WO2006071793A1 - Procede de desulfurisation oxydante - Google Patents

Procede de desulfurisation oxydante Download PDF

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Publication number
WO2006071793A1
WO2006071793A1 PCT/US2005/046849 US2005046849W WO2006071793A1 WO 2006071793 A1 WO2006071793 A1 WO 2006071793A1 US 2005046849 W US2005046849 W US 2005046849W WO 2006071793 A1 WO2006071793 A1 WO 2006071793A1
Authority
WO
WIPO (PCT)
Prior art keywords
sulfur
oxidation
catalyst
distillate
ppm
Prior art date
Application number
PCT/US2005/046849
Other languages
English (en)
Inventor
Kenneth P. Keckler
Janet L. Yedinak
Russell R. Simpson
Jeffrey T. Miller
Original Assignee
Bp Corporation North America Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to MX2007007802A priority Critical patent/MX2007007802A/es
Priority to BRPI0519500-4A priority patent/BRPI0519500A2/pt
Priority to NZ555486A priority patent/NZ555486A/en
Priority to CN2005800453208A priority patent/CN101094908B/zh
Priority to EP05855415A priority patent/EP1841838A1/fr
Priority to AU2005322059A priority patent/AU2005322059B2/en
Application filed by Bp Corporation North America Inc. filed Critical Bp Corporation North America Inc.
Priority to JP2007549514A priority patent/JP2008525624A/ja
Priority to EA200701421A priority patent/EA011964B1/ru
Priority to CA002589399A priority patent/CA2589399A1/fr
Priority to US11/722,138 priority patent/US20080308463A1/en
Publication of WO2006071793A1 publication Critical patent/WO2006071793A1/fr
Priority to NO20073938A priority patent/NO20073938L/no

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Treating Waste Gases (AREA)

Abstract

L'invention concerne un procédé permettant de réduire la teneur en soufre et/ou en azote dans une charge de distillat en vue de la production d'un carburant de transport de raffinerie ou de constituants de mélange pour carburant de transport de raffinerie, et consistant à mettre la charge en contact avec un gaz contenant de l'oxygène dans une zone d'oxydation/adsorption dans des conditions d'oxydation en présence d'un catalyseur d'oxydation renfermant une composition contenant du titane, les espèces sulfureuses étant converties en sulfones et/ou en sulfoxydes, lesquels sont adsorbés sur la composition contenant du titane.
PCT/US2005/046849 2004-12-29 2005-12-22 Procede de desulfurisation oxydante WO2006071793A1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
BRPI0519500-4A BRPI0519500A2 (pt) 2004-12-29 2005-12-22 processo para a dessulfurizaÇço de uma carga de alimentaÇço de destilado para produzir combustÍvel de transporte de refinaria ou componentes de mistura para combustÍvel de transporte de refinaria
NZ555486A NZ555486A (en) 2004-12-29 2005-12-22 Preparation of hydrocarbons through a liquid phase oxidative desulphurisation process utilising a solid titanium catalyst
CN2005800453208A CN101094908B (zh) 2004-12-29 2005-12-22 氧化脱硫方法
EP05855415A EP1841838A1 (fr) 2004-12-29 2005-12-22 Procede de desulfurisation oxydante
AU2005322059A AU2005322059B2 (en) 2004-12-29 2005-12-22 Oxidative desulfurization process
MX2007007802A MX2007007802A (es) 2004-12-29 2005-12-22 Proceso de desulfuracion oxidativa.
JP2007549514A JP2008525624A (ja) 2004-12-29 2005-12-22 酸化的脱硫方法
EA200701421A EA011964B1 (ru) 2004-12-29 2005-12-22 Способ десульфирования дистиллятного сырья
CA002589399A CA2589399A1 (fr) 2004-12-29 2005-12-22 Procede de desulfurisation oxydante
US11/722,138 US20080308463A1 (en) 2004-12-29 2005-12-22 Oxidative Desulfurization Process
NO20073938A NO20073938L (no) 2004-12-29 2007-07-27 Oksidativ desulfuriseringsfremgangsmate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US64003904P 2004-12-29 2004-12-29
US60/640,039 2004-12-29

Publications (1)

Publication Number Publication Date
WO2006071793A1 true WO2006071793A1 (fr) 2006-07-06

Family

ID=36282805

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/046849 WO2006071793A1 (fr) 2004-12-29 2005-12-22 Procede de desulfurisation oxydante

Country Status (15)

Country Link
US (1) US20080308463A1 (fr)
EP (1) EP1841838A1 (fr)
JP (1) JP2008525624A (fr)
KR (1) KR20070091297A (fr)
CN (1) CN101094908B (fr)
AU (1) AU2005322059B2 (fr)
BR (1) BRPI0519500A2 (fr)
CA (1) CA2589399A1 (fr)
EA (1) EA011964B1 (fr)
MX (1) MX2007007802A (fr)
NO (1) NO20073938L (fr)
NZ (1) NZ555486A (fr)
UA (1) UA88346C2 (fr)
WO (1) WO2006071793A1 (fr)
ZA (1) ZA200704539B (fr)

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JP2008106172A (ja) * 2006-10-26 2008-05-08 Idemitsu Kosan Co Ltd 脱硫装置、その方法、燃料電池用燃料ガスの製造装置、および、燃料電池システム
JP2009079155A (ja) * 2007-09-26 2009-04-16 Toshiba Fuel Cell Power Systems Corp 液体燃料脱硫装置及び液体燃料脱硫システム
WO2013009440A1 (fr) 2011-07-12 2013-01-17 Saudi Arabian Oil Company Procédé pour la conversion de sulfone par des super-donneurs d'électrons
US8658027B2 (en) 2010-03-29 2014-02-25 Saudi Arabian Oil Company Integrated hydrotreating and oxidative desulfurization process
WO2014052951A1 (fr) 2012-09-28 2014-04-03 Saudi Arabian Oil Company Procédé pour réduire la teneur en soufre d'hydrocarbures contenant du soufre oxydé
US8741127B2 (en) 2010-12-14 2014-06-03 Saudi Arabian Oil Company Integrated desulfurization and denitrification process including mild hydrotreating and oxidation of aromatic-rich hydrotreated products
US8741128B2 (en) 2010-12-15 2014-06-03 Saudi Arabian Oil Company Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction
US8790508B2 (en) 2010-09-29 2014-07-29 Saudi Arabian Oil Company Integrated deasphalting and oxidative removal of heteroatom hydrocarbon compounds from liquid hydrocarbon feedstocks
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
US8920635B2 (en) 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US8980080B2 (en) 2010-03-16 2015-03-17 Saudi Arabian Oil Company System and process for integrated oxidative desulfurization, desalting and deasphalting of hydrocarbon feedstocks
US9296960B2 (en) 2010-03-15 2016-03-29 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US9555396B2 (en) 2011-07-31 2017-01-31 Saudi Arabian Oil Company Process for oxidative desulfurization with integrated sulfone decomposition
US9574144B2 (en) 2010-09-07 2017-02-21 Saudi Arabian Oil Company Process for oxidative desulfurization and denitrogenation using a fluid catalytic cracking (FCC) unit
US9574142B2 (en) 2010-09-07 2017-02-21 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone management by gasification
US9574143B2 (en) 2010-09-07 2017-02-21 Saudi Arabian Oil Company Desulfurization and sulfone removal using a coker
US9598647B2 (en) 2010-09-07 2017-03-21 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone disposal using solvent deasphalting
US9719029B2 (en) 2012-11-09 2017-08-01 Saudi Arabian Oil Company Oxidative desulfurization process and system using gaseous oxidant-enhanced feed
US9896629B2 (en) 2014-07-25 2018-02-20 Saudi Arabian Oil Company Integrated process to produce asphalt, petroleum green coke, and liquid and gas coking unit products
US10035960B2 (en) 2010-09-07 2018-07-31 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone management by gasification
US10081770B2 (en) 2010-09-07 2018-09-25 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone disposal using solvent deasphalting
US10087377B2 (en) 2010-09-07 2018-10-02 Saudi Arabian Oil Company Oxidative desulfurization of oil fractions and sulfone management using an FCC
US10093872B2 (en) 2010-09-07 2018-10-09 Saudi Arabian Oil Company Oxidative desulfurization of oil fractions and sulfone management using an FCC
US10093871B2 (en) 2010-09-07 2018-10-09 Saudi Arabian Oil Company Desulfurization and sulfone removal using a coker
US10093870B2 (en) 2010-09-07 2018-10-09 Saudi Arabian Oil Company Desulfurization and sulfone removal using a coker
US10125319B2 (en) 2011-07-31 2018-11-13 Saudi Arabian Oil Company Integrated process to produce asphalt and desulfurized oil
US10647926B2 (en) 2010-12-15 2020-05-12 Saudi Arabian Oil Company Desulfurization of hydrocarbon feed using gaseous oxidant
RU2803748C1 (ru) * 2022-10-12 2023-09-19 Общество с ограниченной ответственностью "Безводородная сероочистка" Состав катализатора для аэробного окислительного обессеривания светлых нефтяных фракций

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EP3078726A1 (fr) 2007-05-03 2016-10-12 Auterra, Inc. Produit contenant un monomère et des polymères de titanyle et procédés pour les préparer
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US8888994B2 (en) * 2010-04-22 2014-11-18 The United States Of America As Represented By The Administrator Of The U.S. Environmental Protection Agency Method for deep desulphurization of hydrocarbon fuels
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JP5986203B2 (ja) 2011-07-29 2016-09-06 サウジ アラビアン オイル カンパニー 流動接触分解プロセスにおける酸化的脱硫
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BR112014009803B1 (pt) 2011-10-24 2021-07-06 Aditya Birla Nuvo Limited processo para produzir um negro de fumo modificado na superfície
KR101362939B1 (ko) * 2011-12-22 2014-02-14 에스케이이노베이션 주식회사 메탄올을 극성용매로하는 2단계 흡착을 이용한 황산화물 분리공정
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JP6142785B2 (ja) * 2013-11-27 2017-06-07 株式会社豊田中央研究所 燃料中の硫黄化合物の脱硫方法及び脱硫装置
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Cited By (33)

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Publication number Priority date Publication date Assignee Title
JP2008106172A (ja) * 2006-10-26 2008-05-08 Idemitsu Kosan Co Ltd 脱硫装置、その方法、燃料電池用燃料ガスの製造装置、および、燃料電池システム
JP2009079155A (ja) * 2007-09-26 2009-04-16 Toshiba Fuel Cell Power Systems Corp 液体燃料脱硫装置及び液体燃料脱硫システム
US9644156B2 (en) 2010-03-15 2017-05-09 Saudi Arabian Oil Company Targeted desulfurization apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US9296960B2 (en) 2010-03-15 2016-03-29 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US8980080B2 (en) 2010-03-16 2015-03-17 Saudi Arabian Oil Company System and process for integrated oxidative desulfurization, desalting and deasphalting of hydrocarbon feedstocks
US8658027B2 (en) 2010-03-29 2014-02-25 Saudi Arabian Oil Company Integrated hydrotreating and oxidative desulfurization process
US9464241B2 (en) 2010-03-29 2016-10-11 Saudi Arabian Oil Company Hydrotreating unit with integrated oxidative desulfurization
US10081770B2 (en) 2010-09-07 2018-09-25 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone disposal using solvent deasphalting
US10093872B2 (en) 2010-09-07 2018-10-09 Saudi Arabian Oil Company Oxidative desulfurization of oil fractions and sulfone management using an FCC
US10093870B2 (en) 2010-09-07 2018-10-09 Saudi Arabian Oil Company Desulfurization and sulfone removal using a coker
US10093871B2 (en) 2010-09-07 2018-10-09 Saudi Arabian Oil Company Desulfurization and sulfone removal using a coker
US10087377B2 (en) 2010-09-07 2018-10-02 Saudi Arabian Oil Company Oxidative desulfurization of oil fractions and sulfone management using an FCC
US10035960B2 (en) 2010-09-07 2018-07-31 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone management by gasification
US9598647B2 (en) 2010-09-07 2017-03-21 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone disposal using solvent deasphalting
US9574144B2 (en) 2010-09-07 2017-02-21 Saudi Arabian Oil Company Process for oxidative desulfurization and denitrogenation using a fluid catalytic cracking (FCC) unit
US9574142B2 (en) 2010-09-07 2017-02-21 Saudi Arabian Oil Company Process for oxidative desulfurization and sulfone management by gasification
US9574143B2 (en) 2010-09-07 2017-02-21 Saudi Arabian Oil Company Desulfurization and sulfone removal using a coker
US8790508B2 (en) 2010-09-29 2014-07-29 Saudi Arabian Oil Company Integrated deasphalting and oxidative removal of heteroatom hydrocarbon compounds from liquid hydrocarbon feedstocks
US8741127B2 (en) 2010-12-14 2014-06-03 Saudi Arabian Oil Company Integrated desulfurization and denitrification process including mild hydrotreating and oxidation of aromatic-rich hydrotreated products
US10647926B2 (en) 2010-12-15 2020-05-12 Saudi Arabian Oil Company Desulfurization of hydrocarbon feed using gaseous oxidant
US8741128B2 (en) 2010-12-15 2014-06-03 Saudi Arabian Oil Company Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction
WO2013009440A1 (fr) 2011-07-12 2013-01-17 Saudi Arabian Oil Company Procédé pour la conversion de sulfone par des super-donneurs d'électrons
US10125319B2 (en) 2011-07-31 2018-11-13 Saudi Arabian Oil Company Integrated process to produce asphalt and desulfurized oil
US9889430B2 (en) 2011-07-31 2018-02-13 Saudi Arabian Oil Company Solid base catalyst compositions useful in removal of oxidized sulfur compounds and method for making solid base catalyst compositions
US9555396B2 (en) 2011-07-31 2017-01-31 Saudi Arabian Oil Company Process for oxidative desulfurization with integrated sulfone decomposition
US10369546B2 (en) 2011-07-31 2019-08-06 Saudi Arabian Oil Company Process for oxidative desulfurization with integrated sulfone decomposition
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
US10011782B2 (en) 2012-09-28 2018-07-03 Saudi Arabian Oil Company Process for reducing the sulfur content from oxidized sulfur-containing hydrocarbons
WO2014052951A1 (fr) 2012-09-28 2014-04-03 Saudi Arabian Oil Company Procédé pour réduire la teneur en soufre d'hydrocarbures contenant du soufre oxydé
US9719029B2 (en) 2012-11-09 2017-08-01 Saudi Arabian Oil Company Oxidative desulfurization process and system using gaseous oxidant-enhanced feed
US8920635B2 (en) 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US9896629B2 (en) 2014-07-25 2018-02-20 Saudi Arabian Oil Company Integrated process to produce asphalt, petroleum green coke, and liquid and gas coking unit products
RU2803748C1 (ru) * 2022-10-12 2023-09-19 Общество с ограниченной ответственностью "Безводородная сероочистка" Состав катализатора для аэробного окислительного обессеривания светлых нефтяных фракций

Also Published As

Publication number Publication date
BRPI0519500A2 (pt) 2009-02-03
CA2589399A1 (fr) 2006-07-06
US20080308463A1 (en) 2008-12-18
EA011964B1 (ru) 2009-06-30
NZ555486A (en) 2010-03-26
JP2008525624A (ja) 2008-07-17
CN101094908B (zh) 2010-11-17
AU2005322059B2 (en) 2011-03-10
CN101094908A (zh) 2007-12-26
EP1841838A1 (fr) 2007-10-10
AU2005322059A1 (en) 2006-07-06
KR20070091297A (ko) 2007-09-10
EA200701421A1 (ru) 2007-12-28
UA88346C2 (en) 2009-10-12
NO20073938L (no) 2007-10-01
MX2007007802A (es) 2007-07-25
ZA200704539B (en) 2008-09-25

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