WO2006109458A1 - 毛髪化粧料 - Google Patents

毛髪化粧料 Download PDF

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Publication number
WO2006109458A1
WO2006109458A1 PCT/JP2006/305656 JP2006305656W WO2006109458A1 WO 2006109458 A1 WO2006109458 A1 WO 2006109458A1 JP 2006305656 W JP2006305656 W JP 2006305656W WO 2006109458 A1 WO2006109458 A1 WO 2006109458A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
group
effect
integer
straight
Prior art date
Application number
PCT/JP2006/305656
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
Koichi Yato
Kae Asano
Original Assignee
Kose Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kose Corporation filed Critical Kose Corporation
Priority to JP2007512451A priority Critical patent/JP5243024B2/ja
Priority to CN2006800101561A priority patent/CN101151012B/zh
Priority to HK08110489.9A priority patent/HK1118717B/xx
Publication of WO2006109458A1 publication Critical patent/WO2006109458A1/ja

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/447—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a hair cosmetic, and more specifically, by blending a acetyl cysteine and a specific silicone block copolymer, the hair becomes straight and the flow of the hair is uniform. It is related to hair cosmetics that have an effect of imparting such a sensation (straight feeling), an effect of preventing hair damage, and an effect of making hair smooth and easy to bundle. It is.
  • the flow of hair is uniform, smooth and glossy, and easy to bundle. Hair is representative of beauty and hair conditions. However, the hair is exposed to sunlight, the air on a daily basis, or faded by hot air from a dryer, etc., and suffers damage such as crispness, split ends, and broken hairs with little force.
  • a straight perm is known to make the hair flow beautifully and straighten the hair to make the hair straight.
  • the straight perm while straightening the hair itself, is a normal permanent wave, hair dye, etc.
  • the hair is actually damaged more.
  • cuticles and keratin fibers in the hair are damaged, and melanin pigments, pigments derived from hair dyes, and lipids such as lipids are likely to elute. If the damaged hair is left untouched, the hair damage further proceeds.
  • thiol compounds such as acetyl cystine have been conventionally used as a reducing agent blended with permanent wave and straight permanent agents (see, for example, Patent Documents 7 and 8).
  • Patent Document 1 Japanese Patent Laid-Open No. 6-92824
  • Patent Document 2 Japanese Patent Laid-Open No. 7-69844
  • Patent Document 3 Japanese Patent Laid-Open No. 8-48698
  • Patent Document 4 Japanese Patent Laid-Open No. 9-71516
  • Patent Document 5 JP-A-8-231348
  • Patent Document 6 Japanese Patent Application Laid-Open No. 7-228510
  • Patent Document 7 JP-A-8-269003
  • Patent Document 8 JP-A-5-39211
  • Patent Document 9 Japanese Patent Laid-Open No. 7-138132
  • the present inventors have intensively studied to solve the above problems, and as a result, by using a combination of a specific amount of acetyl cysteine and a specific silicone-based block copolymer, It doesn't have the effect of changing hair straightly like a straight perm, but it gives a feeling that hairs with wrinkles and waves are straightened and the flow of hair is aligned (hereinafter referred to as "straightness").
  • straightness a hair cosmetic composition excellent in the effect of preventing hair damage and excellent in the effect of making the hair smooth and easy to bundle was obtained, and based on this knowledge, the present invention was completed. It was.
  • the present invention provides the following components (a) and (b):
  • R 1 is independently of each other a monovalent hydrocarbon group, hydroxyl group or alkoxy group free of aliphatic unsaturation
  • X 1 is a general formula: R 3 — Z 1 (where R 1 3 represents a direct bond or a divalent hydrocarbon group having 1 to 20 carbon atoms, and Z 1 represents an amino group-containing group or an ammonia group-containing group.
  • each siloxane block has an average molecular weight of about 250 to about 1,000,000, and each polyoxyalkylene block has an average molecular weight of about 200 to about 10,000.
  • the hair cosmetic composition of the present invention is excellent in the effect of preventing hair damage while imparting a straight feeling to the hair, and is excellent in the effect of making the hair smooth and easy to bundle.
  • Acetylcystine of component (a) used in the present invention is a reducing agent that is generally blended as an active ingredient in permanent permanent agents and straight permanent agents, and breaks the disulfide bond in the hair to cause wrinkles and undulations. It is a component that can make certain hair straight.
  • the amount of acetyl cystine as the component (a) used in the present invention is 0.05 to: L 0% by mass (hereinafter, simply referred to as “%”) in the hair cosmetic composition. 1 to 0.5% is more preferable. If it is within this range, the effect of making the hair smoother with a feeling of straightness without feeling the irritation and hair damage as with normal perm can be obtained. Further effects can be obtained by repeated use.
  • R 1 is independently of each other a monovalent hydrocarbon group, a hydroxyl group or an alkoxy group that does not contain aliphatic unsaturation, and among these, a monovalent carbonization that does not contain aliphatic unsaturation
  • the hydrogen group for example, a methyl group, an ethyl group, a propyl group, a butyl group, an octyl group, a dodecyl group, a fullyl group, a phenethyl group, or the like is particularly preferable.
  • alkoxy group examples include a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a isopropyloxy group, a methoxyethoxy group, a phenoxy group, a acetoxy group, a cyclohexoxy group, and a dodecanyloxy group.
  • X 1 is a general formula:
  • R 3 represents a direct bond or a divalent hydrocarbon group having 1 to 20 carbon atoms
  • Z 1 represents an amino group-containing group or an ammonium group-containing group).
  • examples of the R 3 group include, for example, —CH—, —CH CH—, —CH CH CH—, —CH (CH)
  • Is for example, (CH) NH, one (CH) NH (CH) NH, one (CH) N (CH), one
  • R 2 independently of each other represents either R 1 or X 1 , n is an integer of 2 to 4, a is an integer of at least 1 or more, c is at least 2 or more An integer, d is an integer of at least 2 and b X d is at least 1.
  • examples of divalent organic groups represented by Y groups are R '-R- CO -R- NHCO R 4 — NHCONHR 5 — NHCO or R 4 — OOCNH— R 5 — NHCO— (where R 4 is a divalent alkylene group such as an ethylene group, a propylene group, a butylene group, and the like, and R 5 is a divalent alkylene group such as the group exemplified as R 4 or a divalent arylene group such as CHCH— CHCH -CH CHCH— CH (CH
  • Suitable examples of the Y group are: -CH CH
  • the group Y is a divalent alkylene group, CH
  • silicone block copolymer of component (b) of the present invention include those represented by the following formula.
  • e is an integer of 1 600
  • f is a number of 0.120
  • g and h are each an integer of 1 60
  • i is an integer of 250
  • f X i is at least 1 or more is there.
  • silicone-based block copolymer as the component (b) of the present invention includes, for example, those represented by the following formulae.
  • the molecular weight of the silicone-based block copolymer as the component (b) of the present invention is 5,000 to 2,000,000, preferably ⁇ 10,000 to 1,500,000. Mas ⁇ is between 20,000 and 1,000,000. If it is 5,000 or less, the effect of imparting smoothness to the hair will not be sufficiently obtained.
  • Examples of commercially available silicone block copolymers used in the present invention include SILSTYLE 401 (manufactured by Toray Dow Co., Ltd., Silicone Co., Ltd. (former company name: Enomoto New Car)).
  • the blending amount of component (b) in the hair cosmetic composition of the present invention is not particularly limited, but it is preferably 0.01 to 20% as a pure component, and particularly preferably 0.1 to 10%. Within this range, when used in combination with component (a), it is excellent in the effect of imparting a straight feeling that does not cause an unpleasant feel such as oiliness, and the effect of preventing hair damage. A good product that is smooth and smooth and excellent in the effect of making the hair easy to bundle is obtained.
  • the hair cosmetic composition of the present invention has a key-on in a quantitative and qualitative range that does not impair the effects of the present invention depending on the purpose.
  • Surfactant, Cationic Surfactant, Amphoteric Surfactant, Nonionic Surfactant, etc. Oils, Components such as Ester Oil, Higher Fatty Acids, Higher Alcohols, Hydrocarbons, Oils and Fats (components)
  • Silicones natural water-soluble polymers, semi-synthetic water-soluble polymers, water-soluble polymers such as synthetic water-soluble polymers, aqueous components such as polyhydric alcohols, saccharides and lower alcohols, amino acids, amino acids Derivatives, peptides, peptide derivatives, cosmetic ingredients for hair such as plant extracts, metal chelating agents such as edetate, pH adjusters such as citrate, lactic acid, phosphoric acid or their salts, fragrances, preservatives,
  • the method for producing the hair cosmetic composition of the present invention is not particularly limited, and can be produced by a conventional method.
  • the liquid cosmetic, the emulsion, the cream, the gel It can be carried out in various forms such as a shape, a mist shape, and a foam shape. More specifically, it can be used as a shampoo, hair rinse, hair treatment, hair pack, hair lotion, hair cream, hair jersey, etc., as well as propellants such as liquid petroleum gas, dimethyl ether, nitrogen gas, carbon dioxide gas, etc.
  • propellants such as liquid petroleum gas, dimethyl ether, nitrogen gas, carbon dioxide gas, etc.
  • aerosol containers such as hair sprays and hair foams (hair mousses).
  • hair mousses hair sprays and hair foams
  • the hair cosmetic composition of the present invention obtained in this way is excellent in the effect of preventing hair damage while imparting a straight feeling, and excellent in the effect of making the hair smooth and easy to bundle. It is. Such an effect becomes higher by repeatedly using the hair cosmetic composition of the present invention, and is maintained for a long time.
  • the duration of this continuous use is the power that varies depending on the composition, dosage form, amount used, and the quality of the hair to be applied. Wash away lotion etc. If the type is not used, it is preferable to use it once a day for 1 week or more. In addition, it is more preferable to use a wash and flow type and a wash and flow type.
  • Hair styling was prepared by the composition shown in Table 1 and the following production method.
  • Example 1 the effect of imparting a straight feeling and the goodness of unity were evaluated. 20-year-old Japanese wrinkled hair without chemical treatment such as cold perm or bleach
  • hair bundles of about 30 cm and 10 g of female hair wash with a regular commercial shampoo, wipe off the moisture with a towel, and then use 1 bundle as a blank. 2g of this sample was applied. Then, both hair bundles were dried with a drier while combing with a comb for 1 minute. The process from shampooing to drying was repeated 5 times.
  • Fig. 1 shows the state of the hair bundle before treatment and the state of the hair bundle after the sample has been repeatedly applied and treated five times.
  • Example 1 As is apparent from FIG. 1, the hair styling material of Example 1 is clearly superior to the blank in comparison with the blank, and has an excellent effect of imparting a feeling of straightness and a small bunch of hair bundles. It turns out that it becomes good.
  • a shampoo was prepared with the following composition and production method. (Composition)
  • the shampoo of Example 6 was an excellent shampoo that was excellent in the effect of preventing hair damage, had a good slate feeling, and had a smooth, smooth and smooth hair.
  • a hair treatment lotion was prepared with the following composition and production method.
  • the hair treatment lotion of Example 7 obtained as described above can be used effectively in hair in the form of a mist and has an excellent effect of preventing hair damage, good straightness, glossiness It had an excellent effect as a hair treatment lotion with the effect of making hair smooth and smooth. In addition, when used every day, it felt more straight.
  • a hair conditioner was prepared with the composition and production method shown below. (Composition)
  • the compounding amount in the prescription is a value for the amino-modified silicone pure.
  • A is added to B and uniformly emulsified and mixed, and after cooling, (13) dissolved in the remainder of components (1), (12), (14), and (15) is added.
  • the hair conditioner of Example 8 is excellent in the effect of preventing hair damage, excellent in the effect of imparting a straight feeling, and excellent in effect as a hair conditioner having a high effect of making the hair smooth and coherent. It was what had. In addition, it was a good one that felt more straight when used every day.
  • a frog was prepared by the composition and production method shown below. (Composition)
  • Ingredients (1), (2) and (6) are mixed uniformly into a part of ingredient (13).
  • F was filled into a container to obtain a frog.
  • the hair frog of Example 9 is excellent in the effect of preventing hair damage, has an excellent straight feeling, is glossy, smooth and coherent hair. It was expensive.
  • the present invention it is possible to provide a hair cosmetic composition that is excellent in the effect of preventing hair damage while giving a straight feeling, and is excellent in the effect of making the hair smooth and easy to bundle.
  • FIG. 1 is a photograph comparing the state of the hair bundle before and after the treatment with the hair styling prepared in Example 1 with the untreated hair bundle (blank).

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
PCT/JP2006/305656 2005-03-31 2006-03-22 毛髪化粧料 WO2006109458A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2007512451A JP5243024B2 (ja) 2005-03-31 2006-03-22 毛髪化粧料
CN2006800101561A CN101151012B (zh) 2005-03-31 2006-03-22 毛发化妆品
HK08110489.9A HK1118717B (en) 2005-03-31 2006-03-22 Hair cosmetic

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005-101615 2005-03-31
JP2005101615 2005-03-31

Publications (1)

Publication Number Publication Date
WO2006109458A1 true WO2006109458A1 (ja) 2006-10-19

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ID=37086749

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2006/305656 WO2006109458A1 (ja) 2005-03-31 2006-03-22 毛髪化粧料

Country Status (5)

Country Link
JP (1) JP5243024B2 (enrdf_load_stackoverflow)
KR (1) KR101267579B1 (enrdf_load_stackoverflow)
CN (1) CN101151012B (enrdf_load_stackoverflow)
TW (1) TW200724165A (enrdf_load_stackoverflow)
WO (1) WO2006109458A1 (enrdf_load_stackoverflow)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220074426A (ko) 2020-11-27 2022-06-03 주식회사 엘지생활건강 모발의 부스스함을 예방 또는 개선하기 위한 모발 화장료 조성물
EP4319596A4 (en) * 2021-04-05 2025-03-19 EasyFix Hair Design Ltd. SELF-CURING ACRYLIC FORMULATIONS WITH N-ACETYLCYSTEINE FOR HAIR STRAIGHTENING

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53130442A (en) * 1977-04-15 1978-11-14 Matsushita Electric Works Ltd Hair conditioning lotion composition
WO1988008297A1 (en) * 1987-04-23 1988-11-03 Wella Aktiengesellschaft Agent for durable deformation or removal of hair
JPH05178728A (ja) * 1991-12-27 1993-07-20 Kao Corp ２剤式毛髪処理剤組成物及び毛髪処理方法
JPH07138132A (ja) * 1993-11-15 1995-05-30 Kao Corp 毛髪化粧料
JP2004143096A (ja) * 2002-10-24 2004-05-20 Kose Corp ヘアリンス組成物
JP2004161683A (ja) * 2002-11-13 2004-06-10 Kose Corp ヘアコンディショニング組成物
JP2004231606A (ja) * 2003-01-31 2004-08-19 Kose Corp 整髪料組成物
JP2004300081A (ja) * 2003-03-31 2004-10-28 Kose Corp 毛髪化粧料

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53130442A (en) * 1977-04-15 1978-11-14 Matsushita Electric Works Ltd Hair conditioning lotion composition
WO1988008297A1 (en) * 1987-04-23 1988-11-03 Wella Aktiengesellschaft Agent for durable deformation or removal of hair
JPH05178728A (ja) * 1991-12-27 1993-07-20 Kao Corp ２剤式毛髪処理剤組成物及び毛髪処理方法
JPH07138132A (ja) * 1993-11-15 1995-05-30 Kao Corp 毛髪化粧料
JP2004143096A (ja) * 2002-10-24 2004-05-20 Kose Corp ヘアリンス組成物
JP2004161683A (ja) * 2002-11-13 2004-06-10 Kose Corp ヘアコンディショニング組成物
JP2004231606A (ja) * 2003-01-31 2004-08-19 Kose Corp 整髪料組成物
JP2004300081A (ja) * 2003-03-31 2004-10-28 Kose Corp 毛髪化粧料

Also Published As

Publication number Publication date
TW200724165A (en) 2007-07-01
KR101267579B1 (ko) 2013-05-23
JPWO2006109458A1 (ja) 2008-10-16
KR20080007341A (ko) 2008-01-18
TWI362944B (enrdf_load_stackoverflow) 2012-05-01
HK1118717A1 (zh) 2009-02-20
CN101151012B (zh) 2010-06-16
CN101151012A (zh) 2008-03-26
JP5243024B2 (ja) 2013-07-24

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