WO2006070147A2 - Composition d ' encollage de fils textiles - Google Patents
Composition d ' encollage de fils textiles Download PDFInfo
- Publication number
- WO2006070147A2 WO2006070147A2 PCT/FR2005/051098 FR2005051098W WO2006070147A2 WO 2006070147 A2 WO2006070147 A2 WO 2006070147A2 FR 2005051098 W FR2005051098 W FR 2005051098W WO 2006070147 A2 WO2006070147 A2 WO 2006070147A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fibers
- sizing
- sizing agent
- mol
- agent according
- Prior art date
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 48
- 239000004753 textile Substances 0.000 title claims abstract description 14
- 239000000203 mixture Substances 0.000 title claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000000835 fiber Substances 0.000 claims abstract description 24
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920001577 copolymer Polymers 0.000 claims abstract description 7
- 229920001519 homopolymer Polymers 0.000 claims abstract description 7
- 239000000178 monomer Substances 0.000 claims description 14
- 229920000742 Cotton Polymers 0.000 claims description 12
- 238000009941 weaving Methods 0.000 claims description 12
- 229920000728 polyester Polymers 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000009990 desizing Methods 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 239000006085 branching agent Substances 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 claims description 4
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical class O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 4
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 239000004593 Epoxy Chemical class 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000002253 acid Chemical class 0.000 claims description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 2
- 229940015043 glyoxal Drugs 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- WGESLFUSXZBFQF-UHFFFAOYSA-N n-methyl-n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCN(C)CC=C WGESLFUSXZBFQF-UHFFFAOYSA-N 0.000 claims description 2
- CHDKQNHKDMEASZ-UHFFFAOYSA-N n-prop-2-enoylprop-2-enamide Chemical compound C=CC(=O)NC(=O)C=C CHDKQNHKDMEASZ-UHFFFAOYSA-N 0.000 claims description 2
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 125000001453 quaternary ammonium group Chemical class 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 claims description 2
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 claims 1
- LQKULWLXZZHDDH-UHFFFAOYSA-N C(=C)OCCOC(C=C)=O.C(#N)COC(C=C)=O Chemical compound C(=C)OCCOC(C=C)=O.C(#N)COC(C=C)=O LQKULWLXZZHDDH-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 8
- 239000003292 glue Substances 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000004744 fabric Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 238000004026 adhesive bonding Methods 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920006322 acrylamide copolymer Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- NBTXFNJPFOORGI-UHFFFAOYSA-N 2-ethenoxyethyl prop-2-enoate Chemical compound C=COCCOC(=O)C=C NBTXFNJPFOORGI-UHFFFAOYSA-N 0.000 description 1
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 206010020112 Hirsutism Diseases 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 229940048053 acrylate Drugs 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- WJMQFZCWOFLFCI-UHFFFAOYSA-N cyanomethyl prop-2-enoate Chemical compound C=CC(=O)OCC#N WJMQFZCWOFLFCI-UHFFFAOYSA-N 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- CCGKOQOJPYTBIH-UHFFFAOYSA-N ethenone Chemical compound C=C=O CCGKOQOJPYTBIH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Definitions
- the present invention relates to a novel composition based on water-soluble high molecular weight acrylamide (co) polymers for sizing textile threads (or fibers).
- the invention is particularly applicable to the sizing of natural fibers, especially cotton type, possibly in the presence of artificial fibers, especially polyester.
- abrasion the action of using friction. There is ruffling of threads, formation of pilling due to friction on different pieces (lamellae, comb teeth ...), and hairiness: the tendency of the ends of the fibers to move away from the body of the yarn. It will cause interfering bridging that will give wire breaks or insertion faults by the frame vector.
- the sizing must not degrade the wire and the bath must be composed only of compatible products. Furthermore, there should not occur sizing deposits on the comb, which by hardening, could act as abrasives on the son.
- the sizing is an intermediate primer, which is eliminated following the weaving operation. It is an operation prior to the finishing of the fabric, after which the gluing is completely eliminated. This can prove to be very polluting due to the discharges generated. It is therefore interesting to have a product having good solubility for desizing.
- EP-A-262 945 and US Pat. No. 6,736,865 describe treatment products, not of individualized threads, but of finished woven fabrics.
- EP-A-262 945 thus describes a product combining an acrylamide polymer in the presence of other types of polymers to allow the fixing of the color on the previously woven fabric.
- US 6,736,865 discloses an acrylamide-based product in the presence of other components for treating finished textiles to provide wrinkling resistance and dimensional stability, especially at the time of color fixation.
- the document JP 60 258244 describes the possibility of rendering hydrophobic a sheet being formed, by treatment of papermaking fibers (and non-textile fibers) by means of a mixture of a ketene with an acrylamide polymer .
- the choice of sizing depends mainly on the nature of the chain, taking into account also the type of weaving:
- the main types of base products that can be used as sizing agents are natural or synthetic polymers which are classified as follows: - Starchy foods: starches, starches, etc.
- starch derivatives ethers, acetates ...
- cellulosic derivatives carboxymethyl, methyl and ethyl cellulose
- polyesters - acrylics they are especially suitable for synthetic and artificial yarns; but they are also found in combination with starches or cellulosics for natural fibers and mixtures thereof.
- Acrylic-type sizing agents are obtained by homopolymerization or copolymerization of different derivatives of acrylic acid or methacrylic acid with other monomers such as styrene, vinyl acetate, acrylamide, etc.
- macromolecular substances are obtained by synthesis, the physical properties of which can be varied within a very wide range. This explains the many applications in sizing different threads: polyamide, polyester, cellulosic. The main properties they bring are:
- the problem is therefore to find a new gluing product that would glue the natural fibers and / or artificial, on dry looms, and meets the requirements of the industry, that is to say: good affinity with the yarns or fibers, easy implementation (sizing speed %), improvement of the efficiency of the looms: increase of the resistance of the yarns or fibers while limiting the phenomenon of clogging of the combs,
- a sizing bath has now been found for natural and / or artificial textile fibers in the form of an aqueous solution having performance at least as good as that of pre-existing compositions but at significantly lower sizing agent dosages.
- the subject of the present invention is firstly a temporary sizing agent for naturalized and / or artificial individualized textile fibers, in particular of the cotton and / or cotton / polyester type, characterized in that it comprises a water-soluble homopolymer or copolymer of at least one acrylamide monomer having a molecular weight of at least 1 million, advantageously greater than 3 million.
- the sizing agent consists exclusively of a homopolymer or copolymer of acrylamide.
- the sizing agent of the invention is especially obtained by polymerization (or respectively copolymerization, together throughout the text and claims: "polymerization") of at least one nonionic monomer acrylamide type and possibly other ionic monomers, and advantageously has a UL viscosity greater than 3.
- the polymers of the invention do not require development of a particular polymerization process. They can be obtained by any of the polymerization techniques well known to those skilled in the art (solution polymerization, gel polymerization, precipitation polymerization, emulsion polymerization (aqueous or inverse) followed or not by a spray drying step, suspension polymerization, micellar polymerization followed or not by a precipitation step).
- the water-soluble (co) polymer serving as sizing agent is obtained from:
- anionic and / or cationic preferably 0 to 5 mol%, in the presence or absence of a branching agent and optionally a transfer agent.
- ionic monomers that can be used: cationic monomers: dialkylaminoalkyl (meth) acrylate, dialkylaminoalkyl (meth) acrylamide, diallylamine, methyldiallylamine and their quaternary ammonium or acid salts ...
- anionic monomers having a carboxylic function (eg acrylic acid, methacrylic acid, and their salts 10), the monomers having a sulphonic acid function (eg 2-acrylamido-2-methylpropanesulphonic acid (AMPS) and their salts ...) ...
- branching agents methylene bisacrylamide (MBA), ethylene glycol di-acrylate, polyethylene glycol dimethacrylate, diacrylamide, cyanomethylacrylate, vinyloxyethylacrylate or methacrylate and formaldehyde, glyoxal, glycidyl ether type such as ethylene glycol diglycidyl ether, or epoxy or any other means well known to those skilled in the art for crosslinking.
- MBA methylene bisacrylamide
- ethylene glycol di-acrylate polyethylene glycol dimethacrylate
- diacrylamide diacrylamide
- cyanomethylacrylate vinyloxyethylacrylate or methacrylate and formaldehyde
- glyoxal glycidyl ether type
- epoxy any other means well known to those skilled in the art for crosslinking.
- the invention also relates to a sizing bath comprising the sizing agent described above in a proportion of less than 2% by weight of dry matter, preferably less than 1.5% by weight.
- the present invention also relates to a sizing / de-bonding process of natural and / or artificial textile fibers consisting of immersing said fibers in the bath described above, then, after weaving, to de-stick the fibers using hot water only.
- the concentration of the sizing agent in the bath may vary within the range described above, taking into account the equipment used for carrying out the sizing cycle, in particular the squeezing power of the rolls, and the amount of glue that we want to raise on the son. It is known that this depends on the one hand on the strength of the yarns which is itself a function of their texturing, their degree of torsion, the number of strands per unit yarn and, on the other hand, the adhesion capacity. from the sizing agent to the son to be treated.
- compositions of the invention give coatings having a good protective power and a high adhesive power to textile yarns of cotton and polyester / cotton type; as a result, a concentration of less than or equal to 2% by weight, preferably less than 1.5%, of the composition is sufficient for all the cases of application, including the most difficult son to glue.
- a deposit representing a larger quantity is perfectly conceivable but it does not bring real benefits and can even be detrimental.
- Glued string yarns under the conditions of the invention have sufficient strength for subsequent dry weaving operations.
- the unitary strands are properly agglomerated and there is no evidence of scuffing and breaking wires or fouling looms.
- the desizing step according to the invention is typically carried out with hot water. We then finish with a drying.
- the sizing compositions according to the invention can be prepared either well before their use for sizing and be stored, or on the contrary immediately before use, from their constituents.
- ADC dimethylaminoethyl acrylate quaternized by methyl chloride
- the UL viscosity is measured using a Brookfield viscometer (UL type module) at a speed of 60 rpm and at a temperature of 25 ° C. on a saline (1 N NaCl) polymer at 0.1% concentration (dry weight).
- the composition is then ready to be used to form a sizing bath.
- This bath is immersed in various chains of threads, which are wrung out by passing between two rolls and then dried.
- the weavings made from the son described above are made in good conditions without stripping or strand breakage.
- the fabric After weaving, the fabric is treated off by unwrapping it in a bath of hot water at 50 ° C. and then dried (desizing operation).
- the finished, dried fabric was very flexible; it showed, in addition, a excellent color homogeneity and good fastness to washing and light.
- a sizing was carried out under conditions strictly identical to the previous ones but using the sizing products currently on the market of types - homopolymer of sodium acrylate (MW: 800,000 and 350,000) and homopolymer of acrylamide ( MS: 800,000 and 350,000).
- the high molecular weights of the water-soluble acrylamide (co) polymers of the invention give the sizing bath: a marked improvement in the conditions of use: a preparation and easy desizing as well as a reduced kinematic viscosity of the bath (viscosity cuts), and a highly developed sizing efficiency, thereby significantly limiting the concentration of bath application compared to that required for products. of the same chemical nature and of lower molecular weight.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/722,385 US8007678B2 (en) | 2004-12-22 | 2005-12-16 | Textile yarn sizing composition |
EP05847578A EP1828470A2 (fr) | 2004-12-22 | 2005-12-16 | Composition d'encollage de fils textiles |
MX2007007593A MX2007007593A (es) | 2004-12-22 | 2005-12-16 | Nueva composicion de encolado de hilos textiles. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0453145 | 2004-12-22 | ||
FR0453145A FR2879630B1 (fr) | 2004-12-22 | 2004-12-22 | Nouvelle composition d'encollage de fils textiles |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2006070147A2 true WO2006070147A2 (fr) | 2006-07-06 |
WO2006070147A3 WO2006070147A3 (fr) | 2006-12-14 |
Family
ID=35094188
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2005/051098 WO2006070147A2 (fr) | 2004-12-22 | 2005-12-16 | Composition d ' encollage de fils textiles |
Country Status (5)
Country | Link |
---|---|
US (1) | US8007678B2 (fr) |
EP (1) | EP1828470A2 (fr) |
FR (1) | FR2879630B1 (fr) |
MX (1) | MX2007007593A (fr) |
WO (1) | WO2006070147A2 (fr) |
Cited By (3)
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US9068776B2 (en) | 2009-10-30 | 2015-06-30 | Suncor Energy Inc. | Depositing and farming methods for drying oil sand mature fine tailings |
US9404686B2 (en) | 2009-09-15 | 2016-08-02 | Suncor Energy Inc. | Process for dying oil sand mature fine tailings |
US9909070B2 (en) | 2009-09-15 | 2018-03-06 | Suncor Energy Inc. | Process for flocculating and dewatering oil sand mature fine tailings |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2998309B1 (fr) * | 2012-11-20 | 2015-04-10 | Snf Sas | Composition et procede d'encollage pour materiaux textile |
CN106245332A (zh) * | 2016-08-19 | 2016-12-21 | 桐乡市星邦科技发展有限公司 | 一种纺织浆料及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0066078A2 (fr) * | 1981-06-01 | 1982-12-08 | American Cyanamid Company | Procédé d'encollage de fils textiles |
US4413087A (en) * | 1982-08-23 | 1983-11-01 | Nalco Chemical Company | Stable polymer solutions for spray drift control |
JPS60258244A (ja) * | 1984-06-04 | 1985-12-20 | Dick Hercules Kk | ケテンダイマ−系水性分散液 |
EP0262945A2 (fr) * | 1986-10-01 | 1988-04-06 | Ciba Specialty Chemicals Water Treatments Limited | Compositions de polymères solubles dans l'eau |
EP0659929A2 (fr) * | 1993-12-21 | 1995-06-28 | Rhone-Poulenc Specialty Chemicals Co. | Emollage textiles contenant des dispersions aqueuses ultrafines de polymères |
US6736865B1 (en) * | 1998-06-18 | 2004-05-18 | Clariant Finance (Bvi) Limited | Aqueous dispersions, their production and use |
-
2004
- 2004-12-22 FR FR0453145A patent/FR2879630B1/fr not_active Expired - Fee Related
-
2005
- 2005-12-16 WO PCT/FR2005/051098 patent/WO2006070147A2/fr active Application Filing
- 2005-12-16 EP EP05847578A patent/EP1828470A2/fr not_active Withdrawn
- 2005-12-16 US US11/722,385 patent/US8007678B2/en not_active Expired - Fee Related
- 2005-12-16 MX MX2007007593A patent/MX2007007593A/es active IP Right Grant
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0066078A2 (fr) * | 1981-06-01 | 1982-12-08 | American Cyanamid Company | Procédé d'encollage de fils textiles |
US4413087A (en) * | 1982-08-23 | 1983-11-01 | Nalco Chemical Company | Stable polymer solutions for spray drift control |
JPS60258244A (ja) * | 1984-06-04 | 1985-12-20 | Dick Hercules Kk | ケテンダイマ−系水性分散液 |
EP0262945A2 (fr) * | 1986-10-01 | 1988-04-06 | Ciba Specialty Chemicals Water Treatments Limited | Compositions de polymères solubles dans l'eau |
EP0659929A2 (fr) * | 1993-12-21 | 1995-06-28 | Rhone-Poulenc Specialty Chemicals Co. | Emollage textiles contenant des dispersions aqueuses ultrafines de polymères |
US6736865B1 (en) * | 1998-06-18 | 2004-05-18 | Clariant Finance (Bvi) Limited | Aqueous dispersions, their production and use |
Non-Patent Citations (1)
Title |
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PATENT ABSTRACTS OF JAPAN vol. 010, no. 131 (C-346), 15 mai 1986 (1986-05-15) & JP 60 258244 A (DEITSUKU HAAKIYURESU KK), 20 décembre 1985 (1985-12-20) * |
Cited By (4)
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US9404686B2 (en) | 2009-09-15 | 2016-08-02 | Suncor Energy Inc. | Process for dying oil sand mature fine tailings |
US9909070B2 (en) | 2009-09-15 | 2018-03-06 | Suncor Energy Inc. | Process for flocculating and dewatering oil sand mature fine tailings |
US10590347B2 (en) | 2009-09-15 | 2020-03-17 | Suncor Energy Inc. | Process for flocculating and dewatering oil sand mature fine tailings |
US9068776B2 (en) | 2009-10-30 | 2015-06-30 | Suncor Energy Inc. | Depositing and farming methods for drying oil sand mature fine tailings |
Also Published As
Publication number | Publication date |
---|---|
FR2879630B1 (fr) | 2007-02-23 |
US20090249596A1 (en) | 2009-10-08 |
WO2006070147A3 (fr) | 2006-12-14 |
FR2879630A1 (fr) | 2006-06-23 |
EP1828470A2 (fr) | 2007-09-05 |
MX2007007593A (es) | 2007-12-11 |
US8007678B2 (en) | 2011-08-30 |
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