WO2005007595A3 - Materiau perovskite, procede de preparation et utilisation dans un reacteur catalytique membranaire - Google Patents

Materiau perovskite, procede de preparation et utilisation dans un reacteur catalytique membranaire Download PDF

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Publication number
WO2005007595A3
WO2005007595A3 PCT/FR2004/001798 FR2004001798W WO2005007595A3 WO 2005007595 A3 WO2005007595 A3 WO 2005007595A3 FR 2004001798 W FR2004001798 W FR 2004001798W WO 2005007595 A3 WO2005007595 A3 WO 2005007595A3
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WIPO (PCT)
Prior art keywords
atom selected
membrane reactor
catalytic membrane
perovskite material
preparation
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Application number
PCT/FR2004/001798
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English (en)
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WO2005007595A2 (fr
Inventor
Gregory Etchegoyen
Thierry Chartier
Gallo Pascal Del
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Air Liquide
Gregory Etchegoyen
Thierry Chartier
Gallo Pascal Del
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Publication date
Application filed by Air Liquide, Gregory Etchegoyen, Thierry Chartier, Gallo Pascal Del filed Critical Air Liquide
Priority to EP04767630A priority Critical patent/EP1646595A2/fr
Priority to CA002531592A priority patent/CA2531592A1/fr
Priority to US10/562,521 priority patent/US20060145126A1/en
Publication of WO2005007595A2 publication Critical patent/WO2005007595A2/fr
Publication of WO2005007595A3 publication Critical patent/WO2005007595A3/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/0271—Perovskites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B01J35/59—Membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C01B13/0229—Purification or separation processes
    • C01B13/0248—Physical processing only
    • C01B13/0251—Physical processing only by making use of membranes
    • C01B13/0255—Physical processing only by making use of membranes characterised by the type of membrane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/26—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on ferrites
    • C04B35/2641—Compositions containing one or more ferrites of the group comprising rare earth metals and one or more ferrites of the group comprising alkali metals, alkaline earth metals or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/26—Electrical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00—Purification or separation of specific gases
    • C01B2210/0043—Impurity removed
    • C01B2210/0046—Nitrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • Catalysts (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

Matériau conducteur mixte électronique et d'anions O2- de type perovskite, de formule (I) : A(a)(1 -x-u) A′(a-1) x A′′(a′′)u B(b)(1-s-y-v) B(b+1)s B′(b+β)y B′′(b′′)v O3-δ, formule (I) dans laquelle : a, a-1, a′′, b, b+1, b+β et b′′ sont des nombres entiers représentant les valences respectives des atomes A, A′, A′′, B, B′, B′′ ; a, a′′, b, b′′, β, x, y, s, u, v et δ sont tels que la neutralité électrique du réseau cristallin est conservée, A représente un atome choisi parmi le scandium, l'yttrium ou dans les familles des lanthanides, des actinides ou des métaux alcalino-terreux, A′ est un atome choisi parmi le scandium, l'yttrium ou dans les familles des lanthanides, des actinides ou des métaux alcalin-terreux ; A′′ un atome choisi parmi Al, Ga, In ou Tl ; B, B′, B′′ un atome choisi parmi les métaux de transition, Al, In, Ga, Ge, Sb, Bi, Sn ou Pb ; procédé pour sa préparation et son utilisation comme matériau conducteur mixte d'un réacteur catalytique membranaire, destiné à être mis en œuvre pour synthétiser du gaz de synthèse par oxydation de méthane ou de gaz naturel.
PCT/FR2004/001798 2003-07-11 2004-07-08 Materiau perovskite, procede de preparation et utilisation dans un reacteur catalytique membranaire WO2005007595A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP04767630A EP1646595A2 (fr) 2003-07-11 2004-07-08 Materiau perovskite, procede de preparation et utilisation dans un reacteur catalytique membranaire
CA002531592A CA2531592A1 (fr) 2003-07-11 2004-07-08 Materiau perovskite, procede de preparation et utilisation dans un reacteur catalytique membranaire
US10/562,521 US20060145126A1 (en) 2003-07-11 2004-07-08 Perovskite material, preparation method and use in catalytic membrane reactor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0350324A FR2857355B1 (fr) 2003-07-11 2003-07-11 Materiau perovskite, procede de preparation et utilisation dans un reacteur catalytique membranaire
FR03/50324 2003-07-11

Publications (2)

Publication Number Publication Date
WO2005007595A2 WO2005007595A2 (fr) 2005-01-27
WO2005007595A3 true WO2005007595A3 (fr) 2005-03-24

Family

ID=33523102

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PCT/FR2004/001798 WO2005007595A2 (fr) 2003-07-11 2004-07-08 Materiau perovskite, procede de preparation et utilisation dans un reacteur catalytique membranaire

Country Status (7)

Country Link
US (1) US20060145126A1 (fr)
EP (1) EP1646595A2 (fr)
CN (1) CN100363300C (fr)
CA (1) CA2531592A1 (fr)
FR (1) FR2857355B1 (fr)
WO (1) WO2005007595A2 (fr)
ZA (1) ZA200600220B (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030140052A1 (en) * 2001-12-18 2003-07-24 Shawn Thomas Method and system for asset transition quality control
US7122072B2 (en) * 2003-11-17 2006-10-17 Air Products And Chemicals, Inc. Controlled heating and cooling of mixed conducting metal oxide materials
CN100381205C (zh) * 2005-08-17 2008-04-16 江汉大学 膜反应法制备凝胶及纳米催化剂
JP2009215149A (ja) * 2008-02-14 2009-09-24 Sumitomo Chemical Co Ltd 焼結体および熱電変換材料
ES2331828B2 (es) * 2008-06-27 2011-08-08 Universidad Politecnica De Valencia Capa catalitica para la activacion de oxigeno sobre electrolitos solidos ionicos a alta temperatura.
EP2374526A1 (fr) 2010-03-29 2011-10-12 Centre National de la Recherche Scientifique (C.N.R.S) Membrane composite solide démontrant une bonne conductivité de l'oxygène et interface de catalyseur de substrat
CN103943368A (zh) * 2014-04-28 2014-07-23 中国科学院青岛生物能源与过程研究所 一种新型含锗钙钛矿材料及其太阳能电池
FR3086282B1 (fr) * 2018-09-20 2020-09-25 Saint Gobain Ct Recherches Produit fondu polycristallin a base de brownmillerite
KR102315375B1 (ko) * 2019-12-18 2021-10-20 한국과학기술원 산화물 지지체-나노입자 복합 구조체의 제조 방법
CN116217226B (zh) * 2023-02-23 2024-03-12 中国科学院上海硅酸盐研究所 一种bs-pt基高温压电陶瓷材料及其制备方法

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JP2000251533A (ja) * 1999-02-24 2000-09-14 Mitsubishi Materials Corp 酸化物イオン混合伝導体とその用途
JP2001093325A (ja) * 1999-09-27 2001-04-06 Tatsuki Ishihara ＬａＧａＯ３系電子−酸素イオン混合伝導体及びそれを用いた酸素透過膜

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Also Published As

Publication number Publication date
ZA200600220B (en) 2007-04-25
EP1646595A2 (fr) 2006-04-19
CN1823025A (zh) 2006-08-23
WO2005007595A2 (fr) 2005-01-27
FR2857355A1 (fr) 2005-01-14
FR2857355B1 (fr) 2007-04-20
CA2531592A1 (fr) 2005-01-27
US20060145126A1 (en) 2006-07-06
CN100363300C (zh) 2008-01-23

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