WO2007018015A1 - インドール化合物、光学フィルター及び光学記録材料 - Google Patents
インドール化合物、光学フィルター及び光学記録材料 Download PDFInfo
- Publication number
- WO2007018015A1 WO2007018015A1 PCT/JP2006/314229 JP2006314229W WO2007018015A1 WO 2007018015 A1 WO2007018015 A1 WO 2007018015A1 JP 2006314229 W JP2006314229 W JP 2006314229W WO 2007018015 A1 WO2007018015 A1 WO 2007018015A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- carbon atoms
- compound
- optical recording
- layer
- Prior art date
Links
- -1 Indole compound Chemical class 0.000 title claims abstract description 140
- SIKJAQJRHWYJAI-UHFFFAOYSA-N benzopyrrole Natural products C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 title claims abstract description 37
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 title claims abstract description 36
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 230000003287 optical effect Effects 0.000 title claims description 126
- 239000000463 material Substances 0.000 title claims description 33
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 44
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 23
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 11
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 125000005843 halogen group Chemical group 0.000 claims abstract description 9
- 125000001424 substituent group Chemical group 0.000 claims abstract description 7
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims abstract description 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims abstract description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract 6
- 150000001875 compounds Chemical class 0.000 claims description 63
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 125000006367 bivalent amino carbonyl group Chemical group [H]N([*:1])C([*:2])=O 0.000 claims 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 113
- 238000001816 cooling Methods 0.000 description 33
- 238000010521 absorption reaction Methods 0.000 description 29
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- 229910052757 nitrogen Inorganic materials 0.000 description 23
- 239000007787 solid Substances 0.000 description 22
- 239000002904 solvent Substances 0.000 description 22
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 239000000203 mixture Substances 0.000 description 18
- 238000001914 filtration Methods 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 13
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 239000010408 film Substances 0.000 description 11
- 239000010419 fine particle Substances 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 9
- 238000000354 decomposition reaction Methods 0.000 description 9
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- 238000005160 1H NMR spectroscopy Methods 0.000 description 8
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 239000001913 cellulose Substances 0.000 description 8
- 229920002678 cellulose Polymers 0.000 description 8
- 230000031700 light absorption Effects 0.000 description 8
- 239000002244 precipitate Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000003667 anti-reflective effect Effects 0.000 description 7
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 229920000515 polycarbonate Polymers 0.000 description 7
- 239000004417 polycarbonate Substances 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 230000001050 lubricating effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000012046 mixed solvent Substances 0.000 description 6
- 239000002966 varnish Substances 0.000 description 6
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 5
- 229920002799 BoPET Polymers 0.000 description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 5
- 238000002835 absorbance Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- WRKCIHRWQZQBOL-UHFFFAOYSA-N octyl dihydrogen phosphate Chemical compound CCCCCCCCOP(O)(O)=O WRKCIHRWQZQBOL-UHFFFAOYSA-N 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000001953 recrystallisation Methods 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- BLRHMMGNCXNXJL-UHFFFAOYSA-N 1-methylindole Chemical compound C1=CC=C2N(C)C=CC2=C1 BLRHMMGNCXNXJL-UHFFFAOYSA-N 0.000 description 3
- NBUKAOOFKZFCGD-UHFFFAOYSA-N 2,2,3,3-tetrafluoropropan-1-ol Chemical compound OCC(F)(F)C(F)F NBUKAOOFKZFCGD-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 150000002475 indoles Chemical class 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000004528 spin coating Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000004763 sulfides Chemical class 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000013076 target substance Substances 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229940124543 ultraviolet light absorber Drugs 0.000 description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 3
- SFWZZSXCWQTORH-UHFFFAOYSA-N 1-methyl-2-phenylindole Chemical compound C=1C2=CC=CC=C2N(C)C=1C1=CC=CC=C1 SFWZZSXCWQTORH-UHFFFAOYSA-N 0.000 description 2
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 229940008309 acetone / ethanol Drugs 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003522 acrylic cement Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- JKOSHCYVZPCHSJ-UHFFFAOYSA-N benzene;toluene Chemical compound C1=CC=CC=C1.C1=CC=CC=C1.CC1=CC=CC=C1 JKOSHCYVZPCHSJ-UHFFFAOYSA-N 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 125000000490 cinnamyl group Chemical group C(C=CC1=CC=CC=C1)* 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 229910003437 indium oxide Inorganic materials 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 229920000609 methyl cellulose Polymers 0.000 description 2
- 239000001923 methylcellulose Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920005596 polymer binder Polymers 0.000 description 2
- 239000002491 polymer binding agent Substances 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 125000005504 styryl group Chemical group 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 238000002211 ultraviolet spectrum Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 1
- QMDAZABTUWKOJM-UHFFFAOYSA-N 1-[3,5-bis(trifluoromethyl)phenyl]indole Chemical compound FC(F)(F)C1=CC(C(F)(F)F)=CC(N2C3=CC=CC=C3C=C2)=C1 QMDAZABTUWKOJM-UHFFFAOYSA-N 0.000 description 1
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 1
- WMVJWKURWRGJCI-UHFFFAOYSA-N 2,4-bis(2-methylbutan-2-yl)phenol Chemical group CCC(C)(C)C1=CC=C(O)C(C(C)(C)CC)=C1 WMVJWKURWRGJCI-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- MOMFXATYAINJML-UHFFFAOYSA-N 2-Acetylthiazole Chemical group CC(=O)C1=NC=CS1 MOMFXATYAINJML-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 1
- 125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- DTBDAFLSBDGPEA-UHFFFAOYSA-N 3-Methylquinoline Natural products C1=CC=CC2=CC(C)=CN=C21 DTBDAFLSBDGPEA-UHFFFAOYSA-N 0.000 description 1
- HIHCTGNZNHSZPP-UHFFFAOYSA-N 4-chloro-3-methylaniline Chemical compound CC1=CC(N)=CC=C1Cl HIHCTGNZNHSZPP-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000004861 4-isopropyl phenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- XURABDHWIADCPO-UHFFFAOYSA-N 4-prop-2-enylhepta-1,6-diene Chemical class C=CCC(CC=C)CC=C XURABDHWIADCPO-UHFFFAOYSA-N 0.000 description 1
- SBOITLSQLQGSLO-UHFFFAOYSA-N 5-bromo-1-methylindole Chemical compound BrC1=CC=C2N(C)C=CC2=C1 SBOITLSQLQGSLO-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical class NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- ODEGFPCTGGIJCF-UHFFFAOYSA-A P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+] Chemical compound P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].P(=O)([O-])([O-])[O-].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+].[K+] ODEGFPCTGGIJCF-UHFFFAOYSA-A 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052773 Promethium Inorganic materials 0.000 description 1
- 102100038239 Protein Churchill Human genes 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical class CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- OPISSGAHNMQVJL-UHFFFAOYSA-N [Mn].[Os] Chemical compound [Mn].[Os] OPISSGAHNMQVJL-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000005036 alkoxyphenyl group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000006295 amino methylene group Chemical group [H]N(*)C([H])([H])* 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 238000007611 bar coating method Methods 0.000 description 1
- MIAUJDCQDVWHEV-UHFFFAOYSA-N benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1S(O)(=O)=O MIAUJDCQDVWHEV-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000000319 biphenyl-4-yl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000006355 carbonyl methylene group Chemical group [H]C([H])([*:2])C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000013066 combination product Substances 0.000 description 1
- 229940127555 combination product Drugs 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000001047 cyclobutenyl group Chemical group C1(=CCC1)* 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 1
- 229920005994 diacetyl cellulose Polymers 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical class C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000005678 ethenylene group Chemical group [H]C([*:1])=C([H])[*:2] 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000003983 fluorenyl group Chemical class C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- YZMHQCWXYHARLS-UHFFFAOYSA-N naphthalene-1,2-disulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(S(=O)(=O)O)=CC=C21 YZMHQCWXYHARLS-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 150000002815 nickel Chemical group 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 150000004893 oxazines Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JZRYQZJSTWVBBD-UHFFFAOYSA-N pentaporphyrin i Chemical class N1C(C=C2NC(=CC3=NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 JZRYQZJSTWVBBD-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical class OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 125000000587 piperidin-1-yl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- GLGXXYFYZWQGEL-UHFFFAOYSA-M potassium;trifluoromethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)F GLGXXYFYZWQGEL-UHFFFAOYSA-M 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000006410 propenylene group Chemical group 0.000 description 1
- DSNYFFJTZPIKFZ-UHFFFAOYSA-N propoxybenzene Chemical compound CCCOC1=CC=CC=C1 DSNYFFJTZPIKFZ-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical class [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000005156 substituted alkylene group Chemical group 0.000 description 1
- QBMMZNNTFYRGBN-UHFFFAOYSA-N sulfinyllead Chemical compound S(=O)=[Pb] QBMMZNNTFYRGBN-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000004897 thiazines Chemical class 0.000 description 1
- OKYDCMQQLGECPI-UHFFFAOYSA-N thiopyrylium Chemical class C1=CC=[S+]C=C1 OKYDCMQQLGECPI-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 125000001834 xanthenyl group Chemical class C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/04—Indoles; Hydrogenated indoles
- C07D209/10—Indoles; Hydrogenated indoles with substituted hydrocarbon radicals attached to carbon atoms of the hetero ring
- C07D209/14—Radicals substituted by nitrogen atoms, not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/245—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing a polymeric component
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/2467—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes azo-dyes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
- G11B7/2472—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes cyanine
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
- G11B7/2478—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes oxonol
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/248—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes porphines; azaporphines, e.g. phthalocyanines
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/249—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing organometallic compounds
- G11B7/2495—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing organometallic compounds as anions
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/256—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers improving adhesion between layers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/258—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers
- G11B7/2595—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers based on gold
Definitions
- the present invention relates to novel indole compounds, optical filters and optical recording materials.
- the indole compound is useful as an optical element or the like.
- the indole compound is particularly useful as an ultraviolet light absorber to be contained in an optical filter for an image display device, and is high in wavelength by a low energy laser or the like having wavelengths in the visible and near infrared regions. It is useful for an optical recording material used for an optical recording medium capable of high density optical recording and reproduction.
- Optical recording media are in widespread use because they have excellent characteristics such as large recording capacity and non-contact recording or reproduction.
- WORM high definition optical disks
- CD-R compact disc-read-only optical disks
- DVD-R write-once optical disks
- the laser is focused to a minute area of the optical recording layer, the properties of the optical recording layer are changed, and recording is performed. Reproduction is performed according to the difference in light intensity.
- the wavelength of the semiconductor laser used for recording and reproduction is 750 to 830 nm for CD-R and 620 nm to 690 nm for DVD-R, but a further increase in capacity is realized.
- An optical disc using a very short wavelength laser is under study, for example, one using a light of 380 to 420 nm as a recording light is under consideration.
- an azo compound is reported in Patent Document 1
- a porphyrin compound is reported in Patent Document 2
- a metal complex of a triazole compound is reported in Patent Document 3.
- these compounds do not necessarily match the absorption wavelength characteristics as an optical recording material used to form an optical recording layer.
- an image display apparatus such as a liquid crystal display (LCD), a plasma display panel (PDP), an electroluminescent display (ELD), a cathode ray tube display (CRT), a fluorescent display tube, and a field emission display.
- LCD liquid crystal display
- PDP plasma display panel
- ELD electroluminescent display
- CRT cathode ray tube display
- fluorescent display tube a fluorescent display tube
- field emission display a field emission display.
- Optical filter for the wavelength of 300-390 nm Compounds that absorb light are used as ultraviolet light absorbers.
- Patent Document 4 reports a filter for an organic EL display element that contains an ultraviolet light absorber and blocks light of 200 to 410 nm.
- the UV absorber used in the filter for an organic EL display device is not necessarily suitable as an UV absorber for an optical filter, as to its absorption wavelength characteristics.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2004-209771
- Patent Document 2 Japanese Patent Application Laid-Open No. 2004-58365
- Patent Document 3 Japanese Patent Application Laid-Open No. 2004-174838
- Patent Document 4 Japanese Patent Application Laid-Open No. 2004-102223
- an object of the present invention is, in particular, a compound having optical properties suitable for an optical filter for an image display device and an optical element used for an optical recording material for an optical recording medium for short wavelength laser light.
- the present invention has been made based on the above findings, and it is an indole compound represented by the following general formula (I), an optical filter comprising the indole compound, and a substrate Further, the present invention provides an optical recording material comprising the indole compound used for the optical recording layer of the optical recording medium having the optical recording layer formed thereon.
- R 1 and R 2 are each independently a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms Or a substituent represented by the following general formula ( ⁇ ), wherein R 3 and R 4 are each independently an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or the number of carbon atoms R 6 represents an aryl group of 6 to 30, and R 5 represents R 7 and R 8 each independently represent a hydrogen atom, a hydrocarbon group having 1 to 30 carbon atoms, a halogen atom, a hydroxyl group, a nitro group, a cyano group, NHR or NR′R ′ ′, R, R ′ and R ', Each independently represents an alkyl group having 1 to: carbon atom, and R' and R ', may combine with each other to form a ring; R 5 and R 6 , R 6 and R 7 , R 7 and R 8 may be linked to each other to form a ring An q
- R a to R ′ each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and the methylene group in the alkyl group may be substituted with O 2 or —CO 2!
- Z represents a direct bond or an alkylene group having 1 to 8 carbon atoms which may have a substituent
- the methylene group in the alkylene group is one o-, one S-, one CO-, one coo- , One oco-, -so
- Examples of the hydrocarbon group having 1 to 30 carbon atoms represented by R 5 , R 6 , R 7 and R 8 include methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, sec-butyl, tert-butyl, isobutyl and amyl , Isoamyl, tertiary amyl, hexyl, cyclohexyl, cyclohexylmethyl, 2-cyclohexyl Norechinole, Heptole Nore, Iso-Heptole Nore, Third-Heptole Nore, N-Octinole, Iso-Octinole, Third-Octyl, 2-Ethyl Hexyl, Noel, Isonoel, Decyl, Dodecyl, Tridecyl, Tetradecyl, Penta
- these groups may be substituted with one or more selected alkoxy, alkenyl, and cyano groups selected from alkoxy, alkenyl, nitro, cyano, halogen atoms and the like. In such a case, the total number of carbon atoms including these substituents is at most 30.
- alkyl group having 1 to: carbon atoms represented by R 4 , R, R ′ and R ′ ′ in the above general formula (I) methyl, ethyl, propyl, isopropyl, butyl, sec-butyl and the like can be mentioned.
- alkoxy group having 1 to 10 carbon atoms include methyloxy, ethyloxy, isopropyloxy, propyloxy and And the like.
- Examples of the aryl group having 6 to 30 carbon atoms include phenyl, naphthyl, 2-methylphenyl and the like. 3-methyl cellulose 4-methyl cellulose 4-butyl cellulose 3-isopropyl cellulose 4-isopropyl cellulose 4 butyl cellulose 4 butyl cellulose 4 isobutyl cellulose 4 tert-butyl ether -4-, 4-hydroxyphenyl, 4-alkoxyphenyl, 4- (2-ethylhexyl) phenyl, 4-stearyl gel, 2, 3-dimethylphenyl Le, 2,4 Dimethylphenyl, 2,5 Dimethylphenyl, 2,6 Dimethylphenyl, 3,4 Dimethylphenyl, 3,5 Dimethylphenyl, 2,4 Di-tert-butylphenyl, 2,5 Di-tert-butyl Hue Nil, 2,6 di-tert-butylphenyl, 2,4 di-tert-pentylphenyl, 2,5-di-tertiary
- Examples of the halogen atom represented by R 5 , R 6 , R 7 and R 8 in the above general formula (I) include fluorine, chlorine, bromine and iodine.
- the ring R 'and R are formed by linking in the general formula (I), the piperidine ring, piperidines Rajin ring, pyrrolidine ring, Morufuorin ring and the like, R 5 and the ring R 6, R 6 and R 7 and R 7 and R 8 are formed by connecting, cyclobutene ring, cyclopentene ring, cyclohexene ring cyclohexane, benzene ring, a pyridine ring, and the like.
- alkyl group having 1 to 4 carbon atoms represented by the above general formula (II) examples include methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, tert-butyl, isobutyl, methoxy, Ethoxy, propyloxy, isopropyloxy, methoxymethyl, tetramethyl, 2-methoxyethyl, 2-acetyl, acetyl, 1-carbonylethyl, acetylmethyl, 1-carbonylpropyl, 2-oxobutyl, 2-acetylethyl, 1-carbonylisopropyl, etc.
- the optionally substituted alkylene group having 1 to 8 carbon atoms exemplified are methylene, ethylene, propylene, methylethylene, butylene, 1-methylpropylene, 2 methylpropylene, 1,2 dimethylpropylene , 1, 3 Dimethyl Lopylene, 1-Methylbutylene, 2-Methylbutylene, 3-Methylbutylene, 4-Methylbutylene, 2,4 Dimethylbutylene, 1,3 Dimethylbutylene, Pentylene, Hexylene, Heptylene, Heptylene, Otylene, Ethane 1, 1-Diyl, Propane 2, 2 —Diyl, ethenylene, propenylene, methyleneoxyl, ethyleneoxyl, oxymethylene, thiomethylene, carbonylmethylene, carbonyloxymethylene, methylenecarbonyloxyl, sulfolmethylene, aminomethylene, acetylethylated ethylene car
- examples of the a-on represented by An q — include, as monovalent, chlora-on, bromine-on, iodine-on and fluorine-on.
- Inorganics such as halogen halides such as perchlorate, chlorate, cyanocyanide, phosphorus hexafluoride, antimony hexafluoride, and boron tetrafluoride Benzenesulfonic acid, toluenesulfonic acid, trifluoromethanesulfonic acid, diphenylamine-1, 4-sulfonic acid, 2-amino-4-methyl-5-chlorobenzene Organic sulfonic acid ions such as sulfonic acid ions, 2-amino-5-thiobenzenesulfonic acid ions; octyl phosphate ions, octyl phosphate ions, dodecyl phosphate ions, octadec
- valence examples include benzenedisulfonic acid and naphthalenedisulfonic acid.
- valence has a function to de-excite (taunting) active molecules in the excited state.
- phenothiene having a carboxyl group, phosphonic acid group, sulfonic acid group or other anionic group in the chaer-one or cyclopentagel ring, meta-portane compound anion such as luteothene, etc. It can be used accordingly.
- quencher-on examples include the following general formulas (A) and (B) or the following formulas
- R 9 and R 1Q are each independently a halogen atom, an alkyl group having 1 to 8 carbon atoms, an aryl group having 6 to 30 carbon atoms, or SO 2
- G represents an alkyl group, an aryl group which may be substituted with a halogen atom, a dialkylamino group, a diallylamino group, a piperidino group or a morpholino group, and a and b each represent 0 to 4 Represent.
- R u , R 12 , R 13 and R 14 each independently represent an alkyl group, an alkyl phenyl group, an alkoxy phenyl group or a halogenated phenyl group.
- R 1 is a hydrocarbon group having 1 to 30 carbon atoms, particularly an alkyl group having 1 to 8 carbon atoms or 6 to 13 carbon atoms.
- R 2 is a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms, particularly a hydrogen atom, an alkyl group having 1 to 8 carbon atoms or an aryl group having 6 to 13 carbon atoms
- R 3 is an alkyl group having 1 to 10 carbon atoms, particularly an alkyl group having 1 to 4 carbon atoms
- R 4 is an alkyl group having 1 to 10 carbon atoms, in particular 1 to 4 carbon atoms Alkyl groups are preferred because they are excellent in cost and optical properties.
- indole compound of the present invention include the following compound Nos. 1 to 24.
- the method for producing the indoleyl compound of the present invention represented by the above general formula (I) is not particularly limited, and the compound can be obtained by a method utilizing a well-known reaction. Examples of such a method include, in the case of obtaining an indoleyl compound having a monovalent a-ion, a synthesis method such as the route shown in the following [6].
- the indole compound of the present invention is useful as an optical element that exerts a function by absorbing light of a specific wavelength, particularly a wavelength of 320 to 420 nm.
- an optical element examples thereof include an ultraviolet absorber to be contained in an optical filter, and an optical recording agent used for forming an optical recording layer of an optical recording medium such as an optical disk.
- the indoleyl compound of the present invention can also be used as a synthetic intermediate for pharmaceuticals, agricultural chemicals, perfumes, dyes, etc., or as various functional materials.
- the optical filter according to the present invention contains the indoil compound according to the present invention. Since the indol compound of the present invention has an absorption maximum wavelength at 340 to 390 nm and can absorb and block ultraviolet light of 410 nm or less and a part of visible light, the indol compound of the present invention contains the indole compound of the present invention.
- the optical filter according to the invention is particularly suitable as an optical filter for an image display device used for high quality display images.
- the optical filter of the present invention can be used not only for image display devices, but also for various applications such as for analyzers, for manufacturing semiconductor devices, for astronomical observation, for optical communication, for ophthalmic lenses and the like.
- the optical filter of the present invention is usually disposed on the front of the display.
- an optical filter according to the present invention may be attached directly to the surface of the display, and a front plate may be provided in front of the display, in which case the front side (outside) or back side (display side) of the front plate You may paste it on
- each layer such as an undercoat layer, an antireflective layer, a hard coat layer, a lubricating layer, etc.
- a transparent support As a typical constitution of the optical filter of the present invention, one in which each layer such as an undercoat layer, an antireflective layer, a hard coat layer, a lubricating layer, etc. is provided on a transparent support, as needed.
- Examples of the method of incorporating an optional component such as the indole compound of the present invention, dye compounds other than the indole compound of the present invention, and various types of stabilizers into the optical filter of the present invention include: (1) transparent support or (2) a transparent support or an optional method of coating on each layer, (3) a transparent support and an adhesive layer between any two adjacent layers selected from any layer (4) a method of providing a light absorbing layer containing a light absorbing agent such as an indole compound of the present invention separately from each layer, and the like.
- the amount of use of the indoil compound of the present invention is usually 1 to: LOOOmg / m 2 , preferably 5 to: LOOmg Zm 2 per unit area of the optical filter, lmg Zm 2 If the amount used is less than 2 , the light absorption effect can not be fully exhibited, and if it is used beyond 1 OOOmg Zm 2 , the color of the filter becomes too strong, and the display item is displayed. There is a possibility that the quality etc. may be lowered, and furthermore, the brightness may be lowered.
- the indole compound of the present invention is usually used as follows in order to bring the amount used per unit area of the optical filter into the above-mentioned range.
- the indolyl compound of the present invention is preferably used per 100 parts by mass of the adhesive such as an acrylic adhesive.
- a varnish is prepared by adding 0.05 to 0.01 parts by mass of a solvent such as methyl ethyl ketone and preferably 40 to 500 parts by mass, and the varnish is subjected to easy adhesion treatment.
- a transparent support such as a PET film The composition is coated and cured to obtain an optical filter having an adhesive layer (cured film) with a thickness of 0.1 to 10 microns.
- the material of the transparent support examples include inorganic materials such as glass; diacetyl cellulose, triacetinolecenorulose (TAC), propio-norecenoreulose, butyrinoresenorellose, acetinole propio-norecenolose Polyphenols; Polycarbonate; polyethylene terephthalate, polyethylene naphthalate, polyethylene terephthalate, poly 1,4-dimethyl hexane dimethylene terephthalate, polyethylene 1,2 diphenoxetane 4,4 '-Dicarboxylate, polyesters such as polybutylene terephthalate; polystyrenes; polyolefins such as polyethylene, polypropylene and polymethylpentene; acrylic resins such as polymethylmetatalylate; polycarbonates; Sulfone; polyethersulfones; polyether ketone; polyetherimides; Porioki Shiechiren, and polymer materials such
- An infrared absorber, inorganic fine particles and the like can be added to these transparent supports, and the transparent supports can be subjected to various surface treatments.
- inorganic fine particles examples include layered clay mineral, silicon dioxide, titanium dioxide, and sulfur. Acid, calcium carbonate and the like.
- the various surface treatments described above include, for example, chemical treatment, mechanical treatment, corona discharge treatment, flame treatment, ultraviolet irradiation treatment, high frequency treatment, glow discharge treatment, active plasma treatment, laser one treatment, mixed acid treatment And ozone oxidation treatment.
- the subbing layer is a layer used between the transparent support and the light absorbing layer in the case of providing a light absorbing layer containing a light absorbing agent.
- the subbing layer is a layer containing a polymer having a glass transition temperature of ⁇ 60 to 60 ° C., a layer having a rough surface on the light absorbing layer side, or a layer containing a polymer having an affinity to the polymer of the light absorbing layer.
- the undercoat layer is provided on the surface of the transparent support on which the light absorption layer is not provided, and the adhesion between the transparent support and the layers (for example, the antireflective layer and the hard coat layer) provided thereon.
- the thickness of the undercoat layer is 2 ⁇ ! -20 m preferred 5 nm-5 ⁇ m more preferred 20 nm-2 ⁇ m even more preferred 50 nm-1 ⁇ m even more preferred 80 ⁇ ⁇ ! -300 nm is most preferred.
- a primer layer comprising a polymer having a glass transition temperature of ⁇ 60 to 60 ° C. adheres to the polymer and bonds the transparent support to the filter layer. Polymers having a glass transition temperature of ⁇ 60 to 60 ° C.
- the glass transition temperature is preferably 50 ° C. or less, more preferably 40 ° C. or less, still more preferably 30 ° C. or less, and further preferably 25 ° C. or less It is most preferable that the temperature be below 20 ° C. which is preferable.
- the modulus of elasticity of the subbing layer at 25 DEG C.
- the undercoat layer having a rough surface on the light absorption layer side bonds the transparent support to the light absorption layer by forming the light absorption layer on the rough surface.
- the subbing layer whose surface on the light absorbing layer side is rough can be easily formed by application of a polymer latex.
- the average particle diameter of the latex is preferably 0.2 to 3 / ⁇ ⁇ ⁇ ⁇ , and more preferably 0.05 to 1 / ⁇ ⁇ .
- acrylic resin, cellulose derivative, gelatin And casein, starch, polybutyl alcohol, soluble nylon, and polymer latex As a polymer having an affinity to the binder polymer of the light absorption layer, acrylic resin, cellulose derivative, gelatin And casein, starch, polybutyl alcohol, soluble nylon, and polymer latex.
- the optical filter of the present invention may be provided with two or more subbing layers.
- the undercoat layer may be added with a solvent for swelling the transparent support, a matting agent, a surfactant, an antistatic agent, a coating aid, a hardener and the like.
- a low refractive index layer is essential.
- the refractive index of the low refractive index layer is lower than the refractive index of the above-mentioned transparent support.
- the refractive index of the low refractive index layer is preferably 1.20 to L55, and more preferably 1.30 to L50.
- the thickness of the low refractive index layer is more preferably 50 to 400 nm, preferably 50 to 400 nm.
- the low refractive index layer is a layer comprising a fluorine-containing polymer having a low refractive index (JP-A-57-34526, JP-A-3-130103, JP-A-6-115023, JP-A-8-313702, JP-A-7- 16800 4, each layer obtained by a sol-gel method (as described in JP-A-5-208811, JP-A-6-299091, JP-A-7-168003), or a layer containing fine particles (Japanese Patent Publication No. No. 59250, JP-A-5-13021, JP-A-6-56478, JP-A-7-92306 and JP-A-9-288201).
- voids can be formed in the low refractive index layer as microvoids between the fine particles or in the fine particles.
- the layer containing fine particles further preferably has a porosity of 5 to 35% by volume, which preferably has a porosity of 3 to 50% by volume.
- a layer having a high refractive index may be laminated to the above-mentioned antireflective layer.
- the refractive index of the high refractive index layer is 1.65-2.40.
- the refractive index of the middle refractive index layer is adjusted to be an intermediate value between the refractive index of the low refractive index layer and the refractive index of the high refractive index layer.
- the refractive index of the middle refractive index layer is preferably 1. 50 to: L 90 and more preferably 1. 55 to: L 70.
- the thickness of the medium-high refractive index layer is preferably 5 10 ⁇ to 100 / ⁇ , more preferably 10 ⁇ to 10 / ⁇ m, and most preferably 30 ⁇ to 1 / ⁇ preferable. Most preferably, the haze of the medium-high refractive index layer is 1% or less, more preferably 3% or less, which is preferably 5% or less.
- the medium 'high refractive index layer can be formed using a polymer binder having a relatively high refractive index.
- polymers with high refractive index examples include polystyrene and styrene copolymerization And polycarbonate, melamine resin, phenol resin, epoxy resin, polyurethane obtained by the reaction of cyclic (alicyclic or aromatic) isocyanate and polyol, and the like.
- Polymers having other cyclic (aromatic, heterocyclic or alicyclic) groups and polymers having a halogen atom other than fluorine as a substituent also have a high refractive index. It is also possible to use a polymer formed by the polymerization reaction of monomers in which a double bond is introduced to enable radical curing.
- inorganic fine particles may be dispersed in the above-mentioned polymer binder.
- the refractive index of the inorganic fine particles is preferably 1.80 to 2.80.
- the inorganic fine particles are preferably formed of metal oxides or sulfides.
- metal oxides or sulfides titanium oxide (eg, mixed crystals of rutile, rutile Z anatase, anatase, amorphous structure), tin oxide, indium oxide, zinc oxide, zirconium oxide, sulfur oxide Lead and the like can be mentioned.
- titanium oxide, tin oxide and indium oxide are particularly preferable.
- the inorganic fine particles contain oxides or sulfides of these metals as main components, and can further contain other elements.
- the main component means a highest content (Weight 0/0) among the components constituting the particles.
- Other elements include Ti, Zr, Sn, Sb, Cu, Fe, Mn, Pb, Cd, As, Cr, Hg, Zn, Al, Mg, Si, P, S and the like.
- An inorganic material which is film-forming and dispersible in a solvent, or is itself a liquid such as alkoxides of various elements, salts of organic acids, coordination complexes bonded with coordination complexes (for example, It is also possible to form a medium-high refractive index layer by using a chelating agent, an active inorganic polymer.
- the surface of the antireflective layer can be provided with an antiglare function (a function of preventing incident light from being scattered on the surface to prevent a scene around the film from migrating to the film surface).
- an antiglare function a function of preventing incident light from being scattered on the surface to prevent a scene around the film from migrating to the film surface.
- an antiglare function a function of preventing incident light from being scattered on the surface to prevent a scene around the film from migrating to the film surface.
- an antiglare function a function of preventing incident light from being scattered on the surface to prevent a scene around the film from migrating to the film surface.
- the hard coat layer has a height higher than the hardness of the transparent support.
- the hard coat layer preferably comprises a crosslinked polymer.
- the hard coat layer is made of an acrylic, urethane, epoxy polymer, oligomer or monomer (eg, UV curable) It can be formed using a resin) or the like. Silica-based materials also form a hard coat layer.
- a lubricating layer may be formed on the surface of the above-mentioned antireflection layer (low refractive index layer).
- the lubricating layer has a function of imparting slipperiness to the surface of the low refractive index layer and improving scratch resistance.
- the lubricating layer can be formed using a polyorganosiloxane (eg, silicone oil), a natural wax, a petroleum wax, a metal salt of a higher fatty acid, a fluorine-based lubricant or a derivative thereof, or the like.
- the thickness of the lubricating layer is preferably 2 to 20 nm.
- the indole compound of the present invention can be used as it is, or a ndinder can be used.
- a binder for example, natural polymer materials such as gelatin, casein, starch, cellulose derivatives, alginic acid or polymethyl methacrylate, polybul butyral, polybul pyrrolidone, polyvinyl alcohol, polyvinyl chloride, styrene butadiene copolymer, Synthetic high molecular weight materials such as polystyrene, polycarbonate, polyamide, polyurethane, polyester, and polyurethane are used.
- the undercoat layer, the antireflective layer, the hard coat layer, the lubricating layer, the light absorbing layer, etc. can be formed by a general coating method.
- a coating method dip coating method, air knife coating method, curtain coating method, roller coating method, wire bar coating method, gravure coating method, estrudel coat method using a hopper (described in US Pat. No. 2,681,294) Etc.
- Two or more layers may be formed by simultaneous application. With respect to the simultaneous application method, for example, each specification of US Pat. No. 2761791, US Pat. No. 2941898, US Pat. No. 3508947, US Pat. No. 3,526,528 and Yuji Harasaki "Coating Engineering” p. 253 (1974 Asakura, Japan). Described in the bookstore issue).
- the optical recording material of the present invention contains the indole compound of the present invention and is used to form an optical recording layer of an optical recording medium, and various kinds of the optical recording material according to the light absorption characteristics of the contained indole compound. It can be applied to optical recording media.
- the optical recording materials of the present invention it is particularly suitable for an optical disc for short wavelength lasers with a wavelength of 380 nm to 420 nm that the indole compound contained has the maximum absorption wave in light absorption characteristics in solution state. It has a long max in the range of 320 to 420 nm.
- the absorption intensity if ⁇ at max is smaller than 1.
- OX 10 4 there is a possibility that the recording sensitivity may be lowered, therefore 1.0 ⁇ 10 4 or more is preferable.
- the measurement of ⁇ max and ⁇ in the solution state of the above-mentioned indole complex can be carried out by selecting the concentration of the sample solution, the solvent used for the measurement and the like according to a conventional method.
- the method for forming the optical recording layer of the optical recording medium using the optical recording material of the present invention containing the above-mentioned indole compound is not particularly limited.
- lower alcohols such as methanol and ethanol
- ether alcohols such as methyl seport sorb, ethyl seport sorb, butyl seport sorb and butyl diglycol
- acetone methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, diacetone Ketones
- alcohol, esters such as ethyl acetate, butyl acetate, methoxyethyl acetate, etc .
- acrylic esters such as ethyl acrylate, butyl acrylate etc., 2, 2, 3, 3-tetrafluoropropanoe
- Indole compounds of the present invention and various kinds of organic solvents such as fluorinated alcohols such as benzene; toluene; hydrocarbons such as
- the above optical recording layer is formed as a thin film, and the thickness thereof is usually 0.000 to 1: LO / z m, and preferably in the range of 0.01 to 5 ⁇ m.
- the content of the indole compound of the present invention in the optical recording material of the present invention is preferably 10% by mass to LOO% by mass in the solid content contained in the optical recording material of the present invention. It is preferable that the above optical recording layer is formed to contain 50 to 100% by mass of the indole compound represented by the above general formula (I) in the optical recording layer.
- the optical recording material of the present invention comprises the indole compound represented by the above general formula (I), based on the solid content contained in the optical recording material of the present invention. More preferably, containing 100% by mass.
- the optical recording material of the present invention may contain, in addition to the indole compound of the present invention, if necessary, a cyanine compound, an azo compound, a phthalocyanine compound, an oxanol compound, Squarylium compounds, styryl compounds, porphine compounds, azlenium compounds, croco-ttamethine compounds, pyrilium compounds, thiopyrylium compounds, triallylmethane compounds, diphenylmethane compounds, tetrahydrocholine compounds, indole choline compounds
- Compounds that can be used for ordinary optical recording layers such as anthracene compounds, naphthoquinone compounds, xanthene compounds, thiazine compounds, atalidine compounds, oxazine compounds, spiropyran compounds, fluorene compounds, rhodamine compounds, etc.
- the optical recording material of the present invention is an aromatic-trosoxy compound, an ammonium compound, an imidazole compound, a bisimidazole compound, a transition metal chelate as a quencher such as singlet oxygen. It may contain a compound or the like, or may use quan- teranion. In the optical recording material of the present invention, these various composites are preferably used in an amount of 0 to 50% by mass in the solid content contained in the optical recording material of the present invention. .
- the material of the above-mentioned base on which such an optical recording layer is formed is not particularly limited as long as it is substantially transparent to the writing (recording) light and the reading (reproducing) light.
- Chil metatalylate, resins such as polyethylene terephthalate and polycarbonate, glass and the like are used. Also, depending on the application, any shape such as tape, drum, belt, disk, etc. can be used.
- gold, silver, aluminum, copper or the like can be used to form a reflective film by a vapor deposition method or a sputtering method, or an acrylic resin or an ultraviolet curing property.
- the protective layer can also be formed by resin or the like.
- the reaction solution was cooled to room temperature, gradually added dropwise to a 500 ml aqueous solution of 23.5 g (127 mmol) of potassium hexafluorophosphate, and stirred at room temperature for 1 hour.
- the precipitate was separated by filtration and dried to obtain 16.2 g (yield 99.4%) of a brown solid. It was confirmed that the obtained brown solid was Compound No. 21, which is the target substance. Obtained
- the analysis results for Compound No. 21 are shown below.
- a UV varnish was prepared by the following composition, and the UV varnish was applied by means of a bar coater # 9 to a 188 ⁇ m-thick PET film which was treated to be easily adhered, and then dried at 100 ° C. for 10 minutes. After that, ultraviolet light was irradiated with lOOmJ with a high pressure mercury lamp with an infrared ray cut film filter to obtain an optical filter having a film layer (pressure-sensitive adhesive layer) having a cured film thickness of about 5 microns on a PET film. When this optical filter was measured by JASCO Corporation UV-visible near-infrared spectrophotometer V-570, ⁇ max was 353 nm.
- a UV varnish was prepared by the following composition, and the UV varnish was applied by means of a bar coater # 9 to a 188 ⁇ m-thick PET film which was treated to be easily adhered, and then dried at 100 ° C. for 10 minutes. After that, ultraviolet light was irradiated with 100 mOg with a high pressure mercury lamp with an infrared ray cut film filter to obtain an optical filter having a film layer with a cured film thickness of about 5 microns on a PET film. When this optical filter was measured using an ultraviolet visible near infrared spectrophotometer V-570 manufactured by JASCO Corporation, the max was 354 nm.
- Example 12 Production of Optical Recording Material and Optical Recording Medium, and Evaluation of Optical Recording Medium
- concentration of the compound No. 4 in the compound No. 4 obtained in the above production example 4 is 1.0 mass%.
- This material was dissolved to obtain an optical recording material as a 2, 2, 3, 3-teraphanolol propanol solution.
- a filter using the indole compound of the present invention has an absorption maximum at a specific wavelength (340 to 390 nm) (Examples 10 and 11), and is suitable as a UV absorber for an optical filter was confirmed.
- An optical recording medium having an optical recording layer formed of an optical recording material containing the indole compound of the present invention has an absorption maximum of reflected light at a specific wavelength (340 to 390 nm).
- Example 12 In the reproduction mode of the optical recording medium represented by the optical disc, the presence or absence of recording is detected from the difference in the light quantity of the laser wavelength for the reflected light that reflects the laser light to the optical recording medium. In the absorption spectrum of the above, it is more preferable to show a large absorption intensity in the vicinity of the wavelength of the laser light. Therefore, the optical recording material of the present invention containing the indole compound of the present invention is used for forming an optical recording layer of an optical recording medium using a 405 nm laser beam such as an optical disk for short wavelength laser. Is preferred.
- the light resistance evaluation was performed on the compounds No. 21, No. 23 and No. 24 obtained in Examples 7 to 9 and the comparative compound 1.
- a compound of the present invention is dissolved in 2, 2, 3, 3- tetrafluoropropanol to 1% by mass to prepare a 2, 2, 3, 3- tetrafluoropropanol solution,
- the obtained solution was applied on a polycarbonate plate of 20 2011 11 111 for 2000 ⁇ 111 in 60 seconds by spin coating to prepare a test piece.
- the evaluation was carried out by irradiating the test piece with light of 55000 lux, irradiating each for 24 hours and 150 hours, and then measuring the absorbance residual rate at ⁇ max of the UV absorption spectrum before irradiation.
- the present invention can provide a novel indole compound suitable as an optical element.
- an optical filter using the indoil compound is suitable as an optical filter for an image display device, and an optical recording material containing the indoli compound is a light of an optical recording medium. It is suitable for forming a magnetic recording layer.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06781236A EP1921063B1 (en) | 2005-08-11 | 2006-07-19 | Indole compound, optical filter and optical recording material |
DE602006016619T DE602006016619D1 (de) | 2005-08-11 | 2006-07-19 | Indolverbindung, optischer filter und material für optische aufzeichnung |
KR1020087002962A KR101354109B1 (ko) | 2005-08-11 | 2006-07-19 | 인돌화합물, 광학필터 및 광학기록 재료 |
US11/996,502 US7923091B2 (en) | 2005-08-11 | 2006-07-19 | Indole compound, optical filter and optical recording material |
JP2007529470A JP5046936B2 (ja) | 2005-08-11 | 2006-07-19 | インドール化合物、光学フィルター及び光学記録材料 |
CN2006800292395A CN101238100B (zh) | 2005-08-11 | 2006-07-19 | 吲哚化合物、滤光器以及光学记录材料 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005233329 | 2005-08-11 | ||
JP2005-233329 | 2005-08-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007018015A1 true WO2007018015A1 (ja) | 2007-02-15 |
Family
ID=37727205
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2006/314229 WO2007018015A1 (ja) | 2005-08-11 | 2006-07-19 | インドール化合物、光学フィルター及び光学記録材料 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7923091B2 (ja) |
EP (1) | EP1921063B1 (ja) |
JP (1) | JP5046936B2 (ja) |
KR (1) | KR101354109B1 (ja) |
CN (1) | CN101238100B (ja) |
DE (1) | DE602006016619D1 (ja) |
TW (1) | TW200720251A (ja) |
WO (1) | WO2007018015A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2172804B1 (en) * | 2008-10-03 | 2016-05-11 | Semiconductor Energy Laboratory Co, Ltd. | Display device |
CN102959435A (zh) * | 2010-06-25 | 2013-03-06 | 旭硝子株式会社 | 光学薄膜及其制造方法 |
KR20210041568A (ko) * | 2018-08-09 | 2021-04-15 | 스미또모 가가꾸 가부시키가이샤 | 수지 및 점착제 조성물 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2681294A (en) | 1951-08-23 | 1954-06-15 | Eastman Kodak Co | Method of coating strip material |
US2761791A (en) | 1955-02-23 | 1956-09-04 | Eastman Kodak Co | Method of multiple coating |
US2941898A (en) | 1957-12-16 | 1960-06-21 | Ilford Ltd | Production of multilayer photographic materials |
US3508947A (en) | 1968-06-03 | 1970-04-28 | Eastman Kodak Co | Method for simultaneously applying a plurality of coated layers by forming a stable multilayer free-falling vertical curtain |
US3526528A (en) | 1965-10-28 | 1970-09-01 | Fuji Photo Film Co Ltd | Multiple doctor coating process and apparatus |
JP2002234259A (ja) * | 2001-02-14 | 2002-08-20 | Ricoh Co Ltd | 光記録媒体及びこれを用いる光記録方法 |
JP2003237233A (ja) | 2002-02-15 | 2003-08-27 | Mitsubishi Chemicals Corp | 光学記録媒体及び記録方法 |
JP2003313447A (ja) | 2002-04-19 | 2003-11-06 | Ind Technol Res Inst | インドールスチリル化合物およびこれを用いた高密度記録媒体 |
JP2004058365A (ja) | 2002-07-26 | 2004-02-26 | Matsushita Electric Ind Co Ltd | 光記録媒体および製造方法 |
JP2004102223A (ja) | 2002-07-15 | 2004-04-02 | Fuji Photo Film Co Ltd | 有機elディスプレイ素子用フィルター |
JP2004174838A (ja) | 2002-11-26 | 2004-06-24 | Fuji Photo Film Co Ltd | 光情報記録媒体および情報記録方法 |
JP2004209771A (ja) | 2002-12-27 | 2004-07-29 | Fuji Photo Film Co Ltd | 光情報記録媒体 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6558768B2 (en) * | 2000-03-07 | 2003-05-06 | Ricoh Company, Ltd. | Optical recording medium and optical recording and reading method using the same |
-
2006
- 2006-07-19 JP JP2007529470A patent/JP5046936B2/ja not_active Expired - Fee Related
- 2006-07-19 KR KR1020087002962A patent/KR101354109B1/ko not_active IP Right Cessation
- 2006-07-19 DE DE602006016619T patent/DE602006016619D1/de active Active
- 2006-07-19 US US11/996,502 patent/US7923091B2/en not_active Expired - Fee Related
- 2006-07-19 EP EP06781236A patent/EP1921063B1/en not_active Expired - Fee Related
- 2006-07-19 WO PCT/JP2006/314229 patent/WO2007018015A1/ja active Application Filing
- 2006-07-19 CN CN2006800292395A patent/CN101238100B/zh not_active Expired - Fee Related
- 2006-08-04 TW TW095128767A patent/TW200720251A/zh not_active IP Right Cessation
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2681294A (en) | 1951-08-23 | 1954-06-15 | Eastman Kodak Co | Method of coating strip material |
US2761791A (en) | 1955-02-23 | 1956-09-04 | Eastman Kodak Co | Method of multiple coating |
US2941898A (en) | 1957-12-16 | 1960-06-21 | Ilford Ltd | Production of multilayer photographic materials |
US3526528A (en) | 1965-10-28 | 1970-09-01 | Fuji Photo Film Co Ltd | Multiple doctor coating process and apparatus |
US3508947A (en) | 1968-06-03 | 1970-04-28 | Eastman Kodak Co | Method for simultaneously applying a plurality of coated layers by forming a stable multilayer free-falling vertical curtain |
JP2002234259A (ja) * | 2001-02-14 | 2002-08-20 | Ricoh Co Ltd | 光記録媒体及びこれを用いる光記録方法 |
JP2003237233A (ja) | 2002-02-15 | 2003-08-27 | Mitsubishi Chemicals Corp | 光学記録媒体及び記録方法 |
JP2003313447A (ja) | 2002-04-19 | 2003-11-06 | Ind Technol Res Inst | インドールスチリル化合物およびこれを用いた高密度記録媒体 |
JP2004102223A (ja) | 2002-07-15 | 2004-04-02 | Fuji Photo Film Co Ltd | 有機elディスプレイ素子用フィルター |
JP2004058365A (ja) | 2002-07-26 | 2004-02-26 | Matsushita Electric Ind Co Ltd | 光記録媒体および製造方法 |
JP2004174838A (ja) | 2002-11-26 | 2004-06-24 | Fuji Photo Film Co Ltd | 光情報記録媒体および情報記録方法 |
JP2004209771A (ja) | 2002-12-27 | 2004-07-29 | Fuji Photo Film Co Ltd | 光情報記録媒体 |
Non-Patent Citations (8)
Title |
---|
BABIEVSKII K.K.: "Reaction of nitro compounds with immonium salts. 1. Nitrovinylation of indoles", IZVESTIYA AKADEMII NAUK SSSR, SERIYA KHIMICHESKAYA, no. 10, 1977, pages 2310 - 2313, XP003002977 * |
BLUNT J.W.: "Syntheses of haptens related to the benzenoid and indole portions of sporidesmin A; carbon-13 NMR spectra of indole derivatives", AUSTRALIAN JOURNAL OF CHEMISTRY, vol. 32, no. 5, 1979, pages 1045 - 1054, XP003002975 * |
CHEMICAL ABSTRACTS, vol. 104, 1986, Columbus, Ohio, US; abstract no. 5282U, GENKINA N.K.: "Kinetics of hydrolysis of 3-indolylmethylidenedimethylimmonium fluoroborate in a phosphate buffer" XP003002976 * |
HARASAKI YUJI: "Coating Kogaku", 1973, ASAKURA SHOTEN, pages: 253 |
KOBAYASHI T.: "Azafulvenes. 2. Formation of iminium salt from pyrrole- and indolecarbaldehyde and its reaction with bases", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, vol. 48, no. 11, 1975, pages 3255 - 3258, XP003002978 * |
See also references of EP1921063A4 |
TIMOKHINA L.V.: "Mesomerically stabilized thioaldehydes. 3-Thioformylindole and its alkyl(phenyl) derivatives", KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, no. 4, 1996, pages 493 - 496, XP003002974 * |
ZH ORG. KHIM., vol. 21, no. 6, 1985, pages 1253 - 1256 * |
Also Published As
Publication number | Publication date |
---|---|
TW200720251A (en) | 2007-06-01 |
US7923091B2 (en) | 2011-04-12 |
DE602006016619D1 (de) | 2010-10-14 |
US20090092782A1 (en) | 2009-04-09 |
KR20080042810A (ko) | 2008-05-15 |
EP1921063A4 (en) | 2009-07-15 |
JPWO2007018015A1 (ja) | 2009-02-19 |
KR101354109B1 (ko) | 2014-01-22 |
EP1921063B1 (en) | 2010-09-01 |
CN101238100A (zh) | 2008-08-06 |
CN101238100B (zh) | 2011-06-22 |
TWI376369B (ja) | 2012-11-11 |
JP5046936B2 (ja) | 2012-10-10 |
EP1921063A1 (en) | 2008-05-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101272742B1 (ko) | 시아닌화합물, 광학필터 및 광학기록재료 | |
CN101589113B (zh) | 花青化合物、使用了该化合物的滤光器以及光学记录材料 | |
JP4781123B2 (ja) | 光学フィルター | |
KR101226194B1 (ko) | 시아닌화합물, 광학 필터 및 광학 기록재료 | |
TWI397560B (zh) | A novel compound, a filter using the compound, and an optical recording material | |
WO2007018015A1 (ja) | インドール化合物、光学フィルター及び光学記録材料 | |
JP5501716B2 (ja) | シアニン化合物、該化合物を用いた光学記録材料及び色補正材料 | |
JP4912010B2 (ja) | ジオキシノン構造を有する化合物並びに該化合物を用いた光学フィルター及び光学記録材料 | |
TW201206892A (en) | Complex compound and optical recording medium including the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200680029239.5 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2007529470 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2006781236 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 11996502 Country of ref document: US |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020087002962 Country of ref document: KR |
|
NENP | Non-entry into the national phase |
Ref country code: DE |