WO2005097965A1 - 固形石鹸組成物および固形石鹸 - Google Patents

固形石鹸組成物および固形石鹸 Download PDF

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Publication number
WO2005097965A1
WO2005097965A1 PCT/JP2005/004184 JP2005004184W WO2005097965A1 WO 2005097965 A1 WO2005097965 A1 WO 2005097965A1 JP 2005004184 W JP2005004184 W JP 2005004184W WO 2005097965 A1 WO2005097965 A1 WO 2005097965A1
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Prior art keywords
solid
acid
integer
composition according
solid stone
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PCT/JP2005/004184
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English (en)
French (fr)
Japanese (ja)
Inventor
Yoshinobu Saito
Daiji Nagahama
Shinya Yamasaki
Takahiro Okuda
Tetsuo Nishina
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P & Pf Co., Ltd.
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Application filed by P & Pf Co., Ltd. filed Critical P & Pf Co., Ltd.
Priority to DE602005012956T priority Critical patent/DE602005012956D1/de
Priority to US10/593,615 priority patent/US7709432B2/en
Priority to EP05720455A priority patent/EP1767612B1/en
Publication of WO2005097965A1 publication Critical patent/WO2005097965A1/ja

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3738—Alkoxylated silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/225—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/36—Organic compounds, e.g. vitamins containing silicon
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

Definitions

  • the present invention relates to a solid stone and a raw material composition thereof, and more particularly, to a solid stone for washing skin that can remove makeup at the same time as washing a face.
  • Cleansing of the makeup skin is performed first by using a cleansing agent for removing makeup such as a cleansing cream or a cleansing oil containing a large amount of oil, which is easily compatible with the makeup cosmetics. Rinsing off with water or lukewarm water, and then using a face wash such as stone cleansing foam to remove oil and sebum and dirt on the skin, along with the oil of cleansing agent remaining on the skin. It was done by. In such a two-stage washing, the washing and fining were dull.
  • a cleansing agent for removing makeup such as a cleansing cream or a cleansing oil containing a large amount of oil, which is easily compatible with the makeup cosmetics.
  • a face wash such as stone cleansing foam
  • Patent Document 1 a detergent containing a polyoxyethylene glycerin fatty acid ester and a polyoxyalkylene-modified polysiloxane
  • Patent Document 2 polyoxyethylene diester, anionic surfactant, and amphoteric surfactant
  • skin cleansers containing an activator and a polyoxyalkylene modified methylpolysiloxane. These facial cleansers are also in a liquid state or a gel state.
  • polyoxyalkylene-modified methylpolysiloxane mainly removes makeup cosmetics.
  • this component causes insufficient foaming, After washing the face, this ingredient remains on the skin and gives a refreshing feeling There was an inconvenience.
  • this component can remove the foundation and the like among the makeup cosmetics, but if the makeup is insufficient for acidic makeup cosmetics (for example, lipstick, etc.), it is difficult to remove the foundation. There were inconveniences.
  • Patent document 1 Japanese Patent Publication No. 5-75723
  • Patent Document 2 JP-A-11-106331
  • the present invention is intended to solve the above-mentioned problem, and an object of the present invention is to provide a cleaning agent capable of simultaneously performing make-up removal and normal facial cleaning with a single facial cleansing, which has sufficient foaming. It is an object of the present invention to provide a cleaning agent which can give a feeling of swelling, and can sufficiently remove not only a foundation but also an acidic pigment.
  • the inventors of the present invention have conducted intensive studies on the above-mentioned problems, and as a result, by forming a solid lactic acid composition in which a polyoxyalkylene-modified polysiloxane and a specific amine conjugate are mixed with a lithic acid component, They have found that the above problems can be solved, and have completed the invention.
  • the present invention provides:
  • Rl represents a hydrogen atom or an alkyl group having 115 carbon atoms
  • m represents an integer of 1-60
  • n represents an integer of 1-60
  • a represents an integer of 1-10
  • B represents an integer of 1 to 30, and c represents an integer of 0 to 30.
  • R 2 -R 5 are the same or different and represent a hydrogen atom or an alkyl group having 115 carbon atoms
  • Is a solid stone composition comprising:
  • the polyoxyalkylene-modified polysiloxane (b) of the general formula (1) is preferably a polyoxyethylene-modified polysiloxane.
  • the 2-hydroxyalkyl) ethylenediamine (c) is selected from tetrakis (2-hydroxypropyl) ethylenediamine and tetrakis (2-hydroxybutyl) ethylenediamine.
  • the fatty acid ester-based non-surfactant (d), which preferably further contains a fatty acid ester-based non-on-surfactant (d), is a polyalkylene alcohol derivative.
  • Fatty acid esters, trifatty acid glyceryl and trifatty acid polyoxyalkylene glyceryl forces are preferably selected.
  • the amphoteric surfactant (e), which preferably contains Sarako, amphoteric surfactant (e) and a polyhydric alcohol (f), comprises an imidazoli-pumbetaine type, Amidoalkyl betaine and alkyl betaine forces are preferably selected.
  • the polyhydric alcohol (f) is preferably selected from glycerin, diglycerin, 1,3-butylene glycol, propylene glycol, polyoxypropylene glyceryl ether and polyoxypropylene diglyceryl ether.
  • the solid stone composition of the present invention comprises a stone component (a),
  • the polyoxyalkylene-modified polysiloxane (b) of the general formula (1) and the tetrakis (2-hydroxyalkyl) ethylenediamine (c) of the general formula (2) are contained as essential components.
  • the stone component (a) used in the present invention includes alkali salts of higher fatty acids.
  • the higher fatty acid is a saturated or unsaturated fatty acid having 8 to 24, preferably 12 to 18 carbon atoms, and may be linear or branched.
  • saturated fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid and isostearic acid; unsaturated fatty acids such as oleic acid; coconut oil fatty acid, palm oil fatty acid, and palm kernel oil which are mixtures thereof.
  • alkali examples include alkali metals such as sodium and potassium, alkaline earth metals, alkanolamine, ammonium, and basic amino acids. These alkalis may be used alone or in combination of two or more.
  • Suitable lithic acid components include sodium laurate, sodium myristate, sodium palmitate, sodium stearate, sodium oleate, sodium isostearate, coconut oil fatty acid sodium, palm oil fatty acid sodium, palm kernel oil fatty acid sodium. And the like.
  • the content of the above-mentioned oxalic acid component (a) is preferably 20 to 40% by weight, particularly preferably 25 to 35% by weight of the whole solid lactic acid material. If this content is less than 20% by weight, the freezing point will be low, so that if stored for a long period of time, the surface will melt and the commercial value may be lost. On the other hand, if it exceeds 40% by weight, the transparency may be poor or a feeling of curling after use may occur.
  • the polyoxyalkylene-modified polysiloxane (b) used in the present invention is a compound represented by the above general formula (1).
  • This polyoxyalkylene-modified polysiloxane (b) plays a role mainly when a makeup diy cosmetic (especially a foundation) is blended in and dropped off. ) Does not hinder the foaming and makes the composition transparent. In some cases, there is an additional advantage that transparency is not hindered.
  • the “alkyl group having 115 carbon atoms” of R 1 may be linear or branched, and preferably has 13 carbon atoms.
  • m is an integer of 1 to 60, preferably an integer of 5 to 30.
  • n is an integer of 1 to 60, preferably an integer of 1 to 10.
  • a is an integer of 110, preferably an integer of 115.
  • b is an integer of 110, preferably an integer of 115.
  • c is an integer of 0-30, preferably an integer of 0-15.
  • polyoxyalkylene-modified polysiloxane (b) examples include a copolymer of dimethylpolysiloxane and polyethylene glycol, and a copolymer of dimethylpolysiloxane and polyoxyethylenepolyoxypropylene glycol.
  • the above polyoxyalkylene-modified polysiloxane (b) preferably has an HLB of 3-20, particularly preferably 418. If the HLB is less than 3, transparency and foaming may be inferior. If the HLB is more than 20, the effect of dropping the makeup cosmetics may be insufficient.
  • the above polyoxyalkylene-modified polysiloxane (b) may be used alone or in combination of two or more.
  • polyoxyalkylene-modified polysiloxanes (b) polyoxyethylene-modified polysiloxanes (that is, c is 0) are preferably used from the viewpoint of hydrophilicity.
  • silicone KF6011 (R1 is a methyl group, m is 5-10, n is 4-16, a is 3, b is 9-13: manufactured by Shin-Etsu Danigaku), silicone SC9450 (R1 is a hydrogen atom, m is 50-60, n is 2-5, a is 3, b is 8-10: Shin-Etsu Chemical Co., Ltd., silicone KF945 (R1 is hydrogen atom, m is 20-30, n is 2-5, a is 3 And b is 2-5: Shin-Etsu Gakugaku).
  • the content of the above polyoxyalkylene-modified polysiloxane (b) is preferably 11 to 15% by weight, and particularly preferably 2 to 10% by weight, based on the total amount of the solid rock acid raw material. Good. If the content is less than 1% by weight, the effect of removing makeup cosmetics may be insufficient. Conversely, if it exceeds 15% by weight, the solidification properties and foaming may be inferior.
  • the tetrakis (2-hydroxyalkyl) ethylenediamine (c) used in the present invention is as described above. It is a compound represented by the general formula (2).
  • the tetrakis (2-hydroxyalkyl) ethylene diamine (c) is mainly used when the makeup polystyrene (particularly an acidic pigment such as lipstick) is blended with the polyoxyalkylene-modified polysiloxane (b) and dropped. It plays a role, but has the following additional advantages: it does not inhibit foaming of the lithic acid component (a), and does not impair the transparency of the composition when it is made transparent.
  • alkyl group having 15 carbon atoms of R 2 —R 5 is preferably a straight-chain or branched-chain alkyl group having a carbon number of 113. is there.
  • the above tetrakis (2-hydroxyalkyl) ethylenediamine (c) may be used alone or in combination of two or more.
  • tetrakis (2-hydroxypropyl) is preferred among the above tetrakis (2-hydroxyalkyl) ethylenediamines (c) because of its good effect of removing makeup cosmetics.
  • Ethylenediamine that is, R2-R5 is also a methyl group
  • tetrakis (2-hydroxybutyl) ethylenediamine that is, R2-R5 is!, And the deviation is also an ethyl group
  • the content of the above-mentioned tetrakis (2-hydroxyalkyl) ethylenediamine (c) is 110 to 10% by weight, particularly 1 to 10% by weight, based on the whole solid acid acid raw material.
  • One to 5% by weight is preferred. If the content is less than 1% by weight, the effect of dropping the makeup cosmetics may be insufficient. Conversely, if the content exceeds 10% by weight, problems of discoloration and odor may occur.
  • the total content of the above polyoxyalkylene-modified polysiloxane (b) and the above tetrakis (2-hydroxyalkyl) ethylenediamine (c) is 3% in the solid stone composition of the present invention. — Preferably 15% by weight, especially 4-10% by weight.
  • the mixing ratio (weight ratio) of the above-mentioned polyoxyalkylene-modified polysiloxane (b) and the above-mentioned tetrakis (2-hydroxyalkyl) ethylenediamine (c) is such that (b) :( c) is 10: 1-
  • the ratio is preferably 1:10, particularly preferably 3: 1 to 1: 3.
  • the solid stone composition of the present invention is prepared by adding a solid component (a), a polyoxyalkylene-modified polysiloxane (b) and tetrakis (2-hydroxyalkyl) ethylenediamine (c) to a fat composition. It preferably contains an acid ester-based nonionic surfactant (d). This fatty acid ester-based nonionic surfactant (d) is used to make up the makeup cosmetics together with the polyoxyalkylene-modified polysiloxane (b) and tetrakis (2-hydroxyalkyl) ethylenediamine (c). The power to drop it, and it also gives calories and gives a moist feeling after washing.
  • the fatty acid ester-based nonionic surfactant (d) used in the present invention includes polyalkylene glycol difatty acid ester, trifatty acid glyceryl, trifatty acid polyoxyalkylene glyceryl, polyoxyethylene hydrogenated castor oil, and the like. Among them, polyalkylene glycol difatty acid ester, trifatty acid glyceryl and trifatty acid polyoxyalkylene glyceryl are preferably used.
  • the polyalkylene glycol difatty acid ester is a compound represented by the following general formula (3)
  • the trifatty acid glyceryl is a compound represented by the following general formula (4)
  • the trifatty acid polyoxyalkylene glyceryl is It is a compound represented by the following general formula (5).
  • R 6 and R 7 are the same or different and each represent an alkyl group having 8 to 22 carbon atoms or an alkenyl group having 8 to 22 carbon atoms, and R 8 represents a hydrogen atom or a carbon atom having 1 to 5 carbon atoms. And X represents an integer of 1 to 40.
  • R9—R11 are the same or different and represent an alkyl group having 8 to 22 carbon atoms or an alkyl group having 8 to 22 carbon atoms.
  • R12—R14 are the same or different and represent an alkyl group having 10-20 carbon atoms or an alkenyl group having 10-20 carbon atoms, and R15 represents a hydrogen atom or a carbon atom
  • yl-y3 are the same or different and represent an integer of 180.
  • the “alkyl group having 8 to 22 carbon atoms” of R6 and R7 may be linear or branched, and preferably has 10 to 20 carbon atoms.
  • the “alkenyl group having 8 to 22 carbon atoms” of R6 and R7 may be linear or branched, and preferably has 10 to 20 carbon atoms.
  • the “alkyl group having 15 carbon atoms” of R8 may be linear or branched, and preferably has 13 carbon atoms.
  • X is an integer of 1 to 40, preferably an integer of 2 to 20.
  • the "C8-C22 alkyl group" of R9-Rl1 may be linear or branched, and preferably has 10-20 carbon atoms. It is.
  • the “alkenyl group having 8 to 22 carbon atoms” of R9 to R11 may be linear or branched, and preferably has 10 to 20 carbon atoms.
  • the “alkyl group having 10 to 20 carbon atoms” for R 12 to R 14 may be linear or branched, and preferably has 14 to 20 carbon atoms.
  • the “alkenyl group having 10 to 20 carbon atoms” of R12 to R14 may be linear or branched, and preferably has 14 to 20 carbon atoms.
  • the “alkyl group having 15 to 15 carbon atoms” of R15 may be linear or branched, and preferably has 13 to 13 carbon atoms.
  • yl-y3 is an integer of 1 to 80, preferably an integer of 10 to 60.
  • polyethylene glycol difatty acid esters that is, R8 is a hydrogen atom
  • R8 is a hydrogen atom
  • preferred polyalkylene glycol difatty acid esters polyethylene glycol difatty acid esters (that is, R8 is a hydrogen atom) are preferably used.
  • Specific examples thereof include: Examples include polyethylene glycol diisostearate, polyethylene glycol dioleate, polyethylene glycol distearate, and polyethylene glycol dilaurate.
  • Suitable glyceryl trifatty acids include glyceryl tri (2-ethylhexanoate), glyceryl triisostearate, glyceryl tri (capryluric acid), glyceryl trihydrogenated coconut oil, and the like.
  • trifatty acid polyoxyalkylene glyceryl that is, R15 is a hydrogen atom
  • trifatty acid polyoxyethylene glyceryl that is, R15 is a hydrogen atom
  • R15 is a hydrogen atom
  • Specific examples thereof include polyisoethylene glyceryl triisostearate and tristearic acid.
  • polyoxyethylene daliseryl that is, R15 is a hydrogen atom
  • the fatty acid ester-based nonionic surfactant (d) preferably has an HLB of 3 to 15, particularly preferably 4 to 10. If the HLB is less than 3, the solubility may be inferior and the appearance may be deteriorated. If the HLB is more than 15, the effect of removing the makeup cosmetic may be insufficient.
  • the above fatty acid ester-based nonionic surfactant (d) may be used alone or in combination of two or more.
  • the content of the above-mentioned fatty acid ester-based nonionic surfactant (d is 11 to 10% by weight, and particularly If the content is less than 1% by weight, the effect of removing makeup cosmetics may be insufficient, and the moist feeling after washing may be insufficient. Exceeding the washing may cause stickiness in the washing.
  • the blending ratio (weight ratio) of the polyoxyalkylene-modified polysiloxane (b) and the fatty acid ester-based nonionic surfactant (d) is such that (b) :( d) is 4: 1.
  • the ratio of 1: 1: 4, especially 3: 1-1: 3 is preferred.
  • the compounding ratio (weight ratio) of (c) :( d) is preferably 1: 1 to 1: 4, particularly 2: 1 to 1: 2.
  • the solid stone composition of the present invention preferably further contains, in addition to the above components, an amphoteric surfactant (e) and a polyhydric alcohol (f).
  • Solid stone mainly composed of lithic acid component (a)
  • An amphoteric surfactant (e) and a polyhydric alcohol (f) are added to the acid composition together with the polyoxyalkylene-modified polysiloxane (b) and the fatty acid ester-based non-ionic surfactant (d), which are non-ionic surfactants. )
  • a transparent composition having a beautiful appearance can be obtained, and by adding the amphoteric surfactant (e), foaming of the composition can be improved.
  • amphoteric surfactant (e) used in the present invention examples include, for example, imidazoly-dumbetaine type represented by the following general formula (6), amide alkyl betaine type represented by the following general formula (7), and An alkyl betaine type represented by the general formula (8) is given. These amphoteric surfactants may be used alone or in combination of two or more.
  • R16 represents an alkyl group or an alkyl group having 7 to 21 carbon atoms
  • n and m are the same or different and represent an integer of 113
  • Z is ,
  • R17 represents an alkyl group or an alkenyl group having 7 to 21 carbon atoms
  • R18 and R19 represent the same or different and represent a lower alkyl group
  • A represents a lower alkylene group
  • R20 represents an alkyl group or an alkenyl group having 8 to 22 carbon atoms
  • R21 and R22 are the same or different and represent a lower alkyl group.
  • the “alkyl group having 7 to 21 carbon atoms” for R16 may be linear or branched, and preferably has 7 to 17 carbon atoms. Further, the “alkenyl group having 712 carbon atoms” of R16 may be linear or branched, and preferably has 717 carbon atoms.
  • Examples of the “alkali metal” of Y include sodium and potassium, examples of the “alkaline earth metal” include calcium and magnesium, and examples of the “organic amine” include monoethanolamine and Diethanolamine, triethanolamine and the like can be mentioned.
  • imidazolinidum betaine-type amphoteric surfactant of the chemical formula (6) include, for example, 2-pindecyl-N-carboxymethyl-N-hydroxyethylimidazoli-dumbetaine (synthesized from lauric acid).
  • the “alkyl group having 7 to 21 carbon atoms” and the “alkalyl group having 7 to 21 carbon atoms” of R17 are the same as R16 of the chemical formula (6).
  • the “lower alkyl group” for R18 and R19 is a straight-chain or branched-chain, preferably one having 113 carbon atoms. Is a alkyl group.
  • the “lower alkylene group” of A is a linear or branched alkylene group having preferably 3 to 5 carbon atoms.
  • amidoalkyl betaine type amphoteric surfactant of the formula (7) include amidopropyl pyrbetaine type, for example, coconut oil fatty acid amidopropyl dimethylaminoamino betaine (
  • R17 is a mixture of C7—C17).
  • the “alkyl group having 8 to 22 carbon atoms” of R20 may be linear or branched, and preferably has 8 to 18 carbon atoms. is there. Further, the “alkenyl group having 8 to 22 carbon atoms” of R20 may be linear or branched, and preferably has 8 to 18 carbon atoms. Further, the “lower alkyl group” of R21 and R22 is the same as R18 and R19 in chemical formula (7).
  • alkyl betaine-type amphoteric surfactant of the chemical formula (8) include lauryl dimethylamino acetic acid betaine, alkyl synthesized from coconut oil fatty acid and alkenyl dimethyl amino acetic acid betaine (where R20 is C8-C18). And the like).
  • imidazolinidum betaine type amphoteric surfactants of the above chemical formula (6) particularly cocoyl imidazolinidum betaine, are particularly preferably used.
  • the content of the amphoteric surfactant (e) is preferably 2 to 10% by weight, particularly preferably 418 to 8% by weight, based on the total amount of the solid rock acid raw material. If this content is less than 2% by weight, transparency and foaming may be inferior. Conversely, if the content exceeds 10% by weight, problems of discoloration and odor may occur.
  • polyhydric alcohol (f) used in the present invention for example, polyhydric alcohol (f) used in the present invention
  • Alkylene glycols such as ethylene glycolone, propylene glycol, 1,3-butylene glycol, diethylene glycolone, dipropylene glycol, polyethylene glycol and polypropylene glycolone;
  • Glycerins such as glycerin, diglycerin and polyglycerin;
  • Sugars such as sucrose, trehalose, fructose and maltose
  • Sugar alcohols such as sorbitol, erythritol, xylitol, and maltitol; and glycerin, diglycerin, 1,3-butylene glycol, propylene glycol, polyoxypropylene glyceryl ether, and polyoxypropylene diglyceryl ether. It is preferably used.
  • These polyhydric alcohols (f) may be used alone or in combination of two or more.
  • the content of the polyhydric alcohol (f) is preferably 5 to 45% by weight, particularly preferably 15 to 35% by weight of the whole raw material of the solid stone. If the content is less than 5% by weight, it may not be solidified uniformly. Conversely, if it exceeds 45% by weight, it does not solidify and becomes liquid.
  • the solid stone composition of the present invention preferably further contains alkaline ionized water (g) in addition to the above components.
  • alkaline ionized water (g) By the addition of the alkaline ionized water (g), the solid composition of the present invention has an improved penetrating power into the makeup cosmetics, and thus an effect of removing the makeup cosmetics.
  • the alkali ion water (g) used in the present invention is not particularly limited as long as it is an alkali ion water obtained by electrolyzing water.
  • “multi-cleaner S-100”, “ Multi-cleaner GE-100 ”(both sold by Seki Co., Ltd.) and the like are preferably used.
  • the pH of alkaline ionized water (g) is preferably from 8 to 13, particularly from 10 to 13, from the viewpoint of the makeup removing effect.
  • the content of alkaline ionized water (g) is preferably 0.1 to 20% by weight, and particularly preferably 110 to 10% by weight, based on the entire solid carboxylic acid raw material. If the content is less than 0.1% by weight, the effect of removing the makeup cosmetics may not be improved. Conversely, if it exceeds 20% by weight, the cost increases and the economy becomes disadvantageous.
  • the lithic acid composition of the present invention contains the following components within a range that does not impair the above-mentioned effects. Can be arbitrarily compounded.
  • This optional component includes a bactericide such as trichlorocarba-lide, hinokitiol, and thiol; a humectant such as pyrrolidone carboxylic acid, sodium pyrrolidone carboxylate, sodium hyaluronate, hyaluronic acid, and polyoxyethylene alkyl darcoside ether; Chelating agents such as trisodium edetate dihydrate; ultraviolet absorbers; antioxidants; natural extracts such as dipotassium glycyrrhizinate, obaco extract, lecithin, savonin, aloe, obata, and potato beetle Non-ionic, cationic or ion-soluble water-soluble polymer; Usability enhancer such as lactate ester; Alkyl ether a
  • the solid stone composition of the present invention is mixed with water in a range of 7% by weight or less including the above-mentioned alkali ion water (g) in order to thoroughly mix and dissolve the whole, Alcohol is blended in a range of 10% by weight or less.
  • the total amount of the solid stone raw material including these water and alcohol is 100% by weight.
  • the method for producing the solid stone from the solid stone ⁇ composition ⁇ of the present invention can be obtained by applying a general method such as a frame kneading method or a mechanical kneading method to the mixture of the above-mentioned components.
  • the solid stone ⁇ after forming is a complete product after a predetermined aging period. During this maturation period, most of the alcohol contained in the solid stone composition is volatilized to reduce the irritation of the solid stone and complete the product. Completion of the aging period can be determined by a change in volume of the solid stone ⁇ due to volatilization of alcohol or ion-exchanged water. Specifically, the volume of these volatile components, that is, within the range of 10% to 20% volume reduction, is appropriately determined.
  • the solid stone composition of the present invention comprises a stone component (a), a polyoxyalkylene-modified polysiloxane (b) of the above general formula (1), and a tetrakis (2-butane) of the above general formula (2).
  • (Hydroxyalkyl) It contains ethylenediamine (c) as an essential component.
  • the composition can be used for the makeup pigment of an acidic pigment that can be removed only by a foundation. Can be dropped sufficiently.
  • the solid stone composition of the present invention it is possible to sufficiently remove even a makeup cosmetic of an acidic pigment which can be removed only by a foundation, and it is possible to give a washing feeling and a feeling of swelling. It is possible to provide a solid stone that can be formed.
  • Example 116 From the solid stone compositions having the formulations shown in Table 1, the solid stones of Example 116 and Comparative Example 116 were produced. In addition, in Table 1, the compounding amount of each component is shown by weight%.
  • Example 16 The solid stones obtained in Example 16 and Comparative Example 16 were subjected to an evaluation test by the following method. The results are shown in Table 1.
  • the evaluation was performed based on the following three criteria.
  • Each sample was cut to a thickness of 20 mm, placed on a 26-point type, and evaluated according to the following four criteria.
  • the solid stone composition of the present invention can remove makeup at the same time as washing a face, it can be sufficiently washed with a single face wash on the makeup skin, which is a very convenient solid stone washing composition for skin washing. Become a product.

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PCT/JP2005/004184 2004-03-30 2005-03-10 固形石鹸組成物および固形石鹸 WO2005097965A1 (ja)

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DE602005012956T DE602005012956D1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 2004-03-30 2005-03-10
US10/593,615 US7709432B2 (en) 2004-03-30 2005-03-10 Solid soap composition comprising polysilxoxane and diamine
EP05720455A EP1767612B1 (en) 2004-03-30 2005-03-10 Solid soap composition and solid soap

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JP2004100210A JP3699719B1 (ja) 2004-03-30 2004-03-30 固型石鹸組成物

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JP3699719B1 (ja) 2004-03-30 2005-09-28 株式会社ピーアンドピーエフ 固型石鹸組成物
ATE484273T1 (de) * 2004-04-15 2010-10-15 Dow Corning Niedermolekulare öl-in-wasser-silikonemulsion
WO2009045408A1 (en) * 2007-10-01 2009-04-09 Ethox Chemicals, Llc Alkoxylated polyamines and polyetherpolyamine polyol compositions for foam control
WO2010003819A1 (en) * 2008-07-10 2010-01-14 Unilever Nv A personal wash composition
JP5272680B2 (ja) * 2008-11-20 2013-08-28 日油株式会社 石鹸組成物
MX2012011475A (es) 2010-04-01 2012-11-16 Procter & Gamble Composiciones que comprenden organosiliconas.
CN103627545A (zh) * 2013-11-27 2014-03-12 许伟 一种防虫肥皂
US9415003B2 (en) * 2014-03-03 2016-08-16 Lift Laboratories, Inc. Skin care method and kit
WO2018087940A1 (ja) * 2016-11-10 2018-05-17 サントリーホールディングス株式会社 マイクロエマルションを含有する固体石けん組成物
EP3743495B1 (en) 2018-01-26 2025-09-03 Ecolab USA Inc. Solidifying liquid betaine and/or sultaine surfactants with a sodium chloride carrier
WO2019148076A1 (en) 2018-01-26 2019-08-01 Ecolab Usa Inc. Solidifying liquid amine oxide, betaine, and/or sultaine surfactants with a binder and optional carrier
AU2019212823B2 (en) 2018-01-26 2021-09-23 Ecolab Usa Inc. Solidifying liquid anionic surfactants
PH12021550631B1 (en) 2018-10-12 2023-05-19 Unilever Ip Holdings B V 5 Cleaning composition comprising foam boosting silicone

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JPS5796099A (en) * 1980-12-01 1982-06-15 Neutrogena Corp Transparent soap composition
JPH02273618A (ja) * 1989-04-14 1990-11-08 Shiseido Co Ltd 洗浄剤組成物
JP2000247892A (ja) * 1999-02-26 2000-09-12 Ikeda Bussan Kk 製剤組成物
JP2003129094A (ja) * 2001-10-25 2003-05-08 P & P F:Kk 固型石鹸組成物

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JPS63122618A (ja) 1986-11-12 1988-05-26 Sunstar Inc 透明洗浄剤組成物
JPH11106331A (ja) 1997-09-30 1999-04-20 Shiseido Co Ltd 皮膚洗浄料
JP3699719B1 (ja) 2004-03-30 2005-09-28 株式会社ピーアンドピーエフ 固型石鹸組成物

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JPS5796099A (en) * 1980-12-01 1982-06-15 Neutrogena Corp Transparent soap composition
JPH02273618A (ja) * 1989-04-14 1990-11-08 Shiseido Co Ltd 洗浄剤組成物
JP2000247892A (ja) * 1999-02-26 2000-09-12 Ikeda Bussan Kk 製剤組成物
JP2003129094A (ja) * 2001-10-25 2003-05-08 P & P F:Kk 固型石鹸組成物

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ES2320469T3 (es) 2009-05-22
US7709432B2 (en) 2010-05-04
EP1767612A4 (en) 2008-04-09
EP1767612B1 (en) 2009-02-25
TWI266799B (en) 2006-11-21
JP2005281596A (ja) 2005-10-13
CN1965070A (zh) 2007-05-16
DE602005012956D1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 2009-04-09
EP1767612A1 (en) 2007-03-28
US20070225195A1 (en) 2007-09-27
CN100543125C (zh) 2009-09-23
TW200536937A (en) 2005-11-16

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