WO2006075041A1 - Un material cristalino microporoso, zeolita itq-33, procedimiento de preparación y uso - Google Patents
Un material cristalino microporoso, zeolita itq-33, procedimiento de preparación y uso Download PDFInfo
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- WO2006075041A1 WO2006075041A1 PCT/ES2006/070002 ES2006070002W WO2006075041A1 WO 2006075041 A1 WO2006075041 A1 WO 2006075041A1 ES 2006070002 W ES2006070002 W ES 2006070002W WO 2006075041 A1 WO2006075041 A1 WO 2006075041A1
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- Prior art keywords
- crystalline material
- geo
- synthesis mixture
- oxide
- crystals
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- 239000002178 crystalline material Substances 0.000 title claims abstract description 56
- 239000010457 zeolite Substances 0.000 title claims description 10
- 229910021536 Zeolite Inorganic materials 0.000 title claims description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 8
- 238000002360 preparation method Methods 0.000 title description 6
- 239000000203 mixture Substances 0.000 claims abstract description 71
- 238000000034 method Methods 0.000 claims abstract description 37
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 238000002441 X-ray diffraction Methods 0.000 claims abstract description 5
- 238000001354 calcination Methods 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims abstract description 3
- 229910005793 GeO 2 Inorganic materials 0.000 claims description 56
- 230000015572 biosynthetic process Effects 0.000 claims description 45
- 238000003786 synthesis reaction Methods 0.000 claims description 45
- 239000013078 crystal Substances 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 17
- 238000011084 recovery Methods 0.000 claims description 14
- 150000001768 cations Chemical class 0.000 claims description 12
- PYIHTIJNCRKDBV-UHFFFAOYSA-L trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;dichloride Chemical class [Cl-].[Cl-].C[N+](C)(C)CCCCCC[N+](C)(C)C PYIHTIJNCRKDBV-UHFFFAOYSA-L 0.000 claims description 11
- GYLUMIIRFKDCKI-UHFFFAOYSA-L trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;dihydroxide Chemical group [OH-].[OH-].C[N+](C)(C)CCCCCC[N+](C)(C)C GYLUMIIRFKDCKI-UHFFFAOYSA-L 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 8
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052732 germanium Inorganic materials 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 230000010933 acylation Effects 0.000 claims description 3
- 238000005917 acylation reaction Methods 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 230000029936 alkylation Effects 0.000 claims description 3
- 238000005804 alkylation reaction Methods 0.000 claims description 3
- 238000004523 catalytic cracking Methods 0.000 claims description 3
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 239000005416 organic matter Substances 0.000 claims description 3
- 238000009331 sowing Methods 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 230000008030 elimination Effects 0.000 claims description 2
- 238000003379 elimination reaction Methods 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 238000005453 pelletization Methods 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 150000005621 tetraalkylammonium salts Chemical class 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 230000002194 synthesizing effect Effects 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 abstract 2
- 235000013305 food Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 239000007787 solid Substances 0.000 description 10
- 230000003068 static effect Effects 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 9
- 239000004809 Teflon Substances 0.000 description 9
- 229920006362 Teflon® Polymers 0.000 description 9
- 239000012153 distilled water Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 9
- 238000001914 filtration Methods 0.000 description 9
- 229950002932 hexamethonium Drugs 0.000 description 9
- 229950006187 hexamethonium bromide Drugs 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- FAPSXSAPXXJTOU-UHFFFAOYSA-L trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;dibromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C FAPSXSAPXXJTOU-UHFFFAOYSA-L 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 238000002425 crystallisation Methods 0.000 description 6
- 230000008025 crystallization Effects 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- -1 metal ions Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000002447 crystallographic data Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910017855 NH 4 F Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002892 organic cations Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
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- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
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- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
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- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
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- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
Definitions
- the present application relates to a new microporous crystalline material, ITQ-33, to its preparation process and its use in the catalytic conversion of organic compounds.
- Zeolites are porous crystalline aluminosilicates that have found important applications as catalysts, adsorbents and ion exchangers. Many of these zeolitic materials have well-defined structures that form channels and cavities inside them of uniform size and shape that allow the adsorption of certain molecules, while preventing the passage into the glass of other molecules of size too large to diffuse through of the pores. This characteristic gives these materials molecular sieve properties. These molecular sieves can include in the Si network and other elements of the IHA group of the periodic system, all of them tetrahedrally coordinated, the tetrahedra being joined by their vertices through oxygen forming a three-dimensional network.
- the negative charge generated by the elements of the HIA group in network positions is compensated by the presence in the cation crystal, such as alkaline or alkaline earth.
- cation crystal such as alkaline or alkaline earth.
- One type of cation can be totally or partially exchanged for another type of cations by ion exchange techniques, thus being able to vary the properties of a given silicate by selecting the desired cations.
- zeolites have been synthesized in the presence of an organic molecule that acts as a structure directing agent.
- Organic molecules that act as structure directing agents generally contain nitrogen in their composition, and can give rise to stable organic cations in the reaction medium.
- the mobilization of the silica can be carried out in the presence of OH " groups and basic medium, which can be introduced as hydroxide of the same ADE, such as tetrapropylammonium hydroxide in the case of zeolite ZSM-5. Description of the invention
- the present invention relates to a new microporous crystalline material ITQ-33 having a chemical composition in calcined form represented by the formula:
- X 2 O 3 n YO 2 : m GeO 2 in which (n + m) is at least 5, X is a trivalent element, Y corresponds to one or several tetravalent elements other than Ge, and the Y / Ge ratio is greater than 1, and has an X-ray diffraction pattern whose main lines for its synthesized form without calcining are
- the new porous crystalline material can be obtained therefore it is absence of germanium.
- This new material called ITQ-33, both in its calcined and synthesized form without calcining has an X-ray diffraction pattern that is different from other known zeolitic materials and whose most important diffraction lines are given in Table 1 for calcined form.
- Table 1
- the crystalline material preferably has a composition in its calcined anhydrous form, represented by:
- X 2 O 3 n YO 2 : m GeO 2 in which (n + m) is at least 5, and the value n / m is at least 1,
- X is one or more trivalent elements selected from the group of Al, B , In, Ga, Fe and Cr; and
- Y is one or more tetravalent elements selected from Si, Sn, Ti, V.
- the crystalline material has the formula indicated above in calcined form, in which X is selected from B, Al and a mixture of both; and Y is Yes.
- the organic component of the material as it has been synthesized can be removed, for example by extraction or by heat treatment by heating at a temperature above 250 ° C for a period of time between 2 minutes and 25 hours.
- the compensation cations in the material in its uncalcined form, or after thermal treatment, can be exchanged in the case of being present, by other cations such as metal ions, H + and precursors of H + such as NH4 + .
- cations that can be introduced by ion exchange those that can have a positive role in the activity of the material as a catalyst are preferred, and more specifically cations such as H + , rare earth cations, and group VIII metals are preferred, as well as Group IIA, HIA, VAT, VA, IB, HB, HIB, IVB, VB, VIIB of the periodic table of the elements.
- the crystalline material of the present invention can also be intimately combined with hydrogenating-dehydrogenating components such as platinum, palladium, nickel, rhenium, cobalt, tungsten, molybdenum, vanadium, chromium, manganese, iron and combinations thereof.
- these elements can be carried out in the crystallization stage, by exchange (if applicable), and / or by impregnation or by physical mixing. These elements can be introduced in their cationic form and / or from salts or other compounds that by decomposition generate the metal component or oxide in its appropriate catalytic form.
- the present invention also relates to a process for the preparation of the crystalline material defined above, comprising at least:
- the process for the preparation of the crystalline material defined above comprises at least:
- R / (YO 2 ) 0.1-1.0 A further preferred embodiment of the process comprises:
- the process for the preparation of the crystalline material defined above comprises at least: - preparing a synthesis mixture comprising at least:
- the molar ratios of preferred oxides are: YO 2 / X 2 O 3 greater than 7
- Another additional preferred embodiment of the process comprises: preparing a synthesis mixture comprising at least H2O, a source of one or more trivalent elements X; a source of one or more tetravalent elements Y, Ge oxide, and an organic compound as the structure directing agent (R),
- the molar ratios of oxides are:
- ITQ-33 zeolite crystals (up to 20% by weight) that act as sowing can be added to the synthesis mixture.
- the organic compound used as the structure directing agent is preferably selected from an amine and a tetraalkylammonium salt, preferably the hydroxide.
- the process of the present invention when it is intended to obtain the calcined crystalline material, comprises a stage of elimination of the organic matter occluded inside the material, which can be carried out by extraction and / or heat treatment at temperatures above 250 ° C for a period of time between 2 minutes and 25 hours. According to a further preferred embodiment of the process of the present invention, it comprises;
- SiO 2 / GeO 2 greater than l SiO 2 / GeO 2 greater than l, - maintaining the synthesis mixture at a temperature between 80 and 200 0 C until the crystals of the porous crystalline material form; and - recovery of the crystalline material.
- the crystallization of ITQ-33 can be carried out in static or stirring, in autoclaves at a temperature between 80 and 200 ° C, at times sufficient to achieve crystallization, for example between 12 hours and 60 days.
- ITQ-33 crystals are separated from the mother liquors, and recovered. It should be taken into account that the components of the synthesis mixture can come from different sources, and depending on these, crystallization times and conditions may vary.
- ITQ-33 crystals can be added as seeds, in amounts of up to 20% by weight with respect to the total oxides, to the synthesis mixture. These can be added before or during the crystallization of ITQ-33.
- the material produced by this invention can be pelletized in accordance with known techniques, and can be used in catalytic cracking of hydrocarbons, catalytic hydro-cracking of hydrocarbons, alkylation of aromatics with olefins and in processes of esterification, acylation, reaction of aniline with formaldehyde in its acid form and / or exchanged with suitable cations.
- the material is present as a component of other catalysts.
- the present invention further relates to a method for converting feeds formed by organic compounds, characterized in that it comprises contacting said feedstock with an active form of the porous crystalline material of the invention.
- said method is selected from catalytic cracking of hydrocarbons, catalytic hydro-cracking of hydrocarbons, alkylation of aromatics with olefins, esterification, acylation and reaction of aniline with formaldehyde, and comprises pelletizing the material in a form selected from its acid form, exchanged with cations and a combination of both. More preferably, said material is present as a catalyst component.
- the gel is heated for 4 days in steel autoclaves with an internal Teflon sheath at 175 ° C in static.
- the solid obtained after filtering, washing with distilled water and drying at 100 ° C is ITQ-33.
- the material is calcined at 540 ° C for 3 hours in air flow to remove organic matter.
- the powder X-ray diffraction pattern of the solid obtained coincides with the values in Table 1.
- the gel is heated for 14 days in steel autoclaves with an internal Teflon sheath at 175 ° C in static.
- the solid obtained after filtering, washing with distilled water and drying at 100 ° C is ITQ-33.
- the gel is heated for 5 days in steel autoclaves with an internal Teflon sheath at 175 ° C in static.
- the solid obtained after filtering, washing with distilled water and drying at 100 ° C is the ITQ-33 zeolite.
- the gel is heated for 8 days in steel autoclaves with an internal Teflon sheath at 175 ° C in static.
- the solid obtained after filtering, washing with distilled water and drying at 100 ° C is the ITQ-33 zeolite.
- Example 6 0.174 g of GeO 2 are dissolved in 0.317 g of hexamethonium hydroxide solution (18.3% weight) and 0.830 g of hexamethonium bromide solution (50% weight). 6.9 mg of Al 2 O 3 and 0.513 g of Ludox AS-40 are added in the solution obtained, and it is kept under stirring, allowing it to evaporate until the mixture reaches the composition: 0.67 SiO 2 : 0.33 GeO 2 : 0.020 Al 2 O 3 : 0.10 R (OH) 2 : 0.16 R (Br) 2 : 2.78 H 2 O where R is hexamethonium.
- the gel is heated for 25 days in steel autoclaves with an internal Teflon sheath at 150 ° C in static.
- the solid obtained after filtering, washing with distilled water and drying at 100 ° C is the ITQ-33 zeolite.
- Example 8 In 0.320 g of hexamethonium hydroxide solution (18.3% by weight) and 0.823 g of hexamethonium bromide solution (50% by weight) 0.174 g of GeO 2 is dissolved. 0.311 g of H 3 BO 3 solution (5% weight) and 0.507 g of Ludox AS-40 are added in the obtained solution, and it is kept under stirring, allowing it to evaporate until the mixture reaches the composition: 0.67 SiO 2 : 0.33 GeO 2 : 0.025 B 2 O 3 : 0.10 R (OH) 2 : 0.15 R (Br) 2 : 4.7 H 2 O where R is hexamethonium.
- ITQ-33 crystals 0.018 g are added and the mixture is homogenized.
- the gel is heated at 175 ° C in static for 20 hours in steel autoclaves with an internal Teflon sheath.
- the solid obtained after filtering, washing with distilled water and drying at 100 ° C is ITQ-33.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06701611A EP1847510A4 (en) | 2005-01-17 | 2006-01-17 | MICROPOROUS CRYSTALLINE MATERIAL, ITQ-33 ZEOLITE, PROCESS FOR PREPARING THE SAME, AND USE THEREOF |
CA2637272A CA2637272C (en) | 2005-01-17 | 2006-01-17 | Microporous crystalline material, zeolite itq-33, method of preparation and use |
JP2007550803A JP5222563B2 (ja) | 2005-01-17 | 2006-01-17 | 多孔質結晶性材料、ゼオライトitq−33の調製法および使用法 |
AU2006205762A AU2006205762A1 (en) | 2005-01-17 | 2006-01-17 | Microporous crystalline material, zeolite ITQ-33, preparation method thereof and use of same |
CN2006800024936A CN101124162B (zh) | 2005-01-17 | 2006-01-17 | 微孔结晶材料、沸石itq-33、及其制备方法和用途 |
US11/795,432 US7947252B2 (en) | 2005-01-17 | 2006-01-17 | Microporous crystalline material, zeolite ITQ-33, method of preparation and use |
IL184237A IL184237A0 (en) | 2005-01-17 | 2007-06-26 | Microporous crystalline material, zeolite itq-33, preparation method thereof and use of same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ESP200500120 | 2005-01-17 | ||
ES200500120A ES2259537B1 (es) | 2005-01-17 | 2005-01-17 | Sintesis de la zeolita itq-33. |
Publications (1)
Publication Number | Publication Date |
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WO2006075041A1 true WO2006075041A1 (es) | 2006-07-20 |
Family
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PCT/ES2006/070002 WO2006075041A1 (es) | 2005-01-17 | 2006-01-17 | Un material cristalino microporoso, zeolita itq-33, procedimiento de preparación y uso |
Country Status (10)
Country | Link |
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US (1) | US7947252B2 (es) |
EP (1) | EP1847510A4 (es) |
JP (1) | JP5222563B2 (es) |
CN (1) | CN101124162B (es) |
AU (1) | AU2006205762A1 (es) |
CA (1) | CA2637272C (es) |
ES (1) | ES2259537B1 (es) |
IL (1) | IL184237A0 (es) |
WO (1) | WO2006075041A1 (es) |
ZA (1) | ZA200706865B (es) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008014904A1 (en) * | 2006-07-31 | 2008-02-07 | Universidad Politécnica De Valencia | Alkylation of aromatic compounds using zeolite itq-33 |
WO2008014921A2 (en) * | 2006-08-01 | 2008-02-07 | Universidad Politécnica De Valencia | Hydrocracking of organic compounds using zeolite itq-33 |
WO2008014920A2 (en) * | 2006-08-01 | 2008-02-07 | Universidad Politecnica De Valencia | Catalytic cracking of organic compounds using zeolite itq-33 |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2284379B1 (es) * | 2006-02-28 | 2008-11-01 | Universidad Politecnica De Valencia | Un material cristalino microporoso, zeolita itq-37, procedimiento de preparacion y uso. |
CA2671481C (en) * | 2006-12-07 | 2013-11-26 | Exxonmobil Research And Engineering Company | Itq-34, new crystalline microporous material |
US9359216B2 (en) | 2010-11-23 | 2016-06-07 | Reliance Industries Limited | Method for the preparation of MWW type zeolite |
BRPI1102638B1 (pt) * | 2011-06-16 | 2020-10-20 | Universidade Federal Do Rio Grande Do Sul | zeólita e materiais mesoporosos organizados como carga para a formulação de compostos de borracha, borracha termoplástica, plástico e fabricação de produtos |
JP6060974B2 (ja) * | 2011-08-04 | 2017-01-18 | エクソンモービル ケミカル パテンツ インコーポレイテッド | Emm−23分子篩材料、その合成および使用 |
ES2430404B1 (es) * | 2012-04-18 | 2014-09-29 | Consejo Superior De Investigaciones Científicas (Csic) | Material ITQ-49, su procedimiento de obtención y su uso |
SG11201911569RA (en) * | 2017-07-27 | 2020-02-27 | Exxonmobil Res & Eng Co | Emm-23 materials and processes and uses thereof |
CN113955770B (zh) * | 2021-11-11 | 2023-03-24 | 南京大学 | 一种超大孔itt结构硅酸盐分子筛材料及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2204257A1 (es) * | 2001-11-30 | 2004-04-16 | Universidad Politecnica De Valencia. Consejo Superior De Investigaciones Cientificas | Sintesis de itq-21 en ausencia de iones fluoruro. |
ES2217962A1 (es) * | 2003-02-14 | 2004-11-01 | Universidad Politecnica De Valencia | Material cristalino poroso zeolita itq-24, su procedimiento de preparacion y su uso en la conversion catalitica de componentes organicos. |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4676958A (en) * | 1985-03-06 | 1987-06-30 | Chevron Research Company | Preparation of crystalline zeolites using magadiite |
US5141729A (en) * | 1988-04-08 | 1992-08-25 | Mobil Oil Corporation | Synthesis of crystalline metalloaluminophosphate composition |
GB9116668D0 (en) * | 1991-08-01 | 1991-09-18 | British Petroleum Co Plc | Novel zeolite-type material |
US6043179A (en) * | 1997-08-13 | 2000-03-28 | California Institute Of Technology | Zeolite CIT-5 and method of making |
ES2186487B1 (es) * | 2000-10-11 | 2004-01-16 | Univ Valencia Politecnica | Zeolita itq-15. |
US6471941B1 (en) * | 2001-05-29 | 2002-10-29 | Exxonmobil Research And Engineering Company | Synthetic porous crystalline material ITQ-13, its synthesis and use |
ES2196963B1 (es) * | 2001-07-03 | 2005-02-16 | Universidad Politecnica De Valencia | Sintesis de itq-17 en ausencia de iones fluoruro. |
US6899628B2 (en) * | 2001-07-13 | 2005-05-31 | Game Account Limited | System and method for providing game event management to a user of a gaming application |
US6787124B2 (en) * | 2002-03-15 | 2004-09-07 | Exxonmobil Research And Engineering Company | Synthetic porous crystalline material, EMM-1, its synthesis and use |
US6723300B2 (en) * | 2002-03-15 | 2004-04-20 | Exxonmobil Research And Engineering Company | Synthesis of porous crystalline materials in fluoride media |
FR2852024B1 (fr) * | 2003-03-05 | 2005-04-15 | Inst Francais Du Petrole | Solide cristallise im-10 et son procede de preparation |
FR2860224B1 (fr) * | 2003-09-26 | 2006-06-02 | Inst Francais Du Petrole | Solide cristallise im-12 et son procede de preparation |
FR2908127B1 (fr) * | 2006-11-07 | 2009-02-06 | Inst Francais Du Petrole | Solide cristallise im-15 et son procede de preparation |
-
2005
- 2005-01-17 ES ES200500120A patent/ES2259537B1/es not_active Expired - Fee Related
-
2006
- 2006-01-17 US US11/795,432 patent/US7947252B2/en not_active Expired - Fee Related
- 2006-01-17 AU AU2006205762A patent/AU2006205762A1/en not_active Abandoned
- 2006-01-17 CA CA2637272A patent/CA2637272C/en not_active Expired - Fee Related
- 2006-01-17 EP EP06701611A patent/EP1847510A4/en not_active Withdrawn
- 2006-01-17 CN CN2006800024936A patent/CN101124162B/zh not_active Expired - Fee Related
- 2006-01-17 WO PCT/ES2006/070002 patent/WO2006075041A1/es active Application Filing
- 2006-01-17 JP JP2007550803A patent/JP5222563B2/ja not_active Expired - Fee Related
-
2007
- 2007-06-26 IL IL184237A patent/IL184237A0/en unknown
- 2007-08-16 ZA ZA200706865A patent/ZA200706865B/xx unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2204257A1 (es) * | 2001-11-30 | 2004-04-16 | Universidad Politecnica De Valencia. Consejo Superior De Investigaciones Cientificas | Sintesis de itq-21 en ausencia de iones fluoruro. |
ES2217962A1 (es) * | 2003-02-14 | 2004-11-01 | Universidad Politecnica De Valencia | Material cristalino poroso zeolita itq-24, su procedimiento de preparacion y su uso en la conversion catalitica de componentes organicos. |
Non-Patent Citations (2)
Title |
---|
MATHIEU Y. ET AL.: "Synthesis and characterization of IM-10: a new microporous silicogermanate with a novel topology", MICROPOROUS AND MESOPOROUS MATERIALS, vol. 75, 2004, pages 13 - 22, XP008119964 * |
See also references of EP1847510A4 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008014904A1 (en) * | 2006-07-31 | 2008-02-07 | Universidad Politécnica De Valencia | Alkylation of aromatic compounds using zeolite itq-33 |
ES2302442A1 (es) * | 2006-07-31 | 2008-07-01 | Universidad Politecnica De Valencia | Aquilacion de compuestos aromaticos utilizando la zeolita itq-33. |
WO2008014921A2 (en) * | 2006-08-01 | 2008-02-07 | Universidad Politécnica De Valencia | Hydrocracking of organic compounds using zeolite itq-33 |
WO2008014920A2 (en) * | 2006-08-01 | 2008-02-07 | Universidad Politecnica De Valencia | Catalytic cracking of organic compounds using zeolite itq-33 |
WO2008014920A3 (en) * | 2006-08-01 | 2008-04-10 | Univ Valencia Politecnica | Catalytic cracking of organic compounds using zeolite itq-33 |
WO2008014921A3 (en) * | 2006-08-01 | 2008-04-24 | Univ Valencia Politecnica | Hydrocracking of organic compounds using zeolite itq-33 |
ES2303449A1 (es) * | 2006-08-01 | 2008-08-01 | Universidad Politecnica De Valencia | Hidrocraqueo de compuestos organicos utilizando la zeolita itq-33. |
ES2303448A1 (es) * | 2006-08-01 | 2008-08-01 | Universidad Politecnica De Valencia | Craqueo catalitico de compuestos organicos utilizando la seolita itq-33. |
Also Published As
Publication number | Publication date |
---|---|
CA2637272C (en) | 2014-12-30 |
CA2637272A1 (en) | 2006-07-20 |
JP5222563B2 (ja) | 2013-06-26 |
ZA200706865B (en) | 2008-09-25 |
CN101124162A (zh) | 2008-02-13 |
US20090124484A1 (en) | 2009-05-14 |
CN101124162B (zh) | 2011-02-16 |
JP2008526679A (ja) | 2008-07-24 |
EP1847510A1 (en) | 2007-10-24 |
EP1847510A4 (en) | 2011-03-02 |
US7947252B2 (en) | 2011-05-24 |
AU2006205762A1 (en) | 2006-07-20 |
ES2259537B1 (es) | 2007-11-01 |
ES2259537A1 (es) | 2006-10-01 |
IL184237A0 (en) | 2007-10-31 |
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