WO2005000757A1 - Kunststoffmasse, erzeugnis mit der kunststoffmasse und verwendung der kunststoffmasse - Google Patents
Kunststoffmasse, erzeugnis mit der kunststoffmasse und verwendung der kunststoffmasse Download PDFInfo
- Publication number
- WO2005000757A1 WO2005000757A1 PCT/EP2004/051267 EP2004051267W WO2005000757A1 WO 2005000757 A1 WO2005000757 A1 WO 2005000757A1 EP 2004051267 W EP2004051267 W EP 2004051267W WO 2005000757 A1 WO2005000757 A1 WO 2005000757A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- glass
- plastic
- ceramic
- plastic mass
- product
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0054—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing PbO, SnO2, B2O3
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/004—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of particles or flakes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/008—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in molecular form
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/46—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes silicones
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/12—Polymers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2214/00—Nature of the non-vitreous component
- C03C2214/30—Methods of making the composites
Definitions
- the invention relates to a plastic composition with at least one polymer, at least one organic starting compound at least one ceramic material and at least one glass material to form a glass ceramic with the ceramic material which has a glass and / or a starting material of the glass.
- a product with the plastic mass and a use of the plastic mass is specified.
- a plastic ace of the type mentioned, a product with the plastic mass and a use of the plastic mass are known from WO 01/85634 AI.
- the plastic mass can be ceramized. This means that the plastic mass can be converted into a ceramic material by thermal decomposition (pyrolysis).
- Plastic mass is a base material from which the
- Plastic mass mainly consists.
- Plastic mass is, for example, a polyorganosiloxane (polysiloxane, silicone, [P - 2 (SiO)] x ).
- the polyorganosiloxane for example poly (dimethylsiloxane) ([(CH3) 2 (SiO)] x ), is not only the base material of the plastic mass, but also the organic starting compound of the ceramic material of the plastic mass.
- the polyorganosiloxane for example poly (dimethylsiloxane) ([(CH3) 2 (SiO)] x .
- Plastic mass on an inorganic starting material of the ceramic material for example aluminum oxide (AI2O3).
- the glass material for forming the glass ceramic is, for example, a borosilicate glass.
- the thermal decomposition of the plastic mass forms a glass ceramic that has ceramic phases and glass phases.
- the thermal decomposition of the polyorganosiloxane in air (decomposition temperature Tz of about 500 ° C.) initially occurs a more or less porous, amorphous basic structure (matrix) made of silicon dioxide (Si ⁇ 2).
- the silicon dioxide reacts at higher temperatures (1000 ° C to 1200 ° C) with the aluminum oxide to form the ceramic material in the form of an aluminum or aluminum silicate.
- the ceramic material is, for example, the aluminum silicate mullite (I2O3 x SiC> 2) -
- the presence of the borosilicate glass forms a glass ceramic with the ceramic material.
- the borosilicate glass has a glass point Tg of approximately 560 ° C.
- Tg glass point
- the borosilicate glass leads to a compression of the starting compounds and / or of intermediate products of the ceramic material by viscous flow. This creates a high-density glass ceramic from the initially porous framework made of silicon dioxide.
- the plastic compound is used, for example, as an FRNC (Flame Retardant Non Corrosive) cable sheathing for the electrical insulation of a cable. If the cable burns, the plastic mass is thermally decomposed.
- the cable sheathing forms a dense, mechanically resilient, electrically insulating layer made of a glass ceramic. The cable will continue to function even in the event of a fire, at least for a certain period of time. Failure of a function of the cable due to a fire in the cable is delayed.
- the plastic mass is converted into a very dense glass ceramic during a time-dependent thermal decomposition, which is associated with a very rapid increase in temperature.
- the object of the present invention is to provide a plastic composition which, even in the case of thermal decomposition, which is accompanied by a relatively slow increase in temperature, leads to a dense glass ceramic.
- a plastic mass with at least one polymer, at least one organic starting compound of at least one ceramic material and at least one glass material is used to form a
- Glass ceramic specified with the ceramic material which has a glass and / or a starting material of the glass.
- the plastic mass is characterized in that the glass has a glass point Tg which essentially corresponds to a decomposition temperature Tz of the organic starting compound.
- a product is specified with the plastic mass for chemical and / or electrical insulation of at least one component of the product.
- the plastic mass is used to produce a glass ceramic by thermally decomposing the plastic mass.
- the pyrolysis of the plastic mass decomposes the organic starting compound of the ceramic material.
- the organic starting compound is in particular a polyorganosiloxane.
- the polyorganosiloxane is, for example, poly (dimethylsiloxane).
- Polyorganosiloxanes have a decomposition temperature Tz below 500 ° C. Thereby forms a porous framework made of silicon dioxide or silicon oxycarbide. Glass is now infiltrated into this porous framework at a relatively low temperature. This is achieved in that the glass used has a low viscosity at the decomposition temperature Tz of the organic starting compound. Due to capillary forces, the more or less liquid glass is infiltrated into the porous silicon dioxide framework.
- a compaction of the starting materials of the glass ceramic or the intermediate stages of the glass ceramic is thus ensured even in the case of thermal decomposition, which is accompanied by a relatively slow increase in temperature.
- the result is a glass-ceramic material with a high level of tightness.
- a solid, dense ash layer is obtained even with a rapid temperature increase.
- organic starting compounds are conceivable as organic starting compounds.
- the polymer itself is preferably the organic starting compound.
- the organic starting compound is an organosilicon polymer such as polysilane, polycarbosilane, polysilazane or polyorganosiloxane.
- a mixture of different polymers or a copolymer of different organometallic and non-organometallic monomers is also conceivable.
- the organic starting compound can be polymerized or monomeric. Monomer means that the organic starting compound is uncrosslinked and polymerizes, that the organic starting compound is partially or completely crosslinked.
- the organic starting compound can form the base material of the plastic mass. It is also conceivable that the organic starting compound an admixture of the base material Plastic mass is.
- the organic starting compound is an organometallic salt or an organometallic complex.
- the glass in particular has a glass point Tg of less than 500 ° C. If the organic starting compound only decomposes at a higher temperature, a glass with a glass point Tg above 500 ° C. can also be used.
- the ceramic material and / or the glass ceramic with the ceramic material have in particular at least one element selected from the group aluminum, boron, barium, bismuth, calcium, magnesium, nitrogen, oxygen, silicon, titanium, zinc and / or zirconium.
- the ceramic material is a silicate.
- Silicate is an aluminum or aluminum silicate.
- Such silicates are, for example, mullite, sillimanite or kyanite.
- the polymer of the plastic mass and / or the organic starting compound of the ceramic material has a halogen content of less than one mol. % on.
- Cable jackets made of halogen-containing polymers are usually used to protect a cable against fire.
- a common, flame-retardant polymer is, for example, polyvinyl chloride (PVC).
- PVC polyvinyl chloride
- These halogen-containing polymers cleave halogens or halogen compounds during thermal decomposition.
- the halogens or halogen compounds lead to containment of a fire in the plastic mass. Released halogens and halogen compounds can, however, lead to high environmental pollution.
- hydrochloric acid (HC1) is formed during the thermal decomposition of polyvinyl chloride.
- the plastic mass is almost halogen-free, so that halogens or the acids of the halogens are not released in the event of a fire in the plastic mass.
- Glasses which have a low glass point Tg. Such glasses are in particular glasses with alkali, lead and / or phosphate ions. These glasses can release hazardous reaction products. In this way, phosphorous acid can be formed from the glasses containing phosphate ions. Glasses containing lead ions are a burden on the environment due to the existing lead alone. In addition, glasses containing lead ions and those containing alkali ions are characterized by a relatively high electrical conductivity. In view of good electrical insulation and in view of high environmental compatibility, in a particular embodiment of the invention the glass has an alkali ion fraction and / or a lead ion fraction and or a phosphate ion fraction of less than one mol% each.
- the glass ceramic produced by thermal decomposition of the plastic mass has a low electrical conductivity. This is important in connection with the electrical insulation effect of the glass ceramic that is formed during the thermal decomposition of the plastic mass.
- the plastic mass or the reaction product of the plastic mass is environmentally friendly.
- At least one inorganic starting material of the ceramic material is available.
- the inorganic starting material can be present as a salt or even as a ceramic material.
- the inorganic starting material Alumina.
- Other inorganic starting materials, for example silicon carbide (SiC), are also conceivable. These starting materials can already be in a reactive form. This means that the starting materials react directly with the basic structure generated by the thermal decomposition of the organic starting material or with the material of the basic structure. This creates the ceramic material.
- the inorganic starting material or materials are preferably in the form of oxides. It is also conceivable that the reactive inorganic
- Fire can contribute.
- aluminum hydroxide ((AI (OH) 3) is formed by splitting off water
- Low temperature range i.e. an area below the
- the inorganic compound inorganic
- the inorganic starting compound is in particular aluminum oxide.
- the aluminum oxide is a fine powder that is homogeneously distributed in the plastic mass. In this form, the alumina performs two functions. The aluminum oxide reacts with pyrolysis products of the organic starting compound to form the ceramic material. Since the fine powder particles made of aluminum oxide have a large surface area, they are characterized by a high surface area
- Starting material of the glass on the plastic mass selected from the range from 1 vol.% To 30 vol.% And in particular from the range from 5 vol.% To 15 vol.%. This relatively small volume fraction of the glass is sufficient to produce a dense thermal decomposition of the plastic mass
- Get glass ceramic A low-melting glass solder can be used.
- a glass solder is inexpensive.
- the glass point Tg of the glass solder can be varied over a wide range, so that the viscosity of the glass solder can be easily adapted to the decomposition temperature Tz of the organic starting compound.
- the glass material preferably has highly reactive glasses.
- Such glasses are in particular glasses with boron oxide (B2O3), bismuth oxide (Bi2Ü3), zinc oxide (ZnO) and small fractions of
- the plastic mass is particularly suitable for chemical and / or electrical insulation of at least one component of the product.
- the product is a fireproof product. Any product is conceivable.
- the product is a household appliance and the component is an electrical component of the household appliance.
- the plastic mass is processed, for example, to form a fire protection plate or a fire-resistant rubber seal, so that the component of the household appliance is protected against a fire.
- the processing of the fire protection plate or the rubber seal can be done in a press or injection molding process.
- the component of the product has a covering with the plastic mass.
- a product is in particular an optical conductor or a cable.
- the component of such a product is a cable core of the cable.
- the sheathing is a cable sheathing of the cable core.
- the cable sheathing is used for the electrical insulation of the cable core.
- Plastic mass of the cable sheathing leads to a dense, mechanically resilient and electrically insulating glass ceramic, which takes over the function of the original cable sheathing. Due to these properties of the plastic mass, the cable sheathing can be used as a FRNC
- Cable sheathing can be used.
- An extrusion process is used, for example, to produce the cable sheathing.
- the plastic mass leads to the electrical insulation of the product or the component of the product being retained.
- the glass ceramic produced during the thermal decomposition of the plastic mass means that the component is chemically isolated.
- a dense coating of the component that is almost impervious to chemicals is formed. The coating acts as a barrier to the chemicals.
- a Part of the component must not come into contact with a part of the environment of the component and react accordingly.
- a cable could have an outer and an inner cable jacket.
- the cable sheathing with the plastic compound forms the outer cable sheathing.
- the inner cable sheathing is arranged between the outer cable sheathing with the plastic compound and the cable core and consists of an inexpensive, easily flammable plastic.
- the outer cable sheathing with the plastic mass forms a dense layer of glass ceramic, which ensures that, for example, oxygen does not reach the easily flammable plastic of the inner cable sheathing.
- the inner cable sheath does not burn and remains intact, so that the electrical insulation of the cable core is ensured even in the event of a fire.
- the outer cable sheathing is produced, for example, by brushing or spraying a thin layer of the plastic mass with uncrosslinked or partially crosslinked polymer on the inner cable sheathing applied.
- a refractory coating is formed from the ceramicizable plastic.
- the sheathing of the component of the product has, in addition to the plastic mass, further, for example easily flammable and non-ceramizable, plastic masses.
- plastic mass for example easily flammable and non-ceramizable, plastic masses.
- the degree of filling of the ceramizable plastic mass chosen so high that a dense glass ceramic layer is formed in the event of a fire. Due to the dense glass ceramic layer formed in the event of a fire, there is almost no exchange of material with the surroundings. This means that no oxygen can reach the easily combustible plastic mass. The fire of the cable can be contained.
- the glass is infiltrated into the porous structure produced by the thermal decomposition of the plastic mass. This contributes to the stability of the structure of the glass ceramic.
- the glass ceramic is compacted by reactive liquid phase sintering. This leads to a high-density layer made of the glass ceramic.
- the plastic mass can be used as an efficient FRNC cable sheathing due to the chemical, electrical and mechanical stability of the glass ceramic produced by the thermal decomposition.
- Figure 1 shows a cross section of an electrical product with the plastic mass.
- Figure 2 shows a cross section of a further electrical product with the plastic mass.
- the electrical product 1 is a cable with a
- Cable core 2 made of an electrically conductive material and one
- Plastic base has a polymer made of poly (dimethylsiloxane) as the base material.
- the poly (dimethylsiloxane) acts as an organic starting compound of at least one ceramic material.
- the inorganic material and a glass material to form the glass ceramic with the ceramic material included.
- the starting compound is powdered aluminum oxide.
- Powder particles have an average powder particle size D50 of approximately 1 ⁇ m.
- the glass material is also in powder form with a powder particle size D 0 of approximately 1 ⁇ m.
- the glass material is a glass powder mixture with the following composition: 27.5 mol.% Boron oxide, 34.8 mol.% Bismuth oxide, 32.5 mol.% Zinc oxide and 6 mol.% Silicon dioxide.
- the glass powder mixture is about 10 vol.% Contained in the plastic mass.
- the cable sheathing essentially consists only of the plastic compound (FIG. 1).
- an electrically insulating protective layer made of glass ceramic is formed from the electrically insulating plastic compound.
- the cable sheathing does not only consist of the ceramizable one
- the cable sheath also has an easily flammable elastomer.
- the proportion of the ceramizable plastic mass in the cable sheathing is chosen so high that in the event of a fire, a chemically insulating protective layer of glass ceramic is formed. This protective layer ensures that the easily flammable Elastomer is largely protected from attack by oxygen. The cable fire comes to a standstill.
- the cable has an inner cable sheathing 4 and an outer cable sheathing 3 (FIG. 2).
- the outer cable sheath 3 consists of the ceramizable plastic mass.
- the inner cable sheathing 4 consists of an easily combustible polymer.
- the outer cable jacket forms a dense, chemically and electrically insulating protective layer made of glass ceramic. The electrically insulating, inner cable sheath is largely retained. The function of the cable is secured.
- partially crosslinked organosilicon polymer is mixed and homogenized together with the glass powder mixture and the aluminum oxide powder in a double Z kneader.
- the cable core of the cable is coated in an extruder, a preheated wire, which forms the cable core, being coated with a melt of the plastic compound in the extruder head by means of a quill head.
- the crosslinking of the polymer is advanced, forming the cable jacket.
- the plastic mass is characterized, for example, by the following characteristic data: average heat release rate: 80 kW / m ⁇ ; Time of ignition (ti e to ignition): 117 s; Flame development index: 0.98 m2s / k; Development of smoke (smoke parameter): 121 (MW / kg); high ash stability.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04766086A EP1641718A1 (de) | 2003-06-27 | 2004-06-28 | Kunststoffmasse, erzeugnis mit der kunststoffmasse und verwendung der kunststoffmasse |
JP2006516194A JP2007526866A (ja) | 2003-06-27 | 2004-06-28 | プラスチック材料、該プラスチック材料を用いた製品および該プラスチック材料の使用 |
US10/561,004 US20070267215A1 (en) | 2003-06-27 | 2004-06-28 | Plastic Compound, Product Composed of Said Compound and Use of Said Compound |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10329117.2 | 2003-06-27 | ||
DE10329117A DE10329117A1 (de) | 2003-06-27 | 2003-06-27 | Kunststoffmasse, Erzeugnis mit der Kunststoffmasse und Verwendung der Kunststoffmasse |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005000757A1 true WO2005000757A1 (de) | 2005-01-06 |
Family
ID=33521131
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2004/051267 WO2005000757A1 (de) | 2003-06-27 | 2004-06-28 | Kunststoffmasse, erzeugnis mit der kunststoffmasse und verwendung der kunststoffmasse |
Country Status (7)
Country | Link |
---|---|
US (1) | US20070267215A1 (de) |
EP (1) | EP1641718A1 (de) |
JP (1) | JP2007526866A (de) |
KR (1) | KR20060026069A (de) |
CN (1) | CN1812939A (de) |
DE (1) | DE10329117A1 (de) |
WO (1) | WO2005000757A1 (de) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100273011A1 (en) * | 1996-12-20 | 2010-10-28 | Bianxiao Zhong | Silicone Composition, Silicone Adhesive, Coated and Laminated Substrates |
JP5357046B2 (ja) * | 2006-12-20 | 2013-12-04 | ダウ・コーニング・コーポレイション | 硬化シリコーン組成物で被覆またはラミネートされたガラス基板 |
EP2125651A1 (de) * | 2006-12-20 | 2009-12-02 | Dow Corning Corporation | Mit mehreren schichten von gehärteten silikonharzzusammensetzungen beschichtete oder laminierte glassubstrate |
CN101959939B (zh) * | 2008-03-04 | 2013-02-06 | 陶氏康宁公司 | 硼硅氧烷组合物,硼硅氧烷粘合剂,涂布和层压的基底 |
EP2250221A1 (de) * | 2008-03-04 | 2010-11-17 | Dow Corning Corporation | Silikonzusammensetzung, silikonhaftmittel sowie beschichtete und laminierte substrate |
WO2009128527A1 (ja) * | 2008-04-18 | 2009-10-22 | 日本電気硝子株式会社 | 色素増感型太陽電池用ガラス組成物および色素増感型太陽電池用材料 |
US20110045277A1 (en) * | 2008-05-27 | 2011-02-24 | Nathan Greer | Adhesive Tape and Laminated Glass |
EP2299536A4 (de) * | 2008-06-17 | 2011-12-21 | Nippon Electric Glass Co | Substrat für solarzelle und oxidhalbleiterelektrode für farbstoffsensibilisierte solarzelle |
TW201004795A (en) * | 2008-07-31 | 2010-02-01 | Dow Corning | Laminated glass |
JP2011044426A (ja) | 2009-07-24 | 2011-03-03 | Nippon Electric Glass Co Ltd | 太陽電池用導電膜付ガラス基板 |
EP2638106A1 (de) | 2010-11-09 | 2013-09-18 | Dow Corning Corporation | Anhand von organophosphorverbindungen weichgemachte hydrosilylierungsgehärtete silikonharze |
DE102015009409A1 (de) | 2015-07-20 | 2017-01-26 | Adamy GmbH | Elektrisches Kabel mit thermochromen Substanzen enthaltender Isolierschicht und Verfahren zu seiner Herstellung |
DE102015009407A1 (de) | 2015-07-20 | 2017-01-26 | Adamy GmbH | Thermochromes Kabel zur Verbindung von Batterien und Verfahren zu seiner Herstellung |
DE202015005175U1 (de) | 2015-07-20 | 2015-09-16 | Adamy GmbH | Elektrisches Kabel mit thermochromen Substanzen enthaltender Isolierschicht |
DE202015005173U1 (de) | 2015-07-20 | 2015-09-16 | Adamy GmbH | Thermochromes Kabel zur Verbindung von Batterien |
WO2021067288A1 (en) * | 2019-09-30 | 2021-04-08 | Champlain Cable Corp. | Fire resistant cable |
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US2684349A (en) * | 1952-12-17 | 1954-07-20 | Gen Electric | Silicone rubber having improved flame-retardant properties |
EP0456557A1 (de) * | 1990-05-07 | 1991-11-13 | Shin-Etsu Chemical Co., Ltd. | Schäumbare Silikonkautschukzusammensetzung |
WO2001085634A1 (de) * | 2000-05-08 | 2001-11-15 | Siemens Aktiengesellschaft | Kunststoffmasse, verwendung der kunststoffmasse und erzeugnis mit der kunststoffmasse |
JP2003003069A (ja) * | 2001-06-21 | 2003-01-08 | Fujikura Ltd | シリコーン樹脂組成物およびそれを用いた低圧耐火ケーブル |
WO2004013255A1 (en) * | 2002-08-01 | 2004-02-12 | Polymers Australia Pty Limited | Fire-resistant silicone polymer compositions |
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---|---|---|---|---|
US4184995A (en) * | 1976-11-05 | 1980-01-22 | General Electric Company | Flame insulative silicone compositions |
JPS55120658A (en) * | 1979-03-13 | 1980-09-17 | Toray Silicone Co Ltd | Silicone composition forming ceramic at high temperature |
-
2003
- 2003-06-27 DE DE10329117A patent/DE10329117A1/de not_active Withdrawn
-
2004
- 2004-06-28 JP JP2006516194A patent/JP2007526866A/ja not_active Withdrawn
- 2004-06-28 WO PCT/EP2004/051267 patent/WO2005000757A1/de not_active Application Discontinuation
- 2004-06-28 KR KR1020057025040A patent/KR20060026069A/ko not_active Application Discontinuation
- 2004-06-28 CN CNA2004800181957A patent/CN1812939A/zh active Pending
- 2004-06-28 US US10/561,004 patent/US20070267215A1/en not_active Abandoned
- 2004-06-28 EP EP04766086A patent/EP1641718A1/de not_active Withdrawn
Patent Citations (5)
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---|---|---|---|---|
US2684349A (en) * | 1952-12-17 | 1954-07-20 | Gen Electric | Silicone rubber having improved flame-retardant properties |
EP0456557A1 (de) * | 1990-05-07 | 1991-11-13 | Shin-Etsu Chemical Co., Ltd. | Schäumbare Silikonkautschukzusammensetzung |
WO2001085634A1 (de) * | 2000-05-08 | 2001-11-15 | Siemens Aktiengesellschaft | Kunststoffmasse, verwendung der kunststoffmasse und erzeugnis mit der kunststoffmasse |
JP2003003069A (ja) * | 2001-06-21 | 2003-01-08 | Fujikura Ltd | シリコーン樹脂組成物およびそれを用いた低圧耐火ケーブル |
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Also Published As
Publication number | Publication date |
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EP1641718A1 (de) | 2006-04-05 |
US20070267215A1 (en) | 2007-11-22 |
KR20060026069A (ko) | 2006-03-22 |
DE10329117A1 (de) | 2005-01-20 |
CN1812939A (zh) | 2006-08-02 |
JP2007526866A (ja) | 2007-09-20 |
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