WO2009057716A1 - 含フッ素共重合体および耐水耐油剤組成物、ならびにその製造方法 - Google Patents

含フッ素共重合体および耐水耐油剤組成物、ならびにその製造方法 Download PDF

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Publication number
WO2009057716A1
WO2009057716A1 PCT/JP2008/069801 JP2008069801W WO2009057716A1 WO 2009057716 A1 WO2009057716 A1 WO 2009057716A1 JP 2008069801 W JP2008069801 W JP 2008069801W WO 2009057716 A1 WO2009057716 A1 WO 2009057716A1
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WIPO (PCT)
Prior art keywords
proof
fluorinated copolymer
oil
water
agent composition
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PCT/JP2008/069801
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English (en)
French (fr)
Inventor
Shuichiro Sugimoto
Takao Hirono
Eiji Morimoto
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Asahi Glass Company, Limited
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Publication date
Application filed by Asahi Glass Company, Limited filed Critical Asahi Glass Company, Limited
Priority to EP08843932A priority Critical patent/EP2206735B1/en
Priority to JP2009539115A priority patent/JP5418229B2/ja
Priority to CN200880114187.0A priority patent/CN101842399B/zh
Priority to AT08843932T priority patent/ATE550360T1/de
Priority to ES08843932T priority patent/ES2383047T3/es
Publication of WO2009057716A1 publication Critical patent/WO2009057716A1/ja
Priority to US12/695,246 priority patent/US8193276B2/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/07—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from polymer solutions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/14—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C08J2333/16—Homopolymers or copolymers of esters containing halogen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Epoxy Resins (AREA)
  • Lubricants (AREA)
  • Polyethers (AREA)

Abstract

　ペルフルオロアルキル基が短鎖でありながら、優れた耐水性、耐油性を発揮できる含フッ素共重合体およびこれを含有する耐水耐油剤組成物を提供する。 　炭素数１～６のペルフルオロアルキル基を有する重合単位（ａ’）の４０～９８質量％、アルキレンオキシドを有する重合単位（ｂ’）の１～５０質量％、およびＣＨ２＝Ｃ（ＣＯＯＨ）－Ｑ－ＣＯＯＨ（Ｑは炭素数１～４のアルキレン基等）で表される単量体に基づく重合単位（ｃ’）の１～１０質量％を含む含フッ素共重合体（Ａ）を含有する耐水耐油剤組成物。
PCT/JP2008/069801 2007-11-01 2008-10-30 含フッ素共重合体および耐水耐油剤組成物、ならびにその製造方法 WO2009057716A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP08843932A EP2206735B1 (en) 2007-11-01 2008-10-30 Fluorinated copolymer, water-proof and oil-proof agent composition, and their production methods
JP2009539115A JP5418229B2 (ja) 2007-11-01 2008-10-30 耐水耐油剤組成物およびその製造方法
CN200880114187.0A CN101842399B (zh) 2007-11-01 2008-10-30 含氟共聚物、耐水耐油剂组合物及其制备方法
AT08843932T ATE550360T1 (de) 2007-11-01 2008-10-30 Fluoriniertes copolymer, zusammensetzung aus einem wasserdichten und einem öldichten stoff und verfahren zu ihrer herstellung
ES08843932T ES2383047T3 (es) 2007-11-01 2008-10-30 Copolímero fluorado, composición de agente impermeabilizante frente a agua y aceite y sus métodos de producción
US12/695,246 US8193276B2 (en) 2007-11-01 2010-01-28 Fluorocopolymer and water and oil proofing composition, and processes for their production

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007285128 2007-11-01
JP2007-285128 2007-11-01

Related Child Applications (1)

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US12/695,246 Continuation US8193276B2 (en) 2007-11-01 2010-01-28 Fluorocopolymer and water and oil proofing composition, and processes for their production

Publications (1)

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WO2009057716A1 true WO2009057716A1 (ja) 2009-05-07

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PCT/JP2008/069801 WO2009057716A1 (ja) 2007-11-01 2008-10-30 含フッ素共重合体および耐水耐油剤組成物、ならびにその製造方法

Country Status (9)

Country Link
US (1) US8193276B2 (ja)
EP (1) EP2206735B1 (ja)
JP (1) JP5418229B2 (ja)
KR (1) KR20100087143A (ja)
CN (1) CN101842399B (ja)
AT (1) ATE550360T1 (ja)
ES (1) ES2383047T3 (ja)
TW (1) TWI457352B (ja)
WO (1) WO2009057716A1 (ja)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831842A (zh) * 2010-05-31 2010-09-15 漯河市天马化工有限公司 新型含氟含硅施胶增强剂及其制备方法
WO2011027877A1 (en) 2009-09-01 2011-03-10 Daikin Industries, Ltd. Water and oil resistant agent for paper, treatment process and paper
JP2012001590A (ja) * 2010-06-15 2012-01-05 Riken Vitamin Co Ltd 表面特性が改質された熱可塑性樹脂組成物
JP2015507103A (ja) * 2012-01-17 2015-03-05 エージーシー ケミカルズ アメリカズ，インコーポレイテッド 処理物品を調製する方法およびそれにより生成された処理物品
WO2015129634A1 (ja) * 2014-02-25 2015-09-03 旭硝子株式会社 パルプスラリー添加用耐油剤組成物、耐油紙の製造方法および耐油紙
WO2016182028A1 (ja) * 2015-05-13 2016-11-17 旭硝子株式会社 耐油紙および耐油紙の製造方法
JP2019119938A (ja) * 2017-12-28 2019-07-22 ダイキン工業株式会社 パルプモールド製品およびその製造方法
US10829576B2 (en) 2016-04-27 2020-11-10 AGC Inc. Liquid repellent composition, method for its production, and method for producing oil resistant paper

Families Citing this family (11)

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DE112011103312T5 (de) * 2010-09-29 2013-08-22 Nippon Carbide Industries Co., Inc. Melamin-Epoxidharzmonomer und -Harzzusammensetzung
US8808868B2 (en) 2010-12-17 2014-08-19 E I Du Pont De Nemours And Company Fluorinated copolymers of (meth)acrylates and (meth)acrylic acid amine complexes
US8563672B2 (en) * 2010-12-17 2013-10-22 E I Du Pont De Nemours And Company Process for producing fluorinated copolymers of (meth)acrylates and (meth)acrylic acid amine complexes
US8809209B2 (en) * 2010-12-17 2014-08-19 E I Du Pont De Nemours And Company Fluorinated copolymers
US8852693B2 (en) * 2011-05-19 2014-10-07 Liquipel Ip Llc Coated electronic devices and associated methods
JPWO2013115196A1 (ja) * 2012-01-31 2015-05-11 旭硝子株式会社 含フッ素共重合体およびその製造方法、ならびに撥水撥油剤組成物
EP2810967A1 (en) * 2012-01-31 2014-12-10 Asahi Glass Company, Limited Fluorine-containing copolymer, method for producing same, and water-/oil-repellant agent composition
US8642177B2 (en) 2012-03-20 2014-02-04 E I Du Pont De Nemours And Company Acid etch resistance for calcareous substrates
CN103408692A (zh) * 2013-08-08 2013-11-27 中科院广州化学有限公司 一种水分散可交联性无规含氟聚合物及构筑的超双疏涂层
WO2015182475A1 (ja) * 2014-05-28 2015-12-03 ダイキン工業株式会社 メーソンリー処理組成物
WO2021079774A1 (ja) * 2019-10-24 2021-04-29 Ａｇｃ株式会社 耐水耐油剤組成物、及びその製造方法

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JPS62299598A (ja) * 1986-06-11 1987-12-26 三井東圧化学株式会社 紙の表面サイジング剤
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011027877A1 (en) 2009-09-01 2011-03-10 Daikin Industries, Ltd. Water and oil resistant agent for paper, treatment process and paper
CN102575435A (zh) * 2009-09-01 2012-07-11 大金工业株式会社 纸张用防水防油剂、处理方法和纸张
JP2013503267A (ja) * 2009-09-01 2013-01-31 ダイキン工業株式会社 紙用耐水耐油剤、紙処理方法および加工紙
US9249540B2 (en) 2009-09-01 2016-02-02 Daikin Industries, Ltd. Water and oil resistant agent for paper, treatment process and paper
CN101831842A (zh) * 2010-05-31 2010-09-15 漯河市天马化工有限公司 新型含氟含硅施胶增强剂及其制备方法
JP2012001590A (ja) * 2010-06-15 2012-01-05 Riken Vitamin Co Ltd 表面特性が改質された熱可塑性樹脂組成物
JP2015507103A (ja) * 2012-01-17 2015-03-05 エージーシー ケミカルズ アメリカズ，インコーポレイテッド 処理物品を調製する方法およびそれにより生成された処理物品
WO2015129634A1 (ja) * 2014-02-25 2015-09-03 旭硝子株式会社 パルプスラリー添加用耐油剤組成物、耐油紙の製造方法および耐油紙
WO2016182028A1 (ja) * 2015-05-13 2016-11-17 旭硝子株式会社 耐油紙および耐油紙の製造方法
US10829576B2 (en) 2016-04-27 2020-11-10 AGC Inc. Liquid repellent composition, method for its production, and method for producing oil resistant paper
JP2019119938A (ja) * 2017-12-28 2019-07-22 ダイキン工業株式会社 パルプモールド製品およびその製造方法
US11434606B2 (en) 2017-12-28 2022-09-06 Daiken Industries, Ltd. Pulp molded product and method for manufacturing same

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JPWO2009057716A1 (ja) 2011-03-10
US20100168319A1 (en) 2010-07-01
TW200936615A (en) 2009-09-01
ATE550360T1 (de) 2012-04-15
CN101842399B (zh) 2013-01-23
US8193276B2 (en) 2012-06-05
KR20100087143A (ko) 2010-08-03
TWI457352B (zh) 2014-10-21
ES2383047T3 (es) 2012-06-15
EP2206735B1 (en) 2012-03-21
EP2206735A1 (en) 2010-07-14
CN101842399A (zh) 2010-09-22
EP2206735A4 (en) 2011-02-23
JP5418229B2 (ja) 2014-02-19

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