WO2004085714A1 - Dispositif et partie de ce dispositif pour la formation par depot galvanique de pieces faconnees dentaires - Google Patents

Dispositif et partie de ce dispositif pour la formation par depot galvanique de pieces faconnees dentaires Download PDF

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Publication number
WO2004085714A1
WO2004085714A1 PCT/EP2004/002955 EP2004002955W WO2004085714A1 WO 2004085714 A1 WO2004085714 A1 WO 2004085714A1 EP 2004002955 W EP2004002955 W EP 2004002955W WO 2004085714 A1 WO2004085714 A1 WO 2004085714A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrode
connecting means
magnetic connecting
magnet
electrodeposition
Prior art date
Application number
PCT/EP2004/002955
Other languages
German (de)
English (en)
Other versions
WO2004085714A8 (fr
Inventor
Alexander SCHRÖCK
Ralf Hornung
Jürgen Laubersheimer
Original Assignee
Wieland Dental + Technik Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wieland Dental + Technik Gmbh & Co. Kg filed Critical Wieland Dental + Technik Gmbh & Co. Kg
Priority to JP2006504778A priority Critical patent/JP2006521465A/ja
Priority to AT04722179T priority patent/ATE480649T1/de
Priority to CA002519519A priority patent/CA2519519A1/fr
Priority to DE502004011639T priority patent/DE502004011639D1/de
Priority to EP04722179A priority patent/EP1606436B1/fr
Priority to US10/549,682 priority patent/US20060131162A1/en
Publication of WO2004085714A1 publication Critical patent/WO2004085714A1/fr
Publication of WO2004085714A8 publication Critical patent/WO2004085714A8/fr

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/005Contacting devices
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49567Dental appliance making

Definitions

  • the invention relates to a device and its essential parts for the electroplating, in particular for the electroplating of dental molded parts such as frameworks for crowns, inlays, bridges and the like, according to the preamble of claim 1.
  • Galvanic deposition i. H. the deposition under current flow, metallic layers has been known for a long time. If molded parts are formed, i.e. bodies that are stable in themselves, this is known as electroforming.
  • Electroplated gold layers have a much higher hardness than cast ones, which is between 60-80 HV or between 100-130 HV depending on the electrolyte composition. These electroplated gold layers are usually free of voids, inhomogeneities and contaminants, which are inevitable when casting. Nevertheless, it can be caused by improper work and due to the introduction of contaminants or manufacturer-related process fluctuations in the separation process. These show up e.g. B. by electroplating impurities, bud formation, layer formation or holes in the layer. In the worst case, such disturbances can lead to loss of firing stability and thus make the layers / moldings obtained unsuitable for further processing in dental technology.
  • the problem with the production of dental prostheses / dental molded parts by galvanic means lies in the sometimes complicated geometric shapes and the special precipitation properties that are required. For reasons of stability and processing technology, a uniformly homogeneous layer structure and a layer thickness distribution that is as uniform as possible are desirable.
  • the current-controlled galvanic deposits, as z. B. in the AGC ® devices of the applicant are significantly more reliable and deliver reproducible good properties.
  • These devices can usually be placed and operated on a simple work table, usually with a usable volume of electrolyte from about a liter or less, and a capacity of a few dentures, e.g. B. crown caps, which can be produced in one process.
  • the users of such electroplating devices are generally employed in a dental laboratory, for example dental technicians - that is, not specially trained personnel for electroplating. It is therefore important that such electroplating devices are easy and risk-free to operate, both with regard to the quality of the dental prosthesis manufactured therein and with regard to the health hazard to the operator. Therefore, the manufacturers of such electroplating devices endeavor to offer devices with the greatest possible user friendliness and process reliability. Examples include the AGC ® range of devices from the applicant, which covers, for example, capacities from 1 to 16 objects that can be galvanized simultaneously and process times from 1 to 16 hours.
  • the contact rods / holding rods are then connected to the current / voltage source in the device using a plug contact (e.g. a socket), a metal collet or a crimp contact. It is also important for contact with the device that it has a long service life and, if it is inside the electroplating cell, that it is not susceptible to corrosion. Corrosion products can contaminate the electrolyte and endanger the entire function of the process.
  • the operator establishes the contact, that is, equips the device with duplicate models and makes the electrical contact.
  • a disadvantage of the types of contacts mentioned is that contact resistances always occur, which can be undefined and, under certain circumstances, prevent sufficient current flow to the duplicate model to be galvanized. In such cases, there may be a failure in the galvanizing process, which manifests itself in the fact that the galvanized gold framework is too thin and / or the layer structure is disturbed, or in the extreme case the galvanizing process is completely prevented. In addition, the above-mentioned contacts are sometimes difficult for the operator to handle and the parts connected to each other are difficult to adjust.
  • the object of the invention is therefore to avoid or to largely rule out the problems associated with contacting in the prior art.
  • the parts to be galvanized or Models should be easily connectable to the current / voltage source, and this connection should be reliably maintained throughout the process time.
  • the electrical contact should also be able to be broken again in a simple manner in order to be able to introduce new parts / models into the electroplating device.
  • the device according to the invention has at least one current / voltage source and electrodes which can be arranged in a vessel which can be filled with an electrolyte. At least one magnetic connecting means between at least one electrode and the current / voltage source is provided for producing the electrical contact for the galvanic deposition.
  • the essence of the invention is based on the fact that a magnetic contact is provided for establishing the electrical contact between the electrode and the current voltage source.
  • the magnetic adhesive force of two electrical metal magnetic parts causes an electrical circuit to be closed by the corresponding contact of these parts.
  • the magnetic connecting means provided according to the invention is preferably formed in two parts.
  • Such a two-part design can a magnet as the first part and a second part made of a magnetizable metal.
  • the two-part magnetic connecting means consists of two magnets which, by their attraction, make the necessary contact. When using two magnets, a particularly good holding force and minimal contact resistance are achieved.
  • the magnets mentioned are preferably so-called permanent magnets, as are known from the prior art. These provide the required holding force on the magnetizable metal or on one another without the use of further aids. Furthermore, the magnets used preferably have a circular cross section. Such magnets can be referred to as round magnets.
  • a magnet is assigned to the current / voltage source in the device according to the invention. If the invention is implemented in connection with the electroplating devices mentioned at the outset, such devices often have a so-called head or cover part which is arranged above the vessel which holds the electrolyte when the electrodeposition is carried out. In such designs, the magnet associated with the current / voltage source is preferably arranged on this head or cover part. In this way, contact with the electrodes can then be made particularly easily. In the above-mentioned embodiments, there is a sleeve in particular on the current / voltage source, preferably on the head or cover part, which receives the magnet. Such a particularly preferred embodiment will be explained later in connection with the drawing.
  • a magnet is assigned to the electrode or to a part of the electrode.
  • the electrodes are expediently rod-like components, which can be referred to as contact rods / holding rods. Accordingly, in the last-mentioned embodiments, the magnet is preferably attached to these rod-shaped components.
  • the invention also includes a new electrode for the electrodeposition, in particular for the electrodeposition of dental molded parts.
  • this electrode is designed such that it has at least one magnetic connecting means, in particular at least part of a two-part magnetic connecting means.
  • This electrode preferably has the shape of a rod, as it basically corresponds to the shape of the previously known contact rods / holding rods.
  • the magnetic connecting means or a part thereof is provided at one end of the electrode in the new electrode. This is usually the end that is assigned to the current / voltage source in the electrodeposition after the electrical contact has been made.
  • the magnetic connecting means can be a magnetizable metal, which then interacts with a magnet that is assigned to the current-Z voltage source.
  • the magnetic connecting means on the electrode is preferably a magnet, as has already been described above.
  • a magnet is preferably a permanent or permanent magnet.
  • Magnets with a round cross section are preferred.
  • the magnet is located in a sleeve-like receptacle at one end of the (preferably rod-shaped) electrode.
  • this receptacle can preferably be closed with a cover part. This cover part is preferably flat. The upper side of the cover forms the contact surface which interacts with the other part of the magnetic connecting means associated with the current voltage source.
  • the electrode itself can be constructed from any conductive material.
  • the electrode and also a cover part, if present, for closing the receptacle receiving the magnet are made of stainless steel. This material offers good protection against corrosion.
  • the entire outer surface of the electrode, or preferably at least the upper side of a cover part forming the contact surface can be coated with another metal. Such a metal coating can serve to further increase the corrosion resistance or the electrical conductivity.
  • coatings made of gold or gold alloys which can preferably be deposited galvanically on the electrode or only on the cover part.
  • the electrode according to the invention preferably has a smaller cross section at its “lower” end, which carries the parts / models to be coated during the electrodeposition, than at its “upper” end facing the current / voltage source or the head or cover part.
  • the electrode preferably tapers at its “lower” end or tapers there. In this way, the parts / models to be coated can be attached more easily to the electrode, which also serves as a holding rod.
  • the outer surface of the electrode can be provided with an electrically non-conductive coating, in particular with a plastic coating. This prevents galvanic metal from being deposited there and / or the electrode being attacked and damaged by corrosion.
  • the “lower” end of the electrode is preferably free of such a coating in order to ensure simple contacting of the electrode on the parts / models to be coated.
  • the invention comprises a current / voltage source and a head or cover part (explained above) for the electrodeposition, in particular for the electrodeposition of dental molded parts.
  • These components are also characterized in that they have at least one magnetic connecting means, in particular at least part of a two-part magnetic connecting means.
  • This can be a magnetizable metal or preferably a magnet.
  • Permanent or permanent magnets are particularly noteworthy here.
  • the magnets preferably have a round cross section (round magnets).
  • the magnet is preferably located in a sleeve-like receptacle.
  • this receptacle is preferably provided with a cover part.
  • the contact surface is formed by the top of the cover part.
  • the essence of the invention can also be used as at least one magnetic connecting means for establishing the electrical contact between at least one electrode and one
  • This galvanic deposition is preferably one for the production of dental molded parts such as frameworks for crowns, inlays, bridges and the like.
  • the device according to the invention and the components according to the invention of this device have a whole series of advantages over those with the previously known contacts.
  • the required electrical contact is produced by means of a directed magnetic force. This is sufficiently strong that this contact is maintained throughout the galvanic deposition. If the preferred versions with two interacting parts of the magnetic connecting means, in particular the two mentioned magnets, are used, this advantage is particularly evident.
  • the directed magnetic force inevitably pulls the two interacting parts into the correct position with respect to one another, so that the two parts, in particular the two magnets, are located one above the other. In this way it is ensured that there is always a defined contact area and a poor electroplating result due to undefined high contact resistance is virtually impossible.
  • Another advantage of the invention is that the electrical contact can be made quickly and easily by the operator.
  • the electrode and the contact rod are easily exchangeable, which significantly increases the work efficiency for the operator.
  • no maintenance of the components is necessary since, for example, contamination of the contact surfaces is largely excluded. Should a cleaning be necessary, then so. can be done simply by wiping.
  • a further advantage of the embodiments according to the invention is evident when the process temperatures of conventional galvanic deposits, in particular in the dental field, are taken into account. Such process temperatures are usually in the range between 50 ° C and 70 ° C, usually around 65 ° C. As a result, condensation products from the electrolyte usually collect in the upper part of the vessel or the galvanizing cell.
  • condensation products can lead to corrosion on the parts that make the electrical contact.
  • the products formed during the corrosion can then get into the electrolyte and contaminate it.
  • impurities can then also be separated off, for example together with the gold, and in this way the quality of the electrodeposited molded parts, in particular the denture frameworks, deteriorate greatly. This can be almost certainly excluded by the contacting effected according to the invention.
  • the electrode according to the invention or the holding Z contact rod according to the invention is permanently reusable. This applies in particular if it is additionally coated on its surface with a protective layer, preferably a non-conductive protective layer such as. B. a plastic is coated.
  • FIG. 1 shows a schematic cross-sectional representation of an electrode according to the invention or of a holding Z contact rod according to the invention with inserted magnet
  • Fig. 2 is a schematic sectional view of a component according to the invention with inserted magnet, which can be assigned to a current-Z voltage source or a head or cover part of a device according to the invention.
  • a galvanizing device from the applicant of the type AGC ® Speed is modified according to the invention.
  • the Device consists essentially of a housing that the current Z Voltage source and the controller takes.
  • the device has an electrolyte container with a head or lid part, to which the anode and the cathode, which is provided with the part / model to be electroplated, are attached.
  • the AGC ® Speed device from the applicant, the complete electrolyte container with head or lid part can be removed from the device. This simplifies the introduction of the parts / models to be coated into the electrolyte container and protects the other components of the device from contamination, for example by the electrolyte.
  • plug-in contacts were used for fastening / contacting the anode, which is usually designed as a ring anode, and in particular the holding Z-contact rod connected as a cathode.
  • the rod-shaped upper ends of these electrodes were inserted into corresponding receptacles in the head or cover part and locked, for example.
  • this contacting which in itself worked reliably, often did not allow for quick interchangeability.
  • the contact surfaces had to be protected against corrosion by vapors rising from the electrolyte in a comparatively complex manner.
  • FIGS. 1 and 2 For the modification according to the invention of the device described by the applicant, the two components shown in FIGS. 1 and 2 are used.
  • FIG 1 shows an electrode 1 according to the invention in the manner of a holding or contact rod.
  • This electrode 1 is made of stainless steel and has at its one end 2 a smaller cross-sectional area than at its other end 3.
  • the end 2 is designed in the manner of a tip, which is used to fasten the electrode to a part or model not shown in FIG serves which is to be galvanically coated. This is explained in more detail below.
  • a sleeve-like receiving recess 4 is provided, into which a magnet 5 is inserted.
  • This magnet 5 is a permanent magnet with a round cross-sectional area, ie a so-called round magnet.
  • a cover part 6 is provided on the electrode 1, which is also made of stainless steel and seals the receptacle 4 tightly. Due to the construction of the end 3 of the electrode 1, the magnet 5 is thus fully encased.
  • the surface 7 on the outside of the cover part 6 forms the contact surface via which the magnet 5, as part of the two-part magnetic connecting means, can interact with a second part.
  • the surface 7 or, if appropriate, the entire outer surface of the electrode 1 can be gold-plated. This is not shown in more detail in FIG. 1.
  • the outer surfaces of the electrode 1, with the exception of the surface 7 serving as a contact surface can be provided with a plastic coating. This then prevents an undesired galvanic deposition from taking place on the electrode itself. If the plastic coating is not present, the operator prevents this separation by other measures, for example by covering the electrode 1 with a shrink tube.
  • Figure 2 shows a sleeve-like component 1 1 with a round cross section, which is also made of stainless steel.
  • This component 1 1 illustrates the counterpart serving as the holding ZKontaktstab electrode 1 of Figure 1.
  • the component 11 may be introduced, for example in the above-explained head or cover part of the AGC ® speed device of the applicant or in another construction of a Electroplating device can be assigned in another way to the current-Z voltage source.
  • the component 11 has at one end 12 a receptacle / recess 13 into which a magnet 14 is inserted.
  • the magnet 14 is a permanent magnet with a round cross section, ie a round magnet.
  • the receptacle 13 with the round magnet 14 is sealed with a cover part 15, which is also made of stainless steel. This also prevents the magnet 14 from being corroded by rising vapors from the electrolyte.
  • the outer surface 16 present on the cover part 15 represents in the component 11 the contact surface for the interaction of the magnet 14 with the other part of the two-part magnetic connecting means.
  • the surface 16 and possibly the entire outer surface of the component 11 can be gold-plated.
  • Corresponding plastic coatings are also possible.
  • Anode switched electrode can be produced. Such an anode will usually just be a metal rod.
  • dental prostheses are produced by electroforming.
  • the component 11 is introduced into the head or cover part of the device, and the electrode 1 (see FIG. 1) is used as a holding / contact rod for the tooth replacement part or the model.
  • a plaster stump is used, which is made conductive with silver in the usual way.
  • a metallic primary crown is assumed, which is also coated with conductive silver to take account of the cement that will later connect the primary crown to the secondary crown (double crown technique).
  • a sulfitic gold bath from the applicant is used as the electrolyte.
  • the composition of the bath is not critical for the advantages according to the invention to occur.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
  • Dental Preparations (AREA)

Abstract

L'invention concerne un dispositif pour le dépôt galvanique, en particulier pour la formation par dépôt galvanique de pièces façonnées dentaires. Ce dispositif comporte, en plus des composants habituels, au moins un moyen de connexion magnétique servant à l'établissement d'un contact électrique pour le dépôt galvanique entre au moins une électrode et la source de courant/tension du dispositif. L'invention concerne également une électrode servant d'élément de maintien/contact, laquelle comporte un aimant, ainsi qu'un composant coopérant avec cette électrode, lequel comporte un second aimant pour la mise en contact magnétique. Ce composant est associé à la source de courant/tension ou à une partie de tête ou de couverture d'un appareil galvanoplastique.
PCT/EP2004/002955 2003-03-24 2004-03-20 Dispositif et partie de ce dispositif pour la formation par depot galvanique de pieces faconnees dentaires WO2004085714A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2006504778A JP2006521465A (ja) 2003-03-24 2004-03-20 成形加工される歯科部品の電着のための装置及びその部品
AT04722179T ATE480649T1 (de) 2003-03-24 2004-03-20 Vorrichtung und deren teile für die galvanische abscheidung von dentalen formteilen
CA002519519A CA2519519A1 (fr) 2003-03-24 2004-03-20 Dispositif et partie de ce dispositif pour la formation par depot galvanique de pieces faconnees dentaires
DE502004011639T DE502004011639D1 (de) 2003-03-24 2004-03-20 Vorrichtung und deren teile für die galvanische abscheidung von dentalen formteilen
EP04722179A EP1606436B1 (fr) 2003-03-24 2004-03-20 Dispositif et partie de ce dispositif pour la formation par depot galvanique de pieces faconnees dentaires
US10/549,682 US20060131162A1 (en) 2003-03-24 2004-03-20 Device and the parts thereof for producing electrodeposited dental shaped pieces

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10313818A DE10313818A1 (de) 2003-03-24 2003-03-24 Vorrichtung und deren Teile für die galvanische Abscheidung von dentalen Formteilen
DE10313818.8 2003-03-24

Publications (2)

Publication Number Publication Date
WO2004085714A1 true WO2004085714A1 (fr) 2004-10-07
WO2004085714A8 WO2004085714A8 (fr) 2006-01-26

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PCT/EP2004/002955 WO2004085714A1 (fr) 2003-03-24 2004-03-20 Dispositif et partie de ce dispositif pour la formation par depot galvanique de pieces faconnees dentaires

Country Status (8)

Country Link
US (1) US20060131162A1 (fr)
EP (1) EP1606436B1 (fr)
JP (1) JP2006521465A (fr)
CN (1) CN1791704A (fr)
AT (1) ATE480649T1 (fr)
CA (1) CA2519519A1 (fr)
DE (2) DE10313818A1 (fr)
WO (1) WO2004085714A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5184308B2 (ja) * 2007-12-04 2013-04-17 株式会社荏原製作所 めっき装置及びめっき方法
US8177944B2 (en) 2007-12-04 2012-05-15 Ebara Corporation Plating apparatus and plating method
KR102190642B1 (ko) * 2018-12-26 2020-12-14 주식회사 에스에프에이 고온 증착 소스

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EP0690151A2 (fr) * 1994-06-08 1996-01-03 Mtu Motoren- Und Turbinen-Union MàœNchen Gmbh Electrode pour le revêtement électrolytique d'éléments

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US2094308A (en) * 1935-02-12 1937-09-28 Snell Foster Dee Dental prosthetic
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US3575832A (en) * 1968-06-03 1971-04-20 Ford Motor Co Method for electrocoating small objects
US3567592A (en) * 1968-09-16 1971-03-02 Horst L Wismann Method of making dental restorations
US3810258A (en) * 1972-07-11 1974-05-07 W Mathauser Quick connect electrical coupler
GB1448584A (en) * 1973-04-03 1976-09-08 Lucas Electrical Ltd Work piece support assembly for use in electro-plating
DE2537362C2 (de) * 1975-08-19 1986-12-04 Schering AG, 1000 Berlin und 4709 Bergkamen Vorrichtung zur Aufnahme von Kleinteilen zum Zwecke der galvanischen Oberflächenbehandlung
US4288298A (en) * 1979-03-14 1981-09-08 Rogers Olbert W Method and apparatus for electroplating or electroforming metal objects
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JP2000034598A (ja) * 1998-07-15 2000-02-02 Mitsumi Electric Co Ltd 電解メッキ用電極
DE19845506A1 (de) * 1998-10-02 2000-04-06 Wieland Edelmetalle Verfahren zur Herstellung von prothetischen Formteilen für den Dentalbereich und prothetisches Formteil

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
FR1226638A (fr) * 1959-02-25 1960-07-13 Nobel Bozel Perfectionnements au maintien des pièces conductrices destinées à recevoir des revêtements dans des bains électrolytiques ou à subir des traitements analogues
EP0690151A2 (fr) * 1994-06-08 1996-01-03 Mtu Motoren- Und Turbinen-Union MàœNchen Gmbh Electrode pour le revêtement électrolytique d'éléments

Also Published As

Publication number Publication date
JP2006521465A (ja) 2006-09-21
CA2519519A1 (fr) 2004-10-07
DE502004011639D1 (de) 2010-10-21
CN1791704A (zh) 2006-06-21
WO2004085714A8 (fr) 2006-01-26
EP1606436A1 (fr) 2005-12-21
DE10313818A1 (de) 2004-10-07
ATE480649T1 (de) 2010-09-15
EP1606436B1 (fr) 2010-09-08
US20060131162A1 (en) 2006-06-22

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