WO2009028113A1 - 低温水素製造用触媒及びその製造方法と水素製造方法 - Google Patents
低温水素製造用触媒及びその製造方法と水素製造方法 Download PDFInfo
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- WO2009028113A1 WO2009028113A1 PCT/JP2007/072395 JP2007072395W WO2009028113A1 WO 2009028113 A1 WO2009028113 A1 WO 2009028113A1 JP 2007072395 W JP2007072395 W JP 2007072395W WO 2009028113 A1 WO2009028113 A1 WO 2009028113A1
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- oxide
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- oxygen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/46—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using discontinuously preheated non-moving solid materials, e.g. blast and run
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
外部からのエネルギー供給を必要としない自立型のオンサイト改質型燃料電池システムを実現するためには、常温で炭化水素の直接熱供給型改質反応を駆動することが必要である。本発明は、活性金属と酸化数変化の可能な希土類元素を含有する酸化物としてCeO2又はPr6O11の酸化物又はCeとZrの複合酸化物又はCeとZrとYの複合酸化物とし、これを高温で還元性ガスにより活性化処理して酸素欠陥を導入する。この触媒に低温で炭化水素と酸素を含む反応ガスを流通すると、酸素欠陥が酸素と反応し元の酸化物に戻ろうとする。この反応は発熱反応であるため触媒自体が加熱される。このことが駆動力となり、炭化水素の燃焼反応が進行し、触媒層は一層、加熱される。そのため、改質反応が進行し水素が生成する。以上のようにして低温、特に常温であっても水素製造反応を駆動できる。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07832125.4A EP2184104A4 (en) | 2007-08-29 | 2007-11-19 | Catalyst for the production of hydrogen at low temperature, process for production of the catalyst, and process for production of hydrogen |
US12/675,716 US9073043B2 (en) | 2007-02-21 | 2007-11-19 | Hydrogen production catalyst, production method of the same and hydrogen production method |
PCT/JP2007/072395 WO2009028113A1 (ja) | 2007-08-29 | 2007-11-19 | 低温水素製造用触媒及びその製造方法と水素製造方法 |
CN200780100393A CN101808736A (zh) | 2007-02-21 | 2007-11-19 | 低温氢制造用催化剂及其制造方法与氢制造方法 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007222834A JP5428103B2 (ja) | 2007-02-21 | 2007-08-29 | 低温水素製造用触媒及びその製造方法と水素製造方法 |
JP2007-222834 | 2007-08-29 | ||
PCT/JP2007/072395 WO2009028113A1 (ja) | 2007-08-29 | 2007-11-19 | 低温水素製造用触媒及びその製造方法と水素製造方法 |
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WO2009028113A1 true WO2009028113A1 (ja) | 2009-03-05 |
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PCT/JP2007/072395 WO2009028113A1 (ja) | 2007-02-21 | 2007-11-19 | 低温水素製造用触媒及びその製造方法と水素製造方法 |
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WO (1) | WO2009028113A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011075845A1 (en) * | 2009-12-22 | 2011-06-30 | Airscience Technologies | System and process for the production of hydrogen from raw gas using a nanoparticle ceria based catalyst |
WO2011106876A1 (en) | 2010-03-05 | 2011-09-09 | University Of Regina | Catalysts for feedstock-flexible and process-flexible hydrogen production |
JP2011183284A (ja) * | 2010-03-05 | 2011-09-22 | Dowa Holdings Co Ltd | 水素製造用触媒、水素製造用触媒の製造方法、水素製造方法、水素製造装置及び燃料電池システム |
JP2015054267A (ja) * | 2013-09-10 | 2015-03-23 | Dowaホールディングス株式会社 | 触媒、触媒の製造方法、水素含有ガスの製造方法、水素製造装置および燃料電池システム |
JP2015150486A (ja) * | 2014-02-13 | 2015-08-24 | Jx日鉱日石エネルギー株式会社 | 水素製造用触媒、水素製造用触媒の製造方法及び水素製造方法 |
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JP2002336702A (ja) * | 2001-05-11 | 2002-11-26 | Nippon Oil Corp | オートサーマルリフォーミング触媒および燃料電池用燃料ガスの製造方法 |
JP2005131469A (ja) * | 2003-10-28 | 2005-05-26 | Research Institute Of Innovative Technology For The Earth | エタノール水蒸気改質触媒、その製造方法及び水素の製造方法 |
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EP0582004B1 (en) * | 1992-07-29 | 1997-01-29 | Council of Scientific and Industrial Research | Novel composite catalysts and their use in a process for the oxidative conversion of methane or natural gas to synthesis gas |
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GB0115850D0 (en) * | 2001-06-28 | 2001-08-22 | Isis Innovations Ltd | Catalyst |
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JP2006167501A (ja) * | 2004-12-13 | 2006-06-29 | Matsushita Electric Ind Co Ltd | 改質触媒、水素生成装置および燃料電池システム |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011075845A1 (en) * | 2009-12-22 | 2011-06-30 | Airscience Technologies | System and process for the production of hydrogen from raw gas using a nanoparticle ceria based catalyst |
WO2011106876A1 (en) | 2010-03-05 | 2011-09-09 | University Of Regina | Catalysts for feedstock-flexible and process-flexible hydrogen production |
JP2011183284A (ja) * | 2010-03-05 | 2011-09-22 | Dowa Holdings Co Ltd | 水素製造用触媒、水素製造用触媒の製造方法、水素製造方法、水素製造装置及び燃料電池システム |
JP2015054267A (ja) * | 2013-09-10 | 2015-03-23 | Dowaホールディングス株式会社 | 触媒、触媒の製造方法、水素含有ガスの製造方法、水素製造装置および燃料電池システム |
JP2015150486A (ja) * | 2014-02-13 | 2015-08-24 | Jx日鉱日石エネルギー株式会社 | 水素製造用触媒、水素製造用触媒の製造方法及び水素製造方法 |
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EP2184104A4 (en) | 2017-08-23 |
EP2184104A1 (en) | 2010-05-12 |
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