WO2009004182A1 - Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant - Google Patents
Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant Download PDFInfo
- Publication number
- WO2009004182A1 WO2009004182A1 PCT/FR2008/000758 FR2008000758W WO2009004182A1 WO 2009004182 A1 WO2009004182 A1 WO 2009004182A1 FR 2008000758 W FR2008000758 W FR 2008000758W WO 2009004182 A1 WO2009004182 A1 WO 2009004182A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- polyelectrolyte
- lithium
- association according
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Definitions
- Lithium-ion is as follows: firstly an insertion material (for example LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , LiMnO 2 or a mixture of these materials) or agglomerates of the insertion material, of dimension from 1 to 50 ⁇ m are dispersed in an organic solvent. To this dispersion is added electroconductive carbon black and a binder of the polytetrafluoroethylene or polyvinylidene difluoride type. Then the mixture is applied and squeezed onto an aluminum sheet which serves as a current collector.
- an insertion material for example LiCoO 2 , LiNiO 2 , LiMn 2 O 4 , LiMnO 2 or a mixture of these materials
- electroconductive carbon black and a binder of the polytetrafluoroethylene or polyvinylidene difluoride type To this dispersion is added electroconductive carbon black and a binder of the polytetrafluoroethylene or polyvinylidene difluoride
- polyelectrolyte is understood to mean any water-soluble polymer which, in solution, carries numerous ionizable groups (at least 20% of the monomers), which induce electrostatic charges.
- electrostatic charges along the molecular chain induces medium and short-range interactions, which gives the polyelectrolytes remarkable physicochemical properties.
- Polyelectrolytes have many fields of application: medicine, paper, paint, food industry, cosmetics, pharmacy, water treatment ... Polyelectrolytes are used for their rheological and adsorption properties at interfaces, generally irreversible .
- the polyelectrolyte must respond to the various constraints related to the introduction of a polymer into a Li-ion accumulator electrode, that is to say, sufficient elasticity to undergo the expansions during insertion and de-insertion cycles, stability chemical and especially electrochemical. Its potential stability window must indeed be compatible with that of the electrode considered in the battery, which depends on materials and operating potentials.
- Amino-functional cationic polyelectrolytes are infinitely derivable.
- synthetic polyelectrolytes are selected.
- composition A a method of preparation may be provided in at least two steps: - dissolving the amino-functional cationic polyelectrolyte (iii) in water, and then
- a filtration step of the composition B may be provided.
- composition is deposited on an aluminum current collector (20 microns thick).
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL08805646T PL2176919T3 (pl) | 2007-06-04 | 2008-06-04 | Nowa kompozycja do wytwarzania elektrod, powstałe z niej elektrody i baterie |
| CN2008801009947A CN101772856B (zh) | 2007-06-04 | 2008-06-04 | 用于制造电极的新的组合物以及包含该组合物的电极和电池 |
| ES08805646T ES2392777T3 (es) | 2007-06-04 | 2008-06-04 | Nueva composición para la fabricación de electrodos, electrodos y baterías resultantes de la misma |
| EP08805646A EP2176919B1 (fr) | 2007-06-04 | 2008-06-04 | Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant |
| US12/602,865 US8475962B2 (en) | 2007-06-04 | 2008-06-04 | Composition for manufacture of electrodes and electrodes and batteries resulting therefrom |
| JP2010510842A JP5688967B2 (ja) | 2007-06-04 | 2008-06-04 | 電極の作製のための新しい組成物、ならびにその組成物から得られる電極および電池 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0703940A FR2916905B1 (fr) | 2007-06-04 | 2007-06-04 | Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant. |
| FR0703940 | 2007-06-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2009004182A1 true WO2009004182A1 (fr) | 2009-01-08 |
Family
ID=38715203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/FR2008/000758 Ceased WO2009004182A1 (fr) | 2007-06-04 | 2008-06-04 | Nouvelle composition pour la fabrication d'electrodes, electrodes et batteries en resultant |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8475962B2 (enExample) |
| EP (1) | EP2176919B1 (enExample) |
| JP (1) | JP5688967B2 (enExample) |
| CN (1) | CN101772856B (enExample) |
| ES (1) | ES2392777T3 (enExample) |
| FR (1) | FR2916905B1 (enExample) |
| PL (1) | PL2176919T3 (enExample) |
| WO (1) | WO2009004182A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2941875A1 (fr) * | 2009-02-11 | 2010-08-13 | Commissariat Energie Atomique | Procede de preparation d'un melange d'une poudre d'un compose actif d'electrode et d'une poudre d'un compose conducteur electronique, melange ainsi obtenu, electrode, cellule et accumulateur |
| WO2011068243A1 (ja) * | 2009-12-02 | 2011-06-09 | 住友化学株式会社 | 非水電解液二次電池電極用組成物、電極および電池 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2535976B1 (en) * | 2010-02-12 | 2015-09-02 | Mitsubishi Chemical Corporation | Non-aqueous electrolyte solution, and secondary battery comprising the same |
| US20120171576A1 (en) * | 2010-12-29 | 2012-07-05 | Industrial Technology Research Institute | Non-aqueous electrolyte and lithium secondary battery including the same |
| US9136559B2 (en) | 2010-12-29 | 2015-09-15 | Industrial Technology Research Institute | Non-aqueous electrolyte and lithium secondary battery including the same |
| JP6396799B2 (ja) | 2011-07-25 | 2018-09-26 | エイ123・システムズ・リミテッド・ライアビリティ・カンパニーA123 Systems, Llc | 混合カソード材料 |
| JP5985184B2 (ja) * | 2011-12-20 | 2016-09-06 | 三星電子株式会社Samsung Electronics Co.,Ltd. | 正極及びこれを用いた電気化学デバイス |
| US20150004486A1 (en) * | 2012-02-02 | 2015-01-01 | Toyo Ink Sc Holdings Co., Ltd. | Composition for forming secondary cell electrode, secondary cell electrode, and secondary cell |
| US9997777B2 (en) | 2013-06-20 | 2018-06-12 | The Regents Of The University Of Michigan | Electrochemical device electrode including cobalt oxyhydroxide |
| EP3355384A1 (en) * | 2017-01-31 | 2018-08-01 | Universite De Liege | Flexible thin-films for battery electrodes |
| US20180349720A1 (en) * | 2017-05-31 | 2018-12-06 | Dawn Mitchell | Sound and image identifier software system and method |
| KR102264703B1 (ko) | 2018-06-07 | 2021-06-11 | 삼성에스디아이 주식회사 | 양극 활물질, 양극 활물질의 제조 방법, 및 이를 포함하는 리튬 이차 전지 |
| WO2020241838A1 (ja) | 2019-05-31 | 2020-12-03 | 株式会社村田製作所 | 電解液および二次電池 |
| CN111106386A (zh) * | 2019-12-27 | 2020-05-05 | 惠州市豪鹏科技有限公司 | 一种电解液和锂离子电池 |
| JP7698471B2 (ja) | 2021-05-26 | 2025-06-25 | Tdk株式会社 | リチウムイオン二次電池 |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995024741A1 (en) * | 1994-03-08 | 1995-09-14 | Valence Technology, Inc. | Conductive-polymer-coated electrode particles |
| EP0905804A2 (en) * | 1997-08-08 | 1999-03-31 | Japan Storage Battery Company Limited | Process for producing electrode of nonaqueous electrolyte battery |
| US20020048706A1 (en) * | 1996-10-11 | 2002-04-25 | Mayes Anne M. | Polymer electrolyte, intercalation compounds and electrodes for batteries |
| WO2002047188A1 (en) * | 2000-11-28 | 2002-06-13 | Kemijski, Institut | Method for the preparation of a cathode for lithium ion batteries |
| DE10118639A1 (de) * | 2001-04-12 | 2002-10-24 | Dilo Trading Ag Zug | Kontinuierliche Herstellung von Trilaminaten für Polymer-Lithium-Batterien durch Co-Extrusion |
| US20030134196A1 (en) * | 2001-10-05 | 2003-07-17 | Show-An Chen | Non-aqueous organic secondary battery |
| US20040048154A1 (en) * | 2002-09-11 | 2004-03-11 | Samsung Sdi Co., Ltd. | Positive electrode for lithium-sulfur battery and lithium-sulfur battery and article of manufacture including same |
| DE10250747A1 (de) * | 2002-10-31 | 2004-05-19 | Gaia Akkumulatorenwerke Gmbh | Verfahren zur Herstellung einer Lithium-Sekundär-Batterie mit einer Kathodenmasse, die ein Li-Cobaltoxid als Li-interkalierbares Schwermetalloxid enthält |
| WO2006052313A1 (en) * | 2004-11-08 | 2006-05-18 | 3M Innovative Properties Company | Polyimide electrode binders |
| EP1722439A1 (en) * | 2005-05-13 | 2006-11-15 | Kabushiki Kaisha Toshiba | Nonaqueous electrolyte battery, lithium-titanium composite oxide, battery pack and vehicle |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11283630A (ja) * | 1998-03-30 | 1999-10-15 | Nippon Zeon Co Ltd | リチウムイオン二次電池の電極用スラリー、バインダー組成物、電極、及び電池 |
| JP2003036884A (ja) * | 2001-07-19 | 2003-02-07 | Sony Corp | 非水電解質及び非水電解質電池 |
| JP4050024B2 (ja) * | 2001-09-26 | 2008-02-20 | 三星エスディアイ株式会社 | 電極材料及びその製造方法、電極並びに電池 |
| JP2003217568A (ja) * | 2002-01-17 | 2003-07-31 | Mitsubishi Heavy Ind Ltd | 非水電解質2次電池用正極及び非水電解質2次電池 |
| KR100560539B1 (ko) * | 2003-11-17 | 2006-03-15 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 및 이를 포함하는 리튬 이차 전지 |
| JP4819342B2 (ja) * | 2004-11-08 | 2011-11-24 | エレクセル株式会社 | リチウム電池用正極及びこれを用いたリチウム電池 |
| JP2007052940A (ja) * | 2005-08-16 | 2007-03-01 | Ngk Insulators Ltd | リチウム二次電池及びそれに用いる電極材料の製造方法 |
| JP4696954B2 (ja) * | 2006-02-21 | 2011-06-08 | 株式会社デンソー | 攪拌機、その攪拌機を用いたスラリー製造装置およびそのスラリー製造装置を用いたスラリーの製造方法。 |
-
2007
- 2007-06-04 FR FR0703940A patent/FR2916905B1/fr active Active
-
2008
- 2008-06-04 ES ES08805646T patent/ES2392777T3/es active Active
- 2008-06-04 PL PL08805646T patent/PL2176919T3/pl unknown
- 2008-06-04 EP EP08805646A patent/EP2176919B1/fr not_active Not-in-force
- 2008-06-04 WO PCT/FR2008/000758 patent/WO2009004182A1/fr not_active Ceased
- 2008-06-04 JP JP2010510842A patent/JP5688967B2/ja not_active Expired - Fee Related
- 2008-06-04 CN CN2008801009947A patent/CN101772856B/zh not_active Expired - Fee Related
- 2008-06-04 US US12/602,865 patent/US8475962B2/en not_active Expired - Fee Related
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995024741A1 (en) * | 1994-03-08 | 1995-09-14 | Valence Technology, Inc. | Conductive-polymer-coated electrode particles |
| US20020048706A1 (en) * | 1996-10-11 | 2002-04-25 | Mayes Anne M. | Polymer electrolyte, intercalation compounds and electrodes for batteries |
| EP0905804A2 (en) * | 1997-08-08 | 1999-03-31 | Japan Storage Battery Company Limited | Process for producing electrode of nonaqueous electrolyte battery |
| WO2002047188A1 (en) * | 2000-11-28 | 2002-06-13 | Kemijski, Institut | Method for the preparation of a cathode for lithium ion batteries |
| DE10118639A1 (de) * | 2001-04-12 | 2002-10-24 | Dilo Trading Ag Zug | Kontinuierliche Herstellung von Trilaminaten für Polymer-Lithium-Batterien durch Co-Extrusion |
| US20030134196A1 (en) * | 2001-10-05 | 2003-07-17 | Show-An Chen | Non-aqueous organic secondary battery |
| US20040048154A1 (en) * | 2002-09-11 | 2004-03-11 | Samsung Sdi Co., Ltd. | Positive electrode for lithium-sulfur battery and lithium-sulfur battery and article of manufacture including same |
| DE10250747A1 (de) * | 2002-10-31 | 2004-05-19 | Gaia Akkumulatorenwerke Gmbh | Verfahren zur Herstellung einer Lithium-Sekundär-Batterie mit einer Kathodenmasse, die ein Li-Cobaltoxid als Li-interkalierbares Schwermetalloxid enthält |
| WO2006052313A1 (en) * | 2004-11-08 | 2006-05-18 | 3M Innovative Properties Company | Polyimide electrode binders |
| EP1722439A1 (en) * | 2005-05-13 | 2006-11-15 | Kabushiki Kaisha Toshiba | Nonaqueous electrolyte battery, lithium-titanium composite oxide, battery pack and vehicle |
Non-Patent Citations (1)
| Title |
|---|
| T. CASSAGNEAU ET AL.: "High Density Rechargeable Lithium-Ion Batteries Self-Assembled From Graphite Oxide Nanoplatelets and Polyelectrolytes", ADVANCED MATERIALS, vol. 10, no. 11, 3 August 1998 (1998-08-03), pages 877 - 881, XP000777031, ISSN: 0935-9648 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2941875A1 (fr) * | 2009-02-11 | 2010-08-13 | Commissariat Energie Atomique | Procede de preparation d'un melange d'une poudre d'un compose actif d'electrode et d'une poudre d'un compose conducteur electronique, melange ainsi obtenu, electrode, cellule et accumulateur |
| WO2010092044A1 (fr) * | 2009-02-11 | 2010-08-19 | Commissariat A L'energie Atomique Et Aux Energies Alternativesmique | Procédé de préparation d'un mélange d'une poudre d'un composé actif d'électrode et d'une poudre d'un composé conducteur électronique, mélange ainsi obtenu, électrode, cellule et accumulateur |
| US9537138B2 (en) | 2009-02-11 | 2017-01-03 | Commissariat à l'énergie atomique et aux energies alternatives | Method for preparing a mixture of an electrode active compound powder and an electronic conductor compound powder, resulting mixture, electrode, cell and battery |
| WO2011068243A1 (ja) * | 2009-12-02 | 2011-06-09 | 住友化学株式会社 | 非水電解液二次電池電極用組成物、電極および電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2176919B1 (fr) | 2012-07-04 |
| EP2176919A1 (fr) | 2010-04-21 |
| CN101772856A (zh) | 2010-07-07 |
| US20100209778A1 (en) | 2010-08-19 |
| PL2176919T3 (pl) | 2013-01-31 |
| FR2916905A1 (fr) | 2008-12-05 |
| ES2392777T3 (es) | 2012-12-13 |
| CN101772856B (zh) | 2013-12-25 |
| JP5688967B2 (ja) | 2015-03-25 |
| US8475962B2 (en) | 2013-07-02 |
| JP2010529608A (ja) | 2010-08-26 |
| FR2916905B1 (fr) | 2010-09-10 |
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