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  • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
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  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
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  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
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  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
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  • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
  • Y10T428/2991—Coated

Definitions

• Inorganic particles hydrophobized with fluorosilanes have been used to impart hydrophobic as well as oleophobic properties as exemplified by U.S. Patent Application, US2006/0222815, filed by Oles et al. which teaches making such hydrophobized particles by the covalent bonding (i.e. grafting) of fluorosilanes upon the surface of inorganic particles (e.g. silica).
• the fluorosilanes employed by Oles et al. consist of a silicon atom having four bonds, three of which are direct bonds to hydrolysable groups which can react with the surface of an inorganic particle thereby covalently bonding the fluorosilane to particle. The remaining bond is a direct bond from the silicon atom to a perfluoroalkyl group.
• FIG 1 is a simplified depiction of a hydrophobized particle made from silica particles (AEROSIL 200) obtained in accordance with the invention.
• AEROSIL 200 silica particles
• Figure 2 are spectra obtained by solid-state 29 Si NMR cross- polarization magic angle spinning analysis (CPMAS) of: 1 ) hydrophobized particle made from silica particles (AEROSIL 200) obtained in accordance with the invention; and 2) untreated silica particles (AEROSIL 200).
• CPMAS solid-state 29 Si NMR cross- polarization magic angle spinning analysis
• hydrophobized inorganic particles comprise residues from fluorosilanes wherein the silicon atom is directly bonded to a perfluoroalkyl group
• the hydrophobized inorganic particles of the present invention comprise residues from fluorosilanes wherein the silicon atom is first bonded to a divalent organic linking group which in turn is bonded to a perfluoroalkyl group. It has been discovered that incorporation of the aforementioned divalent organic linking group can improve the ability of resulting hydrophobized inorganic particles to impart hydrophobic as well as oleophobic properties.
• the present invention relates to surface modified inorganic particles (also known as hydrophobized inorganic particles) made by the method of covalently grafting fluorosilanes to their surface thereby imparting to the particles hydrophobic and/or oleophobic properties.
• the fluorosilanes used in the present invention have a divalent organic linking group which bonds the silicon atom thereof to a fluorine rich group such as a perfluoroalkyl group.
• the fluorosilanes useful in the aforementioned method of covalent grafting are described in U.S. Patent Application 12/323,593 filed November 26, 2008 hereby incorporated by reference.
• the surface modified inorganic oxide particles comprise an oxide of M wherein M is independently selected from the group consisting of Si, Ti, Zn, Zr, Mn, Al, and combinations thereof; at least one of said particles having a surface covalently bonded to at least one fluorosilane group represented by Formula (1 ):
• Q 1 is chosen from the group consisting of a C2-C12 hydrocarbylene optionally interrupted by at least one divalent organic group;
• X 1 is chosen from O or S;
• Z 1 and Z 2 are chosen such that: a) Z 1 is -NH- and Z 2 is from the group consisting of -NH-, -O-, -S-, -NH-S(O) 2 -, -N[C(O)H]-, -[HC(COOH)(R 1 )]CH-S- and -(R 1 )CH-[HC(COOH)]-S-;
• Z 2 is -NH- and Z 1 is from the group consisting of -O-, and -S-;
• each R 1 is independently chosen from hydrogen, phenyl, or a monovalent d-Cs alkyl optionally terminated by -C ⁇ Hs, preferably H Or CH 3 ;
• Z 1 is -N[-Q 3 -(R f )]-; and b) Q 1 and Q 3 are independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one of -C(O)-O- or -O-C(O)-, and optionally further interrupted by at least one divalent organic group.
• Z 1 is -NH- and Z 2 is -NH-; said urea or thiourea fluorosilane group represented by the formula:
• Q 1 is independently chosen from the group consisting of a C2-C12 hydrocarbylene optionally interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O)2-, and -0-C(O)-NH -.
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a urea or thiourea fluorosilane group such that R f is chosen from a C 2 -Ci 2 perfluoroalkyl and Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -, and -0-C(O)-NH -.
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a urea or thiourea fluorosilane group such that R f is chosen from a C 2 -Ci 2 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl is replaced by hydrogen, and/or ii) the perfluoroalkyl is interrupted by at least one oxygen, methylene, or ethylene; Q is chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent organic group.
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a carbamate fluorosilane such that in Formula (1 ):
• Z 1 is -NH- and Z 2 is -O- or Z 1 is -O- and Z 2 is -NH-; and X 1 is O; said particle having a surface covalently bonded to an isocyanate derived a carbamate fluorosilane group represented by the formulae:
• Q 1 is a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting Of -NH-C(O)-NH-, -NH-C(S)-
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a carbamate fluorosilane group such that R f is chosen from a C 2 -Ci 2 perfluoroalkyl and Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -, and - 0-C(O)-NH -.
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a carbamate fluorosilane group such that R f is chosen from a C 2 -Ci 2 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl is replaced by hydrogen, and/or ii) the perfluoroalkyl is interrupted by at least one oxygen, methylene, or ethylene; Q is chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent organic group.
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a thiolcarbamate fluorosilane group such that in Formula (1 ):
• Z 1 is -NH- and Z 2 is -S-, or Z 1 is -S- and Z 2 is-NH-;
• X 1 is O; said thiolcarbamate fluorosilane group represented by the formulae: (L 1 ) d (L 2 ) c Si-(CH 2 ) n -NH-C(O)-S-Q 1 -R f ⁇ r (L 1 ) d (L 2 ) c Si-(CH 2 ) n -S-C(O)-NH-Q 1 -R f wherein:
• Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -, -N(R 1 )-C(O)-,
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a thiolcarbamate fluorosilane group such that R f is chosen from a C 2 -Ci 2 perfluoroalkyl and Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -, and - 0-C(O)-NH -.
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a thiolcarbamate fluorosilane group such that R f is chosen from a C 2 -Ci 2 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl is replaced by hydrogen, and/or ii) the perfluoroalkyl is interrupted by at least one oxygen, methylene, or ethylene; Q is chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent organic group.
• the surface modified inorganic oxide particles comprise at least one particle having a surface covalently bonded to a N-sulfone urea fluorosilane group such that in Formula (1 ):
• Z 1 is -NH- and Z 2 is -NH-S(O) 2 -; and X 1 is O; said N-sulfone urea fluorosilane group represented by the formula:
• Q 1 is independently chosen from the group consisting of an uninterrupted C 2 -Ci 2 hydrocarbylene.
• Z 1 is -NH- and Z 2 is -N[C(O)H]-; said N-formyl urea group represented by the formula:
• Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting of -S- and -NH-.
• Z 1 is -NH- and Z 2 is -[HC(COOH)(R 1 )]CH-S- or -(R 1 )CH-[HC(COOH)]-S-;
• X 1 is O; and Q 1 is -(CH 2 ) 2 - said thioether succinamic acid group represented by the formulae: (L) 3 Si-(CH 2 ) n -NH-C(O)-[HC(COOH)(R 1 )]CR 1 -(CH 2 ) m -S-(CH 2 ) 2 -R f , or
• Q 1 and Q 3 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one -C(O)-O- and optionally further interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 - -N(R 1 )-C(O)-, -C(O)-N(R 1 )- - f V-
• the hydrophobized inorganic particles of the present invention can be made by covalently grafting fluorosilanes to their surface in order to impart to them both hydrophobic and oleophobic properties.
• the fluorosilanes used in the present invention have a divalent organic linking group which connects the silicon atom to a fluorine rich group such as a perfluoroalkyl group.
• Fluorosilanes useful for the invention have at least one hydrolysable group which reacts with the surface of an inorganic particle thereby creating a covalent bond between the fluorosilane and the inorganic particle.
• Fluorosilanes that are useful in the present invention are also known as fluoroalkyl silanes which are further described in U.S. Patent Application 12/323,593 filed November 26, 2008 hereby incorporated by reference.
• the hydrophobized inorganic particles of the present invention can be made by dispersing inorganic particles in a non-polar solvent (e.g. toluene) and adding to this dispersion the desired fluorosilane.
• a non-polar solvent e.g. toluene
• the dispersion is then heated to an elevated temperature (e.g. 80-100 0 C) for about 8-10 hours.
• the dispersion is then allowed to cool to ambient temperature (about 20 0 C).
• the dispersion is then placed in a centrifuge, the solvent is decanted, and the resulting inorganic particles are washed with fresh solvent. Washing is preferably done at least twice.
• the washed inorganic particles are then dried in an oven at elevated temperature (about 100-110 0 C).
• the resulting dried inorganic particles are the final product of the invention.
• the resulting dried inorganic particles can be re-dispersed in a non-polar solvent (e.g. toluene) and additional fluorosilane can be added to this dispersion by repeating the entire procedure described in this paragraph.
• a non-polar solvent e.g. toluene
• hydrophobized inorganic particles of the present invention can also be made via a "divergent” approach wherein “functionalized inorganic particles” are made by reacting untreated inorganic particles with a first precursor wherein the first precursor comprises a silicon atom bonded to at least one terminal hydrolysable group which reacts with the surface of the inorganic particle thereby creating a covalent bond between the first precursor and the inorganic particle.
• the first precursor further comprises a terminal reactive group (e.g.
• an amine or an isocyante derived from an amine or an isothiocyanate derived an amine thereby creating functionalized inorganic particles having "anchors" which comprise the terminal reactive group.
• These functionalized inorganic particles are then reacted with a second precursor wherein the second precursor comprises a corresponding reactive group (e.g.
• the second precursor is also known herein by the term "capping agent.”
• An example of a useful first precursor and second precursor combination is wherein the first precursor comprises a terminal amine group and the second precursor comprises a terminal isocyante, isothiocyanate, vinyl, sulfonyl chloride, or sulfonamide.
• Inorganic particles useful to the invention include any inorganic particles that have reactive groups on the surface thereof wherein such groups are capable of reacting with the hydrolysable groups of the fluorosilanes (or precursors thereof) of the invention thereby creating a covalent bond between the inorganic particle and the fluorosilane (or precursor thereof).
• Particularly useful inorganic particles are oxides, such as oxides of silicon, titanium, zinc, zirconium, manganese, and aluminum.
• Rf is chosen from a C2-C12 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl can be optionally replaced by hydrogen, and/or ii) the perfluoroalk can be optionally interrupted by at least one oxygen, methylene, or ethylene;
• Q is chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent organic group;
• Q 1 is chosen from the group consisting of a C2-C12 hydrocarbylene optionally interrupted by at least one divalent organic group;
• X 1 is chosen from O or S;
• Z 1 and Z 2 are chosen such that: a) Z 1 is -NH- and Z 2 is from the group consisting of -NH-, -O-,
• Z 2 is -NH- and Z 1 is from the group consisting of -O- and -S-; c) when Z 1 or Z 2 is O, Q 1 is interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -,
• each R 1 is independently chosen from hydrogen, phenyl, or a monovalent d-Cs alkyl optionally terminated by -C ⁇ Hs, preferably
• Z 1 is-N(-Q 3 -R f ; and b) Q 1 and Q 3 are independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one of -C(O)-O- or -O-C(O)-, and optionally further interrupted by at least one divalent organic group.
• a preferred fluorosilane of Formula 2 is an isocyanate derived fluorosilane being a urea or thiourea fluorosilane wherein: Z 1 and Z 2 are both -NH-; said urea or thiourea represented by the formula: (L) 3 Si-(CH 2 ) n -NH-C(X 1 )-NH-Q 1 -R f wherein:
• X 1 is O to form a urea fluorosilane, or X 1 is S to form a thiourea fluorosilane;
• Q 1 is independently chosen from the group consisting of a C2-C12 hydrocarbylene optionally interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O)2-, and -0-C(O)-NH -.
• a preferred urea or thiourea fluorosilane is one wherein R f is chosen from a C 2 -Ci 2 perfluoroalkyl and Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -, and -0-C(O)-NH -.
• a preferred urea or thiourea fluorosilane is one wherein R f is chosen from a C 2 -Ci 2 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl is replaced by hydrogen, and/or ii) the perfluoroalkyl is interrupted by at least one oxygen, methylene, or ethylene; Q is chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent organic group.
• Another preferred isocyanate derived fluorosilane of Formula 2 is a carbamate fluorosilane wherein: Z 1 is -NH- and Z 2 is -O-, or Z 1 is -O- and Z 2 is -NH-; and
• X 1 is O; said carbamate represented by the formulae: (L) 3 Si-(CH 2 ) n -NH-C(O)-O-Q 1 -R f , or
• Q 1 is a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting Of -NH-C(O)-NH-, -NH-C(S)-
• a preferred carbamate fluorosilane is one wherein R f is chosen from a C2-C12 perfluoroalkyl and Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -, and -0-C(O)-NH -.
• a preferred carbamate fluorosilane is one wherein R f is chosen from a C 2 -Ci 2 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl is replaced by hydrogen, and/or ii) the perfluoroalkyl is interrupted by at least one oxygen, methylene, or ethylene; Q is chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent organic group.
• Another preferred isocyanate derived fluorosilane of Formula 2 is a thiolcarbamate fluorosilane wherein: Z 1 is -NH- and Z 2 is -S-, or Z 1 is -S- and Z 2 is-NH-; and
• X 1 is O; said carbamate represented by the formulae: (L) 3 Si-(CH 2 ) n -NH-C(O)-S-Q 1 -R f or (L) 3 Si-(CH 2 ) n -S-C(O)-NH-Q 1 -R f wherein:
• Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -, -N(R 1 )-C(O)-,
• a preferred thiolcarbamate fluorosilane is one wherein R f is chosen from a C2-C12 perfluoroalkyl and Q 1 is independently chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 -, and -0-C(O)-NH -.
• a preferred thiolcarbamate fluorosilane is one wherein R f is chosen from a C 2 -Ci 2 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl is replaced by hydrogen, and/or ii) the perfluoroalkyl is interrupted by at least one oxygen, methylene, or ethylene; Q is chosen from the group consisting of a C 2 -Ci 2 hydrocarbylene optionally interrupted by at least one divalent organic group.
• Another preferred isocyanate derived fluorosilane of Formula 2 is a N-sulfone urea fluorosilane wherein:
• Z 1 is -NH-, and Z 2 is -NH-S(O) 2 -; and X 1 is O; said N-sulfone urea represented by the formula:
• Q 1 is independently chosen from the group consisting of an uninterrupted C 2 -Ci 2 hydrocarbylene.
• Z 1 is -NH-, and Z 2 is -N[C(O)H]-; said N-formyl urea represented by the formula:
• Q 1 is independently chosen from the group consisting of a C2-C12 hydrocarbylene interrupted by at least one divalent moiety chosen from the group consisting of -S- and -NH-.
• Z 1 is -NH- and Z 2 is -[HC(COOH)(R 1 )]CH-S- or -(R 1 )CH-[HC(COOH)]-S-;
• X 1 is O; and
• Q 1 is -(CH 2 ) 2 - said thioether succinamic acid represented by the formulae:
• Q 1 and Q 3 is independently chosen from the group consisting of a C 2 - C12 hydrocarbylene interrupted by at least one -C(O)-O- and optionally further interrupted by at least one divalent moiety chosen from the group consisting of -S-, -S(O)-, -S(O) 2 - -N(R 1 )-C(O)-, -C(O)-N(R 1 )- - EXAMPLES The following inorganic particles were used as indicated in the examples below.
• the term "convergent fluorosilane single grafting" as used throughout the examples refers to the following procedure. About 125 g of a chosen inorganic oxide was placed in a 3 liter round bottom flask equipped with a mechanical stirrer and under nitrogen atmosphere. The stirred mixture was heated to about 50 0 C for about 2 hours in order to achieve a homogeneous dispersion. 25 g of a chosen fluohnated silane was then quickly added to the stirred mixture followed by nitrogen sparging for 30 minutes. The reaction mixture temperature was then raised to 75 0 C and stirred for about 15 hours under a nitrogen atmosphere. After this allotted reaction time period, the reaction mixture was cooled and centrifuged in portions at 3000 rpm for about 2 minutes. Excess hydrocarbon solvent was decanted and the remaining fluorine grafted fumed inorganic oxide product were washed 3 times with ethanol and centrifuged followed by drying in a vacuum oven at 110 0 C for about 12 hours.
• convergent fluorosilane double grafting refers to a procedure identical to "convergent fluorosilane single grafting" with the following additional steps.
• About 125 g the inorganic oxide product obtained after a convergent fluorosilane double grafting was placed in a 3 liter round bottom flask equipped with a mechanical stirrer and under nitrogen atmosphere. The stirred mixture was heated to about 50 0 C for about 2 hours in order to achieve a homogeneous dispersion. 25 g of the same fluohnated silane used in the convergent fluorosilane single grafting was then quickly added to the stirred mixture followed by nitrogen sparging for 30 minutes.
• reaction mixture temperature was then raised to 75 0 C and stirred for about 15 hours under a nitrogen atmosphere. After the allotted reaction time period, the reaction mixture was cooled and centhfuged in portions at 3000 rpm for about 2 minutes. Excess hydrocarbon solvent was decanted and the remaining fluorine double grafted fumed inorganic oxide product were washed 3 times with ethanol and centrifuged followed by drying in a vacuum oven at 110 0 C for about 12 hours.
• Thin Film Casting refers to the following procedure. About 5 wt. % of chosen hydrophobized inorganic particles or untreated inorganic particles were dispersed in isopropanol. A thin film was made by casting three layers of this solution onto a clean glass slides wherein the slide were allowed to dry for about 10 minutes at 60 0 C after each casting thereby creating a homogenous coating of particles on the glass slides.
• advancing water contact angle or "H 2 O Adv.” refer to the results of a measurement conducted using a Rame-Hart Standard Automated Goniometer Model 200 employing DROP image standard software and equipped with an automated dispensing system with 250 ⁇ l syringe, having an illuminated specimen stage assembly. A sample was glued to a glass slide using double-sided tape.
• the goniometer which is connected through an interface to a computer with computer screen, had an integral eye piece connected to a camera having both horizontal axis line indicator and an adjustable rotating cross line and angle scale, both independently adjustable by separate verniers.
• the syringe used were carefully cleaned with alcohol and allowed to dry completely before use.
• the sample on the glass slide was clamped into place and the vertical vernier adjusted to align the horizontal line (axis) of the eye piece coincident to the horizontal plane of the sample, and the horizontal position of the stage relative to the eye piece positioned so as to view one side of the test fluid droplet interface region at the sample interface.
• test fluid approximately one drop of test fluid was dispensed onto the sample using a small syringe fitted with a stainless steel needle and a micrometer drive screw to displace a calibrated amount of the test fluid, which was deionized water.
• Horizontal and cross lines were adjusted via the software in the Model 200 after leveling the sample via stage adjustment, and the computer calculated the contact angle based upon modeling the drop appearance.
• the rotatable vernier was adjusted to align the cross line and cross position, that is the intersection of the rotatable cross line and the fixed horizontal line, coincident with the edge of the test fluid droplet and the sample, and the cross line angle (rotation) then positioned coincident with the tangent to the edge of the test droplet surface, as imaged by the eye piece.
• the contact angle was then read from the angle scale, which was equivalent to the tangent angle. Contact angle was measured after the droplet has been added to a surface.
• receiving water contact angle or "H 2 O Rec.” refer to the results of a measurement identical to the advancing water contact angle measurement described above except contact angle was measured after the droplet was partially withdrawn from a surface.
• Advancing Oil Contact Angle Measurement (“CIRHI? Adv.")
• advancing oil contact angle or "C16H12 Adv.” refer to the results of a measurement identical to the advancing water contact angle measurement described above except hexadecane was used as the test liquid instead of water.
• receiving oil contact angle or "C16H12 Rec.” refer to the results of a measurement identical to the advancing oil contact angle measurement described above except contact angle was measured after the droplet was partially withdrawn from a surface.
• a surface is said to be “super oleophobic" in cases where the advancing oil contact angle and receding oil contact angle was greater than about 150 degrees and the hysteresis (difference between advancing and receding oil contact angle) is less than about 10 degrees.
• a surface that is both super hydrophobic and super oleophobic is said to be “super amphiophobic.”
• the percent fluorine in any given hydrophobized particle was determined by the Wickbold Torch method and are shown in the tables below under a column labeled "%F.”
• Comparative Example A Convergent fluorosilane single grafting was conducted wherein the chosen inorganic oxide was SiO 2 #1 and the chosen fluorosilane was FS #A resulting in hydrophobized particles. A film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Convergent fluorosilane single grafting was conducted wherein the chosen inorganic oxide was SiO 2 #1 and the chosen fluorosilane was FS #B.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Comparative Example C Convergent fluorosilane single grafting was conducted wherein the chosen inorganic oxide was SiO 2 #1 and the chosen fluorosilane was FS #C. A film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Convergent fluorosilane single grafting was conducted wherein the chosen inorganic oxide was SiO 2 #1 and the chosen fluorosilane was FS #1.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Convergent fluorosilane single grafting was conducted wherein the chosen inorganic oxide was ZnO #1 and the chosen fluorosilane was FS #1.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Example 3 Convergent fluorosilane single grafting was conducted wherein the chosen inorganic oxide was TiSiO 4 #1 and the chosen fluorosilane was FS #1. A film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Convergent fluorosilane double grafting was conducted wherein the chosen inorganic oxide was SiO 2 #1 and the chosen fluorosilane was FS #B.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Convergent fluorosilane double grafting was conducted wherein the chosen inorganic oxide was SiO 2 #1 and the chosen fluorosilane was FS #C.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Convergent fluorosilane double grafting was conducted wherein the chosen inorganic oxide was SiO 2 #1 and the chosen fluorosilane was FS #1.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Convergent fluorosilane double grafting was conducted wherein the chosen inorganic oxide was ZnO #1 and the chosen fluorosilane was FS #1.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• Example 6 Convergent fluorosilane double grafting was conducted wherein the chosen inorganic oxide was TiSiO 4 #1 and the chosen fluorosilane was FS #1. A film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 3.
• the fluorosilane used in Comparative Examples A-E is a fluorosilane wherein the silicon atom is directly bonded to a perfluoroalkyl group.
• the fluorosilane used in Examples 1 -6 is a fluorosilane wherein the silicon atom is first bonded to a divalent organic linking group, represented by -N H-C(O)-N H-(CH 2 ) 2 -S- (CH 2 ) 2 -, which in turn is bonded to a perfluoroalkyl group.
• Example 1 As shown by comparing the contact angle measurements of Example 1 to Comparative Examples A-C, without the incorporation of a divalent organic linking group it was only possible to achieve adequate water repellency but impossible to also achieve adequate oil repellency.
• the incorporation of a divalent organic linking group in Example 1 results in adequate water repellency as well as adequate oil repellency.
• Comparative Examples D-E Even when double grafting is performed such as in Comparative Examples D-E, without the incorporation of a divalent organic linking group it was only possible to achieve adequate water repellency but impossible to also achieve adequate oil repellency.
• Table 3 also shows that double grafting improves oil repellency over single grafting as evidenced by comparing: Example 1 to Example 4; Example 2 to Example 5; and Example 3 to Example 6.
• single functionalization refers to the following procedure. About 125 g of a chosen inorganic oxide was placed in a 3 liter round bottom flask equipped with a mechanical stirrer and under nitrogen atmosphere. The stirred mixture was heated to about 50 0 C for about 2 hours in order to achieve a homogeneous dispersion. 25 g of a first precursor, (CH 3 O) 3 Si-(CH 2 )3- NH 2 (commercially available as AMMO from Degussa AG), was then quickly added to the stirred mixture followed by nitrogen sparging for 30 minutes. The reaction mixture temperature was then raised to 75 0 C and stirred for about 15 hours.
• a first precursor (CH 3 O) 3 Si-(CH 2 )3- NH 2
• reaction mixture was cooled and centrifuged in portions at 3000 rpm for about 2 minutes. Excess hydrocarbon solvent was decanted and the remaining fluorine grafted fumed inorganic oxide product were washed 3 times with ethanol and centrifuged followed by drying in a vacuum oven at 110 0 C for about 12 hours. All of the above steps were preformed in a nitrogen atmosphere.
• double functionalization refers to a procedure identical to "single functionalization” with the following additional steps.
• About 125 g of the inorganic oxide product obtained after single functionalization was placed in a 3 liter round bottom flask equipped with a mechanical stirrer and under nitrogen atmosphere. The stirred mixture was heated to about 50 0 C for about 2 hours in order to achieve a homogeneous dispersion.
• 25 g of the first precursor, (CH 3 O) 3 Si-(CH 2 )S-NH 2 (commercially available as AMMO from Degussa AG), was then quickly added to the stirred mixture followed by nitrogen sparging for 30 minutes. The reaction mixture temperature was then raised to 75 0 C and stirred for about 15 hours.
• reaction mixture was cooled and centhfuged in portions at 3000 rpm for about 2 minutes. Excess hydrocarbon solvent was decanted and the remaining fluorine double grafted fumed inorganic oxide product were washed 3 times with ethanol and centrifuged followed by drying in a vacuum oven at 110 0 C for about 12 hours. All of the above steps were preformed in a nitrogen atmosphere.
• Comparative Example G Single functionalization was conducted wherein the chosen inorganic oxide was SiO 2 #1 resulting in treated particles. A film sample was made by thin film casting using these treated particles. Contact angle measurements were conducted on this film sample and are shown in Table 4.
• Double functionalization was conducted wherein the chosen inorganic oxide was SiO 2 #6 resulting in treated particles.
• a film sample was made by thin film casting using these treated particles. Contact angle measurements were conducted on this film sample and are shown in Table 4.
• Double functionalization was conducted wherein the chosen inorganic oxide was SiO 2 #1 resulting in treated particles.
• a film sample was made by thin film casting using these treated particles. Contact angle measurements were conducted on this film sample and are shown in Table 4. Table 4
• capping step refers to the following procedure. Inorganic particles obtained after single functionalization or after double functionalization are reacted with a chosen "capping agent" in an inert environment in toluene solvent.
• the capping agent was a succinic -(CH 2 ) 2 -(CF 2 ) 7 -CF 3
• the capping agent was synthesized in toluene and immediately reacted with the inorganic particles obtained after single functionalization or after double functionalization. Synthesis of the succinic anhydride was conducted as taught in US4171282 hereby incorporated by reference.
• capping agent was thereby making hydrophobized particles.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 5. The resulting fluorosilane residue on these hydrophobized particles was
• S represents three covalent bonds from silicon, at least one of which is bonded to the particle surface.
• Example 7 was repeated except the chosen inorganic oxide was SiO 2 #1.
• Example 9 Example 7 was repeated except the chosen inorganic oxide was
• Example 7 was repeated except the chosen inorganic oxide was SiO 2 #4.
• Example 7 was repeated except the chosen inorganic oxide was SiO 2 #5.
• Example 7 was repeated except the chosen inorganic oxide was SiO 2 #6.
• Example 13 is repeated except the chosen inorganic oxide was SiO 2 #6.
• Double functionalization was conducted wherein the chosen inorganic oxide was SiO2 #2 resulting in treated particles. These treated particles wherein subjected to the capping step wherein the chosen
• capping agent was hydrophobized particles.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 5. The resulting fluorosilane residue on these hydrophobized particles was
• S represents three covalent bonds from silicon, at least one of which is bonded to the particle surface.
• Example 13 was repeated except the chosen inorganic oxide was SiO 2 #1.
• Example 15 was repeated except the chosen inorganic oxide was SiO 2 #1.
• Double functionalization was conducted wherein the chosen inorganic oxide was SiO 2 #2 resulting in treated particles. These treated particles wherein subjected to the capping step wherein the chosen capping agent was CI-S(O) 2 -(CH 2 ) 2 -(CF 2 ) 5 -CF 3 thereby making hydrophobized particles having a fluorosilane residue of ⁇ Si-(CH 2 ) 3 -NH- S(O) 2 -(CH 2 ) 2 -(CF 2 ) 5 -CF 3 .
• the symbol " ⁇ " represents three covalent bonds from silicon, at least one of which is bonded to the particle surface.
• a film sample was made by thin film casting using these hydrophobized particles. Contact angle measurements were conducted on this film sample and are shown in Table 6.
• Example 18 Example 17 was repeated except the chosen inorganic oxide was
• the symbol " ⁇ " represents three covalent bonds from silicon, at least one of which is bonded to the particle surface.
• a film sample was made by thin film casting using the hydrophobized particles obtained after second precursor double grafting. Contact angle measurements were conducted on this film sample and are shown in Table 7.
• hydrophobized particles made from SiO 2 #1 (AEROSIL 200) silica particles obtained in Example 14 were subjected to solid-state 29 Si NMR cross-polarization magic angle spinning analysis (CPMAS) resulting in the spectra shown in Figure 2. Also shown in Figure 2 is the spectra using the same 29 Si NMR CPMAS analysis of untreated SiO 2 #1 (AEROSIL 200) silica particles.
• Figure 1 is a simplified depiction of a hydrophobized particle made from SiO 2 #1 (AEROSIL 200) silica particles obtained in Example 14.
• the silicon atom of fluorosilane residues is depicted by A1 , A2, B1 , B2, C1 , and C2.
• L 2 represents -OCH 3 or -OH.
• A1 and A2 show the silicon atom of fluorosilane residues bonded to the surface of the silica particle through one oxygen atom.
• B1 and B2 show the silicon atom of fluorosilane residues bonded to the surface of the silica particle through two oxygen atoms.
• C1 and C2 show the silicon atom of fluorosilane residues bonded to the surface of the silica particle through three oxygen atoms.
• D1 , D2, D3, and D4 depict silicon atoms at the surface of the silica particle which are not bonded to a fluorosilane residue.
• FIG. 1 depicts a signal consistent with the silicon atom of fluorosilane residues depicted as C1 and C2 in Figure 1.
• FIG. 2 and the spectra of hydrophobized particles 2 depicts a signal consistent with the silicon atom of fluorosilane residues depicted as B1 and B2 in Figure 1.
• FIG. 3 depicts a signal consistent with the silicon atom of fluorosilane residues depicted as A1 and A2 in Figure 1.
• FIG. 6 depicts a signal consistent silicon atoms at the surface of the silica particle which are not bonded to a fluorosilane residue depicted as D1 , D2, D3, and D4 in Figure 1.
• FIG. 5 depicts a signal consistent with silicon atoms at the surface of the silica particle which are not bonded to a fluorosilane residue depicted as D1 , D2, D3, and D4 in Figure 1.
• D1 , D2, D3, and D4 a fluorosilane residue depicted as D1 , D2, D3, and D4 in Figure 1.
• D1 , D2, D3, and D4 a fluorosilane residue depicted as D1 , D2, D3, and D4 in Figure 1.
• FIG. 2 and the spectra of untreated particles notably absent are any signals corresponding to those depicted by 1 , 2, and 3 in the spectra of hydrophobized particles.

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