WO2009047070A3 - Silan-substituierte raft-reagenzien und silan-vernetzbare polymere - Google Patents

Silan-substituierte raft-reagenzien und silan-vernetzbare polymere Download PDF

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Publication number
WO2009047070A3
WO2009047070A3 PCT/EP2008/061960 EP2008061960W WO2009047070A3 WO 2009047070 A3 WO2009047070 A3 WO 2009047070A3 EP 2008061960 W EP2008061960 W EP 2008061960W WO 2009047070 A3 WO2009047070 A3 WO 2009047070A3
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WO
WIPO (PCT)
Prior art keywords
silane
substituted
raft
optionally
reagents
Prior art date
Application number
PCT/EP2008/061960
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English (en)
French (fr)
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WO2009047070A2 (de
Inventor
Oliver Minge
Peter Ball
Sabine Delica
Original Assignee
Wacker Chemie Ag
Oliver Minge
Peter Ball
Sabine Delica
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wacker Chemie Ag, Oliver Minge, Peter Ball, Sabine Delica filed Critical Wacker Chemie Ag
Priority to US12/681,980 priority Critical patent/US20100222504A1/en
Priority to EP08803927A priority patent/EP2197888A2/de
Priority to CN200880110559A priority patent/CN101821275A/zh
Publication of WO2009047070A2 publication Critical patent/WO2009047070A2/de
Publication of WO2009047070A3 publication Critical patent/WO2009047070A3/de

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
    • C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
    • C09K3/1018—Macromolecular compounds having one or more carbon-to-silicon linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C08L101/10—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Gegenständeder Erfindung sind Silan-substituierte RAFT- Reagenzien der allgemeinen Formeln R1 n(OR2 )3-nSi-L1 -Rf -R3 (1a), R1 n(OR2 )3-nSi-L1 -Rf -L2 -Si(OR2 )3-nR1 n (1b), und R1 n(OR2 )3-n Si-L1 -Rf -L2 -Rf -L3 -Si(OR2 )3-n R1 n (1c), wobei R1, R2 und R3 jeweils unabhängig voneinander für Wasserstoffatome oder monovalente C1-C20-Kohlenwasserstoffreste stehen, die gegebenenfalls mit -CN, -NCO, -NR1 2, -COOH, -COOR1, - PO(OR1 ) 2, -Halogen, -Acyl, -Epoxy, -SH, -OH oder CONR1 2 substituiert sind, und in denen gegebenenfalls ein oder mehrere, einander nicht benachbarte Kohlenstoffatome durch Gruppen -O-, -CO-, -COO-, -OCO-, -OCOO-, CONR1 -, -S-, -CSS-, -CSO-, -COS-oder NR1 -, -N= oder P= ersetzt sind, njeweils ganzzahlige Wertevon 0 bis 2 annimmt, L1, L2 undL3 jeweils unabhängig voneinander lineare oder cyclische,divalente C1-C20-Kohlenwasserstoffreste sind, die gegebenenfalls mit -CN, -NCO, -NR12, -COOH, -COOR1, -PO(OR1 ) 2, -Halogen, -Acyl, -Epoxy, -SH, -OH oder CONR12 substituiert sind, und in denen gegebenenfalls ein oder mehrere, einander nicht benachbarte Kohlenstoffatome durch Gruppen -O-, -CO-, -COO-, -OCO-, -OCOO-, CONR1 -, -S-, -CSS-, -CSO-, -COS-oder NR1 -, -N= oder P= ersetzt sind,und Rf jeweils eine divalente RAFT-reaktive Gruppe ist; sowie Silan-vernetzbare Polymere erhältlich durch radikalisch initiierte Polymerisation von A) einem oder mehreren ethylenisch ungesättigten Monomeren ausgewählt aus der Gruppe umfassend (Meth)
PCT/EP2008/061960 2007-10-08 2008-09-10 Silan-substituierte raft-reagenzien und silan-vernetzbare polymere WO2009047070A2 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/681,980 US20100222504A1 (en) 2007-10-08 2008-09-10 Silane-substituted raft-reagents and silane-cross-linkable polymers
EP08803927A EP2197888A2 (de) 2007-10-08 2008-09-10 Silan-substituierte raft-reagenzien und silan-vernetzbare polymere
CN200880110559A CN101821275A (zh) 2007-10-08 2008-09-10 硅烷取代的raft试剂和硅烷可交联的聚合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200710000833 DE102007000833A1 (de) 2007-10-08 2007-10-08 Silan-substituierte RAFT-Reagenzien und Silan-vernetzbare Polymere
DE102007000833.5 2007-10-08

Publications (2)

Publication Number Publication Date
WO2009047070A2 WO2009047070A2 (de) 2009-04-16
WO2009047070A3 true WO2009047070A3 (de) 2009-08-06

Family

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Application Number Title Priority Date Filing Date
PCT/EP2008/061960 WO2009047070A2 (de) 2007-10-08 2008-09-10 Silan-substituierte raft-reagenzien und silan-vernetzbare polymere

Country Status (5)

Country Link
US (1) US20100222504A1 (de)
EP (1) EP2197888A2 (de)
CN (1) CN101821275A (de)
DE (1) DE102007000833A1 (de)
WO (1) WO2009047070A2 (de)

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DE102010060780A1 (de) 2010-11-24 2012-05-24 Continental Reifen Deutschland Gmbh Verfahren zur Herstellung von polymer-funktionalisierten Füllstoffpartikeln
US20140141262A1 (en) * 2011-06-29 2014-05-22 Sun Chemical Corporation Vinyl alcohol polymers with silane side chains and compositions comprising the same
JP5924647B2 (ja) * 2012-04-02 2016-05-25 東洋ゴム工業株式会社 ケイ素化合物及びその製造方法、並びにその利用
CN104220447B (zh) * 2012-04-02 2017-09-01 东洋橡胶工业株式会社 硅化合物及其制造方法以及其应用
JP5881059B2 (ja) * 2012-04-02 2016-03-09 東洋ゴム工業株式会社 ゴム又はプラスチック用補強剤、ゴム組成物及びプラスチック組成物の製造方法
CN102924503B (zh) * 2012-11-06 2016-03-09 上海交通大学 一种含有硅烷的raft链转移试剂及其制备与应用
JP6550908B2 (ja) * 2015-05-08 2019-07-31 国立大学法人福井大学 アルケニルエーテル系重合体の製造方法
KR102012787B1 (ko) * 2016-03-03 2019-08-21 주식회사 엘지화학 (공)중합체, (공)중합체의 제조 방법 및, 이를 포함하는 친수성 코팅 조성물
KR102012921B1 (ko) * 2016-03-03 2019-08-21 주식회사 엘지화학 중합체, 중합체의 제조 방법 및, 이를 포함하는 친수성 코팅 조성물
CN108003272B (zh) * 2017-12-29 2020-05-05 陕西科技大学 纳米纤维素/含氟聚丙烯酸酯无皂乳液的制备方法
CN114276547B (zh) * 2021-11-29 2023-11-10 南京林业大学 一种有机硅基raft试剂的制备方法
CN117965070B (zh) * 2024-04-01 2024-06-11 安徽三旺化学有限公司 一种木材用阻燃防水涂料及其制备方法

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Also Published As

Publication number Publication date
EP2197888A2 (de) 2010-06-23
WO2009047070A2 (de) 2009-04-16
DE102007000833A1 (de) 2009-04-09
CN101821275A (zh) 2010-09-01
US20100222504A1 (en) 2010-09-02

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