WO2008143036A1 - アリル化合物の異性化方法 - Google Patents

アリル化合物の異性化方法 Download PDF

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Publication number
WO2008143036A1
WO2008143036A1 PCT/JP2008/058675 JP2008058675W WO2008143036A1 WO 2008143036 A1 WO2008143036 A1 WO 2008143036A1 JP 2008058675 W JP2008058675 W JP 2008058675W WO 2008143036 A1 WO2008143036 A1 WO 2008143036A1
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
allyl compound
isomerizing
compound
raw material
Prior art date
Application number
PCT/JP2008/058675
Other languages
English (en)
French (fr)
Inventor
Masaru Utsunomiya
Yusuke Izawa
Yasuhiko Mitsuba
Masakatsu Mizoguchi
Yoshiyuki Tanaka
Original Assignee
Mitsubishi Chemical Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corporation filed Critical Mitsubishi Chemical Corporation
Priority to CN200880016305.4A priority Critical patent/CN101679198B/zh
Publication of WO2008143036A1 publication Critical patent/WO2008143036A1/ja

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/186—Mono- or diamide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

　触媒を用いるアリル化合物の異性化方法において、触媒劣化を抑え、少量の触媒使用量で高い収率で異性体を得ることを可能とする工業的に有利なアリル化合物の異性化方法を提供する。 　触媒の存在下、原料アリル化合物を対応するアリル化合物に異性化する方法であって、触媒による異性化の前に原料アリル化合物の含有液を有機リン化合物と接触させることを特徴とする異性化方法。
PCT/JP2008/058675 2007-05-17 2008-05-09 アリル化合物の異性化方法 WO2008143036A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200880016305.4A CN101679198B (zh) 2007-05-17 2008-05-09 烯丙基化合物的异构化方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007132184 2007-05-17
JP2007-132184 2007-05-17

Publications (1)

Publication Number Publication Date
WO2008143036A1 true WO2008143036A1 (ja) 2008-11-27

Family

ID=40031746

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/058675 WO2008143036A1 (ja) 2007-05-17 2008-05-09 アリル化合物の異性化方法

Country Status (5)

Country Link
JP (1) JP5374922B2 (ja)
KR (1) KR101540487B1 (ja)
CN (1) CN101679198B (ja)
TW (1) TWI423956B (ja)
WO (1) WO2008143036A1 (ja)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5402286B2 (ja) * 2008-06-20 2014-01-29 三菱化学株式会社 リン化合物の製造方法及びアリル化合物誘導体の製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002105025A (ja) * 2000-09-29 2002-04-10 Mitsubishi Chemicals Corp アリル化合物の製造方法
JP2004115506A (ja) * 2002-09-05 2004-04-15 Mitsubishi Chemicals Corp アリル化合物の製造方法
JP2006282564A (ja) * 2005-03-31 2006-10-19 Mitsubishi Chemicals Corp ジアセトキシアリル化合物の異性化方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002105025A (ja) * 2000-09-29 2002-04-10 Mitsubishi Chemicals Corp アリル化合物の製造方法
JP2004115506A (ja) * 2002-09-05 2004-04-15 Mitsubishi Chemicals Corp アリル化合物の製造方法
JP2006282564A (ja) * 2005-03-31 2006-10-19 Mitsubishi Chemicals Corp ジアセトキシアリル化合物の異性化方法

Also Published As

Publication number Publication date
KR101540487B1 (ko) 2015-07-29
TW200909411A (en) 2009-03-01
TWI423956B (zh) 2014-01-21
JP2008308497A (ja) 2008-12-25
JP5374922B2 (ja) 2013-12-25
KR20100019430A (ko) 2010-02-18
CN101679198B (zh) 2014-07-09
CN101679198A (zh) 2010-03-24

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