, base- and/or acid- modified clay, etc.
  • metals or their compounds such as oxides (e.g. MgO), chloride MgCI 2 , etc.
  • Oxide preferably will not include sulphide and chloride. They are independent of each other) that are dispersed, preferably evenly, on solid materials with a high BET surface area, such as, for example, polymer, metal oxides, SiO 2 , molecular sieves, base- and/or acid- modified clay, etc.
  • the catalyst 425 is provided to promote the reaction of CO 2 with a solvent such as amine or chilled ammonia, thus resulting in the solvent being able to capture more CO 2 per given period of time (i.e. enhanced amine-based CO2 capture efficiency).
  • a catalyst is coated/immobilized on one or more surfaces of the packing materials in the regeneration tower of an amine or ammonia based CO 2 capture system.
  • the catalyst may be either a homogeneous and/or a heterogeneous catalyst.
  • the catalyst is provided to promote the regeneration of solvent (ex: amine or ammonia) after it has reacted/interacted with CO 2 .
  • the catalyst is selected and provided to promote the decomposition of products formed from the interaction/reaction between CO2 and amine, thus resulting in the amine being able to regenerate more efficiently from the rich amine solution per given period of time (i.e. enhanced amine-based CO2 capture efficiency).
  • This embodiment is generally depicted in FIG. 3.
  • a catalyst is added to a solvent, such as, for example, amine or ammonia, that is used to capture CO 2 from a flue gas stream.
  • the catalyst may also be used to promote the regeneration of solvent after it has reacted with CO2.
  • a homogenous catalyst may be used. This embodiment is generally depicted in FIG. 4A and FIG. 4B.
  • FIG. 4A illustrates how the catalyst 425 can be fed directly to the solvent supply tank 510.
  • FIG. 4B illustrates how the catalyst 425 can be combined with the solvent supply that is feeding the liquid distribution system 121.
  • the catalyst 425 used in both the absorber tower 110 and the regeneration tower 330 may be the same catalyst or different catalysts. It is not necessary that the same catalyst be used in connection with both capture and regeneration.
  • the catalyst 425 may be dispersed/layered/coated onto the solid material 320 with a high BET surface area, such as for example, 100-1000 m 2 /g, square meter per gram solid materials, via, for example, a wet impregnation, followed by being coated/immobilized onto the packing materials 315 located in, for example, the Absorber tower 110 and/or regeneration tower/stripper 330. This may be accomplished via, for example, known wash-coating techniques, such as those employed in, for example, industrial catalyst preparation processes. These solid materials may be used to make up the packing materials or parts thereof. Alternately, catalysts (organo-metallic complex, transition metal as well as its salt) may be directly coated onto the packing materials 315 (see FIG.
  • catalyst film (or layer) to form a catalyst film (or layer).
  • This may be accomplished via, for example, known coating technologies such as those employed in, for example, industrial semiconductor preparation or self-assembly process or electrochemical coating processes.
  • catalysts include, but are not limited to, for example, organo-metallic complex catalysts, such as, for example, halogen-type complex, Ni ⁇ py ⁇ Cb) [bpy: bipyridine] and transition metal-based inorganic catalysts.
  • Any homogeneous and/or heterogeneous catalysts can be used in CO2 capture operations to activate CO 2 adsorbed onto the surface of the catalyst 425 and catalyse carbonation/bi-carbonation and carbomation of amine with CO2 via homogeneous and/or heterogeneous processes. Also these catalysts can be used in solvent (example: amine or ammonia) regeneration to catalyse the decomposition of products formed from the carbonation/bi-carbonation and carbomation of amine with CO2.
  • solvent example: amine or ammonia

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  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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PCT/US2009/037608 2008-03-21 2009-03-19 A system and method for enhanced removal of co2 from a mixed gas stream via use of a catalyst Ceased WO2009117546A1 (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
CN2009801101685A CN101977669A (zh) 2008-03-21 2009-03-19 通过使用催化剂来增强从混合气流中脱除co2的系统和方法
EP09721367A EP2252387A1 (en) 2008-03-21 2009-03-19 A system and method for enhanced removal of co2 from a mixed gas stream via use of a catalyst
BRPI0908957-8A BRPI0908957A2 (pt) 2008-03-21 2009-03-19 Sistema e método para remoção melhorada de co2 de um fluxo de gás misto mediante o uso de um catalisador
RU2010143048/05A RU2486947C2 (ru) 2008-03-21 2009-03-19 Устройство и способ усовершенствованного извлечения co2 из смешанного потока газа при использовании катализатора
KR1020107023323A KR101224439B1 (ko) 2008-03-21 2009-03-19 촉매의 사용을 통해 혼합된 가스 스트림으로부터 ｃｏ₂의 제거를 향상시키기 위한 시스템 및 방법
JP2011500946A JP2011515210A (ja) 2008-03-21 2009-03-19 触媒の使用を介して混合ガスストリームからのｃｏ２の除去を増進させたシステム及び方法
MX2010010326A MX2010010326A (es) 2008-03-21 2009-03-19 Un sistema y metodo para eliminacion mejorada de co2 de una corriente de gases mixta, mediante el uso de un catalizador.
CA2718725A CA2718725C (en) 2008-03-21 2009-03-19 A system and method for enhanced removal of co2 from a mixed gas stream via use of a catalyst
AU2009225583A AU2009225583B2 (en) 2008-03-21 2009-03-19 A system and method for enhanced removal of CO2 from a mixed gas stream via use of a catalyst
IL207982A IL207982A0 (en) 2008-03-21 2010-09-05 A system and method for enhanced removal of co2 from a mixed gas stream via use of a catalyst
ZA2010/06479A ZA201006479B (en) 2008-03-21 2010-09-09 A system and method for enchanced removal of co2 from a mixed gas stream via use of a catalyst

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US3846708P 2008-03-21 2008-03-21
US61/038,467 2008-03-21
US12/406,289 2009-03-18
US12/406,289 US8414853B2 (en) 2008-03-21 2009-03-18 System and method for enhanced removal of CO2 from a mixed gas stream via use of a catalyst

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WO2009117546A1 true WO2009117546A1 (en) 2009-09-24

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US (2) US8414853B2 (https=)
EP (1) EP2252387A1 (https=)
JP (1) JP2011515210A (https=)
KR (1) KR101224439B1 (https=)
CN (1) CN101977669A (https=)
AU (1) AU2009225583B2 (https=)
BR (1) BRPI0908957A2 (https=)
CA (1) CA2718725C (https=)
IL (1) IL207982A0 (https=)
MX (1) MX2010010326A (https=)
RU (1) RU2486947C2 (https=)
WO (1) WO2009117546A1 (https=)
ZA (1) ZA201006479B (https=)

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CN102917773A (zh) * 2010-03-30 2013-02-06 里贾纳大学 用于从进入气流中分离一种气体组分的催化方法及装置
WO2014142668A3 (en) * 2013-03-14 2014-12-04 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Cos and cs2 abatement method

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US20120024498A1 (en) * 2010-07-29 2012-02-02 Jeffery Pruitt Fluid Recirculating Economizer
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DE102011013318A1 (de) * 2011-03-07 2012-09-13 Hochschule Heilbronn Verfahren zur Regeneration von mit CO2 beladenen aminhaltigen Waschlösungen bei der Sauergaswäsche
WO2013080889A1 (ja) * 2011-11-29 2013-06-06 関西電力株式会社 Ｃｏ２脱離触媒
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CN113351149A (zh) * 2021-06-29 2021-09-07 西安热工研究院有限公司 一种负载金属氧化物/金属硫化物的填料及其制备方法
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AU2009225583B2 (en) 2013-01-31
ZA201006479B (en) 2011-12-28
US20130272939A1 (en) 2013-10-17
KR101224439B1 (ko) 2013-01-22
RU2486947C2 (ru) 2013-07-10
EP2252387A1 (en) 2010-11-24
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AU2009225583A1 (en) 2009-09-24
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