WO2008148363A2 - An agent for surface finishing of objects and strustures by a coating layer with a photocatalytic and self-cleaning effect and respective manufacturing process - Google Patents
An agent for surface finishing of objects and strustures by a coating layer with a photocatalytic and self-cleaning effect and respective manufacturing process Download PDFInfo
- Publication number
- WO2008148363A2 WO2008148363A2 PCT/CZ2008/000062 CZ2008000062W WO2008148363A2 WO 2008148363 A2 WO2008148363 A2 WO 2008148363A2 CZ 2008000062 W CZ2008000062 W CZ 2008000062W WO 2008148363 A2 WO2008148363 A2 WO 2008148363A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- agent
- precursor
- per
- objects
- surface finishing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0219—Coating the coating containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Definitions
- This invention regards an agent for surface finishing of objects and structures by a coating layer with a photocatalytic and self-cleaning effect, above all with the catalytic effects of air pollutants' photodegradation as well as the process of this agent's manufacturing.
- bulding materials there are known eg concrete mixtures containing (as an additive) the photocatalytic active titanium dioxide.
- organo-metallic precursors containing particles of photocatalytic active compounds above all of the titanium dioxide; regarding this, there is known usage of precursors which originated by homogenous hydrolysis of the soluble salts (chlorides) of titanium by urea or thioacetamide in aqueous medium.
- the precursors gained can only be used as the active component of respective paint, not as a paint itself.
- This agent for surface finishing of objects and structures by a coating layer with a photocatalytic and self-cleaning effect as per invention is to a large extent instrumental in removing the aforementioned deficiencies of the status quo in this field.
- This invention stipulates in the fact that it consists of a precursor which iis based on a dispersion of at least one compound from the group of metals' oxids and salts in nanocristalline form, being visible even in the visible band of the solar radiation spectrum; the precursor said is a hydrolysis product of respective metal's soluble salt in the medium of silicates, silicic esters, siloxanes or silicon alcoxides.
- this can be above all the titanium oxide, ferric oxide or zirconium dioxide.
- This metal oxide can be further supported by transient metals Oxides, particularly of Fe, Co, Ni, Mn, Cr, V, Ta, Nb and W, and/or lanthanoide oxides, particularly of La, Ce, Nd, Y, Sm, Eu and Dy.
- transient metals Oxides particularly of Fe, Co, Ni, Mn, Cr, V, Ta, Nb and W
- lanthanoide oxides particularly of La, Ce, Nd, Y, Sm, Eu and Dy.
- the agent for surface finishing of objects and structures as per invention is at the same time a precursor and a paint with final qualities gained after spontaneous curing.
- this can be advantageously the titanium(III) chloride, titanium dichloride or titanium oxide chloride.
- a new composite material can be created which is applicable onto any surface type, with final qualities after spontaneous curing. It is strong, perfectly washable, with a self-cleaning or photocatalytic effect due to presence of metal ocide nanoparticles (above all the titanium oxide ones), and-due to chosen combination of various anorganic polymeres-is also suitable for anti-graffiti systems, being also usable as a precursor in the production of more sofisticated paints with other binding systems.
- This agent can be applicated by brushing, spraying or rolling when (after a sufficient dilution) also thin transparent layers can be obtained.
- the surfaces coated in this way have the advantage thet they gain (as against existing transparent paint films), after being illuminated, a highly wettable surface, and due to the photocatalytic effect the organic inpurities or air pollutants adhering to this surface shall be decomposed.
- TMOS tetramethoxisilane
- MTEOS methyltriethoxisilane
- VTEOS vinyltriethoxisilane
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CZ20070395A CZ301227B6 (cs) | 2007-06-07 | 2007-06-07 | Prostredek pro povrchovou úpravu predmetu a stavebních prvku nánosem ochranné vrstvy s fotakatalytickým a samocisticím úcinkem a zpusob jeho výroby a aplikace |
CZPV2007-395 | 2007-06-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008148363A2 true WO2008148363A2 (en) | 2008-12-11 |
WO2008148363A3 WO2008148363A3 (en) | 2009-04-16 |
Family
ID=40094220
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CZ2008/000062 WO2008148363A2 (en) | 2007-06-07 | 2008-06-06 | An agent for surface finishing of objects and strustures by a coating layer with a photocatalytic and self-cleaning effect and respective manufacturing process |
Country Status (2)
Country | Link |
---|---|
CZ (1) | CZ301227B6 (cs) |
WO (1) | WO2008148363A2 (cs) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009121312A1 (en) * | 2008-04-03 | 2009-10-08 | Rokospol A.S. | Coating and/ or building material intended for object and building treatment with photo-catalytic and self-cleaning effect |
CN102807263A (zh) * | 2011-11-08 | 2012-12-05 | 北京联合大学生物化学工程学院 | 光催化降解水中双对氯苯基三氯乙烷农药的方法 |
US20200181911A1 (en) * | 2016-07-15 | 2020-06-11 | Firestone Building Products Company, Llc | Silicone membranes |
EP3851498A4 (en) * | 2018-09-13 | 2022-06-15 | Sumitomo Osaka Cement Co., Ltd. | AGRICULTURAL COATING COMPOSITION, GLASS-CERAMIC PRODUCT, COATING MATERIAL FOR MAKING AN AGRICULTURAL COATING AND METHOD OF MAKING A GLASS-CERAMIC PRODUCT |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109423886B (zh) * | 2017-08-23 | 2022-01-04 | 上海汽车集团股份有限公司 | 一种车用Alcantara面料及其制备方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3998786B2 (ja) * | 1997-12-16 | 2007-10-31 | 触媒化成工業株式会社 | ハードコート膜形成用塗布液およびハードコート膜付基材 |
TWI276604B (en) * | 2001-12-27 | 2007-03-21 | Tokuyama Corp | Silica composite oxide particles and method of producing the same |
JP4199490B2 (ja) * | 2002-07-26 | 2008-12-17 | パナソニック電工株式会社 | コーティング材組成物 |
CN1478826A (zh) * | 2002-08-27 | 2004-03-03 | �Ϻ��뿵�Ƽ���չ����˾ | 一种可见光光催化的光触媒颜料及其制造方法 |
DE10245729A1 (de) * | 2002-10-01 | 2004-04-15 | Bayer Ag | Beschichtungszusammensetzung und Verfahren zu deren Herstellung |
US20040258581A1 (en) * | 2003-06-19 | 2004-12-23 | Di Wei | Bifunctional manganese oxide/titanium dioxide photocatalyst/thermocatalyst for improving indoor air quality |
US20050147776A1 (en) * | 2004-01-02 | 2005-07-07 | Meng-Song Cheng | Bottle container with protective membrane |
FI116297B (fi) * | 2004-01-07 | 2005-10-31 | Kemira Pigments Oy | Menetelmä pintojen käsittelemiseksi |
DE102004029303B4 (de) * | 2004-06-17 | 2010-05-12 | Ems-Chemie Ag | Nanoskalige Titandioxid-Sole, Verfahren zu dessen Herstellung und seine Verwendung |
CZ17545U1 (cs) * | 2007-04-12 | 2007-05-28 | Card Line S.R.O. | Elektronický informační systém |
-
2007
- 2007-06-07 CZ CZ20070395A patent/CZ301227B6/cs not_active IP Right Cessation
-
2008
- 2008-06-06 WO PCT/CZ2008/000062 patent/WO2008148363A2/en active Application Filing
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009121312A1 (en) * | 2008-04-03 | 2009-10-08 | Rokospol A.S. | Coating and/ or building material intended for object and building treatment with photo-catalytic and self-cleaning effect |
CN102807263A (zh) * | 2011-11-08 | 2012-12-05 | 北京联合大学生物化学工程学院 | 光催化降解水中双对氯苯基三氯乙烷农药的方法 |
CN102807263B (zh) * | 2011-11-08 | 2013-12-11 | 北京联合大学生物化学工程学院 | 光催化降解水中双对氯苯基三氯乙烷农药的方法 |
US20200181911A1 (en) * | 2016-07-15 | 2020-06-11 | Firestone Building Products Company, Llc | Silicone membranes |
EP3851498A4 (en) * | 2018-09-13 | 2022-06-15 | Sumitomo Osaka Cement Co., Ltd. | AGRICULTURAL COATING COMPOSITION, GLASS-CERAMIC PRODUCT, COATING MATERIAL FOR MAKING AN AGRICULTURAL COATING AND METHOD OF MAKING A GLASS-CERAMIC PRODUCT |
Also Published As
Publication number | Publication date |
---|---|
WO2008148363A3 (en) | 2009-04-16 |
CZ2007395A3 (cs) | 2008-12-17 |
CZ301227B6 (cs) | 2009-12-16 |
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