WO2009071216A1 - Dispositif permettant l'évacuation avec faible échange de chaleur de chambres de four à coke - Google Patents

Dispositif permettant l'évacuation avec faible échange de chaleur de chambres de four à coke Download PDF

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Publication number
WO2009071216A1
WO2009071216A1 PCT/EP2008/009964 EP2008009964W WO2009071216A1 WO 2009071216 A1 WO2009071216 A1 WO 2009071216A1 EP 2008009964 W EP2008009964 W EP 2008009964W WO 2009071216 A1 WO2009071216 A1 WO 2009071216A1
Authority
WO
WIPO (PCT)
Prior art keywords
push rod
print head
heat
coke
section
Prior art date
Application number
PCT/EP2008/009964
Other languages
German (de)
English (en)
Inventor
Ronald Kim
Franz-Josef Schuecker
Original Assignee
Uhde Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US12/734,850 priority Critical patent/US20110027050A1/en
Application filed by Uhde Gmbh filed Critical Uhde Gmbh
Priority to BRPI0820111 priority patent/BRPI0820111A2/pt
Priority to JP2010536352A priority patent/JP5460611B2/ja
Priority to CN2008801190167A priority patent/CN101883837A/zh
Priority to AU2008333601A priority patent/AU2008333601B2/en
Priority to UAA201008283A priority patent/UA102829C2/ru
Priority to EP08857818A priority patent/EP2217681A1/fr
Priority to MX2010006087A priority patent/MX2010006087A/es
Priority to RU2010127304/02A priority patent/RU2495907C2/ru
Priority to CA2707587A priority patent/CA2707587A1/fr
Publication of WO2009071216A1 publication Critical patent/WO2009071216A1/fr
Priority to ZA2010/03307A priority patent/ZA201003307B/en
Priority to EG2010060930A priority patent/EG26345A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B33/00Discharging devices; Coke guides
    • C10B33/08Pushers, e.g. rams
    • C10B33/10Pushers, e.g. rams for horizontal chambers

Definitions

  • the invention relates to a device for expressing a coke cake by a coke oven with a double-sided opening.
  • the expression of the coke cake of a coke oven takes place after the end of the fermentation process of a coking cycle.
  • the cooking process may take from 16 to 192 hours, depending on the oven type and process orientation of the plant, by varying the bed height, feed coal mix and oven temperature.
  • the expression is made from the opening of a coke oven side to the other coke oven side.
  • the expressions are usually made with a so-called push rod, which is driven for this purpose on a car in front of the battery to be expressed and is moved by hydraulic devices. After the process of expressing the reloading with coal takes place.
  • the coke oven is preferably a "non-recovery" or “heat-recovery” coke oven, which uses the co-products and coking gases produced during the coking to burn and recover the heat required for coking coke oven chamber but it can also be a conventional, so-called horizontal chamber oven, which absorbs the by-products of the coking process and further processed. Verkokungspro- processes are carried out at temperatures of 800 to 1500 0 C. a considerable part of the heat is stored in the walls and the furnace roof As the combustion of byproducts is usually sufficient to produce the necessary coking energy, it is desirable to minimize the loss of heat during the squeezing process.
  • a print head When expressing the coke according to the prior art, a print head, on which a push rod is attached, pushed by a suitable thruster through the coke oven.
  • the push rod is equipped at its rear end with a device that can exert a compressive force on the push rod.
  • the print head has a plate on the front to protect against the enormous heat of the coke cake.
  • the push rod and printhead are subjected to a considerable heat load in the process of squeezing. As a result, the parts can bend after a short period of operation or material have albruch. For this reason, there are a number of inventions that describe measures against the strong heating of the squeezing device.
  • DE 4224491 A1 describes a device for expressing a coke oven, which consists of a print head and a liquid-cooled push rod.
  • the push rod itself is surrounded by a radiation shield, which surrounds the push rod to the outside at a certain distance and is provided on the inside with cooling coils.
  • a cooling medium which is preferably water or a water-containing liquid.
  • the supply and return of the cooling medium via hose connections.
  • the recooling is carried out via heat exchangers which are connected to the hose connections.
  • the push rod can be formed by T-beams, which are welded, for example, side by side.
  • the device has the disadvantage that the passage of a cooling medium is complicated and prone to failure. For example, leaks in the cooling system can result in unnoticed damage to the squeezing device or the coke oven chamber.
  • DE 840538 C describes a device with a Ausd Wegstange for expressing Kokshuntöfen, which is designed box-shaped and constructed in several parts inside.
  • the push rod is preferably designed in the form of a T-beam. Through the individual parts of the push rod air flows as a cooling medium, which is guided through the rod so that the walls of the rod are always flushed in the same flow direction. As a result, warping the rod is not possible.
  • a printhead is mounted in front, which is not specified in the relevant patent specification.
  • the device cools the push rod, but does not protect the material of the push rod from the intense heat radiation.
  • the design of the push rod depending on the shape of the print head leaves large amounts of cold air of the environment in the coke oven chamber.
  • the push rod is fixed in the center of the print head, so that behind the print head a considerable space remains free, is pressed by the same time when expressing cold air of the coke oven environment in the coke oven chamber.
  • the free space that is forced into the furnace behind the print head adjacent to the push rod emits a considerable portion of the heat stored in the inner coke oven wall to the outside. This represents a considerable heat loss, which must be compensated by the subsequent coking process again.
  • the coal burn is higher and the coke produced is of poorer quality.
  • the push rod Due to the increased heat radiation, the push rod is also exposed to a strong temperature load, which can deform and become brittle after a short period of operation. This is a source of danger because the push rod must absorb strong mechanical forces.
  • the desired device should also prevent cold air from penetrating into the interior of the coking chamber, through which the interior of the coke oven chamber may cool during squeezing and loading, resulting in increased coal consumption and reduced coke quality.
  • a mounted on the printhead baffle which provides the present invention.
  • a baffle or apron is mounted, which covers the push rod almost the entire length.
  • an envelope or enclosure forms around the entire expressing device.
  • the space between the push rod and the enclosure can be left free. But it can also be filled out for better isolation.
  • Glass wool or ceramic fibers are suitable for this purpose, for example.
  • the expressing device takes the form of a cuboid, when the printhead is rectangular and is wrapped on all sides of the enclosure according to the invention. In the interior, the push rod then forms one massive cylinder.
  • the enveloping device is preferably made of a temperature-resistant material.
  • the push rod is protected against the high temperatures of the coke oven chamber and in particular the coke oven walls, which are exposed after expressing the coke. Since the heat capacity and the heating rate of the enclosure is low, the cooling of the coke oven chamber and in particular the coke oven walls is largely prevented. The cold air of the environment can not penetrate to the coke oven walls and thus not cool them. If there is an insulating filling in the interior of the housing, the coke oven walls will remain almost the same temperature if the squeezing process does not last too long.
  • Claimed is in particular a device for pressing out the filling of a coke oven, wherein
  • the device is formed as a push rod in the form of a rod with an oven-side mounted printhead in the form of a plate, and which is characterized in that
  • the printhead is surrounded with mounted rearward baffles or skirts to form an enclosure having the same outer side lengths as the printhead and the outer shape of a square having a uniform cross section when the printhead is rectangular or square; located in the interior pressure rod forms a solid cylinder when it is round in cross-section.
  • the print head has the same cross section as the opening of the coke oven chamber. Then, the outer walls of the enclosure abut exactly on the coke oven chamber walls, so that they are completely shielded from the relatively cold temperatures of the coke oven environment when the contents of the coke oven furnace are pushed out. This allows the process of Koksofenausconces be carried out even in adverse weather conditions.
  • the aprons also protect the rear side of the printhead and the push rod against the high temperatures during squeezing.
  • the printhead may be rectangular or square for use in expressing the coke cake. However, it is also possible to make this round. This is particularly advantageous for a special form of coke oven. It is possible in principle to design the print head in any desired form, if this requires an optimum process of coke ejection.
  • the push rod may have any shape and any cross-section.
  • the push rod is designed as a solid cylinder and round in cross-section. Since the push rod is advantageously mounted in the center of the print head, this forms a solid cylinder in the box or cylinder forming by the housing, depending on the shape of the print head.
  • the push rod can also have any shape for the production of the device according to the invention. So this can be designed as a cuboid.
  • it can also be made of simple, head-mounted T-beams. It is also possible to weld together T-beams and use them as push rods with improved stability.
  • the push rods can be arbitrarily shaped, depending on the requirement of Ausdrückvorganges.
  • the shape that forms the printhead with the mounted enclosure or enclosure in the length of uniform cross-section.
  • the coke oven chamber walls are completely covered by the housing and do not come into contact with the cooler ambient air.
  • this may be tapered or thickened in length and change in cross section. This may be useful, for example, in sensitive secondary air loaf shelves or chambers.
  • the shape may also be irregular in shape if the shape of the coke oven chamber or optimum thermal protection so requires.
  • the entire device for expressing is advantageously formed with the housing in such a way that the process of pushing out the contents of the coke oven chamber is as heat-exchangeable as possible.
  • the baffles may be alsmontiert to manufacture the enclosure according to the invention on all sides of the print head.
  • all oven walls are protected against cooling or cooling down by the simultaneous penetration of cold ambient air.
  • the lower side of the mold may remain free to protect the bottom of the coke oven chamber, which is typically thinner and therefore less robust. It is also possible to protect only one side of the print head with the housing according to the invention.
  • the Aprons can also be of different lengths when an optimal expression process requires it.
  • the aprons or baffles which are used for the construction of the housing according to the invention, can be made of a heat-resistant metallic material. But they can also be made of a ceramic material. It is also possible to make the aprons from a metallic material and to provide it with a ceramic coating. This can advantageously be designed so that it reflects or reflects the heat of the environment.
  • the coating with a heat-reflecting layer by way of example a high-emitting coating, a so-called “high-emission coating", which can be incorporated into the outer layers of the material, for example by a high-sintering temperature method
  • a high-emitting coating inorganic metal oxides mixed with carbides, wherein chromium or iron oxides in a mixture with silicon carbides may be mentioned here by way of example
  • a high-emitting coating is described by way of example in EP 742276 A1
  • the design of an apron made of a heat-resistant material is optimal
  • the heat-protective layer may be applied as a coating, but also in the form of tiles, foils or tiles.
  • the push rod and the print head are made of a material that is resistant to the high temperatures that prevail in the coke oven chamber.
  • the push rod or print head is made of a highly heat-resistant material to withstand the high temperatures prevailing inside coke oven chambers.
  • the print head can also be provided with a heat-resistant coating for better protection against the high temperatures. This can be, for example, a coating of ceramic, firebricks, silica or a hydraulic shotcrete.
  • the push rod may be provided with such a housing, if the protection of this structural part requires it. Usually, however, this is not necessary as the aprons around the push rod have lower temperatures.
  • the enclosure which forms by the assembly of the aprons to the print head, may also contain additional devices that serve to control the Ausd Wegvorganges. These may be, for example, temperature measuring devices or sight glasses.
  • the enclosure may also contain devices that serve to improve the coking process. Examples are insulating materials such as glass wool or ceramic fibers.
  • the device also includes parts for attachment to a coke ejecting machine or a drive device. These parts are preferably attached to the end of the push rod. But they can also be attached to the end of the aprons or the housing. This depends on the type of coke ejector or drive. For operation of the device according to the invention, both mobile coke ejecting machines and stationary coke ejecting machines can be used.
  • a method which uses the device according to the invention for expressing coke is also claimed.
  • the method is designed so that the Koksausd Wegvorgang is made after the process of door opening. This usually happens after the end of the coking process, which typically takes 16 to 192 hours in the "non-recovery” or "heat-recovery” coke oven. The process of Koksaus suitss then followed by a refill. Of course, a cleaning can be carried out with the device according to the invention, if the given apparatus facilities make this seem advantageous. After filling, the doors of the coke oven chamber are closed and a renewed coking cycle follows.
  • the method according to the invention is suitable for all types of coke ovens.
  • the device according to the invention can also serve to protect the measurement technique, which can be mounted on the push rod for monitoring the furnace condition and the coking process and can be protected by the housing described before the radiation of the furnace interior.
  • FIG. Figure 1 shows an opened coke oven chamber in the side view, in which the coke cake is expressed with a device according to the invention.
  • FIG. 2 shows a device according to the invention for expressing in the vertical view from above.
  • FIG. 3 shows a device according to the invention with a push rod made of two welded T-beams in the vertical view from above.
  • FIG. 4 shows a Coke oven in the process of squeezing with a device according to the invention in frontal view.
  • FIG. Figure 1 shows an opened coke oven chamber (1) where the coke cake (2) is exposed after opening the coke oven chamber doors (3).
  • the coke cake (2) is pushed out of the coke oven with the printhead (4) of the coke ejector.
  • the print head (4) with the push rod (5) is pushed through the coke oven.
  • Rearward-facing skirts (6a) are attached to the printhead (4). If the print head is rectangular, only the upper and lower aprons are visible in this view.
  • the side skirts (6b) have been omitted for better illustration. Since cold air would be forced into the coke oven chamber without the skirts behind the printhead, they prevent the coke oven chamber from cooling.
  • the print head is shaped so that it fits exactly between the door-comprehensive coke oven chamber wall (7) and coke oven sole (8). This prevents the entry of other outside air. Under the coke oven sole there are usually still the secondary air soles (9) and the secondary air inlet devices (10), so that the bottom can be made somewhat thinner. Shown here are also still the primary air intake devices (11) in the ceiling with control devices (11a) and the cables (12) for operating the door with the fasteners (12a).
  • FIG. 2 shows an ejection device according to the invention with printhead (4) and push rod (5). To it the aprons (6b) are fixed, which form an enclosure. If the print head is rectangular, only the side aprons are visible in this view. At the push rod is still an attachment for the Koksausd Wegmaschine connects.
  • FIG. 3 shows an ejection device according to the invention with printhead and push rod.
  • the print head (4) and the push rod (5) are formed from two T-beams welded together. You can see the side aprons here.
  • a layer (14) made of a highly heat-resistant material is applied on the printhead.
  • FIG. 4 shows a coke oven (1) in frontal view, the coke cake (2) of which is expressed by means of a device according to the invention.
  • the coke oven chamber is opened by the raised coke oven oven doors (3) so that the coke cake (2) is exposed.
  • the door comprehensive coke oven chamber wall (7) is hidden here by the raised coke oven chamber door (3) and is therefore not visible.
  • the printhead (4) advantageously has a cross-section which fits exactly in the opening, so that the coke cake (2) is behind the print head (4).
  • the print head (4) is pushed out of the coke oven with the help of push rods (5).
  • the print head (4) is equipped with aprons mounted backwards (protruding from the plane of the paper).
  • the print head is here rectangular, so that both horizontal (6a) and vertical (6b) aprons are attached.
  • the aprons prevent behind the printhead (4) cold air can get into the coking chamber.
  • the secondary air soles (9) the openings for the secondary air (10), the openings for the primary air (11) in the furnace roof with control devices (11a) and the cables (12) for pulling up the coke oven chamber with attachment (12a ).

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Coke Industry (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

Dispositif destiné à défourner le contenu d'une chambre de four à coke, qui est constitué d'une tête de pression pourvue de tiges de pression montées à l'arrière. Des tôles déflectrices ou des tabliers, qui sont montés du côté arrière de la tête de pression, empêchent la pénétration simultanée d'air dans la chambre de four à coke et, partant, un refroidissement non souhaité de la chambre de four à coke lors de son évacuation. Les tabliers empêchent également une exposition excessive des tiges de pression et de la face arrière de la tête de pression à la chaleur. Les tabliers peuvent également servir à protéger des dispositifs de mesure montés dans le blindage, et peuvent être fabriqués à partir d'un matériau métallique ou céramique résistant à la chaleur. Les tabliers ou la tête de pression peuvent également comporter un revêtement résistant à la chaleur ou réfléchissant la chaleur ou des carreaux résistant à la chaleur ou réfléchissant la chaleur. La présente invention concerne également un procédé permettant d'évacuer des chambres de four à coke à l'aide du dispositif selon l'invention.
PCT/EP2008/009964 2007-12-04 2008-11-25 Dispositif permettant l'évacuation avec faible échange de chaleur de chambres de four à coke WO2009071216A1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
UAA201008283A UA102829C2 (ru) 2007-12-04 2008-11-25 Устройство и способ выталкивания коксового пирога из камеры коксовой печи
BRPI0820111 BRPI0820111A2 (pt) 2007-12-04 2008-11-25 Dispositivo para impulsão de câmara de forno de coque com baixa troca de calor
JP2010536352A JP5460611B2 (ja) 2007-12-04 2008-11-25 コークス室炉から少ない熱交換で押し出すための装置
CN2008801190167A CN101883837A (zh) 2007-12-04 2008-11-25 用于热交换少地对腔式焦炉推料的装置
AU2008333601A AU2008333601B2 (en) 2007-12-04 2008-11-25 Device for expelling the contents of coke chamber ovens having a low degree of heat exchange
US12/734,850 US20110027050A1 (en) 2007-12-04 2008-11-25 Device for coke oven chamber pushing low in heat exchange
EP08857818A EP2217681A1 (fr) 2007-12-04 2008-11-25 Dispositif permettant l'évacuation avec faible échange de chaleur de chambres de four à coke
CA2707587A CA2707587A1 (fr) 2007-12-04 2008-11-25 Dispositif poussee de coke dans un four a coke a faible echange de chaleur
RU2010127304/02A RU2495907C2 (ru) 2007-12-04 2008-11-25 Устройство для выталкивания кокса с низким теплообменом из камеры коксовой печи
MX2010006087A MX2010006087A (es) 2007-12-04 2008-11-25 Dispositivo para la expulsion del contenido de hornos de camara de coque, que tiene bajo grado de intercambio termico.
ZA2010/03307A ZA201003307B (en) 2007-12-04 2010-05-11 Device for expelling the contents of coke chamber ovens having a low degree of heat exchange
EG2010060930A EG26345A (en) 2007-12-04 2010-06-02 A means of expelling the contents of coke chamber furnaces with a low degree of heat exchange

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007058472A DE102007058472B3 (de) 2007-12-04 2007-12-04 Vorrichtung und Verfahren zum wärmeaustauscharmen Ausdrücken von Kokskammeröfen
DE102007058472.7 2007-12-04

Publications (1)

Publication Number Publication Date
WO2009071216A1 true WO2009071216A1 (fr) 2009-06-11

Family

ID=40380147

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/009964 WO2009071216A1 (fr) 2007-12-04 2008-11-25 Dispositif permettant l'évacuation avec faible échange de chaleur de chambres de four à coke

Country Status (20)

Country Link
US (1) US20110027050A1 (fr)
EP (1) EP2217681A1 (fr)
JP (1) JP5460611B2 (fr)
KR (1) KR101604144B1 (fr)
CN (1) CN101883837A (fr)
AR (1) AR069571A1 (fr)
AU (1) AU2008333601B2 (fr)
BR (1) BRPI0820111A2 (fr)
CA (1) CA2707587A1 (fr)
CL (1) CL2008003607A1 (fr)
CO (1) CO6300871A2 (fr)
DE (1) DE102007058472B3 (fr)
EG (1) EG26345A (fr)
MX (1) MX2010006087A (fr)
MY (1) MY154219A (fr)
RU (1) RU2495907C2 (fr)
TW (1) TWI456041B (fr)
UA (1) UA102829C2 (fr)
WO (1) WO2009071216A1 (fr)
ZA (1) ZA201003307B (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007057410B3 (de) * 2007-11-27 2009-07-30 Uhde Gmbh Mechanismus und Verfahren zur automatisierbaren Verriegelung von Türen, Türkörpern oder Türrahmen horizontaler Koksofenkammern
DE102009054430B4 (de) * 2009-11-25 2012-01-26 Uhde Gmbh Vorrichtung und Verfahren zum Entleeren eines gelöschten oder ungelöschten Kokses aus einem Kokslöschwagen in eine Aufnahmevorrichtung
JP2013095819A (ja) * 2011-10-31 2013-05-20 Jfe Steel Corp コークス炉押出機
RU176825U1 (ru) * 2017-06-05 2018-01-30 Данила Сергеевич Яковлев Установка для выталкивания кокса из коксовых печей
CN112060257B (zh) * 2020-08-24 2022-09-30 山东汇泰混凝土有限公司 一种建筑施工建筑垃圾清运系统
CN113637489B (zh) * 2021-09-16 2023-11-24 攀钢集团西昌钢钒有限公司 一种推焦杆的上弓和旁弯校正装置

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DE459600C (de) 1927-05-07 1928-05-08 Otto & Co Gmbh Dr C Ausdrueckmaschine fuer Koksoefen mit liegenden Kammern
DE840538C (de) 1950-01-14 1952-06-03 Bamag Werke Fuer Eisenverarbei Als Kastentraeger ausgebildete Ausdrueckstange fuer Koksoefen
DE3321918A1 (de) 1982-08-26 1984-03-08 Koppers Co., Inc., 15219 Pittsburgh, Pa. Schieberstempel, insbesondere fuer kokereioefen und dergleichen
DE4224491A1 (de) 1991-10-04 1993-04-08 Ruhrkohle Ag Mechanisch und thermisch allseitig belastete druckstange fuer eine maschinelle drueckvorrichtung
EP0742276A1 (fr) 1995-05-12 1996-11-13 Krupp Koppers GmbH Méthode d'opération de four à coke

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US3501380A (en) * 1968-12-30 1970-03-17 Koppers Co Inc Method and apparatus for measuring the temperature of coke oven walls
JPS4813654Y1 (fr) * 1969-11-22 1973-04-13
US3963451A (en) * 1973-02-15 1976-06-15 United States Steel Corporation Method of forming a high-temperature abrasion-resistant coating on a ferrous metal substrate, and resulting article
US4486138A (en) * 1982-08-26 1984-12-04 Raymond Kaiser Engineers Inc. Pusher ram
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SU1624013A1 (ru) * 1986-06-30 1991-01-30 Донецкий политехнический институт Штанга выталкивающего устройства коксовыталкивател
SU1511268A1 (ru) * 1987-12-14 1989-09-30 Донецкий политехнический институт Проталкивающее устройство горизонтальной коксовой печи
SU1736986A1 (ru) * 1989-03-07 1992-05-30 Донецкий политехнический институт Штанга выталкивающего устройства коксовыталкивател
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CN2540410Y (zh) * 2002-04-16 2003-03-19 张家港长力机械有限公司 推焦杆
CN2861158Y (zh) * 2005-09-14 2007-01-24 大连华锐股份有限公司 推焦机头尾焦槽式收集装置

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE459600C (de) 1927-05-07 1928-05-08 Otto & Co Gmbh Dr C Ausdrueckmaschine fuer Koksoefen mit liegenden Kammern
DE840538C (de) 1950-01-14 1952-06-03 Bamag Werke Fuer Eisenverarbei Als Kastentraeger ausgebildete Ausdrueckstange fuer Koksoefen
DE3321918A1 (de) 1982-08-26 1984-03-08 Koppers Co., Inc., 15219 Pittsburgh, Pa. Schieberstempel, insbesondere fuer kokereioefen und dergleichen
DE4224491A1 (de) 1991-10-04 1993-04-08 Ruhrkohle Ag Mechanisch und thermisch allseitig belastete druckstange fuer eine maschinelle drueckvorrichtung
EP0742276A1 (fr) 1995-05-12 1996-11-13 Krupp Koppers GmbH Méthode d'opération de four à coke

Also Published As

Publication number Publication date
CO6300871A2 (es) 2011-07-21
TW200927905A (en) 2009-07-01
EP2217681A1 (fr) 2010-08-18
AU2008333601A1 (en) 2009-06-11
ZA201003307B (en) 2011-03-30
EG26345A (en) 2013-08-20
US20110027050A1 (en) 2011-02-03
AU2008333601B2 (en) 2013-09-26
KR20100100825A (ko) 2010-09-15
AR069571A1 (es) 2010-02-03
JP5460611B2 (ja) 2014-04-02
CL2008003607A1 (es) 2009-08-14
CN101883837A (zh) 2010-11-10
DE102007058472B3 (de) 2009-05-07
JP2011505475A (ja) 2011-02-24
TWI456041B (zh) 2014-10-11
UA102829C2 (ru) 2013-08-27
RU2495907C2 (ru) 2013-10-20
CA2707587A1 (fr) 2009-06-11
KR101604144B1 (ko) 2016-03-16
BRPI0820111A2 (pt) 2015-05-05
MX2010006087A (es) 2010-06-23
RU2010127304A (ru) 2012-01-10
MY154219A (en) 2015-05-15

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