WO2010100174A3 - Verfahren und vorrichtung zur verwertung von halmgutartiger biomasse in einem festbett-vergasungsprozess - Google Patents

Verfahren und vorrichtung zur verwertung von halmgutartiger biomasse in einem festbett-vergasungsprozess Download PDF

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Publication number
WO2010100174A3
WO2010100174A3 PCT/EP2010/052655 EP2010052655W WO2010100174A3 WO 2010100174 A3 WO2010100174 A3 WO 2010100174A3 EP 2010052655 W EP2010052655 W EP 2010052655W WO 2010100174 A3 WO2010100174 A3 WO 2010100174A3
Authority
WO
WIPO (PCT)
Prior art keywords
biomass
fixed bed
raw material
straw
synthesis gas
Prior art date
Application number
PCT/EP2010/052655
Other languages
English (en)
French (fr)
Other versions
WO2010100174A2 (de
Inventor
Helmut Kammerloher
Sven Johannssen
Van Cung Tran
Original Assignee
Krones Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krones Ag filed Critical Krones Ag
Priority to EA201190154A priority Critical patent/EA021911B1/ru
Priority to EP10707267A priority patent/EP2403927A2/de
Priority to UAA201111658A priority patent/UA105924C2/uk
Priority to CN2010800128363A priority patent/CN102361962A/zh
Priority to US13/254,799 priority patent/US20120017497A1/en
Publication of WO2010100174A2 publication Critical patent/WO2010100174A2/de
Publication of WO2010100174A3 publication Critical patent/WO2010100174A3/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/026—Dust removal by centrifugal forces
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
    • C10K3/003—Reducing the tar content
    • C10K3/008—Reducing the tar content by cracking
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Bei einem erfindungsgemäßen Verfahren zur Verwertung von Biomasse werden folgende Schritte durchgeführt: Zunächst wird die thermische Vergasung mindestens eines kohlenstoffhaltigen Rohstoffes vorgenommen. In einem nächsten Schritt erfolgt die Reinigung des bei der Vergasung entstandenen Synthesegases. Dabei wird eine Temperaturänderung des Synthesegases vorgenommen. Anschließend erfolgt vorzugsweise die Umwandlung des Synthesegases in einen flüssigen Kraftstoff mittels einer katalysierten chemischen Reaktion, wobei als kohlenstoffhaltiger Rohstoff eine halmgutartige Biomasse gewählt wird, die Vergasung in einem Festbettreaktor durchgeführt wird und der Ascheerweichungspunkt des halmgutartigen Rohstoffes durch die Zugabe mindestens eines Erdalkalisalzes erhöht wird.
PCT/EP2010/052655 2009-03-05 2010-03-03 Verfahren und vorrichtung zur verwertung von biomasse in einem biomassen-vergasungsprozess WO2010100174A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EA201190154A EA021911B1 (ru) 2009-03-05 2010-03-03 Способ и устройство для утилизации биомассы в процессе газификации
EP10707267A EP2403927A2 (de) 2009-03-05 2010-03-03 Verfahren und vorrichtung zur verwertung von biomasse in einem biomassen-vergasungsprozess
UAA201111658A UA105924C2 (uk) 2009-03-05 2010-03-03 Спосіб і пристрій для утилізації біомаси в процесі газифікації
CN2010800128363A CN102361962A (zh) 2009-03-05 2010-03-03 在固定床气化工艺中使用秸秆类生物质的方法和装置
US13/254,799 US20120017497A1 (en) 2009-03-05 2010-03-03 Method and device for utilizing biomass in a biomass gasification process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009011358.4 2009-03-05
DE102009011358A DE102009011358A1 (de) 2009-03-05 2009-03-05 Verfahren und Vorrichtung zur Verwertung von Biomasse in einem Biomassen-Vergasungsprozess

Publications (2)

Publication Number Publication Date
WO2010100174A2 WO2010100174A2 (de) 2010-09-10
WO2010100174A3 true WO2010100174A3 (de) 2011-03-10

Family

ID=42557702

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/052655 WO2010100174A2 (de) 2009-03-05 2010-03-03 Verfahren und vorrichtung zur verwertung von biomasse in einem biomassen-vergasungsprozess

Country Status (8)

Country Link
US (1) US20120017497A1 (de)
EP (1) EP2403927A2 (de)
CN (1) CN102361962A (de)
DE (1) DE102009011358A1 (de)
EA (1) EA021911B1 (de)
GE (1) GEP20146097B (de)
UA (1) UA105924C2 (de)
WO (1) WO2010100174A2 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009055300A1 (de) * 2009-12-23 2011-06-30 Krones Ag, 93073 Vorrichtung und Verfahren zum Rückgewinnen von Energie
CN102786994B (zh) * 2012-07-25 2013-12-25 中国科学院广州能源研究所 一种生物质自催化气化制备富甲烷气体的方法
DE102017213189B4 (de) * 2017-07-31 2020-07-23 Rosmarin Holdings Limited Verfahren zum Behandeln von faserigen organischen Abfallstoffen, die bei der Herstellung von Palmöl anfallen sowie ein Verfahren zum Betreiben eines Festbettvergasers zum Erzeugen eines Produktgases mit solchen Abfallstoffen

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0924288A2 (de) * 1997-12-16 1999-06-23 Brunner, Winfried Dipl. Ing. Verfahren zur Erzeugung von Brenngasen aus organischen Feststoffen und Reaktor zur Durchführung des Verfahrens
US20020134019A1 (en) * 2000-12-21 2002-09-26 Paisley Mark A. Biomass gasification system and method

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US2627455A (en) * 1947-06-05 1953-02-03 Union Oil Co Gasification process and apparatus
DE4236619C2 (de) 1992-10-29 1996-11-28 Air Liquide Verfahren und Regenerator zum Aufheizen von Gasen
DE4238652C1 (de) 1992-11-16 1994-05-11 Air Liquide Regenerator zum Aufheizen von Gasen
DE19836428C2 (de) 1998-08-12 2000-07-13 Siempelkamp Guss Und Anlagente Verfahren und Vorrichtungen zum Vergasen von Biomasse, insbesondere Holzstoffen
AU4898699A (en) * 1999-07-16 2001-02-05 Reatech Phosphor addition in gasification
DE102005006305B4 (de) 2005-02-11 2015-11-26 Consulting & Management Friess Gbr (Vertretungsberechtigte Gesellschafter: Dietmar J. Friess 14532 Kleinmachnow, Jessica Friess 14532 Kleinmachnow) Verfahren zur Erzeugung von Brenn- und Synthesegasen mit Hochdruckdampferzeugung
DE102006013394A1 (de) 2006-03-23 2007-10-11 Peter Brinkhege Verfahren und Vorrichtung zur Aufbereitung von Rohholz oder dergleichen Brenngut
DE102006017353A1 (de) * 2006-04-11 2007-10-18 Spot Spirit Of Technology Ag Verfahren und Vorrichtung zur prozessintegrierten heißen Gasreinigung von Staub- und gasförmigen Inhaltsstoffen eines Synthesegases
EP1852490A1 (de) * 2006-05-05 2007-11-07 BIOeCON International Holding N.V. Vorbehandlung eines auf Kohlenstoff basierten teilchenförmigen Energieträgers
CN201201939Y (zh) * 2008-02-26 2009-03-04 古启隆 一种秸秆气化炉及秸秆燃气净化装置

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0924288A2 (de) * 1997-12-16 1999-06-23 Brunner, Winfried Dipl. Ing. Verfahren zur Erzeugung von Brenngasen aus organischen Feststoffen und Reaktor zur Durchführung des Verfahrens
US20020134019A1 (en) * 2000-12-21 2002-09-26 Paisley Mark A. Biomass gasification system and method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
RISNES H ET AL: "Calcium addition in straw gasification<*>", FUEL, IPC SCIENCE AND TECHNOLOGY PRESS, GUILDFORD, GB, vol. 82, no. 6, 1 April 2003 (2003-04-01), pages 641 - 651, XP004404243, ISSN: 0016-2361, DOI: DOI:10.1016/S0016-2361(02)00337-X *

Also Published As

Publication number Publication date
US20120017497A1 (en) 2012-01-26
CN102361962A (zh) 2012-02-22
EP2403927A2 (de) 2012-01-11
EA021911B1 (ru) 2015-09-30
GEP20146097B (en) 2014-05-27
DE102009011358A1 (de) 2010-09-16
UA105924C2 (uk) 2014-07-10
EA201190154A1 (ru) 2012-03-30
WO2010100174A2 (de) 2010-09-10

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