WO2009063623A1 - Ｃｏ2回収ガス化方法及び装置 - Google Patents

Ｃｏ2回収ガス化方法及び装置 Download PDF

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Publication number
WO2009063623A1
WO2009063623A1 PCT/JP2008/003275 JP2008003275W WO2009063623A1 WO 2009063623 A1 WO2009063623 A1 WO 2009063623A1 JP 2008003275 W JP2008003275 W JP 2008003275W WO 2009063623 A1 WO2009063623 A1 WO 2009063623A1
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WO
WIPO (PCT)
Prior art keywords
gasification
cao
column
hydration
caco3
Prior art date
Application number
PCT/JP2008/003275
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English (en)
French (fr)
Inventor
Toru Ishii
Original Assignee
Ihi Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ihi Corporation filed Critical Ihi Corporation
Priority to US12/740,937 priority Critical patent/US8828347B2/en
Priority to EP08850183.8A priority patent/EP2210930B1/en
Priority to AU2008322124A priority patent/AU2008322124B2/en
Publication of WO2009063623A1 publication Critical patent/WO2009063623A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/52—Ash-removing devices
    • C10J3/523—Ash-removing devices for gasifiers with stationary fluidised bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/09—Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C10J2200/158—Screws
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • C10J2300/1815—Recycle loops, e.g. gas, solids, heating medium, water for carbon dioxide

Abstract

　炭素を含む原料をガス化してガス化ガスを生成し、同時にＣＯ2を回収する操作をシステム全体で同一の圧力にて行えるようにする。 　ＣａＯと水蒸気の接触によりＣａ（ＯＨ）2が生成される上限以下の温度を保持して所定の圧力で水和反応を行う水和塔１と、Ｃａ（ＯＨ）2を導入して加熱により脱水して高活性のＣａＯを得る水除去部２ａと、原料と水蒸気を反応してチャーを生成すると共にチャーをガス化してガス化ガスを生成し、且つ水除去部２ａからのＣａＯにＣＯ2を吸収させてＣａＣＯ3を生成しその反応熱を利用して原料のガス化を行い、更にガス化ガスを水除去部２ａでの脱水の熱源とするガス化部２ｂと、を有するガス化反応器２と、ガス化部２ｂから導入したチャーを含むＣａＣＯ3と、ＣＯ2と、水蒸気と、酸素との存在下、チャーの燃焼熱によりＣａＣＯ3をカ焼してＣＯ2とＣａＯとに分離し、得られたＣａＯを水和塔１に供給する吸収剤再生塔３とを有し、水和塔１に接続されるガス化反応器２と吸収剤再生塔３の圧力を、水和塔１と同一の圧力とする。
PCT/JP2008/003275 2007-11-14 2008-11-12 Ｃｏ2回収ガス化方法及び装置 WO2009063623A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/740,937 US8828347B2 (en) 2007-11-14 2008-11-12 Method and apparatus for gasification with CO2 recovery
EP08850183.8A EP2210930B1 (en) 2007-11-14 2008-11-12 Method and apparatus for gasification with co2 recovery
AU2008322124A AU2008322124B2 (en) 2007-11-14 2008-11-12 Method and apparatus for gasification with CO2 recovery

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007295158 2007-11-14
JP2007-295158 2007-11-14
JP2008288397A JP5293099B2 (ja) 2007-11-14 2008-11-11 Ｃｏ２回収ガス化方法及び装置
JP2008-288397 2008-11-11

Publications (1)

Publication Number Publication Date
WO2009063623A1 true WO2009063623A1 (ja) 2009-05-22

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ID=40638478

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/003275 WO2009063623A1 (ja) 2007-11-14 2008-11-12 Ｃｏ2回収ガス化方法及び装置

Country Status (6)

Country Link
US (1) US8828347B2 (ja)
EP (1) EP2210930B1 (ja)
JP (1) JP5293099B2 (ja)
AU (1) AU2008322124B2 (ja)
PL (1) PL2210930T3 (ja)
WO (1) WO2009063623A1 (ja)

Cited By (1)

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EP2296786A1 (en) * 2008-06-05 2011-03-23 Industrial Research Limited Gas separation process

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JP5417753B2 (ja) * 2008-07-11 2014-02-19 株式会社Ｉｈｉ 循環流動層ガス化炉
US8518165B2 (en) * 2009-03-16 2013-08-27 J—Power Entech, Inc. Dry exhaust-gas treating apparatus
CN103249816B (zh) 2010-12-24 2016-05-18 株式会社Ihi 生成气体的重整方法和装置
FI20115023L (fi) * 2011-01-10 2012-07-11 Andritz Oy Menetelmä hiiltä sisältävien aineiden kaasuttamiseksi
FI123704B (fi) * 2011-02-04 2013-09-30 Foster Wheeler Energia Oy Menetelmä happipolttokiertoleijupetikattilan käyttämiseksi
CN102167986B (zh) * 2011-03-17 2013-04-17 开滦能源化工股份有限公司 提供热电气的公用工程岛
WO2012142084A1 (en) 2011-04-11 2012-10-18 ADA-ES, Inc. Fluidized bed method and system for gas component capture
KR101329082B1 (ko) * 2011-11-25 2013-11-14 한국원자력연구원 광섬유 레이저를 이용한 탄소 및 산소 동위원소 분리 방법 및 장치
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EP2296786A4 (en) * 2008-06-05 2012-09-19 Ind Res Ltd GUEST RACE PROCEDURE

Also Published As

Publication number Publication date
JP5293099B2 (ja) 2013-09-18
EP2210930A1 (en) 2010-07-28
EP2210930B1 (en) 2017-01-11
US8828347B2 (en) 2014-09-09
AU2008322124A1 (en) 2009-05-22
AU2008322124B2 (en) 2011-03-03
EP2210930A4 (en) 2012-05-30
JP2009138186A (ja) 2009-06-25
PL2210930T3 (pl) 2017-07-31
US20100266477A1 (en) 2010-10-21

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