WO2007137856A3 - Mit metallsalzen dotierte katalytisch aktive formaktivkohlen und deren verwendung - Google Patents

Mit metallsalzen dotierte katalytisch aktive formaktivkohlen und deren verwendung Download PDF

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Publication number
WO2007137856A3
WO2007137856A3 PCT/EP2007/004842 EP2007004842W WO2007137856A3 WO 2007137856 A3 WO2007137856 A3 WO 2007137856A3 EP 2007004842 W EP2007004842 W EP 2007004842W WO 2007137856 A3 WO2007137856 A3 WO 2007137856A3
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WO
WIPO (PCT)
Prior art keywords
metals
activated carbons
alkaline
catalytically
metal salts
Prior art date
Application number
PCT/EP2007/004842
Other languages
English (en)
French (fr)
Other versions
WO2007137856A2 (de
Inventor
Toralf Goetze
Silvana Polzin
Bernd R Mueller
Original Assignee
Fraunhofer Ges Forschung
Toralf Goetze
Silvana Polzin
Bernd R Mueller
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fraunhofer Ges Forschung, Toralf Goetze, Silvana Polzin, Bernd R Mueller filed Critical Fraunhofer Ges Forschung
Publication of WO2007137856A2 publication Critical patent/WO2007137856A2/de
Publication of WO2007137856A3 publication Critical patent/WO2007137856A3/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/30—Active carbon
    • C01B32/354—After-treatment
    • C01B32/382—Making shaped products, e.g. fibres, spheres, membranes or foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)

Abstract

Die Erfindung betrifft katalytisch aktive Formaktivkohle und ein Verfahren zu deren Herstellung. Die Formaktivkohle wird erhalten, indem aus vermahlenem kohlenstoffhaltigen Material, einem Bindemittel und mindestens einem metallhaltigen Dotierungsreagenz eine pressfähige Masse hergestellt wird, die verpresst, getrocknet, karbonisiert und anschließend mittels eines Aktivierungsgases aktiviert wird, Als Dotierungsreagenz wird hierbei ein Metallsalz, dessen Metall ausgewählt ist aus den Metallen der 3. bis 6. Hauptgruppe, den Übergangsmetallen, den Seltenerdmetallen und den Halbmetallen und/oder ein Iodid der Alkali- oder Erdalkalimetalle eingesetzt. Die Erfindung betrifft ferner die Verwendung von Formaktivkohlen, die mit Metallionen dotiert sind, zur Entfernung von unerwünschten Stoffen wie Schadstoffen oder Giften, insbesondere die Entfernung von H2S. Als Dotierungsreagenz kommen hierbei die vorstehenden Substanzen oder Alkalimetall- oder Erdalkalimetalle der Formel M2p(EOq)r (wobei E ein Element der 3. bis 7. Hauptgruppe ist und p, q und r ganze Zahlen ≥ 1 sind) in Betracht.
PCT/EP2007/004842 2006-05-31 2007-05-31 Mit metallsalzen dotierte katalytisch aktive formaktivkohlen und deren verwendung WO2007137856A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006025450A DE102006025450A1 (de) 2006-05-31 2006-05-31 Mit Metallsalzen dotierte katalytisch aktive Formaktivkohlen und deren Verwendung
DE102006025450.3 2006-05-31

Publications (2)

Publication Number Publication Date
WO2007137856A2 WO2007137856A2 (de) 2007-12-06
WO2007137856A3 true WO2007137856A3 (de) 2008-01-31

Family

ID=38436834

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/004842 WO2007137856A2 (de) 2006-05-31 2007-05-31 Mit metallsalzen dotierte katalytisch aktive formaktivkohlen und deren verwendung

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Country Link
DE (1) DE102006025450A1 (de)
WO (1) WO2007137856A2 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008049778A1 (de) 2008-09-30 2010-04-01 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Gewinnung von gasförmigen Kohlenwasserstoffen aus biogenen Rohstoffen
DE102010024099A1 (de) 2010-06-17 2011-12-22 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Katalytische Konversion von Alkoholen und Aldehyden
DE102011010525A1 (de) 2011-02-08 2012-08-09 Universität Rostock Verfahren zur Reinigung von Biogas, Rauchgas oder Flüssigkeiten, Adsorbens dafür, Filter, sowie Verwendung des Adsorptionsmittels
CN102716653A (zh) * 2011-03-30 2012-10-10 中国人民解放军63971部队 一种磷化氢熏蒸尾气净化方法
DE102011115377A1 (de) 2011-10-10 2013-04-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur Gewinnung von Kohlenwasserstoffen mit mittleren Kettenlängen und dessen Verwendung
DE102011121087A1 (de) 2011-12-14 2013-06-20 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren zur katalytischen Kondensation oder Kopplung
WO2015104430A1 (de) 2014-01-13 2015-07-16 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e. V. Verfahren zur herstellung von pyrolysegas oder pyrolyseöl aus biogenen ausgangsmaterialien und damit herstellbares pyrolyseöl, pyrolysegas und desoxygenierungskatalysator
CN103861600B (zh) * 2014-02-27 2016-02-03 常州耀春格瑞纺织品有限公司 一种过渡金属离子、稀土离子镧、钇掺杂改性TiO2石墨烯复合材料的制备方法
CN103861575B (zh) * 2014-02-27 2015-11-18 常州耀春格瑞纺织品有限公司 一种掺杂改性TiO2/石墨烯复合材料的制备方法
DE102015004154A1 (de) 2015-04-01 2016-10-06 Toralf Goetze Verfahren zur Herstellung von dotierten katalytisch aktiven Formaktivkohlen
CN111389367A (zh) * 2020-04-22 2020-07-10 徐州工程学院 金属污泥基生物炭、制备方法及在去除水体中氮磷的应用
CN111689494B (zh) * 2020-06-23 2023-04-11 新疆大学 非腐蚀性催化剂及催化活化制备活性炭的方法
CN112295724B (zh) * 2020-09-14 2022-03-22 杭州电子科技大学 一种不同再生程度粉末活性炭浮选方法及浮选装置
CN113753894A (zh) * 2021-09-30 2021-12-07 山西华青环保股份有限公司 一种四氧化三铁负载活性炭的制备方法

Citations (5)

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US4421533A (en) * 1978-03-27 1983-12-20 Takeda Chemical Industries, Ltd. Method of removing ozone and composition therefor
US5830414A (en) * 1994-11-30 1998-11-03 Kondoh Industries Limited Air cleaning filter
WO2000078138A2 (de) * 1999-06-18 2000-12-28 German Carbon Teterow Gmbh Verfahren zur herstellung von formaktivkohle
US20020082168A1 (en) * 2000-12-11 2002-06-27 Graham James Richard Activated carbon for odor control and method for making same
WO2007054236A1 (de) * 2005-11-09 2007-05-18 Romold Gmbh Verfahren zur eliminierung von schwefelwasserstoff und gerüchen aus abwassersystemen

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DE686848C (de) * 1934-07-04 1940-01-17 I A C Societa Per L Ind Artico Herstellung aktiver Kohle in gekoernter Form
US3886093A (en) * 1973-12-14 1975-05-27 Westvaco Corp Activated carbon with active metal sites and process for producing same
DE2507672C3 (de) * 1975-02-22 1980-10-09 Laboratorium Fuer Adsorptionstechnik Gmbh, 6000 Frankfurt Verfahren zum Imprägnieren von Aktivkohle
FI790530A (fi) * 1978-02-21 1979-08-22 Siren M J O Filtermaterial samt foerfarande foer framstaellning av och anvaendning av detsamma
US4518488A (en) * 1983-02-28 1985-05-21 Standard Oil Company (Indiana) Metal-containing active carbon and methods for making and using same
US5482915A (en) * 1993-09-20 1996-01-09 Air Products And Chemicals, Inc. Transition metal salt impregnated carbon

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4421533A (en) * 1978-03-27 1983-12-20 Takeda Chemical Industries, Ltd. Method of removing ozone and composition therefor
US5830414A (en) * 1994-11-30 1998-11-03 Kondoh Industries Limited Air cleaning filter
WO2000078138A2 (de) * 1999-06-18 2000-12-28 German Carbon Teterow Gmbh Verfahren zur herstellung von formaktivkohle
US20020082168A1 (en) * 2000-12-11 2002-06-27 Graham James Richard Activated carbon for odor control and method for making same
WO2007054236A1 (de) * 2005-11-09 2007-05-18 Romold Gmbh Verfahren zur eliminierung von schwefelwasserstoff und gerüchen aus abwassersystemen

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DE102006025450A1 (de) 2007-12-06
WO2007137856A2 (de) 2007-12-06

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