WO2009028726A1 - 方向性電磁鋼板用絶縁被膜処理液、および絶縁被膜を有する方向性電磁鋼板の製造方法 - Google Patents
方向性電磁鋼板用絶縁被膜処理液、および絶縁被膜を有する方向性電磁鋼板の製造方法 Download PDFInfo
- Publication number
- WO2009028726A1 WO2009028726A1 PCT/JP2008/065925 JP2008065925W WO2009028726A1 WO 2009028726 A1 WO2009028726 A1 WO 2009028726A1 JP 2008065925 W JP2008065925 W JP 2008065925W WO 2009028726 A1 WO2009028726 A1 WO 2009028726A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- insulating coating
- grain
- steel sheet
- electrical steel
- oriented electrical
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 122
- 239000011248 coating agent Substances 0.000 title claims abstract description 118
- 238000004519 manufacturing process Methods 0.000 title claims description 21
- 229910000831 Steel Inorganic materials 0.000 title abstract description 25
- 239000010959 steel Substances 0.000 title abstract description 25
- 239000010936 titanium Substances 0.000 claims abstract description 75
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 43
- 150000001875 compounds Chemical class 0.000 claims abstract description 43
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 43
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000013522 chelant Substances 0.000 claims abstract description 30
- 239000008119 colloidal silica Substances 0.000 claims abstract description 24
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 12
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 12
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 12
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 9
- 229910052788 barium Inorganic materials 0.000 claims abstract description 8
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 8
- 229910001224 Grain-oriented electrical steel Inorganic materials 0.000 claims description 70
- 238000000137 annealing Methods 0.000 claims description 62
- 238000001953 recrystallisation Methods 0.000 claims description 34
- 229910019142 PO4 Inorganic materials 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 31
- 235000021317 phosphate Nutrition 0.000 claims description 31
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 18
- 239000010452 phosphate Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 238000005097 cold rolling Methods 0.000 claims description 13
- 238000009413 insulation Methods 0.000 claims description 13
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 13
- 238000005096 rolling process Methods 0.000 claims description 7
- 238000005098 hot rolling Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 abstract description 12
- 230000007423 decrease Effects 0.000 abstract description 6
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- 229910052681 coesite Inorganic materials 0.000 abstract description 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 2
- 238000003475 lamination Methods 0.000 abstract description 2
- 229910052682 stishovite Inorganic materials 0.000 abstract description 2
- 229910052905 tridymite Inorganic materials 0.000 abstract description 2
- 150000003016 phosphoric acids Chemical class 0.000 abstract 3
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 44
- 238000010521 absorption reaction Methods 0.000 description 30
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- 239000011777 magnesium Substances 0.000 description 13
- AIFLGMNWQFPTAJ-UHFFFAOYSA-J 2-hydroxypropanoate;titanium(4+) Chemical compound [Ti+4].CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O.CC(O)C([O-])=O AIFLGMNWQFPTAJ-UHFFFAOYSA-J 0.000 description 10
- 229910052839 forsterite Inorganic materials 0.000 description 10
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 10
- 239000011651 chromium Substances 0.000 description 9
- 150000001845 chromium compounds Chemical class 0.000 description 9
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000010828 elution Methods 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000011162 core material Substances 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 230000037303 wrinkles Effects 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 229910000976 Electrical steel Inorganic materials 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 230000000843 anti-fungal effect Effects 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 3
- 239000004137 magnesium phosphate Substances 0.000 description 3
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 3
- 229960002261 magnesium phosphate Drugs 0.000 description 3
- 235000010994 magnesium phosphates Nutrition 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005261 decarburization Methods 0.000 description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- OVSGBKZKXUMMHS-VGKOASNMSA-L (z)-4-oxopent-2-en-2-olate;propan-2-olate;titanium(4+) Chemical compound [Ti+4].CC(C)[O-].CC(C)[O-].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O OVSGBKZKXUMMHS-VGKOASNMSA-L 0.000 description 1
- TYKCBTYOMAUNLH-MTOQALJVSA-J (z)-4-oxopent-2-en-2-olate;titanium(4+) Chemical compound [Ti+4].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O TYKCBTYOMAUNLH-MTOQALJVSA-J 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 239000008896 Opium Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229960001027 opium Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- NMJKIRUDPFBRHW-UHFFFAOYSA-N titanium Chemical compound [Ti].[Ti] NMJKIRUDPFBRHW-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
- C23C22/188—Orthophosphates containing manganese cations containing also magnesium cations
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1277—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular surface treatment
- C21D8/1283—Application of a separating or insulating coating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/20—Orthophosphates containing aluminium cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/22—Orthophosphates containing alkaline earth metal cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
- C23C22/74—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process for obtaining burned-in conversion coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/16—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
- H01F1/18—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets with insulating coating
Definitions
- Insulating coating solution for grain-oriented electrical steel sheet and
- the present invention is a directional electromagnetic wave with excellent tension induced by a coating, moisture absorption resistance, moisture-absorption resistance, rust resistance, and lamination factor.
- the present invention relates to a chromium-free insulation coating for a grain oriented electrical steel sheet used in the manufacture of steel sheets.
- the present invention also relates to a method for producing a grain-oriented electrical steel sheet having an insulating coating using the chromium-free insulating coating treatment liquid for grain-oriented electrical steel.
- noise generated from power transformers has become a problem as pollution.
- the main cause of noise in power transformers is magnetostriction of grain-oriented electrical steel sheets used as transformer core materials.
- an industrially advantageous solution is to coat the grain-oriented electrical steel sheet with an insulating coating.
- the coating tension is the tension applied to the grain-oriented electrical steel sheet by the formation of the insulating coating.
- the coating of grain-oriented electrical steel sheets is usually a ceramic forsterite film formed by secondary recrystallization annealing and a phosphate-based insulation applied on the ceramic forsterite film. It consists of a film.
- Patent Document 1 Japanese Patent Application Laid-Open No. 48-39338
- Patent Document 2 Japanese Patent Application Laid-Open No.
- Patent Document 2 colloidal silica, phosphate, and chromium compounds (for example, one or two selected from chromic anhydride, chromate and dichromate). Insulating coating solution containing the above is applied to the steel sheet and then baked. The insulating coating formed by these methods has an effect of improving magnetostriction characteristics by applying tensile stress to the grain-oriented electrical steel sheet.
- these insulating film treatment liquids contain a chromium compound such as chromic anhydride, chromate or dichromate as a component for maintaining the moisture absorption resistance of the insulating film satisfactorily. Contains hexavalent chromium.
- Patent Document 2 discloses a technique in which a chromium compound is not added.
- the power in terms of moisture absorption resistance is extremely disadvantageous.
- hexavalent chromium contained in the insulation coating solution is reduced to trivalent chromium by baking and rendered harmless.
- Patent Document 3 discloses colloidal silica, aluminum phosphate and boric acid as a so-called chromium-free insulating coating solution for grain-oriented electrical steel sheets that does not substantially contain chromium.
- an insulating film treatment solution containing one or more selected from sulfates of Mg, Al, Fe, Co, Ni, and Zn is disclosed, and Japanese Patent Publication No. 58-44744
- the gazette (Patent Document 4) contains colloidal silica and magnesium phosphate, and further includes an insulating film treatment liquid containing one or more selected from sulfates of Mg, Al, Mn and Zn. Is disclosed.
- Patent Document 3 and Patent Document 4 were used, there were problems in film tension and moisture absorption resistance in response to the recent demand for film characteristics.
- Patent Document 5 JP 2007-233 A (Patent Document 5) describes (I) as a method for solving the problem of coating film tension and lack of moisture absorption resistance, which becomes a problem when the insulating coating solution is made chrome-free.
- a chromium-free insulating coating treatment solution is disclosed. Disclosure of the invention
- the present invention has been developed in view of the above-described present situation, and aims at the following items.
- the inventors have developed a directionality after secondary recrystallization annealing on an insulating coating solution containing various compounds in addition to various phosphates and colloidal silica. It was applied to electrical steel sheets and then baked. The properties of the coatings obtained were investigated.
- the inventors investigated the optimal composition of the chromium-free insulating coating solution for grain-oriented electrical steel sheets using various phosphates and titanium chelate compounds.
- a method for producing a grain-oriented electrical steel sheet having an insulating coating using the chromium-free insulating coating treatment solution was studied. And by these examination, this invention was completed. That is, the gist configuration of the present invention is as follows.
- An insulating coating solution for grain-oriented electrical steel sheets characterized by comprising.
- the insulating film treatment liquid is chromium-free and particularly contains substantially no Cr.
- the treatment liquid is preferably an aqueous solution.
- a method for producing a grain-oriented electrical steel sheet having an insulating film wherein the baking treatment is performed at a temperature of 350 ° C or higher and 1100 ° C or lower.
- the insulating film treatment liquid is chromium-free and particularly contains substantially no Cr.
- the treatment solution should be an aqueous solution! /.
- one cold rolling or intermediate annealing (intermediate) It is preferable that the final thickness is finished by two or more cold rollings that sandwich the annealing). Further, after the primary recrystallization annealing, it is preferable to apply the secondary recrystallization annealing after applying an annealing separator containing MgO as a primary component.
- Figure 1 shows the effect of titanium lactate on the insulating coating solution [Ti (C 3 H 5 ⁇ 2 ) 2 on the moisture absorption resistance of the insulating coating (vertical axis: P elution amount per 150 cm 2 , unit: ⁇ g).
- (OH) 2 ] is a graph showing the effect of the amount added (horizontal axis: amount of added calories in terms of Ti with respect to P0 4 lmol, unit: mol).
- Fig. 2 shows the amount of titanium lactate [Ti (C 3 H 5 0 2 ) 2 (OH) 2 ] added (horizontal axis: the same as in Fig. 1) on the coating tension (vertical axis, unit: MPa) of the insulating coating. It is a graph which shows an influence.
- Si02 27mass% of colloidal silica (water) 450ml (Si0 2: 2mol) , and,
- Ti (C 3 H 5 0 2 ) 2 (OH) 2 ] (titanium lactate) was prepared in an amount of 0.005 to 5.0 mol in terms of Ti.
- a treatment solution not containing titanium lactate was also prepared.
- the titanium latate was supplied as a solid and dissolved in the treatment liquid.
- the amount of the processing solution only the amount necessary for the following experiment was prepared while maintaining the above blending ratio.
- the length direction is the rolling direction
- the width is 30 mm
- X length S A test piece of 280 mm was collected by shearing, and then the insulating coating on one side was removed. The amount of curvature deformation at the end of the test piece was measured with one end 30 mm in the length direction of the steel plate fixed, and the coating tension ⁇ was calculated from the following equation (1). In order to eliminate the influence of the weight of the steel sheet, the amount of warpage was measured with the length direction of the steel sheet in the horizontal direction and the width direction in the vertical direction.
- the steel sheet having the above insulating coating was kept in air at a temperature of 50 ° C and a dew point of 50 ° C for 200 hours. Then, the steel plate surface was observed visually and the area ratio of the wrinkles was measured.
- the space factor was evaluated by a method based on JIS C 2550.
- FIGS. Figure 1 shows the addition of titan lactate [Ti (C 3 H 5 0 2 ) 2 (OH) 2 ] that affects the elution amount of P in the insulation coating (vertical axis: 150 g 2 , unit: ⁇ g), that is, moisture absorption resistance. It shows the effect of the amount (horizontal axis: amount added to P0 4 lmol)
- Fig. 2 shows the effect of the amount of titanium lactate [Ti (C 3 H 5 0 2 ) 2 (OH) 2 ] (horizontal axis) on the coating tension of the insulating coating.
- the added amount of titanium latate [Ti (C 3 H 5 0 2 ) 2 (OH) 2 ] is the number of moles in terms of Ti.
- the amount of titanium lactate [Ti (C 3 H 5 0 2 ) 2 (OH) 2 ] was good in the range of 0.005 to 5.0 mol in terms of Ti.
- the insulating coating solution of the present invention is preferably an aqueous solution. That is, the insulating coating of the present invention
- the treatment liquid preferably comprises at least one selected from the group consisting of phosphates of Mg, Ca, Ba, Sr, Zn, Al, and Mn, colloidal silica, and titanium clay M compound using water as a solvent. Contains. First, the forces that are phosphates Mg, Ca, Ba, Sr, Zn, Al and! It is necessary to select one or more of ln phosphates to contain. This is because with other phosphates, a coating with good moisture absorption resistance cannot be obtained unless a chromium compound (for example, chromates) is added.
- a chromium compound for example, chromates
- Mg (H 2 P0 4 ) 2 , Ca (H 2 P0 4 ) 2 , Ba (H 2 P0 4 ) 2 , Sr are the primary phosphates of Mg Ca, Ba, Sr, Zn, Al and Mn.
- (H 2 P0 4 ) 2 , Zn (H 2 P0 4 ) 2 , A1 (H 2 P0 4 ) 3 , and Mn (H 2 P0 4 ) 2 are easily dissolved in water and are therefore suitable for the present invention. Can be.
- P0 4 in the phosphate For I mol, it is necessary to 0.2 ⁇ 10mol containing colloidal silica as Si0 2.
- Colloidal silica is an indispensable component because it forms a low thermal expansion compound with the phosphate to generate a film tension. Further, in order to exhibit the left effect, the amount, the P0 phosphorus in salt 4: Si0 2 in terms of at 0.2mol or more relative to I mol, it is preferable that the lOmol hereinafter.
- the type of colloidal silica is not particularly limited as long as the stability of the solution and the compatibility with the above-described phosphate are obtained.
- colloidal silica containing a sol containing aluminum (A1) can also be used.
- the amount of A1 is preferably 1.0 or less in terms of Al 2 0 3 / SiO 2 ratio.
- the insulating coating solution of the present invention particularly contains a titanium chelate compound in a range of 0.01 to 4.0 mol in terms of Ti with respect to P0 4 : lmol in the phosphate. is important.
- the titanium chelate compound is a compound in which a ligand having a plurality of coordinates is bound to a tetravalent hexacoordinate titanium atom.
- the titanium chelate compound is represented by the following formula (2): (Formula ()
- any titanium chelate compound that does not cause precipitation when mixed in an insulating coating solution can be advantageously applied.
- R is hydrogen or an organic group
- R 3 and R 4 are organic groups, and each organic group has 10 or less carbon atoms. Examples of suitable compounds will be described later.
- the amount of titanium chelate compound added to P0 4 : lmol in phosphate must be O.Olmol or more in terms of Ti.
- a more preferable addition amount of the titanium chelate compound is 0.05 to 3.0 mol in terms of Ti.
- the reason why the moisture absorption resistance is improved by the addition of the titanium chelate compound is considered as follows.
- P_ ⁇ of-free in phosphate 4 that were not taken into vitreous is silica and phosphorus Sanshioryoku formation are those bound to titanium the titanium chelate compounds, insolubilized in the insulating film it is conceivable that. For this reason, it is estimated that moisture absorption resistance improves. Even when Ca, Mg, Mn, Fe, Zn, Co, Ni, or Cu organic compounds are added, the moisture absorption resistance is slightly improved, but the titanium chelate compounds are more resistant to these. The effect of improving hygroscopicity is remarkably large.
- the titanium chelate compound is a complex in which a chelate compound is coordinated to Ti, and any can be applied as long as it can be blended in the insulating coating solution without causing precipitation.
- titanium diisopropoxy bis (acetylacetonate) [Ti (iC 3 H 7 0) 2 (C 5 H 7 0 2 ) 2 ] (titanium di-iso-propoxy bis-acetylacetonate), titanium tetraacetyl Noreacetonate [Ti (C 5 H 7 0 2 ) 4 ] (titanium tetra-acetyl acetonate), titanium lactate [Ti (C 3 H 5 0 2 ) 2 (OH) 2 ], titanium diisopropoxybis (triethanol Amineto) [Ti (i one C 3 H 7 0) 2 ( C 6 H 14 0 3 N) 2] (titanium di-iso-propoxy bis (triethanol aminato)) and the like.
- relatively strong molecular weight M and titanium lactate are particularly preferable.
- Titanium compounds are generally highly reactive.
- a titanium chelate compound is a compound in which a ligand having a plurality of coordination sites is bonded to a titanium atom, so that the titanium atom is inactivated. For this reason, it is extremely stable in the insulating coating solution without reacting with water, phosphate, or colloidal silica. And, at the beginning of the baking process, that is, until the drying of the coating solution is completed, the hydrolysis hardly occurs and the titanium compound is not precipitated. Therefore, titanium titanium chelate compounds which are added is surely baked into the insulation coating bonded to P0 4.
- the titanium in the applied titanium chelate stays in the insulating film until the end of the baking process where it does not precipitate and fall off due to some reaction during the baking process. And it is estimated that this makes the coating composition uniform and improves the moisture absorption resistance and anti-mold properties.
- the concentration of the above main components in the insulating coating solution is not particularly limited. However, when the concentration is low, the insulating coating becomes thin, and when the concentration is high, the viscosity of the insulating coating treatment liquid increases and the workability of coating and the like decreases.
- the concentration range of the colloidal silica opium titanium chelate compound is automatically determined once the phosphate concentration is determined.
- the following substances may be added to the insulating coating solution of the present invention.
- boric acid may be added to improve the heat resistance of the insulating coating.
- Si0 2 , A1 2 0 3 having a primary particle size of 50 to 2000 nm or less and One or more selected from Ti0 2 may be contained.
- the reason why the fusion resistance is required is as follows. direction When a magnetic steel sheet is used for a steel core type transformer, the steel sheet is rolled and formed into a core shape, and then subjected to strain relief annealing (800 ° CX for about 3 hours). At that time, there is a force S for adhering between adjacent coatings. Such a fusion reduces the interlayer insulation resistance of the iron core, which in turn causes the magnetic properties to deteriorate.
- the insulating coating solution can be collected. Above, a total of about borate 'Si0 2 or the like and other additives, it is preferable that the degree to which the content is equal to or less than 30 mass%.
- the insulating film treatment solution is chromium-free, and it is particularly desirable that it does not substantially contain Cr.
- substantially does not contain means that Cr derived from impurities contained in the raw material is tolerated but not actively added.
- many of the components such as phosphate, colloidal silica, and titanium chelate compound are available as commercial products for industrial use, and any amount of Cr contained in these commercial products is acceptable.
- a steel slab for grain-oriented electrical steel sheets having a predetermined component composition is rolled to a final thickness. Thereafter, after performing primary recrystallization annealing and secondary recrystallization annealing, the above-described insulating coating treatment liquid of the present invention is applied to the surface of the steel sheet and then baked at a temperature of 350 ° C. to 1100 ° C.
- the slab for grain-oriented electrical steel sheets is hot-rolled, hot-rolled sheet annealing is performed as necessary, and the final rolling is performed by one or more cold rollings sandwiching intermediate annealing. The plate thickness.
- any conventionally known slab can be used as the component yarn of the slab.
- the production method is not particularly limited, and any conventionally known production method can be used.
- the main components of a slab for a typical grain-oriented electrical steel sheet are C: 0.10 mass% or less, Si: 2.0 to 4.5 mass%, Mn: 0.01 to 1.0 mass%.
- various inhibitors are usually used in grain-oriented electrical steel sheets.
- elements corresponding to the inhibitors are added. For example, as an inhibitor
- MnSe and Sb When MnSe and Sb are used, Mn, Se (about 100 to 300 ppm) and Sb (about 0.01 to 0.2 mass%) can be added.
- S, Al, N, and Se are generally extracted from the steel sheet in the secondary recrystallization annealing process and reduced to the impurity level.
- a known method can be applied to hot rolling of the slab for grain-oriented electrical steel sheet, but the thickness after hot rolling is preferably in the range of 1.5 to 3.0 mm.
- the hot-rolled sheet after hot rolling may be subjected to hot-rolled sheet annealing as necessary for further improvement of magnetic properties.
- the hot-rolled sheet that has been subjected to hot rolling or further hot-rolled sheet annealing is subjected to cold rolling to obtain a final thickness.
- the cold rolling may be performed once or may be cold rolling performed twice or more with intermediate annealing.
- the primary recrystallization annealing following the cold rolling is performed in order to promote the primary recrystallization, but may be performed also as decarburization by controlling the atmosphere or the like.
- the treatment conditions for primary recrystallization annealing can be set according to the purpose, but it is desirable to perform continuous annealing at a temperature of 800 to 950 ° C for 10 to 600 seconds.
- nitriding treatment may be performed using ammonia gas or the like during the primary recrystallization annealing or after the primary recrystallization annealing.
- the crystal grains obtained by the primary recrystallization annealing have excellent magnetic properties in the rolling direction by secondary recrystallization, so-called Goss orientation (Goss orientation) ) Is a process of preferential growth.
- the conditions for secondary recrystallization annealing are preferably set at a force of 800 to 1250 ° C for about 5 to 300 hours, which can be set according to the purpose.
- a forsterite film is formed. Generate on a steel plate.
- a forsterite film has been formed for the purpose of further improving the iron loss of grain-oriented electrical steel sheets. /, Insulating coating treatment in the state is also being considered! / If the forsterite film is not formed, do not apply an annealing separator or apply an annealing separator that does not contain MgO as the main component (such as alumina).
- the chromium-free insulating treatment film treatment liquid of the present invention can be applied regardless of the presence or absence of a forsterite film.
- the chromium-free insulating coating treatment liquid of the present invention is applied to the grain-oriented electrical steel sheet after the secondary recrystallization manufactured through the series of steps as described above, and then a baking treatment is performed.
- the chromium-free insulating coating solution may be diluted by adding water to adjust the density in order to improve the coating property. Further, at the time of coating are a roll coater (ro ll coater), it can be used known means.
- the baking temperature is desirably 750 ° C or higher. This is because film tension is generated by baking at 750 ° C or higher. However, when grain-oriented electrical steel is used for the iron core of the transformer, the baking temperature should be 350 ° C or higher. This is because the core is often subjected to strain relief annealing for about 3 hours at a temperature of 800 ° C. In this case, the film tension is manifested during this strain relief annealing.
- the maximum baking temperature range is 350 ° C or higher and 1100 ° C or lower.
- the thickness of the insulating coating is not particularly limited, but is preferably in the range of 1 to 5 / z m per side. Since the film tension is proportional to the thickness of the film, if it is less than 1 / im, the film tension may be insufficient depending on the purpose. On the other hand, if it exceeds 5 ⁇ , the space factor may decrease more than necessary.
- the thickness of the insulating film can be controlled to the target value by the concentration of the insulating film treatment liquid, the coating amount, the coating conditions (for example, the pressing condition of the roll coater), and the like.
- the steel slab was hot-rolled to obtain a hot-rolled sheet having a thickness of 2.0 mm, and then subjected to hot-rolled sheet annealing at 1000 ° C. for 60 seconds. After that, this hot-rolled sheet was subjected to a first cold rolling to an intermediate sheet thickness of 1.5 mm, followed by an intermediate annealing at 1100 ° C for 60 seconds, and then a second cold rolling to a final sheet thickness of 0.22 mm. The cold-rolled sheet was used.
- this cold-rolled sheet was subjected to primary recrystallization annealing at 820 ° C x 150 seconds, which also served as decarburization. Then, after applying an annealing separator (MgO slurry), secondary recrystallization annealing was performed at 1200 ° C for 15 hours to obtain a grain-oriented electrical steel sheet having a forsterite coating.
- MgO slurry annealing separator
- An insulating coating solution was prepared by mixing the titanium chelate compound shown in Table 1 with a Ti conversion in the range of 0.005 to 5.0 mol. The liquid volume In this way, only the amount necessary for the following experiment was prepared while maintaining the above blending ratio. The same applies hereinafter.
- These insulating film treatment solutions were applied to the surface of the grain-oriented electrical steel sheet and baked at 750 ° C. for 1 minute. The film thickness was 2 ⁇ m per side.
- the above-mentioned chromium-free insulating coating treatment liquid was not mixed with titanium chelate compound, and magnesium sulfate heptahydrate instead of titanium chelate compound: lmol (Mg conversion ), Titanium oxide colloid (non-chelating Ti compound): 0.3 mol (Ti conversion), and chromic anhydride (chromium compound): lmol (Cr conversion)
- titanium chelate compound lmol (Mg conversion )
- titanium oxide colloid non-chelating Ti compound
- Ti conversion chromic anhydride
- Cr conversion chromium compound
- a grain-oriented electrical steel sheet having an insulating coating was manufactured using the insulating coating treatment liquid shown in “Invention 3” of Example 1 in Patent Document 5.
- this insulation coating solution is 50% primary phosphoric acid A1: 50ml (solid 35g), 20% colloidal silica: 100ml (solid 23g) and dispersion of colloidal compound containing Fe Liquid (Fe: equivalent to 1.2 g) ( ⁇ ⁇ 1.0, average particle size: 12 awakening, Fe203 equivalent solid content concentration: 7.5%).
- the coating tension, moisture absorption resistance, weather resistance and space factor were evaluated by the following methods.
- a test piece having a width of 30 mm and a length of 280 mm was collected by shearing from the grain-oriented electrical steel sheet having the insulating coating, with the length direction being the rolling direction, and then the insulating coating on one side was removed. Then, the length of one end of the steel sheet was fixed at 30 mm, the amount of warpage at the end of the test piece was measured, and the film tension ⁇ was calculated from the following equation (1). Here, the amount of warpage was measured with the length direction of the steel plate being horizontal and the width direction being vertical.
- the grain-oriented electrical steel sheet having the above insulating coating was maintained in air at a temperature of 50 ° C and a dew point of 50 ° C for 200 hours. Thereafter, the surface of the steel plate was visually observed, and the fender resistance was evaluated by the area ratio of the wrinkles.
- the space factor was evaluated by a method based on JIS C 2550. Table 1 shows the measurement results.
- P0 4 0.1 mol of boric acid and Al 2 0 3 0.3 mol are added to 1 mol.
- a chromium-free insulating coating treatment solution to which a titanium chelate compound was added in a range of 0.01 to 4.0 mol in terms of Ti was used, coating tension, moisture absorption resistance, It was possible to form an insulating film excellent in antibacterial properties, space factor, and misaligned film characteristics.
- the insulating film characteristics of these inventive examples were at or above the level of the comparative examples to which chromium compounds were added.
- a slab for grain-oriented electrical steel sheets having a composition was hot-rolled to obtain a hot-rolled sheet having a thickness of 2.5 mm, and then hot-rolled at 1050 ° C. for 60 seconds; Subsequently, a cold-rolled sheet having a thickness of 0.30 mm was obtained by cold rolling. Next! /, The cold rolled sheet was subjected to a first recrystallization annealing at 900 ° C for 30 seconds.
- an annealing separator (MgO slurry) is applied, followed by secondary recrystallization annealing at 880 ° CX for 50 hours, followed by further annealing at 1200 ° CX for 15 hours, thereby providing a directional electromagnetic with a forsterite film.
- a steel plate was obtained.
- 500 ml of various phosphate aqueous solutions shown in Table 2 (containing 1 mol of PO 4 in terms of PO 4 ) and 1000 ml of colloidal silica (aqueous) in various concentrations (0.5 to 10 mol in terms of SiO 2 ).
- Insulating coating solution containing 0.5 mol of Ti (C 3 H 5 0 2 ) 2 (OH) 2 ] in terms of Ti was prepared.
- These treatment liquids were applied to the surface of the grain-oriented electrical steel sheet and subjected to a baking treatment at 1030 ° C. for 60 seconds.
- the film thickness after baking was 3 / zm per side.
- Chromium compound (chromic anhydride (Gr0 3 , PO4: 1 mol to 1 mol)) added instead of titanium chelate compound
- a chromium-free insulating coating solution for grain-oriented electrical steel sheets with appropriate amounts of titanium chelate compound added with appropriate amounts of various phosphates and colloidal silica specified in the present invention is used.
- excellent insulating film characteristics were obtained with respect to all of film tension, moisture absorption resistance, weather resistance and space factor.
- an annealing separator (MgO slurry) is applied, followed by secondary recrystallization annealing at 880 ° CX for 50 hours, followed by bow I and further annealing at 1200 ° CX for 15 hours to have a forsterite coating.
- a grain-oriented electrical steel sheet was obtained.
- the film tension, moisture absorption resistance, and anti-mold space factor were evaluated in the same manner as in Example 1.
- the film tension was also evaluated after strain relief annealing at 800 ° C for 3 hours in order to investigate the effect of strain relief annealing.
- an insulating film having excellent film tension, moisture absorption resistance, and anti-mold space factor can be formed on the surface of the grain-oriented electrical steel sheet. Reduction, and in turn, reduction of noise pollution.
- the chromium-free insulating coating solution for grain-oriented electrical steel sheets of the present invention does not contain a chromium compound, so that waste liquid treatment becomes easy and is preferable from the viewpoint of environmental protection.
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Abstract
Description
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CN2008801045394A CN101790599B (zh) | 2007-08-30 | 2008-08-28 | 方向性电磁钢板用绝缘覆膜处理液以及具有绝缘覆膜的方向性电磁钢板的制造方法 |
US12/675,158 US8409370B2 (en) | 2007-08-30 | 2008-08-28 | Treatment solution for insulation coating for grain oriented electrical steel sheet and method for producing grain oriented electrical steel sheet having insulation coating |
EP08828141.5A EP2186924B1 (en) | 2007-08-30 | 2008-08-28 | Solution for treatment of insulating coating film for oriented electromagnetic steel sheet, and method for production of oriented electromagnetic steel sheet having insulating coating film thereon |
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JP2007224742A JP5104128B2 (ja) | 2007-08-30 | 2007-08-30 | 方向性電磁鋼板用クロムフリー絶縁被膜処理液および絶縁被膜付方向性電磁鋼板の製造方法 |
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CN111902555A (zh) * | 2018-03-22 | 2020-11-06 | 日本制铁株式会社 | 方向性电磁钢板及方向性电磁钢板的制造方法 |
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Publication number | Publication date |
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JP5104128B2 (ja) | 2012-12-19 |
US8409370B2 (en) | 2013-04-02 |
CN101790599B (zh) | 2011-12-21 |
RU2431698C1 (ru) | 2011-10-20 |
KR20100049617A (ko) | 2010-05-12 |
EP2186924B1 (en) | 2016-10-05 |
US20100206437A1 (en) | 2010-08-19 |
CN101790599A (zh) | 2010-07-28 |
KR101175059B1 (ko) | 2012-08-16 |
EP2186924A1 (en) | 2010-05-19 |
JP2009057591A (ja) | 2009-03-19 |
EP2186924A4 (en) | 2015-06-03 |
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