WO2003091743A1 - Procede et systeme de diagnostic de deterioration de bobine - Google Patents
Procede et systeme de diagnostic de deterioration de bobine Download PDFInfo
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- WO2003091743A1 WO2003091743A1 PCT/JP2003/001649 JP0301649W WO03091743A1 WO 2003091743 A1 WO2003091743 A1 WO 2003091743A1 JP 0301649 W JP0301649 W JP 0301649W WO 03091743 A1 WO03091743 A1 WO 03091743A1
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- Prior art keywords
- coil
- potential
- conductor
- insulating layer
- voltage
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- 238000000034 method Methods 0.000 title claims abstract description 80
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/34—Testing dynamo-electric machines
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- G01M3/00—Investigating fluid-tightness of structures
- G01M3/02—Investigating fluid-tightness of structures by using fluid or vacuum
- G01M3/04—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point
- G01M3/16—Investigating fluid-tightness of structures by using fluid or vacuum by detecting the presence of fluid at the leakage point using electric detection means
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01M—TESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
- G01M3/00—Investigating fluid-tightness of structures
- G01M3/40—Investigating fluid-tightness of structures by using electric means, e.g. by observing electric discharges
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/12—Testing dielectric strength or breakdown voltage ; Testing or monitoring effectiveness or level of insulation, e.g. of a cable or of an apparatus, for example using partial discharge measurements; Electrostatic testing
- G01R31/1227—Testing dielectric strength or breakdown voltage ; Testing or monitoring effectiveness or level of insulation, e.g. of a cable or of an apparatus, for example using partial discharge measurements; Electrostatic testing of components, parts or materials
- G01R31/1263—Testing dielectric strength or breakdown voltage ; Testing or monitoring effectiveness or level of insulation, e.g. of a cable or of an apparatus, for example using partial discharge measurements; Electrostatic testing of components, parts or materials of solid or fluid materials, e.g. insulation films, bulk material; of semiconductors or LV electronic components or parts; of cable, line or wire insulation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/34—Testing dynamo-electric machines
- G01R31/346—Testing of armature or field windings
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
- G01R31/00—Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
- G01R31/50—Testing of electric apparatus, lines, cables or components for short-circuits, continuity, leakage current or incorrect line connections
- G01R31/72—Testing of electric windings
Definitions
- the present invention relates to a coil deterioration diagnosis method for diagnosing whether or not water leaks from a conductor to an insulating layer during a direct cooling operation of the conductor with water, thereby causing the coil to deteriorate.
- a coil deterioration diagnostic device applied to the method
- a large-capacity rotating electric machine has a number of grooves provided inside a stator core 1 formed in a cylindrical shape, and a lower coil 2b and an upper coil 2a pass through each groove as a pair. .
- the upper and lower coils 2a, 2b are made of conductors 3a, 3b using hollow rectangular copper wire alone or a mixture of solid rectangular copper wire and hollow rectangular wire as strands.
- the cross-sectional profile of this is shaped into a rectangle, and the outside is covered with insulating layers 4a and 4b.
- the upper and lower coils 2a and 2b are connected by welding the clips 5a and 5b to the ends of the conductors 3a and 3b, and the first hollow connection conductor 6 is used to connect between the clips 5a and 5b.
- the conductors 3a and 3b are connected and cooled directly with water supplied from the insulated connecting pipe 7 such as deionized water.
- Both of these inventions make use of the phenomenon that the capacitance of the insulating layer increases due to the leakage of water, and the electrode is brought into contact with a coil outside the iron core, and the capacitance between the conductor and the electrode is measured. When the measured capacitance is extremely high, it is determined that water is leaking to the insulating layer.
- a large-capacity rotating electrical machine has a coil insulation structure.
- Insulating layers 9, 9a, 9b, 9c are provided with internal electrodes 8a, 8b, 8c to reduce the electric field on the coil surface.
- the internal electrodes 8a, 8b, and 8c may be two to four layers, but the case of three layers will be described here as an example.
- This coil insulation structure covers the outside of the conductor 3 of the coil 2 (2a, 2b), which is a pair of the upper coil 2a and the lower coil 2b, with insulating layers 9, 9a to 9c.
- the three inner electrodes 8a to 8c are attached to the insulating layers 9, 9a to 9c, and the innermost electrode 8c of the outermost layer is attached to the outermost layer of the linear portion of the coil 2 (2a, 2b).
- Low resistance layer
- the capacitance of the insulating layers 9a to 9c is divided by the intermediate internal electrodes 8a and 8b to reduce the electric field on the outer surface of the insulating layer at the coil end.
- a clip 5 (5a, 5b) provided with an outlet pipe 7 for directly cooling the conductor 3 (3a, 3b) with water is provided.
- the technology of detecting water leakage to the insulating layers 9, 9a to 9c of the coil 2 (2, 2b) disclosed in the above-mentioned patent application is applied to the rotating electric machine having such a coil insulation structure. If so, there are some problems.
- the region A is the first internal electrode space region
- the region B is the second internal electrode space region
- the area is referred to as a third internal electrode space area and the D area is referred to as an internal electrode non-existent area
- the above-described leaked water detection technology can be applied only to the D area.
- region D a thick ring is installed to suppress the electromagnetic vibration of coil 2 (2a, 2b), and this ring is tied with a glass string, so there is no room for mounting the measurement electrode.
- this D region is a region where the sheath of the clip 5 around which the self-insulating tape is wound is overlapped with the insulating layer of the coil end portion, and the insulating thickness is not constant. Since it is inversely proportional, measurement cannot be performed unless the insulation thickness is constant.
- the leaked water intrudes between the conductor 3 and the innermost inner electrode 8a, and rarely enters the upper part of the inner electrode 8a. For this reason, even if an electrode is attached to the surface of region A, an AC voltage is applied to conductor 3 (3a, 3b), and the capacitance of conductor 3 (3a, 3b) is measured, the measured value Is determined by the capacitance between the internal electrode 8a and the electrode on the coil surface, so there is almost no difference between a sound coil and a coil with leaked water. meaningless.
- the above-described technology is applied to a rotating electric machine having a structure in which the internal electrodes 8a to 8b are inserted into the insulating layers 9, 9a to 9c. And new improvements were required.
- the present invention has been made in response to such a demand, and in the case of a direct cooling operation using water for a conductor, water leaks from the conductor to the insulating layer, and the insulation deterioration of the coil generated due to the leakage is facilitated. Accordingly, it is an object of the present invention to provide a coil deterioration diagnosis method and a coil deterioration diagnosis device which can detect a coil deterioration early, accurately and reliably. Disclosure of the invention
- a method for diagnosing deterioration of a coil according to the present invention is to cover a conductor directly cooled by a medium with an insulating layer, and to form a coil with the conductor and an internal electrode inserted into the insulating layer. Applying an AC voltage to the conductor of the coil, measuring the potential of the internal electrode with a potential measurement probe facing the coil, and when the measured potential is higher than the potential of a healthy coil, It is determined that the medium leaks from the conductor to the insulating layer and that the insulation is deteriorated.
- the coil deterioration diagnosis method includes: A conductor is covered with an insulating layer, and a coil is formed by the conductor and an internal electrode inserted into the insulating layer. An AC voltage is applied to the conductor of the coil, and a surface to be inserted into the coil is formed. The potential of the surface electrode is measured by a potential measurement probe facing the pole, and when the measured potential is higher than the potential of a sound coil, it is determined that the medium leaks from the conductor to the insulating layer and the insulation is deteriorated. It is characterized by doing.
- a method of diagnosing coil deterioration includes the steps of: covering a conductor directly cooled by a medium with an insulating layer; and forming a coil with the conductor and an internal electrode inserted into the insulating layer.
- An AC voltage is applied to the conductor of the coil, and the potential of the surface electrode inserted into the coil is measured by a high-input impedance electrometer, and the measured potential is compared with the potential of a healthy coil.
- it is high it is determined that the medium leaks from the conductor to the insulating layer and insulation is deteriorated.
- the coil deterioration diagnosis method achieves the above object.
- a conductor directly cooled by a medium is covered with an insulating layer, and a coil is composed of the conductor and an internal electrode inserted into the insulating layer.
- An AC voltage is applied to the conductor of the coil.
- the position of the internal electrode was confirmed by moving the potential measurement probe back and forth along the axial direction of the coil, and after confirming the position of the internal electrode, the potential of the internal electrode deposited on the insulation layer was measured and measured.
- the potential is higher than the potential of a healthy coil, it is determined that the medium leaks from the conductor to the insulating layer and insulation is deteriorated.
- the method for diagnosing coil deterioration comprises the steps of: covering a conductor directly cooled by a medium with an insulating layer; and combining the conductor and an internal electrode adhered in the insulating layer.
- a coil is configured, a voltage is applied to the conductor of the coil, and a potential measurement probe is moved forward and backward along the axial direction of the coil to confirm the position of the internal electrode.
- the potential of the surface electrode attached to the coil is measured, and when the measured potential is higher than the potential of a sound coil, it is determined that the medium leaks from the conductor to the insulating layer and the insulation is deteriorated.
- the potential measured at one of the internal electrode and the surface electrode is determined by the magnitude of the potential and the phase with respect to the voltage applied to the conductor.
- a deviation is found as compared with the phase, it is possible to determine that the medium leaks from the conductor to the insulating layer and the insulation is deteriorated.
- the method for diagnosing deterioration of a coil comprises the steps of: covering a medium directly cooled by a medium with an insulating layer, and combining the conductor and an internal electrode adhered in the insulating layer.
- a coil is formed, and a DC voltage or a square wave voltage is applied to the conductor of the coil, and when the measured potential of the internal electrode or the surface electrode is higher than that of a healthy coil, the medium is transferred from the conductor to the insulating layer. It is characterized by leakage and insulation deterioration.
- the coil deterioration diagnosis method includes a step of covering a conductor directly cooled by a medium with an insulating layer, and including the conductor and an internal electrode inserted into the insulating layer. Configure a coil, and attach a surface electrode to this coil.
- the method is characterized in that after the pole is once grounded, and then the ground is released, a step function DC voltage or a square wave voltage is applied to the conductor to measure the potential of the surface electrode.
- the method for diagnosing deterioration of a coil comprises the steps of: covering a conductor directly cooled by a medium with an insulating layer; and combining the conductor and an internal electrode adhered in the insulating layer.
- a coil is formed, and any one of an AC voltage, a step function DC voltage, and a square wave voltage is applied to the conductor of the coil, and the coil is connected to a surface electrode attached to the coil and has the same potential.
- the potential of the maintained external electrode is measured, and when the measured potential is higher than the potential of a healthy coil, it is determined that the medium has leaked from the conductor to the insulating layer and insulation has been degraded.
- a standard value of the ratio of the potentials of the different internal electrodes is obtained in advance, and is used after being converted to the potential of the internal electrode at the same position.
- the coil deterioration diagnosis apparatus of the present invention by applying the above-described diagnosis method, provides a coil comprising a conductor directly cooled by a medium and an internal electrode inserted in an insulating layer covering the conductor, A power supply for applying a voltage to the conductor, a non-contact surface voltmeter for measuring the potential of the internal electrode via a potential measurement probe, and a voltage reading device for measuring a voltage applied to the conductor from the power supply. It is characterized by having.
- the coil deterioration diagnosis apparatus of the present invention by adapting the above-described diagnosis method, comprises a coil comprising a conductor directly cooled by a medium and an internal electrode inserted into an insulating layer covering the conductor; A power supply for applying a voltage to the conductor, a surface electrode device mounted on the coil, a non-contact surface electrometer for measuring the potential of the surface electrode device via a potential measuring probe, and A voltage reading device for measuring a voltage applied to the conductor.
- the surface electrode device can be configured by bonding an insulating plate to the surface electrode.
- an insulating plate may be attached to the surface electrode, and the insulating plate may have a protrusion.
- the surface electrode device may be configured such that an insulating plate is attached to the surface electrode and a handle is provided on the insulating plate.
- the surface electrode device may be configured such that a flexible portion is interposed on the surface electrode and a holding plate is bonded thereto.
- the board may be provided with a handle.
- the surface electrode device can be provided with a handle on the surface electrode.
- the potential measurement probe may include a probe support for maintaining a predetermined distance between the potential measurement window and the surface electrode.
- the potential measurement probe is supported by a probe support extending from a holding plate that supports the surface electrode, and is connected to the surface electrode, and an external electrode provided on the probe support, and the external electrode A spacer for maintaining the potential measurement window at a predetermined distance may be provided.
- the coil deterioration diagnosis apparatus includes: a coil including a conductor directly cooled by a medium and an internal electrode inserted into an insulating layer covering the conductor; and applying a voltage to the conductor of the coil.
- a computer for recording and storing the measured potential is provided.
- a coil deterioration diagnosis apparatus includes a coil comprising a conductor directly cooled by a medium and an internal electrode inserted into an insulating layer covering the conductor; a power supply for applying a voltage to the conductor of the coil; A surface electrode device mounted on the coil; a non-contact surface electrometer for measuring the potential of the surface electrode device via a potential measurement probe; and a voltage reading device for measuring a voltage applied from the power supply to the coil. And a combination for recording and storing the potential measured by the non-contact surface electrometer.
- Coil deterioration diagnosis method and diagnosis thereof having the features described above
- the coil deterioration diagnosis device applied to the disconnection method measures the potential of the internal electrode covering the conductor from outside using a non-contact type electrometer or high input impedance electrometer, and from the conductor to the insulating layer based on the measured potential. Since the presence or absence of leaked water is determined and the deterioration of the insulation layer is diagnosed, the leakage of water to the insulation layer can be easily, quickly and reliably detected by new means.
- FIG. 1 is a schematic diagram showing a first embodiment of a coil deterioration diagnosis method according to the present invention and a coil deterioration diagnosis apparatus applied to the diagnosis method.
- FIG. 2 is an equivalent electric circuit diagram for calculating the potential of the internal electrode in the first embodiment of the coil deterioration diagnosis method and the coil deterioration diagnosis apparatus applied to the diagnosis method according to the present invention.
- FIG. 3 is a schematic view showing two embodiments of a coil deterioration diagnosis method according to the present invention and a coil deterioration diagnosis apparatus applied to the diagnosis method.
- FIG. 4 is a schematic diagram showing a third embodiment of a coil deterioration diagnosis method according to the present invention and a coil deterioration diagnosis apparatus applied to the diagnosis method.
- FIG. 5 is an equivalent electric circuit diagram for calculating a potential of an internal electrode in the second and third embodiments of the coil deterioration diagnosis method and the coil deterioration diagnosis device applied to the diagnosis method according to the present invention.
- FIG. 6 is a schematic view showing a coil deterioration diagnosis method according to a fourth embodiment of the present invention and a coil deterioration diagnosis apparatus applied to the diagnosis method.
- FIG. 7 shows a change in the surface potential according to the position of the potential measured by the coil degradation diagnosis apparatus according to the present invention and the potential of a sound coil in the coil degradation diagnosis apparatus applied to the diagnosis method.
- FIG. 8 shows the applied voltage, the voltage of the sound coil, and the voltage of the coil in which the leaked water leaks to the insulation layer in the coil deterioration diagnosis method according to the present invention and the coil deterioration diagnosis apparatus applied to the diagnosis method.
- FIG. 3 is a diagram comparing the respective waveforms.
- FIG. 9 shows the applied voltage when a step-like DC voltage is applied in the coil deterioration diagnosis method according to the present invention and the coil deterioration diagnosis apparatus applied to this diagnosis method.
- FIG. 5 is a diagram comparing the time-dependent changes in the voltage of a sound coil and the voltage of a coil in which leaked water leaks to the insulating layer.
- FIG. 10 is a schematic diagram showing a coil deterioration diagnosis method according to a fifth embodiment of the present invention and a coil deterioration diagnosis apparatus applied to the diagnosis method.
- FIG. 11 shows a method for diagnosing a coil deterioration in the coil deterioration diagnosis method according to the present invention and a coil deterioration diagnosis apparatus applied to the coil deterioration diagnosis apparatus (a coil in which leaked water leaks to the insulating layer).
- FIG. 11 shows a method for diagnosing a coil deterioration in the coil deterioration diagnosis method according to the present invention and a coil deterioration diagnosis apparatus applied to the coil deterioration diagnosis apparatus (a coil in which leaked water leaks to the insulating layer).
- FIG. 12 is a schematic diagram showing a first embodiment of a surface electrode device applied to the coil deterioration diagnosis device according to the present invention
- FIG. 12A is a side view of the surface electrode device
- FIG. FIG. 12 is a front view of the surface electrode device as viewed from the direction indicated by arrows ⁇ -XI IB in FIG. 12A
- FIG. 13 is a schematic view showing a second embodiment of the surface electrode device applied to the coil deterioration diagnosis device according to the present invention.
- FIG. 14 is a schematic diagram showing a third embodiment of the surface electrode device applied to the coil deterioration diagnosis device according to the present invention
- FIG. 14A is a side view of the surface electrode device
- FIG. FIG. 14A is a front view of the surface electrode device viewed from the direction of arrows XIVB-XIVB in FIG. 14A
- FIG. 15 is a schematic view showing a surface electrode device applied to a coil deterioration diagnosis device according to the present invention, which is attached to a coil in a third embodiment.
- FIG. 16 is a schematic diagram showing a fourth embodiment of the surface electrode device applied to the coil deterioration diagnosis apparatus according to the present invention, wherein FIG. 16A is a side view of the surface electrode device, and FIG. FIG. 16B is a front view of the surface electrode device as viewed from the direction of arrow XVIB-XVIB in FIG. 16A.
- FIG. 17 is a schematic diagram showing a fifth embodiment of the surface electrode device applied to the coil deterioration diagnosis device according to the present invention, wherein FIG. 17A is a side view of the surface electrode device, and FIG. FIG. 17B is a front view of the surface electrode device viewed from the direction of arrow XVI IB-XVI IB in FIG. 17A.
- FIG. 18 is a schematic view showing a surface electrode device applied to a coil deterioration diagnosis device according to the present invention, which is attached to a coil in a fourth embodiment.
- FIG. 19 is a schematic diagram showing a sixth embodiment of the surface electrode device applied to the coil deterioration diagnosis device according to the present invention
- FIG. 19A is a side view of the surface electrode device
- FIG. FIG. 19 is a front view of the surface electrode device as viewed from the direction of arrows XIXB-XIXB in FIG. 19A
- FIG. 20 shows a surface electrode device applied to the coil deterioration diagnosis device according to the present invention.
- FIG. 20A is a schematic view showing the seventh embodiment
- FIG. 20A is a side view of the surface electrode device
- FIG. 20B is a front view of the surface electrode device viewed from the direction of arrows XXB-XXB in FIG. 20A. .
- FIG. 21 is a schematic view showing an eighth embodiment of the surface electrode device applied to the coil deterioration diagnosis device according to the present invention, wherein FIG. 21A is a side view of the surface electrode device, and FIG. FIG. 21 is a front view of the surface electrode device as viewed in the direction of arrows XXIB-XXI B in FIG. 21A.
- FIG. 22 is a schematic diagram showing a ninth embodiment of the surface electrode device applied to the coil deterioration diagnosis device according to the present invention, FIG. 22A is a side view of the surface electrode device, and FIG. FIG. 22 is a front view of the surface electrode device viewed from the direction of arrow ⁇ ⁇ ⁇ -XXI IB in FIG. 22A.
- FIG. 23 is a schematic diagram showing a first embodiment of a potential detection device applied to the coil deterioration diagnosis device according to the present invention.
- FIG. 24 is a schematic diagram showing a second embodiment of the potential detection device applied to the coil deterioration diagnosis device according to the present invention.
- FIG. 24A is a plan view of the potential detection device
- FIG. FIG. 24A is a cross-sectional view of the potential detection device taken along the line XXIVB-XXIVB of FIG. 24.
- FIG. 25 is a schematic diagram showing a third embodiment of the potential detection device applied to the coil deterioration diagnosis device according to the present invention.
- 25A is a side view of the potential detecting device
- FIG. 25B is a front view of the potential detecting device as viewed in the direction of arrows XXVB-XXVB in FIG. 25A.
- FIG. 26 is a schematic diagram showing a fourth embodiment of the potential detection device applied to the coil deterioration diagnosis device according to the present invention.
- FIG. 27 is a schematic view showing a part of a stator coil of a conventional rotating electric machine.
- FIG. 28 is a schematic diagram showing a part of an end portion of the stator coil shown in FIG. 27.
- FIG. 1 is a schematic diagram showing a first embodiment of a coil deterioration diagnosis method and a coil deterioration diagnosis device applied to the diagnosis method according to the present invention.
- the measurement position Is a cross-sectional position in the region A already shown in FIG. 28 as an example.
- the coil deterioration diagnostic apparatus according to the present embodiment is, for example, a coil directly cooled with water.
- An AC power supply 12 for applying an AC voltage to the power supply 11 and an electric potential measuring device 23 for measuring the potential of the coil 11 are provided.
- the coil 11 is provided between the first insulating layer 14 and the second insulating layer 15 around which the conductor 13 located in the center is wound, and between the first insulating tank 14 and the second insulating layer 15. And a first internal electrode 16 to be inserted.
- the cross section of the coil 11 corresponds to the region A already shown in FIG.
- the potential measuring device 23 is connected to the potential measuring probe 18 provided with the potential measuring window 17 in the measuring portion via the input terminal 21 to the potential measuring probe 18.
- the non-contact surface potentiometer 19 for measuring the potential of the coil 11 is connected to the non-contact surface potentiometer 19 via the output terminal 22, and the AC power supply 12 is applied to the coil 11 It is configured with a voltage reading device 20 such as an oscilloscope or an AC voltmeter for measuring an AC voltage.
- a coil deterioration diagnosis method for detecting a potential based on water leaking from the conductor 13 to the first insulating layer 14 using the coil deterioration diagnosis apparatus having the above-described configuration includes a coil deterioration diagnosis method.
- an AC voltage E is applied from the AC power supply 12 to the conductor 13 of the coil 11, and at this time, the potential of the first internal electrode 16 is measured via the potential measurement probe 18 by the non-contact surface electrometer 1. Measure at 9, and read the voltage with the voltage reading device 20. Note that the voltage reading device 20 may be omitted as long as the AC voltage can be measured by the non-contact surface electrometer 19 itself.
- the capacitance between the conductor 13 and the innermost first internal electrode 16 is C a
- the first internal electrode 16 and the second internal electrode 2 4 is C b
- the capacitance between the second internal electrode 24 and the third internal electrode 25 is C c.
- leaked water enters one of the conductors 13 to the first insulating layer 14, the second insulating layer 15, and the third insulating layer 26, and the relative dielectric constant of the water is extremely high, for example, 80.
- the capacitance C a of the first internal electrode 16 increases, and the electric conductivity of water is higher than the electric conductivity of the second to third insulating layers 15, 26. It is generally well known that the dielectric loss increases significantly.
- an equivalent resistance Ra is provided between the conductor 13 and the first internal electrode 16.
- voltage E is divided by capacitances C a, C b and C c.
- the potential Va of the first internal electrode 16 is represented by the following equation.
- the potential Va of the first internal electrode 16 is calculated.
- V a 72.0 V, which is 37% larger than the value in a healthy case.
- Table 1 also summarizes the calculation results of the potential Vb of the second internal electrode 24. ⁇ table 1 ⁇
- the frequency of the applied voltage must be a frequency that the non-contact surface electrometer 19 can sufficiently follow, and in the above-described example, the frequency of 50 Hz was used.
- the frequency response of the non-contact surface electrometer 19 is lower, for example, lower than the commercial frequency such as 20 Hz, it is necessary to apply a voltage using an AC voltage generator.
- the non-contact surface electrometer 19 can sufficiently follow the frequency of the applied voltage and measure accurately, it is preferable to use an oscilloscope as the voltage reader 20.
- the AC power supply 12 does not necessarily have to be a sine wave, and the same effect can be obtained as long as the waveform is a positive and negative waveform such as a triangular wave and a square wave.
- the present embodiment focuses on the fact that the relationship between the infiltration of leaked water into the insulating layer and the increase in the potential of the internal electrode is inseparably integrated, and the insulation is measured by measuring the potential of the internal electrode. Infiltration of leaked water into the layer can be detected earlier and more reliably, and insulation deterioration can be accurately determined.
- FIG. 3 is a schematic view showing a second embodiment of a coil deterioration diagnosis method according to the present invention and a coil deterioration diagnosis apparatus applied to the diagnosis method. Note that the measurement position is a cross-sectional position in the region A shown in FIG. 28 as in the first embodiment.
- the same components as those used in the first embodiment are denoted by the same reference numerals.
- the coil deterioration diagnosis apparatus has a surface electrode 27 attached to the outer surface of the second insulating layer 15.
- the surface electrode 27 is formed, for example, by applying an adhesive to one surface of a 30 ⁇ 30 mm aluminum foil and affixing the outer surface of the second insulating layer 15. Note that other components are the same as the components used in the first embodiment, and a description thereof will be omitted.
- the coil deterioration diagnosis method for detecting the potential based on the water leaking to the first insulation layer 14 from the conductor 13 using the coil deterioration diagnosis apparatus having such a configuration is based on the second insulation layer 15. Bring the potential measurement window 17 of the potential measurement probe 18 close to the surface electrode 27 affixed to the outer surface, apply AC voltage E from the AC power supply 12 to the conductor 13 of the coil 11, and apply the AC voltage E to the surface electrode 27.
- the voltage reading device 20 may be omitted as in the first embodiment.
- the high input impedance is replaced by replacing the voltage measurement probe 18 and the non-contact surface voltmeter 19 used in the first embodiment.
- An electrometer 28 may be used.
- the equivalent circuit shown in FIG. 5 is the equivalent circuit of the first embodiment shown in FIG. 2, wherein the capacitance between the first internal electrode 16 and the surface electrode 27 is Ce, and the surface electrode The stray capacitance C f between 27 and surrounding coils is added.
- the potential of the surface electrode 27 is a potential obtained by dividing the potential of the first internal electrode 16 and the potential of the surrounding object by the stray capacitance C f and the capacitance C e.
- the capacitance C e is sufficiently larger than the stray capacitance C f
- the potential of the surface electrode 27 is a difference of several percent or less from the potential of the first internal electrode 16. Therefore, the potential of the surface electrode 27 is sufficient even if it is regarded as the potential of the first internal electrode 16.
- the present embodiment focuses on the fact that the potential of the front electrode 27 can be regarded as the potential of the first internal electrode 16, and measures the potential of the front electrode 27. Infiltration of leaked water into the insulation layer can be detected more quickly and more reliably, and insulation deterioration can be accurately determined.
- FIG. 6 is a schematic diagram showing a coil deterioration diagnosis method according to a fourth embodiment of the present invention and a coil deterioration diagnosis apparatus applied to the diagnosis method.
- the outside of the conductor 13 of the coil 11 including the upper coil and the lower coil is covered with an insulating layer 29 and first to third insulating layers 14, 15 and 26, and the insulating layers 29 and 1 ⁇
- First to third internal electrodes 16, 24, 25 are inserted into the third insulating layers 14, 15, 26, and the outermost third internal electrode 25 is connected to the straight portion of the coil 11.
- the first to third internal electrodes 16, 24, and 25 can be viewed from the outside for a rotating electric machine with a coil insulation structure in which the electric field on the outer surface of the insulating layer at the coil end is suppressed.
- the potential of the internal electrodes is measured, and the first to third insulating layers are separated from the conductor 13. Determines whether or not leaked water has entered 14, 15, 26 Is shall.
- a clip 32 having an outlet pipe 31 for directly cooling the conductor 13 with water is provided.
- the region A is the first internal electrode space region
- the region B is the second internal electrode
- the space region, the C region is referred to as a third internal electrode space region, and the D region is referred to as an internal electrode non-existent region.
- an AC voltage from an AC power supply 12 is applied to the conductor 13, and the potential measurement probe 18 of the non-contact surface electrometer 19 is advanced and retracted along the surface of the coil end portion. Measure the potential at ⁇ D.
- FIG. 7 shows that the potential measurement probe 18 of the non-contact surface electrometer 19 is moved back and forth along the surface of the coil end part, and the potential (shown by the broken line) of the coil with the leaked water in each of the areas A to D is measured.
- FIG. 3 is a potential diagram comparing the potential of a coil (shown by a solid line). From FIG. 7, it was found that the potential changes relatively clearly stepwise as the potential measurement probe 18 advances and retreats to the regions A to D.
- the potentials of the first internal electrode 16 and the second internal electrode 24 are respectively in a region of 160 mm to 190 mm from the clip 32 and a distance of 210 mm to 24 mm from the clip 32. By reading the potential value in the 0 mm area, the presence or absence of leaked water can be determined in comparison with a healthy coil.
- the potential measurement probe 18 is advanced and retracted along the outer surface of the insulating layer, and after confirming the positions of the first and second internal electrodes 16 and 24, each of the internal electrodes 16 and Since the potentials of areas A and B in 24 are measured and the presence or absence of leaked water is determined from the measurement results, the infiltration of leaked water into the insulating layer can be detected easily and quickly, and insulation deterioration can be reduced. Recognize early and take appropriate action thereafter.
- the potential measurement probe 18 is moved back and forth along the outer surface of the insulating layer, and the positions of the first and second internal electrodes 16 and 24 are confirmed.
- the potentials of the areas A and B are measured at the time of measurement, when measuring the potential, the surface electrode 27 is attached to the measurement position, and the potential of the surface electrode 27 is measured with the non-contact surface electrometer 19 and the high input impedance. It may be measured by any one of the one-dance electrometer 28.
- the first internal electrode 16 and the second internal electrode 16 measured in the embodiment shown in FIG. 1 or the second embodiment shown in FIG.
- the potential waveform of 24 may be observed, the phase difference of the potential waveform with respect to the applied voltage may be read, and the presence or absence of water leaking to the insulating layer may be determined from the phase difference.
- the present embodiment skillfully utilizes the phenomenon that the phase is delayed as compared with the potential waveform of a sound coil when leakage water enters the insulating layer. As described above, according to the present embodiment, when the measured potential waveform has a phase lag compared to the potential waveform of a sound coil, it is determined that leaked water has entered the insulating layer. And recognize early and take appropriate action.
- the DC voltage applied to the conductor 13 is set to a stepped or square waveform to determine the presence or absence of leaked water.
- the present embodiment skillfully utilizes the phenomenon that when leaked water enters the insulating layer, the potential becomes higher than a healthy coil potential.
- a DC voltage is applied to the conductor 13, and then the potential of the first inner electrode 16 is read.
- the potential is higher than the potential of a sound coil, the leaked water enters the insulating layer. Therefore, it is possible to easily and quickly detect the infiltration of leaked water into the insulating layer, and to recognize insulation deterioration earlier and take appropriate measures thereafter.
- the surface electrode 27 When detecting the infiltration of leaked water from the conductor 13 into the insulating layer, when the surface electrode 27 is attached to the outer surface of the insulating layer, the outer surface of the insulating layer is charged by friction, etc., and the applied voltage is 0. However, the first electrode 27 has a large potential, which may cause a measurement error. Therefore, before applying a voltage to the conductor 13, the surface electrode 27 is once grounded (earthed) and then opened, and then a voltage is applied to the conductor 13, and the potential of the first internal electrode 16 is changed. If the measured value is higher than the healthy coil potential, it may be determined that leaked water has entered the insulating layer. By doing so, it is possible to reduce the measurement error and determine whether or not leaked water has entered the insulating layer.
- FIG. 10 shows a method of diagnosing coil deterioration according to the present invention and an application to the diagnosing method.
- FIG. 9 is a schematic diagram showing a fifth embodiment of a coil deterioration diagnosis device according to the present invention.
- the coil deterioration diagnosis apparatus has a structure in which a surface electrode 27 is attached to the second insulating layer 15 of the outer diameter side coil (lower coil) 33, and the inner side of the inner diameter side coil (upper coil) 34.
- An external electrode 35 is provided, the surface electrode 27 and the external electrode 35 are connected by a connecting wire 36, the surface electrode 27 and the external electrode 35 are set to the same potential, and the leakage water leaks to the insulation layer.
- the potential measurement probe 18 provided with the potential measurement window 17 is brought close to the external electrode 35, and the potential of the surface electrode 27, which has the same potential as the external electrode 35, is measured. It is designed to make it easy to measure potentials in areas where potentials cannot be measured directly.
- the surface electrode 27 and the external electrode 35 have the same potential, so if both are integrated and replaced with the surface electrode 27, this embodiment will be described with reference to FIG. be able to.
- the surface electrode 27 and the external electrode 35 are made of a conductive material such as a fiber-reinforced plastic (FRP) in which a metal, a conductive polymer material, or a conductive fiber is bonded with a resin. Anything can be used as long as it is a polygon, circle, ellipse, etc.
- FRP fiber-reinforced plastic
- Fig. 11 shows a coil deterioration diagnosis method for detecting the potential of the first internal electrode 16 based on water leaking from the conductor 13 to the first insulation layer 14 using the coil deterioration diagnosis device with such a configuration. Will be described.
- the data obtained by measuring the potential of the first internal electrode 16 include the insulation thickness during coil manufacturing, the variation in the length of the first internal electrode 16, the installation condition of the surface electrode 27 and the external electrode 35, and the potential measurement. Includes variations in the positional relationship of the probe 18 with the electrode to be measured, and measurement errors of the measurer. In this embodiment, a statistical study To determine if the coil is healthy or has leaked water.
- the potential distribution diagram in Fig. 11 shows the measurement results of the end portions on the turbine side and the collector side of the inner side coil (upper coil) 34. 84 points were plotted on normal probability paper. Things.
- the average value and the standard deviation of the measured data are obtained, and the value obtained by adding the product of the standard deviation and a predetermined multiple A to the average value is set as a limit value. This is to judge that the leaked water has entered the insulating layer, deviating from the data distribution.
- the average value of this data is 53.59 and the standard deviation is 5.32. As the multiple A, usually 2.5 or 3.0 times is often used.
- the coil method for determining that leaked water has entered the insulating layer may differ from the actual number of coils.
- the response differs depending on the situation, but if you consider it more conservative, you may use a lower limit. If the above-mentioned method is used, the deterioration of the coil can be easily diagnosed by measuring the potential of the internal electrodes for all the coils, but in reality, this may not be the case.
- the end of the coil is always tied with a glass string, sandwiching a block of fiber reinforced plastic (FRP), or tightening the coil with bolts. It may not be possible to measure the internal electrodes 16 or 24 at the same position (already, area A or area B shown in Fig. 6). Therefore, the potential measurement of the first internal electrode 16 in the region A and the potential measurement of the second internal electrode 24 in the region B may be mixed.
- FRP fiber reinforced plastic
- the ratio of the potential of the first internal electrode 16 to the potential of the second internal electrode 24 is determined by the geometric shape of the internal electrode. Unaffected by seepage of leaked water into 4. In the case of the data shown in Table 1, the ratio between the potential of the first internal electrode 16 and the potential of the second internal electrode 24 is 2.2 times, along with the healthy coil and the coil that has leaked into the insulating layer. .
- the potential ratio of both electrodes is determined in advance, and the data is converted into the potential of either the first internal electrode 16 or the second internal electrode 24.
- FIG. 12A and FIG. 12B are schematic views showing a first embodiment of a surface electrode device applied to the coil deterioration diagnosis device according to the present invention.
- FIG. 12A is a side view of the surface electrode device
- FIG. 12B is a view of the surface electrode device viewed from the direction of arrow XI IB-XI IB in FIG. 12A. It is a front view.
- the surface electrode device according to this embodiment is obtained by bonding an insulating plate 37 to a surface electrode 27 made of any one of a conductive plate, a film, and a foil.
- the insulating plate 37 is attached to the surface electrode 27 to form the surface electrode device.
- the present invention is not limited to this example.
- any one of a conductive plate, a film, and a foil may be used.
- the surface electrode 27 and the insulating plate 37 may be bonded in a sandwich shape. For example, as shown in FIG.
- a surface electrode device in which the surface electrode 27 and the insulating plate 37 are arranged in this order on the side may be attached to the outer surface, or the insulating plate may be attached to the outer side as shown on the other side of the coil 11. 37, a surface electrode device arranged in the order of the surface electrode 27 may be attached.
- FIG. 14A and FIG. 14B are schematic diagrams showing a third embodiment of the surface electrode device applied to the coil deterioration diagnosis device according to the present invention.
- FIG. 14A is a side view of the surface electrode device
- FIG. 14B is a front view of the surface electrode device viewed from the direction of arrows XIVB-XIVB in FIG. 14A.
- FIG. 14A is a side view of the surface electrode device
- FIG. 14B is a front view of the surface electrode device viewed from the direction of arrows XIVB-XIVB in FIG. 14A.
- the surface electrode device according to the present embodiment is obtained by bonding a surface electrode 27 to an insulating plate 37 having a plurality of protrusions 38.
- the varnish 29 is applied to the surface of the coil 11. Even if there is unevenness due to the processing, the stability is ensured by the projections 38 provided on the insulating plate 37, so that the variation in the distance between the first internal electrode 16 and the surface electrode 27 is kept small. It is possible to reduce the potential measurement error.
- FIGS. 16A and 16B are applied to the coil deterioration diagnosis apparatus according to the present invention.
- FIG. 9 is a schematic view showing a fourth embodiment of the surface electrode device. Note that in Fig. 16,
- FIG. 6A is a side view of the surface electrode device
- FIG. 16B is a front view of the surface electrode device as viewed from the direction of arrows XVIB-XVIB in FIG. 16A.
- the surface electrode device is configured such that a surface electrode 27 made of a conductive material such as a conductive sponge, a conductive rubber or the like is replaced with a holding plate 40 made of a material having an excellent insulating or conductive property. It is what was pasted on.
- a surface electrode device in which a holding plate 40 is adhered to a surface electrode 27 made of a conductive material is used.
- a surface electrode device in which a holding plate 40 is adhered to a surface electrode 27 made of a conductive material is used.
- the coil 11 follows the irregularities and uses the cushion of the surface electrode 27 made of a conductive material. Because the pressing force is applied from the holding plate 40 to maintain the adhesion, fluctuations in the distance between the first internal electrode 16 and the surface electrode 27 can be kept small, and potential measurement errors can be reduced. You can let In the present embodiment, a pressing plate 40 is bonded to a surface electrode 27 made of a conductive material to form a surface electrode device.
- FIG. 19A and FIG. 19B are schematic diagrams showing a sixth embodiment of the surface electrode device applied to the coil deterioration diagnosis device according to the present invention.
- FIG. 19A is a side view of the surface electrode device
- FIG. 19B is a front view of the surface electrode device as viewed in the direction of arrows XIXB-XI XB in FIG. 19A.
- the surface electrode 27 since the surface electrode 27 is provided with the handle 42, the surface electrode 27 is carried, and the pressing force of the surface electrode 27 to the measurement point of the coil 11 is maintained. Etc. to increase convenience.
- the pattern 42 is provided on the surface electrode 27.
- the present invention is not limited to this example.
- the handle 42 shown in FIGS. 19A, 19B to 22A, and 22B has a mounting angle that can be freely adjusted in order to improve usability.
- the insulating plate 37 and the holding plate 40 are used to hold the surface electrode 27, and Alternatively, it may have a plurality of holes. Further, if the surface electrode 27 itself is a hard material, the insulating plate 37 and the holding plate 40 may be simply frames.
- FIG. 23 is a schematic diagram showing a first embodiment of a potential detection device applied to the coil deterioration diagnosis device according to the present invention.
- a probe support 43 made of an insulating material is attached to the surface electrode 27, and the potential measurement window 17 of the potential measurement probe 18 is attached to the probe support 43.
- a probe holder 44 made of an insulating material is attached to the opposite side of the potential measurement window 17 of the measurement probe 18.
- the probe support 43 has a step portion 46, and the potential measurement probe 18 is supported by the step portion 46, and the gap between the potential measurement window 17 of the potential measurement probe 18 and the surface electrode 27 is fixed distance. Is maintained.
- the potential measuring probe 18 is connected to a non-contact surface electrometer (not shown) via a probe lead wire 45 passing through a probe holder 44.
- the probe holder 44 when measuring the potential, first, the probe holder 44 is held by hand, and the surface electrode 27 is moved along the surface of the coil (not shown). The potential is measured, the measurement location is confirmed from the potential change shown in Fig. 7, the surface electrode 27 is brought into contact with the measurement location, and the potential of the internal electrode of the coil is measured.
- the probe support 43 for supporting the potential measurement probe 18 and the probe holder 44 are provided, and the operator is required to set up the mounting on the surface electrode 27. So that it can be done with one hand, The measurement setup work can be simplified.
- the probe support 43 and the probe holder 44 are mounted at different positions on the electrometering probe 18.
- the present invention is not limited to this example.
- FIG. 24B the potential measurement probe 18 may be supported by using an L-shaped integrated probe support 47.
- FIG. 25A and FIG. 25B are schematic views showing a third embodiment of the potential detecting device applied to the coil deterioration diagnosing device according to the present invention.
- FIG. 25A is a side view of the potential detecting device
- FIG. 25B is a front view of the potential detecting device viewed from the direction of arrows XXVB-XXVB in FIG. 25A. is there.
- the potential detecting device is a probe support that extends from the holding plate 40 while bonding the surface electrode 27 made of a conductive material with the flexible portion 41 interposed on the holding plate 40. While the external electrode 35 and the potential measuring probe 18 are provided on 47, the surface electrode 27 and the external electrode 35 are connected with the connecting wire 36, and the external electrode 35 and the potential measuring probe 18a, potential measurement A spacer 48 is interposed between the window 17.
- the potential measurement probe 18 is connected to a non-contact surface electrometer (not shown) via a probe lead wire 45.
- the setup to the coil is performed.
- the installation work can be simplified, and the work efficiency can be further improved.
- installation and portability are effective when measuring the potential of a place where the coil cannot be directly approached.
- the electrode portions that come into contact with the coil surface are not limited to those described here, but are shown in FIGS. 12, 13, 13, 14, and 16.
- the electrode device shown in FIG. 17 can be used.
- FIG. 26 is a schematic diagram showing a fourth embodiment of the potential detecting device applied to the coil deterioration diagnosing device according to the present invention.
- the potential detecting device comprises a probe support 4 extending from a holding plate 40 bonded to a surface electrode 27 via a flexible portion 41. Attach probe lead wire 45, external electrode 35, potential measuring probe 18 to 7 and install surface electrode 27, external electrode 35, potential measuring probe 18 etc. in an integrated configuration.
- the surface electrode 27 is brought into contact with the coil 11 in which the conductor 13 is covered with the first insulating layer 14, the second insulating layer 15, and the first internal electrode 16, and
- the potential of the internal electrode 16 is measured by the potential measurement probe 18 and the measured potential is taken into the computer 50 via the non-contact surface electrometer 19 and the transmitter / receiver 49a, 49b, and the data is stored. It was made.
- the present embodiment includes a voltage reading device 20 that reads the magnitude and waveform of the AC voltage E applied from the AC power supply 12 to the conductor 13.
- the surface electrode 27, the external electrode 35, the potential measurement probe 18 and the like are mounted on the holding plate 40 and the probe support 47, and the installation and portability are easily integrated.
- the computer 50 stores the potential measured by the potential measurement probe 18, it is possible to more appropriately take measures against subsequent coil deterioration based on the data.
- the non-contact surface electrometer 19 and the computer 50 are connected using radio waves.
- the connection may be performed using infrared rays, and signal connection may be performed directly. You may connect using a cable. Industrial applicability
- a coil deterioration diagnosis method and a coil deterioration diagnosis apparatus applied to the diagnosis method according to the present invention measure the potential of an internal electrode covering a conductor from outside using a non-contact electrometer or a high input impedance electrometer.
- the presence or absence of water leaking from the conductor to the insulating layer can be determined based on the measured potential, and the deterioration of the insulating layer can be diagnosed. It can be done easily, quickly and reliably, and the subsequent measures can be done precisely, so that its industrial applicability is great.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Testing Of Short-Circuits, Discontinuities, Leakage, Or Incorrect Line Connections (AREA)
- Testing Relating To Insulation (AREA)
- Tests Of Circuit Breakers, Generators, And Electric Motors (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002483567A CA2483567C (en) | 2002-04-26 | 2003-02-17 | Coil deterioration diagnostic method and coil deterioration diagnostic apparatus |
EP03705237A EP1503218B1 (en) | 2002-04-26 | 2003-02-17 | Method for diagnosing deterioration of coil and system for diagnosing deterioration of coil |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2002-126293 | 2002-04-26 | ||
JP2002126293A JP4497790B2 (ja) | 2002-04-26 | 2002-04-26 | コイル劣化診断方法およびこの診断方法に適用するコイル劣化診断装置 |
Publications (1)
Publication Number | Publication Date |
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WO2003091743A1 true WO2003091743A1 (fr) | 2003-11-06 |
Family
ID=29267593
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2003/001649 WO2003091743A1 (fr) | 2002-04-26 | 2003-02-17 | Procede et systeme de diagnostic de deterioration de bobine |
Country Status (6)
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EP (2) | EP1503218B1 (ja) |
JP (1) | JP4497790B2 (ja) |
CN (1) | CN100504421C (ja) |
CA (1) | CA2483567C (ja) |
WO (1) | WO2003091743A1 (ja) |
ZA (1) | ZA200408668B (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4497916B2 (ja) * | 2003-10-24 | 2010-07-07 | 株式会社東芝 | コイルの余寿命推定方法およびコイルの余寿命推定装置 |
JP4783069B2 (ja) * | 2005-06-23 | 2011-09-28 | 株式会社東芝 | コイルの水漏れ検出方法およびこの検出方法に適用する水漏れ検出装置 |
DE102012219151A1 (de) * | 2011-10-28 | 2013-05-02 | Robert Bosch Gmbh | Vorrichtung und Verfahren zur Erkennung eines Flüssigkeitseintrags in ein Gehäuse |
TWI470239B (zh) * | 2012-11-19 | 2015-01-21 | Wistron Corp | 絕緣狀態偵測系統、絕緣狀態偵測之方法及其螢光顯微鏡系統 |
CN103743533A (zh) * | 2013-12-28 | 2014-04-23 | 李洪普 | 一种灯泡检漏方法和系统及其装置 |
JP2015206772A (ja) * | 2014-04-23 | 2015-11-19 | 日新電機株式会社 | 部分放電測定装置及び部分放電測定方法 |
EP2983276B2 (de) | 2014-08-04 | 2020-01-29 | Siemens Aktiengesellschaft | Dynamoelektrische Maschine mit einer Isolationsüberwachung |
CN106443444A (zh) * | 2016-09-27 | 2017-02-22 | 北海益生源农贸有限责任公司 | 一种电机运行状态监测管理系统 |
JP2018124240A (ja) * | 2017-02-03 | 2018-08-09 | キヤノンメディカルシステムズ株式会社 | 自動分析装置 |
EP3807611A1 (en) | 2018-06-15 | 2021-04-21 | King Abdullah University of Science and Technology | Leak detector |
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Also Published As
Publication number | Publication date |
---|---|
EP1757948A3 (en) | 2007-03-07 |
EP1503218A1 (en) | 2005-02-02 |
EP1757948B1 (en) | 2010-01-13 |
CA2483567A1 (en) | 2003-11-06 |
EP1503218A4 (en) | 2005-10-12 |
CN1650185A (zh) | 2005-08-03 |
EP1757948A2 (en) | 2007-02-28 |
CN100504421C (zh) | 2009-06-24 |
JP4497790B2 (ja) | 2010-07-07 |
EP1503218B1 (en) | 2007-01-17 |
JP2003315402A (ja) | 2003-11-06 |
CA2483567C (en) | 2009-11-03 |
ZA200408668B (en) | 2005-05-03 |
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