WO2009004182A1 - Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant - Google Patents

Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant Download PDF

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Publication number
WO2009004182A1
WO2009004182A1 PCT/FR2008/000758 FR2008000758W WO2009004182A1 WO 2009004182 A1 WO2009004182 A1 WO 2009004182A1 FR 2008000758 W FR2008000758 W FR 2008000758W WO 2009004182 A1 WO2009004182 A1 WO 2009004182A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
polyelectrolyte
lithium
association according
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2008/000758
Other languages
English (en)
French (fr)
Inventor
Séverine Jouanneau-Si Larbi
Willy Porcher
Bernard Lestriez
Dominique Guyomard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Centre National de la Recherche Scientifique CNRS
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Commissariat a lEnergie Atomique CEA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to PL08805646T priority Critical patent/PL2176919T3/pl
Priority to CN2008801009947A priority patent/CN101772856B/zh
Priority to ES08805646T priority patent/ES2392777T3/es
Priority to EP08805646A priority patent/EP2176919B1/fr
Priority to US12/602,865 priority patent/US8475962B2/en
Priority to JP2010510842A priority patent/JP5688967B2/ja
Publication of WO2009004182A1 publication Critical patent/WO2009004182A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134Electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49108Electric battery cell making

Definitions

  • Lithium-ion is as follows: firstly an insertion material (for example LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , LiMnO 2 or a mixture of these materials) or agglomerates of the insertion material, of dimension from 1 to 50 ⁇ m are dispersed in an organic solvent. To this dispersion is added electroconductive carbon black and a binder of the polytetrafluoroethylene or polyvinylidene difluoride type. Then the mixture is applied and squeezed onto an aluminum sheet which serves as a current collector.
  • an insertion material for example LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , LiMnO 2 or a mixture of these materials
  • electroconductive carbon black and a binder of the polytetrafluoroethylene or polyvinylidene difluoride type To this dispersion is added electroconductive carbon black and a binder of the polytetrafluoroethylene or polyvinylidene difluoride
  • polyelectrolyte is understood to mean any water-soluble polymer which, in solution, carries numerous ionizable groups (at least 20% of the monomers), which induce electrostatic charges.
  • electrostatic charges along the molecular chain induces medium and short-range interactions, which gives the polyelectrolytes remarkable physicochemical properties.
  • Polyelectrolytes have many fields of application: medicine, paper, paint, food industry, cosmetics, pharmacy, water treatment ... Polyelectrolytes are used for their rheological and adsorption properties at interfaces, generally irreversible .
  • the polyelectrolyte must respond to the various constraints related to the introduction of a polymer into a Li-ion accumulator electrode, that is to say, sufficient elasticity to undergo the expansions during insertion and de-insertion cycles, stability chemical and especially electrochemical. Its potential stability window must indeed be compatible with that of the electrode considered in the battery, which depends on materials and operating potentials.
  • Amino-functional cationic polyelectrolytes are infinitely derivable.
  • synthetic polyelectrolytes are selected.
  • composition A a method of preparation may be provided in at least two steps: - dissolving the amino-functional cationic polyelectrolyte (iii) in water, and then
  • a filtration step of the composition B may be provided.
  • composition is deposited on an aluminum current collector (20 microns thick).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
PCT/FR2008/000758 2007-06-04 2008-06-04 Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant Ceased WO2009004182A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
PL08805646T PL2176919T3 (pl) 2007-06-04 2008-06-04 Nowa kompozycja do wytwarzania elektrod, powstałe z niej elektrody i baterie
CN2008801009947A CN101772856B (zh) 2007-06-04 2008-06-04 用于制造电极的新的组合物以及包含该组合物的电极和电池
ES08805646T ES2392777T3 (es) 2007-06-04 2008-06-04 Nueva composición para la fabricación de electrodos, electrodos y baterías resultantes de la misma
EP08805646A EP2176919B1 (fr) 2007-06-04 2008-06-04 Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant
US12/602,865 US8475962B2 (en) 2007-06-04 2008-06-04 Composition for manufacture of electrodes and electrodes and batteries resulting therefrom
JP2010510842A JP5688967B2 (ja) 2007-06-04 2008-06-04 電極の作製のための新しい組成物、ならびにその組成物から得られる電極および電池

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0703940A FR2916905B1 (fr) 2007-06-04 2007-06-04 Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant.
FR0703940 2007-06-04

Publications (1)

Publication Number Publication Date
WO2009004182A1 true WO2009004182A1 (fr) 2009-01-08

Family

ID=38715203

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2008/000758 Ceased WO2009004182A1 (fr) 2007-06-04 2008-06-04 Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant

Country Status (8)

Country Link
US (1) US8475962B2 (enExample)
EP (1) EP2176919B1 (enExample)
JP (1) JP5688967B2 (enExample)
CN (1) CN101772856B (enExample)
ES (1) ES2392777T3 (enExample)
FR (1) FR2916905B1 (enExample)
PL (1) PL2176919T3 (enExample)
WO (1) WO2009004182A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2941875A1 (fr) * 2009-02-11 2010-08-13 Commissariat Energie Atomique Procede de preparation d'un melange d'une poudre d'un compose actif d'electrode et d'une poudre d'un compose conducteur electronique, melange ainsi obtenu, electrode, cellule et accumulateur
WO2011068243A1 (ja) * 2009-12-02 2011-06-09 住友化学株式会社 非水電解液二次電池電極用組成物、電極および電池

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Publication number Priority date Publication date Assignee Title
EP2535976B1 (en) * 2010-02-12 2015-09-02 Mitsubishi Chemical Corporation Non-aqueous electrolyte solution, and secondary battery comprising the same
US20120171576A1 (en) * 2010-12-29 2012-07-05 Industrial Technology Research Institute Non-aqueous electrolyte and lithium secondary battery including the same
US9136559B2 (en) 2010-12-29 2015-09-15 Industrial Technology Research Institute Non-aqueous electrolyte and lithium secondary battery including the same
JP6396799B2 (ja) 2011-07-25 2018-09-26 エイ123・システムズ・リミテッド・ライアビリティ・カンパニーA123 Systems, Llc 混合カソード材料
JP5985184B2 (ja) * 2011-12-20 2016-09-06 三星電子株式会社Samsung Electronics Co.,Ltd. 正極及びこれを用いた電気化学デバイス
US20150004486A1 (en) * 2012-02-02 2015-01-01 Toyo Ink Sc Holdings Co., Ltd. Composition for forming secondary cell electrode, secondary cell electrode, and secondary cell
US9997777B2 (en) 2013-06-20 2018-06-12 The Regents Of The University Of Michigan Electrochemical device electrode including cobalt oxyhydroxide
EP3355384A1 (en) * 2017-01-31 2018-08-01 Universite De Liege Flexible thin-films for battery electrodes
US20180349720A1 (en) * 2017-05-31 2018-12-06 Dawn Mitchell Sound and image identifier software system and method
KR102264703B1 (ko) 2018-06-07 2021-06-11 삼성에스디아이 주식회사 양극 활물질, 양극 활물질의 제조 방법, 및 이를 포함하는 리튬 이차 전지
WO2020241838A1 (ja) 2019-05-31 2020-12-03 株式会社村田製作所 電解液および二次電池
CN111106386A (zh) * 2019-12-27 2020-05-05 惠州市豪鹏科技有限公司 一种电解液和锂离子电池
JP7698471B2 (ja) 2021-05-26 2025-06-25 Tdk株式会社 リチウムイオン二次電池

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WO1995024741A1 (en) * 1994-03-08 1995-09-14 Valence Technology, Inc. Conductive-polymer-coated electrode particles
EP0905804A2 (en) * 1997-08-08 1999-03-31 Japan Storage Battery Company Limited Process for producing electrode of nonaqueous electrolyte battery
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DE10118639A1 (de) * 2001-04-12 2002-10-24 Dilo Trading Ag Zug Kontinuierliche Herstellung von Trilaminaten für Polymer-Lithium-Batterien durch Co-Extrusion
US20030134196A1 (en) * 2001-10-05 2003-07-17 Show-An Chen Non-aqueous organic secondary battery
US20040048154A1 (en) * 2002-09-11 2004-03-11 Samsung Sdi Co., Ltd. Positive electrode for lithium-sulfur battery and lithium-sulfur battery and article of manufacture including same
DE10250747A1 (de) * 2002-10-31 2004-05-19 Gaia Akkumulatorenwerke Gmbh Verfahren zur Herstellung einer Lithium-Sekundär-Batterie mit einer Kathodenmasse, die ein Li-Cobaltoxid als Li-interkalierbares Schwermetalloxid enthält
WO2006052313A1 (en) * 2004-11-08 2006-05-18 3M Innovative Properties Company Polyimide electrode binders
EP1722439A1 (en) * 2005-05-13 2006-11-15 Kabushiki Kaisha Toshiba Nonaqueous electrolyte battery, lithium-titanium composite oxide, battery pack and vehicle

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US20040048154A1 (en) * 2002-09-11 2004-03-11 Samsung Sdi Co., Ltd. Positive electrode for lithium-sulfur battery and lithium-sulfur battery and article of manufacture including same
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WO2006052313A1 (en) * 2004-11-08 2006-05-18 3M Innovative Properties Company Polyimide electrode binders
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2941875A1 (fr) * 2009-02-11 2010-08-13 Commissariat Energie Atomique Procede de preparation d'un melange d'une poudre d'un compose actif d'electrode et d'une poudre d'un compose conducteur electronique, melange ainsi obtenu, electrode, cellule et accumulateur
WO2010092044A1 (fr) * 2009-02-11 2010-08-19 Commissariat A L'energie Atomique Et Aux Energies Alternativesmique Procédé de préparation d'un mélange d'une poudre d'un composé actif d'électrode et d'une poudre d'un composé conducteur électronique, mélange ainsi obtenu, électrode, cellule et accumulateur
US9537138B2 (en) 2009-02-11 2017-01-03 Commissariat à l'énergie atomique et aux energies alternatives Method for preparing a mixture of an electrode active compound powder and an electronic conductor compound powder, resulting mixture, electrode, cell and battery
WO2011068243A1 (ja) * 2009-12-02 2011-06-09 住友化学株式会社 非水電解液二次電池電極用組成物、電極および電池

Also Published As

Publication number Publication date
EP2176919B1 (fr) 2012-07-04
EP2176919A1 (fr) 2010-04-21
CN101772856A (zh) 2010-07-07
US20100209778A1 (en) 2010-08-19
PL2176919T3 (pl) 2013-01-31
FR2916905A1 (fr) 2008-12-05
ES2392777T3 (es) 2012-12-13
CN101772856B (zh) 2013-12-25
JP5688967B2 (ja) 2015-03-25
US8475962B2 (en) 2013-07-02
JP2010529608A (ja) 2010-08-26
FR2916905B1 (fr) 2010-09-10

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