Classifications

• • D—TEXTILES; PAPER
  • D07—ROPES; CABLES OTHER THAN ELECTRIC
  • D07B—ROPES OR CABLES IN GENERAL
  • D07B1/00—Constructional features of ropes or cables
  • D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
  • D07B1/0606—Reinforcing cords for rubber or plastic articles
  • D07B1/0613—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the rope configuration
• • D—TEXTILES; PAPER
  • D07—ROPES; CABLES OTHER THAN ELECTRIC
  • D07B—ROPES OR CABLES IN GENERAL
  • D07B1/00—Constructional features of ropes or cables
  • D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B60—VEHICLES IN GENERAL
  • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
  • B60C15/00—Tyre beads, e.g. ply turn-up or overlap
  • B60C15/06—Flipper strips, fillers, or chafing strips and reinforcing layers for the construction of the bead
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B60—VEHICLES IN GENERAL
  • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
  • B60C15/00—Tyre beads, e.g. ply turn-up or overlap
  • B60C15/06—Flipper strips, fillers, or chafing strips and reinforcing layers for the construction of the bead
  • B60C15/0603—Flipper strips, fillers, or chafing strips and reinforcing layers for the construction of the bead characterised by features of the bead filler or apex
  • B60C15/0607—Flipper strips, fillers, or chafing strips and reinforcing layers for the construction of the bead characterised by features of the bead filler or apex comprising several parts, e.g. made of different rubbers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B60—VEHICLES IN GENERAL
  • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
  • B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
  • B60C9/0007—Reinforcements made of metallic elements, e.g. cords, yarns, filaments or fibres made from metal
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B60—VEHICLES IN GENERAL
  • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
  • B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
  • B60C9/18—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers
  • B60C9/20—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel

Definitions

• the present invention relates to cables which can be used to reinforce tires for heavy vehicles, that is to say industrial vehicles capable of carrying heavy loads, such as
• Heavy goods vehicles i.e., metro, bus, road transport equipment (trucks, tractors, trailers), off-road vehicles - agricultural or civil engineering equipment, aircraft, other transport or handling vehicles.
• the invention relates in particular to the use of such cables in protective plies for crown or carcass reinforcement, or in stiffeners of such tires.
• the invention also relates to composite fabrics which can be used as protective plies or as stiffeners of such tires, as well as these tires themselves.
• the steel cables for tires generally consist of wires made of perlitic (or ferrito-perlitic) carbon steel, hereinafter referred to as "carbon steel", the carbon content of which is generally between 0.2% and 1.2%, the diameter of these wires being most often between approximately 0.10 and 0.40 mm.
• carbon steel perlitic (or ferrito-perlitic) carbon steel
• These wires are required to have a very high tensile strength, generally greater than 2000 MPa, preferably greater than 2500 MPa, obtained by virtue of the structural hardening occurring during the work hardening phase of the wires.
• These wires are then assembled in the form of cables or strands, which requires steels used that they also have sufficient torsional ductility to withstand the wiring operations.
• tires for industrial vehicles such as Heavy goods vehicles usually comprise a carcass reinforcement which is anchored in two beads and which is radially surmounted by a crown reinforcement comprising one or more working crown plies and one or more crown plies of protection surmounting the working crown or plies, this crown reinforcement itself being surmounted by a tread which is joined to the beads by two flanks.
• strand cords are generally used today ("strand cords" in English) which are assembled by the known stranding technique and which are made up by definition of a plurality of metal strands wound together in a helix, each strand comprising steel wires also wound together in a helix.
• the majority of the wires used in these cables for protective crown ply have a diameter which is typically greater than 0.20 mm, by example close to 0.30 mm, diameter in particular larger than that of the wires used in cables for carcass reinforcement of HGV tires.
• strand cables commonly used to reinforce the plies protecting the top of truck tires
• cable of formula (4 x 2) consisting of 4 strands wound together in a helix which each consist of 2 metal wires wound together in a helix.
• the cables for the protective crown ply are intended, on the one hand, to confer optimum flexibility on the ply incorporating them so that this protective crown ply can best "match" the shape of the obstacle on which it rests during rolling, and, on the other hand, to allow this ply to oppose the penetration of foreign bodies radially inside thereof.
• these stranded cables must be impregnated as much as possible by the rubber, so that the latter penetrates into all the spaces between the wires constituting the cables. Indeed, if this penetration is insufficient, then empty channels are formed along the cables, and corrosive agents, for example water, capable of penetrating into the tires for example following cuts or other attacks of the crown reinforcement of the tire, travel along these channels through said reinforcement. The presence of this moisture plays an important role in causing corrosion and accelerating the fatigue processes (so-called "fatigue-corrosion” phenomena), compared to use in a dry atmosphere.
• each bead of tire for an industrial vehicle such as HGV is generally provided with a stiffener which is intended to reinforce it, each stiffener comprising at least one ply of cables extending axially outside the turnaround. carcass ply. These cables form an angle with the circumferential direction of the tire casing generally between 15 ° and 30 °.
• each stiffener can extend along the upturn of the carcass ply both axially on the outside and radially on the inside of this upturn, substantially forming an L, seen in the meridian section of the envelope. .
• stiffeners essentially have a global damping function which in particular tends to minimize the phenomenon of "deradialization" of the carcass reinforcement of the tire each time it is crushed against the road surface, to take up the compression forces linked to this crushing and to minimize wear on the rim.
• layered steel cables consisting of a central core and one or more concentric layers of wires arranged around the soul.
• the most common layered cables in these truck tire stiffeners are cables of formula (L + M) or (L + M + N). These cables are formed in a known manner of a core of L wire (s) surrounded by at least one layer of M wires, possibly itself surrounded by an outer layer of N wires, with in general L varying from 1 to 4. , M varying from 3 to 12, N varying from 8 to 20 if necessary, the assembly possibly being hooped by a hoop wire wound on the last layer.
• L L wire
• M varying from 3 to 12
• N varying from 8 to 20 if necessary
• a major drawback of these cables of formula (3 + 9 + 15) is that they cannot be penetrated to the core by the rubber, in particular because of the saturated structure of the outer layer and the presence of a channel or capillary in the center of the three core wires, which remains empty after impregnation with the rubber and is therefore suitable for the propagation of corrosive agents, such as water.
• the object of the present invention is to provide a new stranded cable which can be used in particular to reinforce a protective crown ply or else a stiffener of a tire casing for an industrial vehicle such as a heavy goods vehicle: having a bulk and a manufacturing cost.
• the stiffeners incorporate these cables according to the invention, in comparison with that imparted by known layered cables for structural stiffeners (3 + 9 + 15) and, on the other hand, also improved corrosion resistance to the stiffeners incorporating them (due to better impregnation by the rubber), in comparison with that conferred by these cables with structural layers (3 + 9 + 15).
• a cable comprising three strands wound together in a helix according to a pitch p2 which each consist of two metal wires wound together in a helix at a pitch pi, the wires of each strand and the strands being wound together in the same direction of twist S / S or Z / Z, the two wires of each of the three strands having diameters (dl, d2), (dl ', d2'), (dl ", d2”), respectively, and said cable satisfying all of the following conditions: (0 0.25 ⁇ dl ⁇ 0.45 ( ⁇ ) 0.25 ⁇ d2 ⁇ 0.45
• a cable according to the invention also satisfies the following condition: (viii) 3 ⁇ pl ⁇ p2 ⁇ 8.
• a cable according to the invention also checks the condition: (ix) 0.5 ⁇ pl / p2 ⁇ 0.75.
• said cable has a structural elongation As, measured in tension according to ISO standard 6892 of 1984, which is greater than 0.25%.
• said cable has an elongation at break At, measured in tension according to ISO 6892 standard of 1984, which is greater than 3.3%. It will be noted that this elongation at break At is defined as representing the sum of the structural elongations As, elastic Ae and plastic Ap.
• This high value of the elongation at break At of the cables according to the invention essentially makes it possible to give the protective crown ply reinforced by these cables, on the one hand, an elastic character during the manufacture of the tire and, on the other hand, reduced rigidity when it is stressed while driving.
• This reduced tension of the protective crown plies reinforced by these cables results in rolling, during severe stresses, by a reduction in the sensitivity of these plies to the propagation of notches and in particular to damage due to corrosion.
• said cable has a Young E modulus, measured in tension according to ISO 6892 standard of 1984, less than 125 GPa.
• a cable according to the invention has a linear mass less than or equal to 5.50 g / m /
• a cable according to the invention has a total diameter less than or equal to 1.40 mm.
• the metal wires that comprise the strands of the cable according to the invention are made of steel, the carbon content of which varies from 0.2 to 1.2% and, preferably, between 0.5 and 1.0%.
• Another object of the invention is to provide a composite fabric which can be used in particular as a protective ply and / or as a stiffener for a tire covering for an industrial vehicle such as a heavy goods vehicle, said fabric comprising a rubber composition based on at least one diene elastomer which is reinforced by reinforcing elements made up of the cables according to the invention mentioned above.
• iene elastomer in known manner an elastomer derived at least in part (ie a homopolymer or a copolymer) from diene monomers, that is to say carriers of two carbon-carbon double bonds, conjugated or not.
• the diene elastomer of the composition according to the invention is preferably "essentially unsaturated", that is to say that it comprises a molar level of units derived from conjugated dienes which is greater than 15% (% by weight ). Even more preferably, the diene elastomer of said composition is said to be "highly unsaturated”, that is to say having a molar rate of units derived from conjugated dienes greater than 50%.
• said diene elastomer belongs to the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene-styrene copolymers, isoprene-butadiene copolymers, isoprene-styrene copolymers, butadiene-styrene-isoprene copolymers, and mixtures of these elastomers.
• said rubber composition is based on natural rubber or synthetic polyisoprene.
• said rubber composition is also possible to use, according to one embodiment of the invention, blends of natural rubber or synthetic polyisoprene with other “highly unsaturated” diene elastomers, in particular with copolymers of styrene and butadiene or with polybutadienes .
• the elastomer matrix of a composite fabric of the invention may contain one or more diene elastomers, the latter can be used in combination with any type of synthetic non-diene elastomer, or even with polymers other than elastomers, for example thermoplastic polymers.
• the rubber compositions of the composite fabrics according to the invention also comprise all or part of the additives usually used in the manufacture of tires, such as reinforcing fillers such as carbon black and / or an inorganic reinforcing filler such as silica, anti-aging agents, for example antioxidants, extension oils, plasticizers or agents facilitating the use of compositions in the non-crosslinked state, a crosslinking system based either on sulfur or on sulfur donors and / or peroxide, accelerators, vulcanization activators or retarders, methylene acceptors and donors, resins, known adhesion promoter systems of the "RFS" (resorcinol-formaldehyde-silica) type or metal salts, such than cobalt salts.
• the additives usually used in the manufacture of tires such as reinforcing fillers such as carbon black and / or an inorganic reinforcing filler such as silica, anti-aging agents, for example antioxidants, extension oils, plasticizers or agents facilitating the use of composition
• the composite fabric according to the invention can be in various forms, for example in the form of a tablecloth, a strip, a strip or a block of rubber in which the metal reinforcement is incorporated using various means known to those skilled in the art, such as for example molding, calendering or sausage means.
• the cables according to the invention are arranged parallel to one another, on the one hand, according to a density (denoted “d”) of cables per dm of fabric and, on the other part, according to a rubber "bridge” width between two adjacent cables (this width hereinafter denoted “ ⁇ L”, expressed in mm, represents in a known manner the difference between the calendering pitch or no laying of the cable in the fabric , and the diameter of said cable), d and ⁇ L being specifically fixed taking into account the specific reinforcement sought in the present invention, ie for the reinforcement of a protective ply and / or a stiffener.
• the distance between two adjacent cables, from axis to axis is preferably between 2 and 4 mm.
• the rubber bridge which is too narrow, risks mechanical deterioration during the working of the ply, in particular during the deformations undergone in its own plane by extension or shearing. Beyond the maximum indicated, there is a risk of perforation between the cables.
• the composite fabric according to the invention is such that its density d of cables is preferably between 20 and 60 cables per dm of fabric and, even more preferably, between 30 and 50 cables per dm of fabric.
• the width ⁇ L of the rubber composition bridge between two adjacent cables is between 0.5 and 1.3 mm and, preferably, this width ⁇ L is between 0, 6 and 1.0 mm.
• said rubber composition presents, in the crosslinked state and measured according to standard ASTM D 412, a secant module M10 of between 5 and 12 MPa.
• said rubber composition in the case where said fabric is used to constitute a stiffener for a bead of tire for an industrial vehicle such as HGV, said rubber composition has, in the state crosslinked and measured according to ASTM D 412, an M10 secant module between 7 and 15 MPa. It is in these areas of modules that the best endurance compromise of the cables according to the invention and of the composite fabrics incorporating them has been recorded.
• a tire envelope for an industrial vehicle such as a truck comprises a carcass reinforcement which is anchored in two beads and which is radially surmounted by a crown reinforcement comprising, with a on the one hand, one or more working crown plies and, on the other hand, one or more protective crown plies surmounting the working crown ply (s), the crown reinforcement itself being surmounted by a tread joined to the beads by two sides; it is characterized in that at least one of said protective crown plies comprises a composite fabric according to the invention as defined above.
• a tire casing for an industrial vehicle such as a heavy goods vehicle comprises in a known manner a carcass reinforcement which is anchored in two beads around two rods, respectively forming two reversals axially outside the rods and which is radially surmounted by a crown reinforcement itself surmounted by a tread joined to the beads by two sides, each bead comprising a stiffener intended to reinforce it, each stiffener extending axially outside the carcass reinforcement upturn and comprising at least one ply of metallic cables which make an angle preferably between the circumferential direction of the envelope 15 ° and 30 °; it is characterized in that at least one of said stiffeners comprises a composite fabric according to the invention as defined above.
• each of said stiffeners extends along said carcass reinforcement reversal axially outside and radially inside thereof, substantially forming an L, seen in meridian section of said envelope.
• FIG. a single is a view in meridian section of a bead of a sidewall of a truck tire according to an exemplary embodiment of the invention.
• a carcass ply 4 with metal cables which is anchored in the bead 1 around a metal rod 5 by forming a reversal 4a axially outside of it, which reversal 4a extends radially towards the outside by an elastomeric border band 4b.
• the rod 5, of rectangular section in the example of FIG. single, is surrounded by an elastomeric layer 7 of substantially circular section which is intended to ensure satisfactory contact with the carcass ply 4 around the upturn 4a.
• the bead 1 also comprises an elastomeric filling layer 8 which is provided, radially outside the rod 5, between the two portions of the carcass ply 4 located on either side of the upturn 4a (we see in the Example of the single Fig. that this layer 8 is in contact with the carcass ply 4, the border strip 4b and the layer 7 surrounding the rod 5).
• the bead 1 further comprises a stiffener 9 intended to reinforce it and formed of a ply of metal cables 9a according to the invention which extends axially outside the reversal 4a of the carcass ply 4 and which form with the circumferential direction of the tire an angle preferably between 15 ° and 30 °. We see in the example of Fig. unique that this stiffener 9 is extended radially outward by an edge band 9b.
• an elastomeric layer 10 intended to reinforce this stiffener 9 and extending axially in contact with the latter, the reversal 4a and the filling layer 8, in the example of FIG. unique.
• elastomeric reinforcing layer 1 1 which extends, radially from the inside to the outside, in contact with the stiffener 9, the edge strip 9a and layer 10.
• the bead 1 further comprises, in this embodiment, a protective elastomer layer 12 which is intended to ensure contact of the bead 1 with the wheel rim and which delimits this bead 1 radially inwards by connecting the sidewall layer external 3 to the internal sealing layer 2.
• this protective layer 12 extends, axially from the outside to the inside of the bead 1, in contact with the reinforcing layer 11, the stiffener 9, the upturn 4a, the reinforcing layer 6 and said layer 12 covers, internally inside, the internal sealing layer 2, substantially forming an L, seen in the meridian section of the tire.
• the cable C has a pitch pi of 3.96 mm between two wires of the same strand and a pitch p2 of 6.09 mm between strands.
• the wires of each strand and the three strands are wound together in the same direction of S / S twist.
• This cable C was obtained in two operations:
• each strand was carried out by means of a rotary feed, by stabilized twisting via a pulley twist and without dressing. To do this, a “BRD” type “96” machine was used.
• the cable C ⁇ * "control” has a pitch pi of 3.98 mm between two wires of the same strand and a pitch p2 of 8.23 mm between strands.
• the wires of each strand and the four strands are wound together in the same direction of S / S twist.
• Table 1 below contains the main characteristics of these two cables, the measurements having been carried out on the cables taken in isolation (i.e. before their incorporation into the composite fabric).
• This cable C ⁇ 2 has, for the layers Ci to C 3 , pitches pi, p2, p3 of 6.5 mm, 12.0 mm and 13.0 mm respectively.
• the hoop pitch is 2.8 mm.
• these windings of layers C] to C 3 and of hoop are characterized by the directions of torsion S / S / Z / S.
• Table 2 below compares the main characteristics of cables C ⁇ 2 and C Behavior, the measurements having also been carried out on cables taken in isolation.
• Each “control” tire P T2 notably includes: in its protective crown ply, known strand cables of formula “18.23” (comprising three metal strands each consisting of five wires wound helically on a core wire) which are arranged at a pitch between cables of 2.5 mm.
• the cable density d is therefore 40 per dm of fabric and the width of the rubber bridge ⁇ L is 1.04 mm (the diameter of each cable being 1.46 mm); - in its two crossed work top plies, cables with non-hooped layers of formula
• Each tire according to the invention P notably comprises: in its protective crown ply, the stranded cables C, according to the invention of formula "6.35" which are arranged in a pitch between cables of 2.25 mm.
• the density d of cables C is therefore 44 per dm of fabric and the width ⁇ L of rubber "bridge” is 0.86 mm (the diameter of each cable C, being 1.39 mm); in its two crossed working top plies, said layered cables of formula “1 1.35” arranged in a pitch between cables of 2.5 mm; in its stiffeners (in accordance with the single FIG.), said stranded cables C, arranged in a pitch of 2.25 mm, a cable density of 44 per dm of fabric and a width ⁇ L of rubber bridge of 0.86 mm.
• the modulus M10 of the rubber composition contained in this stiffener is substantially equal to 10 MPa, and this rubber composition is based on natural rubber.
• the rolling tests were carried out under a load of approximately 5,150 kg on each tire, at a rolling speed of 57 km / h and at a temperature of 25 ° C.
• the criterion for stopping rolling is the first detection over time, after a determined critical mileage, a break in the beads of a tire.
• Table 3 below details, in relative value, the average critical mileage obtained for tires according to the invention P "taking as reference the average critical mileage obtained for" control "tires P ⁇ 2 which is expressed in base 100. For these tires P Wennthe average critical mileage obtained is thus expressed as a percentage of the corresponding mileage obtained for the“ control ”tires P ⁇ 2 *
• stiffeners comprising the stranded cables C, according to the invention of structure (3 x 2) give very improved endurance to the tire beads P, incorporating them, the average mileage obtained without breaking of these beads being increased more than 50% compared to that of "control" tires P T2 whose stiffeners include layered cables

Landscapes

• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Tires In General (AREA)
• Ropes Or Cables (AREA)
• Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Priority Applications (9)

Applications Claiming Priority (2)

Related Child Applications (1)

Publications (1)

Family

ID=32088181

Family Applications (1)

Country Status (12)

Cited By (10)

Families Citing this family (49)

Citations (11)

Family Cites Families (11)

• 2003
  • 2003-10-08 JP JP2004542454A patent/JP4543145B2/ja not_active Expired - Fee Related
  • 2003-10-08 BR BR0306571A patent/BR0306571B1/pt not_active IP Right Cessation
  • 2003-10-08 CA CA 2501392 patent/CA2501392C/fr not_active Expired - Fee Related
  • 2003-10-08 WO PCT/EP2003/011111 patent/WO2004033789A1/fr not_active Ceased
  • 2003-10-08 CN CNB2003801012237A patent/CN100443661C/zh not_active Expired - Fee Related
  • 2003-10-08 EP EP03769355A patent/EP1554427B1/fr not_active Expired - Lifetime
  • 2003-10-08 DE DE60336253T patent/DE60336253D1/de not_active Expired - Lifetime
  • 2003-10-08 AT AT03769355T patent/ATE500381T1/de not_active IP Right Cessation
  • 2003-10-08 KR KR20057006137A patent/KR101062629B1/ko not_active Expired - Fee Related
  • 2003-10-08 RU RU2005113873A patent/RU2326198C2/ru not_active IP Right Cessation
  • 2003-10-08 AU AU2003278053A patent/AU2003278053A1/en not_active Abandoned
• 2005
  • 2005-04-07 US US11/102,128 patent/US7089726B2/en not_active Expired - Lifetime

Patent Citations (18)

Non-Patent Citations (1)

Also Published As

Similar Documents

Legal Events