WO2005010272A1 - Teinture et finition de tissus de lyocell - Google Patents
Teinture et finition de tissus de lyocell Download PDFInfo
- Publication number
- WO2005010272A1 WO2005010272A1 PCT/GB2004/003091 GB2004003091W WO2005010272A1 WO 2005010272 A1 WO2005010272 A1 WO 2005010272A1 GB 2004003091 W GB2004003091 W GB 2004003091W WO 2005010272 A1 WO2005010272 A1 WO 2005010272A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fabric
- treatment
- process according
- dyeing
- tumbling
- Prior art date
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 132
- 229920000433 Lyocell Polymers 0.000 title claims abstract description 40
- 238000004043 dyeing Methods 0.000 title claims description 29
- 238000000034 method Methods 0.000 claims abstract description 59
- 238000011282 treatment Methods 0.000 claims abstract description 42
- 206010061592 cardiac fibrillation Diseases 0.000 claims abstract description 31
- 230000002600 fibrillogenic effect Effects 0.000 claims abstract description 28
- 238000012545 processing Methods 0.000 claims abstract description 15
- 239000002841 Lewis acid Substances 0.000 claims abstract description 14
- 150000007517 lewis acids Chemical class 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000000243 solution Substances 0.000 claims description 31
- 239000002253 acid Substances 0.000 claims description 22
- 238000010438 heat treatment Methods 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 238000005470 impregnation Methods 0.000 claims description 12
- 150000007513 acids Chemical class 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 238000009981 jet dyeing Methods 0.000 claims description 9
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 8
- 239000011975 tartaric acid Substances 0.000 claims description 8
- 235000002906 tartaric acid Nutrition 0.000 claims description 8
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- 150000001735 carboxylic acids Chemical class 0.000 claims description 5
- 238000002203 pretreatment Methods 0.000 claims description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- -1 zinc fluoroborate Chemical compound 0.000 claims description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 4
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 8
- 239000000835 fiber Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 230000001939 inductive effect Effects 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 6
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 6
- 238000010276 construction Methods 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- RTLULCVBFCRQKI-UHFFFAOYSA-N 1-amino-4-[3-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-sulfoanilino]-9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=1)=CC=C(S(O)(=O)=O)C=1NC1=NC(Cl)=NC(Cl)=N1 RTLULCVBFCRQKI-UHFFFAOYSA-N 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 238000009991 scouring Methods 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 108010059892 Cellulase Proteins 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000009990 desizing Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000009972 garment dyeing Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229960002337 magnesium chloride Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000009992 mercerising Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000009980 pad dyeing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/81—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron; with boron halides; with fluoroborates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/84—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67316—Acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2066—Thermic treatments of textile materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
Definitions
- This invention relates to a process for the dyeing and finishing of a lyocell fabric.
- the term ""lyocell fabric” means a fabric formed, particularly woven or knitted, from yarns, particularly staple fibre yarns, comprising lyocell fibres.
- Such yarns may comprise lyocell fibres alone or a blend of lyocell fibres with fibres of one or more other cellulosic or non-cellulosic types, such as cotton, viscose, linen, polyester and nylon.
- the fabric may additionally include yarns which do not incorporate lyocell fibres, for example yarns of the other fibre types referred to and blends thereof.
- Lyocell fibres are produced by extrusion of a solution of cellulose through a spinning jet into a coagulation bath, by a process known as solvent spinning. They are thus alternatively known as solvent-spun cellulose fibres. Such a process is described in US-A-4,246,221 and uses as the solvent an aqueous tertiary amine ⁇ -oxide, particularly ⁇ - methylmorpholine ⁇ -oxide.
- Lyocell fibres are thereby distinguished from other man-made cellulose fibres produced by forming the cellulose into a soluble chemical derivative and then extruding a solution of this derivative into a bath which regenerates the extrudate as cellulose fibres; viscose fibres, including the high-strength modal types, are produced in the latter way.
- Lyocell fibres are known to have a tendency to fibrillate during vigorous dyeing and finishing processes, and various methods of dealing with this phenomenon have been proposed.
- dyeing and finishing of lyocell fabrics is carried out using relatively gentle processing such as pad-dyeing of open- width fabric, and a resin-finishing treatment using a cross-linking agent is carried out on the dyed fabric to protect the fibres against fibrillation in subsequent laundering processes.
- Another method of dealing with this fibrillation tendency of lyocell fibres is to treat the fibres so as to remove the relatively long protruding fibre ends which are formed in the first stage of the fibrillation process (so-called ⁇ primary fibrillation") and which otherwise produce a hairy effect, often matted, on the surface of the fabric and thereby disfigure its appearance.
- ⁇ primary fibrillation the relatively long protruding fibre ends which are formed in the first stage of the fibrillation process
- x secondary fibrillation the development of the shorter fibrils formed in the fibrillation process
- shorter fibrils create a surface finish characterised as being ⁇ x clea " , in the sense of being substantially free from a hairy effect, and as having a soft touch imparted by the shorter fibrils on the surface and referred to as a ⁇ soft-touch finish" .
- a ⁇ soft-touch finish When the shorter fibrils are sufficiently developed then the soft touch of the fabric surface is more pronounced and the soft-touch finish is referred to as a , ⁇ peach-touch finish" .
- a further example is described in GB-A- 2,314,568 and involves use of the dyeing machine itself, for example a jet dyeing machine, to subject the lyocell fabric to an extended treatment with a solution of a strong mineral acid such as sulphuric acid for 30 to 120 minutes before rinsing the fabric and then commencing the dyeing sequence in the machine.
- a strong mineral acid such as sulphuric acid
- One process used successfully in commercial processing involves a post-treatment of a lyocell fabric that has been subjected to a wet processing operation such as dyeing.
- the protruding fibre ends produced in primary fibrillation are removed in this post-treatment by applying to the fabric a solution of a cellulase enzyme.
- the desired secondary fibrillation is developed in subsequent processing, for example in the dyeing process itself (if later) or in subsequent washing and drying steps using rotary tumbling machines, to produce a soft-touch finish on the surface of the fabric.
- Cellulase enzyme treatments are successful in removing the long fibre ends produced in primary fibrillation from the surface of the fabric, but they are expensive both in terms of material costs and in terms of processing time.
- a process was developed by the present applicant to overcome these deficiencies and is described in WO-A- 02/103104. It comprises a pre-treatment of a lyocell fabric carried out before the normal fibrillation-inducing steps of dyeing (such as jet-dyeing) , washing and drying, using vigorous action on the fabric in at least one of those steps so as to produce fibrillation on the surface of the fabric, and it involves evenly impregnating the fabric with an aqueous solution of an acid or acid donor before heat- treating it in a gaseous atmosphere to activate the action of the acid or acid donor.
- the temperature ranges quoted for heat treatment are 120 to 220°C, preferably 140 to 200°C. This process is able to produce dyed and finished lyocell fabrics having a clean, soft-touch finish substantially free from visible crease marks.
- the present invention provides a process for producing a dyed and finished lyocell fabric having a clean, soft-touch finish, comprising, subjecting a lyocell fabric to a wet processing treatment using mechanical action to induce fibrillation on the surface of the fabric and subsequently giving the fabric a tumbling treatment to develop the clean, soft-touch finish, characterised in that, at a stage prior to the tumbling treatment, the fabric is subjected to impregnation with a solution comprising a mixture of a multi-functional carboxylic acid and a Lewis acid, followed by a heat-treatment in a gaseous atmosphere at a temperature of 60°C to below 120°C.
- the process of the invention may be applied to woven and knitted lyocell fabrics in the length. It may also be applied to garments and piece goods made from lyocell fabrics, for which it is especially useful.
- the steps of impregnation with the mixed acids solution followed by the gaseous heat treatment are preferably carried out as a pre-treatment before the fibrillation- inducing step. Surprisingly, it is also possible to achieve effective results by carrying out these steps after the fibrillation-inducing step.
- the fibrillation- inducing step may be a dyeing process involving mechanical action on the fabric, one example being a jet-dyeing process in which the fabric, in fabric rope form, is propelled through a dyeing machine under the influence of jets of air or liquor and is thereby subjected to vigorous action, as by bending and twisting forces and impact and abrasive forces against machine surfaces.
- the effect of the steps of mixed acid impregnation and gaseous heat-treatment seems to be one of weakening the surface fibres of the lyocell fabric so that the relatively long fibres, . formed during the primary fibrillation phase are more easily removed in the normal course of the subsequent process steps.
- the use of the mixed acids is surprisingly more effective at giving rise to a clean, soft-touch finish after a tumbling treatment than using the individual carboxylic or Lewis acids on their own or a mixture of Lewis acids in corresponding amounts, and it allows the use of temperatures in the gaseous heat-treatment step of below 120°C, in particular below 115°C, more particularly below 110°C and preferably no greater than 100°C.
- the solution of the mixed acids is preferably an aqueous solution.
- the fabric may be evenly impregnated with this solution using any of the conventional techniques for applying liquids to fabric.
- Fabric in the length may be passed in open width through a pad bath of the aqueous solution, usually with a wet pick-up of the solution in the range 65 to 80 per cent by weight owf (on weight of fabric) .
- Piece goods or garments may be immersed in the solution in a vessel such as a drum washing machine. In this case, the wet pick-up is lower than with the padding method, usually about 45 to 55 per cent by weight owf .
- Immersion methods also require a hydro-extraction step such as spin-drying before the following heat treatment.
- the multi-functional carboxylic acid preferably is citric acid or tartaric acid.
- the Lewis acid preferably is magnesium chloride, zinc chloride, zinc fluoroborate or zinc nitrate.
- the concentration in the treatment solution of the carboxylic acid is suitably in the range 2 to 30 g/1 (grams per litre) , preferably 3 to 12 g/1, and the concentration of the Lewis acid is suitably in the range 2 to 45 g/1, preferably 8 to 30 g/1.
- the wet pick-up of the treatment solution varies according to the method of application and this will affect the concentration of each of the acids to be used.
- the respective concentration ranges are suitably 2 to 20 g/1, preferably 3 to 8 g/1, for the carboxylic acid and 2 to 30 g/1, preferably 8 to 20 g/1, for the Lewis acid.
- the respective concentration ranges are suitably 3 to 30 g/1, preferably 4 to 12 g/1, for the carboxylic acid and 3 to 45 g/1, preferably 11 to 30 g/1, for the Lewis acid.
- the heat-treatment of the impregnated fabric preferably is carried out in hot air as the gaseous atmosphere.
- treatment times depend upon the temperatures or acid concentrations being used, longer times being needed at the lower ends of the specified ranges.
- the treatment time may be in the range 2 to 15 minutes.
- the treatment time required may extend to 45 to 60 minutes.
- several hours of heat-treatment may be required.
- the fabric preferably is subjected to a desizing or scouring operation, usually carried out prior to the impregnation with the mixed acids solution.
- This desizing or scouring may be . a conventional operation in which the fabric is passed through a scouring bath to remove the size or lubricant. If pre-bleaching of the fabric is required, then it is also preferred that this is carried out prior to the impregnation with the mixed acids solution.
- Another possible treatment of the fabric is a so-called causticising treatment with an aqueous sodium hydroxide solution. If this is carried out, it is preferably carried out after the impregnation with the mixed acids solution and the subsequent heat treatment but before a dyeing step.
- Causticising is often carried out to improve the flexibility of the fabric in the wet state.
- a process for its application to lyocell fabrics is described in EP-A- 0,749,505, where it is described as mercerising.
- Causticising also enhances dyeability of the fabric which may be depressed by the acid treatment and it has the further effect that the fabric is tightened (modified) in structure, which helps to reduce any propensity for shrinkage in later wet processing.
- the fabric should be thoroughly rinsed with hot and then cold water to remove residual caustic soda.
- the acid impregnation and gaseous heat- treatment steps are preferably (but not necessarily) carried out as a pre-treatment before the fibrillation- inducing step.
- the latter step is a wet-processing step in which mechanical action exerted on the wet fabric causes fibrillation to occur on the fabric surface.
- This fibrillation is of the so-called primary fibrillation type in which relatively long protruding fibre ends are produced to give what would be an unsightly, hairy effect on the fabric surface if these long fibre ends were to remain in place.
- the effect of the gaseous heat treatment of the fabric impregnated with the solution of mixed acids is to substantially weaken the strength of these fibre ends, so that they are removed from the fabric surface during processing.
- the fibrillation-inducing step preferably is also the dyeing step, using a dyeing process which exerts the requisite mechanical action on the fabric.
- a dyeing process which exerts the requisite mechanical action on the fabric.
- this may be a jet- dyeing operation using commercial water-driven jet-dyeing machines or air jet-dyeing machines.
- this may be a rotary drum dyeing operation.
- Conventional dyes and dye recipes for cellulose fabrics may be used in the process of the invention, including those based on direct dyes, vat dyes, sulphur dyes and reactive dyes.
- the dyed fabric After being washed to remove any unfixed dye, the dyed fabric may be given one or more conventional finishing treatments including application of a soft-finish. These may be carried out after the dyeing and washing processes without the need for any intermediate drying of the fabric.
- the surface of the dyed fabric does not yet have the desired clean, soft-touch finish. It remains flat and uneven in appearance, possibly with some adherent lint.
- the fabric is given a tumbling treatment, sometimes referred to as a beating treatment, which raises the relatively short fibres of so- called secondary fibrillation in an even nap over the fabric surface.
- This treatment preferably is carried out as a dry treatment, i.e. without added liquid, and may be the step in which the fabric is given its final drying.
- Garments and piece goods may be given a tumbling treatment in a rotary tumbling machine such as a tumble-drier.
- Tumble-driers usually operate at temperatures of less than 100°C, often no greater than 85°C.
- Fabric in fabric rope form may be given a tumbling treatment in a fabric rope tumbler such as a Biancalani Airo tumbling machine. Tumbling treatment, times for a fabric rope are usually no longer than 30 to 50 minutes using air temperatures of 50°C to 150°C.
- the dry lyocell fabric produced by the process of the invention is a dyed fabric having a clean, soft-touch finish.
- the uniform, soft nap on the fabric surface imparts an attractive handle to the fabric and a subtle appearance, sometimes referred to as a frosted effect.
- the fabric surface may be characterized as having a peach- touch finish.
- the invention is illustrated by the following Examples.
- the lyocell fibres comprising the lyocell fabric processed were produced by Tencel Limited under the Trade Mark TENCEL.
- a lyocell fabric comprised a woven fabric of basis weight 180 gsm (grams per square metre) constructed in a 3 by 1 twill weave from yarns of count l/30s Ne comprising 100 per cent lyocell fibres.
- the fabric was scoured in open width - lo ⁇
- the desized fabric was then evenly impregnated with ' an aqueous solution comprising magnesium chloride hexahydrate at a concentration of 10.0 g/1 (grams per litre) and tartaric acid at a concentration of 4.0 g/1 by uniformly squeezing the solution into the fabric using a pad mangle at an . expression of 80 per cent wet pick-up.
- the impregnated fabric was dried and heat-treated on a stenter at an air temperature of 100°C for 15 minutes. After thorough rinsing with water, the treated fabric was then ready for dyeing.
- Dyeing was carried out in an Alliance Colora jet dyeing machine.
- the dyeing method used was a hot exhaust migration dyeing method carried out over a period of six hours using an aqueous dyebath containing:-
- Procion Navy H-EXL dye at 3.0 per cent owf (on weight of fabric) (Procion is a trademark of Dystar AG) Sodium sulphate at 60 g/1 Soda ash at 20 g/1
- the dyed fabric was then treated with a soft finish, Edunine CSA (Edunine is a trade mark of Uniqema) , at 2.0 per cent owf applied from an aqueous bath at a temperature of 40°C before being tumbled in a Thies Rototumbler HT fabric rope tumbling machine.
- the rope speed used was 300 metres per minute and the tumbling treatment was carried out in air at a temperature of 80°C for 45 minutes.
- the treated fabric had a uniformly clean surface appearance showing even dyeing and a soft-touch finish of sufficient development to be characterised as a peach-touch finish.
- a lyocell .fabric comprised a fabric knitted in an interlock construction from yarn of count l/40s Ne comprising 100 per cent lyocell fibres.
- the fabric was evenly impregnated with an aqueous solution comprising 10 g/1 magnesium chloride hexahydrate and 4 g/1 citric acid. Impregnation was achieved by soaking the fabric for 10 seconds in .a bath of the solution and then removing excess solution by hydro-extraction in a spin- drier for 1 minute. The solution pick-up on the fabric was 60 per cent owf.
- the damp fabric was dried and heat-treated in a tumble- drier at a temperature of 80°C for 1 hour.
- Pieces of the treated fabric were then dyed in an open- pocket Tupesa Ecodye 25 garment dyeing machine using the hot exhaust migration dyeing method with the following dye recipe at a final fixation temperature of 80°C :
- the dyed fabric pieces were given a soft-finish treatment as described in Example 1 and were then tumbled for 1 hour in a tumble-drier at a temperature of 80°C. At the end of this tumbling and drying treatment, they were seen to have a uniformly clean surface appearance, were evenly dyed and had a peach-touch finish.
- Example 2 The same construction of knitted fabric as was used in Example 2 was impregnated with an aqueous solution comprising 10 g/1 magnesium chloride hexahydrate and 2.6 g/1 citric acid. Impregnation was carried out by padding at 100 per cent pick-up owf. The wet fabric was dried and heat-treated on a pin stenter at an air temperature of 100°C for 5 minutes.
- Pieces of the treated fabric were dyed and then tumbled according to the procedures described in Example 2.
- the resulting fabric pieces had an attractive, clean surface. with a peach-touch finish.
- Example 2 The same construction of woven lyocell fabric as was used in Example 1 was . scoured and dyed as described in that Example but without the intermediate steps of impregnation and heat-treatment .
- the dyed fabric was seen to have an unsightly hairy and uneven surface caused by primary fibrillation induced during the jet dyeing process.
- This fabric was cut into pieces which were impregnated with an aqueous solution comprising 20 g/1 magnesium chloride hexahydrate and 8 g/1 tartaric acid. Impregnation was effected by soaking the fabric pieces for 10 seconds in a bath of the solution and then removing excess solution by a 1 minute hydro-extraction in a spin-drier to give 60 per cent pick-up owf.
- Example 3 The procedure of Example 3 was repeated using the same fabric construction but using an aqueous impregnating bath comprising: in the case of Example 5, 4 g/1 zinc chloride and 2.5 g/1 tartaric acid, and in the case of Example 6, 17 g/1 zinc fluoroborate and 4 g/1 tartaric acid.
- the impregnated samples were individually heat treated according to one o.f two methods as indicated in the Table below: • Method A Drying and heat treatment of the impregnated fabric sample on a stenter in a heated stenter oven at an air temperature of 100°C for 11 minutes. • Metho B Tumble drying in a tumble-drier at an air temperature of 80°C for 60 minutes.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0316747A GB2403956A (en) | 2003-07-17 | 2003-07-17 | Treatment of lyocell-containing fibres or fabrics with solution of a multifunctional carboxylic acid and solution of a Lewis acid, followed by heat treatment |
GB0316747.5 | 2003-07-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005010272A1 true WO2005010272A1 (fr) | 2005-02-03 |
Family
ID=27763998
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2004/003091 WO2005010272A1 (fr) | 2003-07-17 | 2004-07-16 | Teinture et finition de tissus de lyocell |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB2403956A (fr) |
WO (1) | WO2005010272A1 (fr) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995030043A1 (fr) * | 1994-05-03 | 1995-11-09 | Courtaulds Fibres (Holdings) Limited | Traitement d'une etoffe en fibre lyocell (fibre de cellulose tissee dans un solvant), destine a reduire la tendance de cette fibre a la fibrillation |
WO2001073186A2 (fr) * | 2000-03-29 | 2001-10-04 | The Procter & Gamble Company | Procedes d'amelioration de la resistance de tissus a la fibrillation et au boulochage et tissus presentant des proprietes ameliorees |
WO2002103104A2 (fr) * | 2001-06-15 | 2002-12-27 | Tencel Limited | Teinture et finissage de fibres lyocell |
-
2003
- 2003-07-17 GB GB0316747A patent/GB2403956A/en not_active Withdrawn
-
2004
- 2004-07-16 WO PCT/GB2004/003091 patent/WO2005010272A1/fr active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995030043A1 (fr) * | 1994-05-03 | 1995-11-09 | Courtaulds Fibres (Holdings) Limited | Traitement d'une etoffe en fibre lyocell (fibre de cellulose tissee dans un solvant), destine a reduire la tendance de cette fibre a la fibrillation |
WO2001073186A2 (fr) * | 2000-03-29 | 2001-10-04 | The Procter & Gamble Company | Procedes d'amelioration de la resistance de tissus a la fibrillation et au boulochage et tissus presentant des proprietes ameliorees |
WO2002103104A2 (fr) * | 2001-06-15 | 2002-12-27 | Tencel Limited | Teinture et finissage de fibres lyocell |
Also Published As
Publication number | Publication date |
---|---|
GB0316747D0 (en) | 2003-08-20 |
GB2403956A (en) | 2005-01-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1599630B1 (fr) | Procede de production d'un tissu de fibre lyocell teint et apprete | |
KR100513084B1 (ko) | 셀룰로우스 직물의 염색 및 마무리 방법 | |
EP1404917B1 (fr) | Teinture et finissage de fibres lyocell | |
JP2004518038A (ja) | 染色されたリヨセル衣料品の製造 | |
KR100963697B1 (ko) | 모드 직물의 염색 및 마무리 가공방법 | |
WO2005010272A1 (fr) | Teinture et finition de tissus de lyocell | |
CN108716107B (zh) | 一种煮漂液、预处理液、面料、面料的染色方法及服饰 | |
JP4312337B2 (ja) | セルロース系繊維の改質方法 | |
GB2314568A (en) | Fibre finishing treatment | |
EP1536707B1 (fr) | Vetement capable de reprendre sa forme initiale apres extension et procedes de fabrication | |
WO2021180817A1 (fr) | Procédé pour la réduction du comportement de boulochage d'un tissu contenant des fibres cellulosiques artificielles ou constitué de celles-ci | |
KR19990082009A (ko) | 라이오셀 직물의 일차 피브릴화 경향을 감소시키는 방법 | |
JP2677139B2 (ja) | カラージーンズ調編地衣料の製造方法 | |
JPH01298273A (ja) | 再生セルロース系繊維織編物の加工方法 | |
JPH11124779A (ja) | 溶剤紡糸セルロース繊維含有布帛の加工方法 | |
Hussain | Developments in the Processing of Lyocell Fabrics | |
JP2008266855A (ja) | セルロース系繊維構造物の濃染化方法およびその方法で染色されたセルロース系繊維構造物 | |
JPH0327667B2 (fr) | ||
JP2001234465A (ja) | セルロース系繊維の形態安定加工方法 | |
JP2005139599A (ja) | アクリル繊維布帛用前処理剤及びこれを用いた前処理方法 | |
JPH05321172A (ja) | 縫製品の洗いざらし調加工方法 | |
JPH11256469A (ja) | 緯編物の処理方法 | |
JPH06200486A (ja) | 染色堅牢度に優れた立毛布帛の製造方法 | |
JPH0718588A (ja) | セルロース系繊維構造物の洗い晒し調加工方法 | |
GB2318808A (en) | Lyocell fabric:treatment |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
122 | Ep: pct application non-entry in european phase |