WO2009028676A1 - カルボニル化合物の製造方法およびカルボニル化合物の製造に用いる酸化促進剤 - Google Patents

カルボニル化合物の製造方法およびカルボニル化合物の製造に用いる酸化促進剤 Download PDF

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Publication number
WO2009028676A1
WO2009028676A1 PCT/JP2008/065567 JP2008065567W WO2009028676A1 WO 2009028676 A1 WO2009028676 A1 WO 2009028676A1 JP 2008065567 W JP2008065567 W JP 2008065567W WO 2009028676 A1 WO2009028676 A1 WO 2009028676A1
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WO
WIPO (PCT)
Prior art keywords
carbonyl compound
producing
pro
production
oxidizing
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Application number
PCT/JP2008/065567
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English (en)
French (fr)
Inventor
Kazuaki Ishihara
Muhammet Uyanik
Yukihiro Isogai
Suguru Ohara
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National University Corporation Nagoya University
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Publication date
Application filed by National University Corporation Nagoya University filed Critical National University Corporation Nagoya University
Priority to JP2009510225A priority Critical patent/JPWO2009028676A1/ja
Priority to US12/441,194 priority patent/US8394995B2/en
Priority to CN2008800007183A priority patent/CN101541725B/zh
Priority to EP08828094.6A priority patent/EP2085373B8/en
Priority to ES08828094T priority patent/ES2403203T3/es
Publication of WO2009028676A1 publication Critical patent/WO2009028676A1/ja

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215Sulfur-containing compounds
    • B01J31/0225Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215Sulfur-containing compounds
    • B01J31/0229Sulfur-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0214
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231Halogen-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)

Abstract

 アルコールを酸化することにより、高効率でカルボニル化合物を得ることができる方法を提供する。本発明のカルボニル化合物の製造方法は、下記一般式(I)で表される化合物またはその誘導体あるいはその塩と、酸化剤との存在下、アルコールを酸化する工程を有することよりなる。(式中、R1およびR2は、それぞれ独立して、水素原子、ニトロ基、ハロゲン原子、酸性基、および置換基を有していても良いアルキル基もしくはアルコキシ基を表す。またはR1とR2が隣接する二つの炭素と一緒になって芳香族環を形成しても良い。)
PCT/JP2008/065567 2007-08-31 2008-08-29 カルボニル化合物の製造方法およびカルボニル化合物の製造に用いる酸化促進剤 WO2009028676A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2009510225A JPWO2009028676A1 (ja) 2007-08-31 2008-08-29 カルボニル化合物の製造方法およびカルボニル化合物の製造に用いる酸化促進剤
US12/441,194 US8394995B2 (en) 2007-08-31 2008-08-29 Process for preparation of carbonyl compound and pro-oxidant for preparation of carbonyl compound
CN2008800007183A CN101541725B (zh) 2007-08-31 2008-08-29 羰基化合物的制造方法和用于制造羰基化合物的氧化促进剂
EP08828094.6A EP2085373B8 (en) 2007-08-31 2008-08-29 Method for producing carbonyl compound and pro-oxidant used for production of carbonyl compound
ES08828094T ES2403203T3 (es) 2007-08-31 2008-08-29 Método para producir compuesto carbonilo y prooxidante usado para la producción de compuesto carbonilo

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-226843 2007-08-31
JP2007226843 2007-08-31

Publications (1)

Publication Number Publication Date
WO2009028676A1 true WO2009028676A1 (ja) 2009-03-05

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PCT/JP2008/065567 WO2009028676A1 (ja) 2007-08-31 2008-08-29 カルボニル化合物の製造方法およびカルボニル化合物の製造に用いる酸化促進剤

Country Status (6)

Country Link
US (1) US8394995B2 (ja)
EP (1) EP2085373B8 (ja)
JP (3) JPWO2009028676A1 (ja)
CN (1) CN101541725B (ja)
ES (1) ES2403203T3 (ja)
WO (1) WO2009028676A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010100635A (ja) * 2007-08-31 2010-05-06 Nagoya Univ カルボニル化合物の製造方法およびカルボニル化合物の製造に用いる酸化促進剤
JP2017100988A (ja) * 2015-12-01 2017-06-08 アサヒグループホールディングス株式会社 光学活性なヒドロキシ脂肪酸の製造方法

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WO2012164095A1 (en) 2011-06-01 2012-12-06 Estetra S.A. Process for the production of estetrol intermediates
SG195118A1 (en) 2011-06-01 2013-12-30 Estetra S A Process for the production of estetrol intermediates
EP2383279A1 (en) 2011-07-19 2011-11-02 Pantarhei Bioscience B.V. Process for the preparation of estetrol
JP6218140B2 (ja) * 2014-02-24 2017-10-25 国立大学法人富山大学 磁性鉄粒子担持ヨウ素触媒
CN108218701A (zh) * 2018-03-21 2018-06-29 安徽中医药大学 一种适合双醋瑞因工业化的生产方法
RU2764581C1 (ru) * 2018-03-30 2022-01-18 Дайкин Индастриз, Лтд. Способ получения фторированных органических соединений

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IT1197862B (it) * 1986-08-11 1988-12-21 Montedipe Spa Processo per la trans-alogenazione catalitica di un poli-iodo benzene
ES2403203T3 (es) 2007-08-31 2013-05-16 National University Corporation Nagoya University Método para producir compuesto carbonilo y prooxidante usado para la producción de compuesto carbonilo

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ANNUAL MEETING ON CHEMICAL THE 87TH SOCIETY OF JAPAN IN SPRING,KOEN YOKOSHU II, 12 March 2007 (2007-03-12), pages 876(1 C8-05) *
ANNUAL MEETING ON CHEMICAL THE 88TH SOCIETY OF JAPAN IN SPRING, KOEN YOKOSHU II, 12 March 2008 (2008-03-12), pages 1325(2J4-39) *
ARUN P. THOTTUMKARA ET AL.: "In Situ Generation of o-Iodoxybenzoic Acid (IBX) and the Catalytic Use of It in Oxidation Reactions in the Presence of Oxone as a Co-oxidant", ORGANIC LETTERS, vol. 7, no. 14, 2005, pages 2933 - 2936 *
CHEMICAL SOCIETY OF JAPAN NO. 87 SPRING ANNUAL MEETING PRESENTATION
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KOPOSOV ALEXEY ET AL.: "Preparation and Reductive Decomposition of 2-Iodoxybenzenesulfonic Acid. X-ray Crystal Structure of 1-Hydroxy-1H-1,2,3-benziodoxathiole 3,3-Dioxide", EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, no. 21, 2006, pages 4791 - 4795 *
SCHULZE AGNES ET AL.: "Oxidation of Alcohols with Catalytic Amounts of IBX", SYNTHESIS, no. 2, 2006, pages 257 - 260 *
See also references of EP2085373A4 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010100635A (ja) * 2007-08-31 2010-05-06 Nagoya Univ カルボニル化合物の製造方法およびカルボニル化合物の製造に用いる酸化促進剤
JP2010100636A (ja) * 2007-08-31 2010-05-06 Nagoya Univ カルボニル化合物の製造方法およびカルボニル化合物の製造に用いる酸化促進剤
US8394995B2 (en) 2007-08-31 2013-03-12 National University Corporation Nagoya University Process for preparation of carbonyl compound and pro-oxidant for preparation of carbonyl compound
JP2017100988A (ja) * 2015-12-01 2017-06-08 アサヒグループホールディングス株式会社 光学活性なヒドロキシ脂肪酸の製造方法

Also Published As

Publication number Publication date
CN101541725B (zh) 2013-08-28
JP2010100635A (ja) 2010-05-06
CN101541725A (zh) 2009-09-23
JPWO2009028676A1 (ja) 2010-12-02
EP2085373B8 (en) 2013-06-26
JP4590514B2 (ja) 2010-12-01
ES2403203T3 (es) 2013-05-16
US20100041917A1 (en) 2010-02-18
JP2010100636A (ja) 2010-05-06
US8394995B2 (en) 2013-03-12
EP2085373A1 (en) 2009-08-05
EP2085373A4 (en) 2010-02-17
EP2085373B1 (en) 2013-01-16

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