WO2003089731A1 - Gradient density padding material and method of making same - Google Patents

Gradient density padding material and method of making same Download PDF

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Publication number
WO2003089731A1
WO2003089731A1 PCT/US2003/012173 US0312173W WO03089731A1 WO 2003089731 A1 WO2003089731 A1 WO 2003089731A1 US 0312173 W US0312173 W US 0312173W WO 03089731 A1 WO03089731 A1 WO 03089731A1
Authority
WO
WIPO (PCT)
Prior art keywords
single layer
nonwoven material
thickness
processing
gradient density
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2003/012173
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English (en)
French (fr)
Inventor
Durward Gomez
Steven Borchardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lydall Inc
Original Assignee
Lydall Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lydall Inc filed Critical Lydall Inc
Priority to KR1020047017041A priority Critical patent/KR101002540B1/ko
Priority to AU2003231005A priority patent/AU2003231005B2/en
Priority to JP2003586434A priority patent/JP2005523196A/ja
Priority to EP03724126A priority patent/EP1501987B1/en
Priority to CA002483709A priority patent/CA2483709C/en
Priority to BRPI0309489-8B1A priority patent/BR0309489B1/pt
Priority to MXPA04010440A priority patent/MXPA04010440A/es
Priority to DE60317658T priority patent/DE60317658T2/de
Publication of WO2003089731A1 publication Critical patent/WO2003089731A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/732—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by fluid current, e.g. air-lay
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
    • G—PHYSICS
    • G10—MUSICAL INSTRUMENTS; ACOUSTICS
    • G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
    • G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/162—Selection of materials
    • G—PHYSICS
    • G10—MUSICAL INSTRUMENTS; ACOUSTICS
    • G10K—SOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
    • G10K11/00—Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/16—Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/162—Selection of materials
    • G10K11/168—Plural layers of different materials, e.g. sandwiches
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/69—Autogenously bonded nonwoven fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/696—Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]

Definitions

  • the present invention relates to a padding material for acoustic applications.
  • the present invention relates to a gradient density padding material, wherein the density of a portion of the thickness of the padding material is increased to increase the air flow resistance of the padding material.
  • the acoustic properties of the padding material can be tuned to a particular application.
  • acoustic absorption performance is dependent in part on the airflow resistance of materials. It is also known that by increasing the airflow resistance of an acoustic material, the low to mid frequency (100 - 2500 Hz) absorption performance can be increased. Maximum acoustic absorption in this frequency range occurs when that material has an airflow resistance of 800-1200 MKS Rayls. This frequency range is often the most difficult to combat in vehicle systems where weight, cost, and packaging space (thickness) are limited. All of today's multilayer systems require 2 or more separate layers, where each layer is produced independently with specific stiffness, strength, and airflow resistance properties. These independent layers must then be bonded together in a secondary operation.
  • U.S. Patent No. 6,145,617 a compressed nonwoven fiber layer is bonded to an uncompressed fiber layer.
  • a second example is described in U.S. Patent No. 6,296,075.
  • a high flow resistant facing or coverstock material is attached to the surface of a low density fiber web.
  • a third example is described in U.S. Patent No. 5,824,973.
  • a low density fiber web includes a microporous film attached to a surface thereof.
  • a fourth example is described in U.S. Patent No. 5,334,338. hi this patent, a dense foam layer with low open cell count is produced on top of a porous, low density open cell foam layer.
  • the present invention is based on the discovery that enhanced performance properties can be produced using a single layer of nonwoven fibrous padding material.
  • the present invention is directed to a single layer of nonwoven fibrous padding material with enhanced properties and a process for making the same.
  • a single layer of acoustic padding material is produced with enhanced performance properties.
  • the uniform density nonwoven padding material 1 is processed to form a gradient density padding material 3 having a top surface portion 5 with an increased density and a base material portion 7 with a lower density.
  • the inventors of the present invention have determined that the increased density top portion 5 provides a number of enhancements to the base material portion.
  • the present invention is directed to a product and process for making a nonwoven fibrous padding material, which will provide an acoustic solution that is much less expensive to produce than other lightweight systems using multiple layers of material.
  • the enhancements provided by the increased density top portion include:
  • the increased material strength enables the padding material to be processed through secondary operations, such as die-cutting and molding operations.
  • Many nonwoven and foam padding materials have low strength in their X-Y planes, particular, many of the lightweight padding systems utilize low density materials with tensile and tear strength properties that are not great enough for the intended processes and final applications. Therefore, these materials must include strengthening layers in order to provide the strength necessary for most automotive applications.
  • the present invention provides increased strength in the X-Y plane of a lightweight padding material.
  • the density and thickness of the top surface portion of the single layer of nonwoven material can be designed so that the material will meet most automotive strength requirements without the use of additional strengthening layers.
  • the increased airflow resistance of the increased density top surface greatly increases the low to mid frequency acoustic absorption. Due to the limited packaging space available in a vehicle for acoustical products, the thickness of these materials is usually limited to 1" or less. Low to mid f equency sound waves (100 - 2500 Hz) are the most difficult acoustic waves to absorb with materials less than 1" thick.
  • the increased airflow resistance of the increased density top surface of the single layer of nonwoven fibrous padding material of the present invention greatly improves the acoustic absorption in these frequencies.
  • the increased airflow resistance section By producing the increased airflow resistance section with densely packed fibers, absorption performance is increased even beyond much of the background art on this subject.
  • Much of the background art teaches the addition of a separate microporous film, nonwoven, or similar lightweight cover layer to provide the airflow resistance.
  • the increased density top portion of the single layer of nonwoven fibrous padding material provides the airflow resistance throughout the entirety of the densified portion.
  • the densified portion will have an airflow resistivity that is lower than much of the background art.
  • Airflow resistivity is the total airflow resistance of a material divided by its thickness. Acoustic materials with high airflow resistivity will generally have poor high frequency absorption.
  • the padding material of the present invention provides the necessary total airflow resistance of the material without having a portion of material with high airflow resistivity. Therefore, a material is produced from a single layer with increased low and mid frequency absorption, without loss of absorption in the higher frequencies (2500-10,000 Hz). Also, since the airflow resistance of the material is provided by a densified fiber portion, the acoustic waves must travel through a tortuous path with a large amount of fiber surface area. This tortuous path increases the surface area to increase the acoustic absorption of the present invention over the background art concepts that utilize separate microporous films, nonwovens, or similar lightweight cover layers.
  • the increased density of the top portion of the padding material produces a decoupled mass system helping to reduce vibration transmission. This property is even further enhanced when the material is used with additional top layers such as a carpet. This type of decoupled mass system will generally limit the amount of vibration that is transferred through the material. This property greatly increases the acoustic performance of the product in applications where the material is mounted against vibrating panels such as vehicle floorpans.
  • Producing a single layer padding material with enhanced performance as described above provides a lightweight acoustical material at a very cost effective price.
  • This enhanced padding system can be used in lieu of traditional decoupled mass acoustic systems to provide a significant cost and system weight savings. This system will also cost less to produce than other multi-layer lightweight systems.
  • the product and method of the present invention also avoids the occurrence of delamination during secondary processing. This is a common occurrence in the multilayer structures according to the background art.
  • the shear stresses that are experienced in, for example, molding of the product can separate the individual layers of material.
  • the material is formed from a single layer of material having an increased density portion. Accordingly, there is no attachment line that can be separated during secondary processing.
  • a gradient density padding material comprising a single layer of nonwoven material, said single layer of nonwoven material having at least one surface thereof processed to form a portion of a thickness thereof having a density increased with respect to a remaining portion of the thickness thereof, said single layer of nonwoven material after processing having an airflow resistance within the range of 200-4000 MKS Rayls, wherein said single layer of nonwoven material has an enhanced acoustic performance.
  • a method of making a gradient density padding material having an enhanced acoustic performance comprising the steps of providing a single layer of nonwoven material; and processing at least one surface of said single layer of nonwoven material to form a portion of a thickness thereof having a density increased with respect to a remaining portion of the thickness thereof, said single layer of nonwoven material after processing having an airflow resistance within the range of 200-4000 MKS Rayls.
  • Figure 1 is a schematic of the process of the present invention, which illustrates the gradient density padding material according to the present invention
  • Figure 2 is a schematic of an embodiment of the process of the present invention.
  • Figure 3 is a graph of the absorption coefficient vs. frequency before the gradient density process of the present invention is performed
  • Figure 4 is a graph of the absorption coefficient vs. frequency after the gradient density process of the present invention is performed to illustrate the increased performance of the present invention.
  • Figure 5 is a cross-section through the gradient density padding material of the present invention in conjunction with a carpet.
  • Figure 6 is a cross-section through the gradient density padding material of the present invention according to an embodiment of the present invention.
  • a single layer of low density nonwoven material 1 can be formed by any known means.
  • the nonwoven material 1 can be formed by vertical lapping or horizontal lapping.
  • the nonwoven material 1 can be formed by needle punching, thermal bonding, adhesive bonding, stitch bonding, hydroentangling, wet laying, air laying, meltblowing or spunbonding.
  • the nonwoven material 1 In order to produce a gradient density padding material 3 as described above, the nonwoven material 1 must be originally manufactured using a significant percentage of thermoplastic fibers.
  • the material can be a blend of any fibers as long as the material is made up of at least 20% thermoplastic fiber.
  • the nonwoven material would be made from a blend of 65-80% thermoplastic fibers and 20-35% non-melting fibers.
  • the thermoplastic fibers can be constructed, for example, from polyesters, polyamides or polyolefins or a blend of two or more different thermoplastic fibers.
  • the non-thermoplastic fibers can be inorganic, natural or synthetic materials.
  • the inorganic material fibers can be constructed from glass, ceramic, mineral, basalt, silica, etc.
  • the natural material fibers can be cotton, wool, hemp, ramie, kenaf, flax, etc.
  • the synthetic material fibers can be constructed from acrylics, aramids, sulfars (PPS), PBI, Peek, Melamine, Phenolic, Carbon Preox, etc.
  • the nonwoven material 1 can originally be almost any weight and thickness prior to the surface densification process.
  • the nonwoven material 1 would be a lightweight web in the range of .5-9 oz/ft 2 , preferably 1.5-6 oz/ft 2 .
  • a thickness of the nonwoven material 1 should be within the range of 5-40 mm, preferably 10-35 mm before processing.
  • a portion 5 of the gradient density padding material 3 has an increased density with respect to a remaining portion or non-densified base portion 7 of the gradient density padding material 3.
  • the gradient density padding material 3 should be processed to result in an air flow resistance of the gradient density padding material 3 to be within the range of 200-4000 MKS Rayls, preferably 400 - 2000 MKS Rayls. Such processing obtains a very effective acoustic product, which is cost effective.
  • the gradient density padding material 3 of the present invention is an acoustically tunable material. Specifically, the air flow resistance can be manipulated under a predetermined amount of heat and pressure in order to obtain a product which has improved performance in a particular frequency range. Accordingly, the gradient density padding material 3 of the present invention can be easily designed to a particular application, depending on the results that are intended to be achieved.
  • the nonwoven material 1 can be preheated on a top surface thereof before being heated and compressed by, for example, a hot knife, infrared, etc.
  • the amount of heat and pressure that should be applied will vary depending upon the results that are intended to be achieved. However, heat within the range of 450 to 550 °F would be sufficient to obtain a desirable product, depending on the melt point of the fibers used in a particular application.
  • the padding material 3 of the present invention is referred to as a "gradient density" padding material, since the density of the densified portion does not have to be a uniform density throughout a thickness thereof.
  • a gradient density padding material
  • heat and pressure is applied to the top surface of the nonwoven material 1 in order to increase the density of the increased density portion 5 to change the air flow resistance of the resulting padding material 3.
  • the top most surface of the nonwoven material 1 which is closest to the source of heat, becomes more dense than a portion spaced from the top most portion (the bottom most portion of the increased density portion 5).
  • the non-densif ⁇ ed base portion 7 has a density after processing, which is substantially the same as the original density of the nonwoven material 1. Accordingly, the padding material 3 has a "gradient density.”
  • Figure 2 illustrates that the nonwoven material 1 is preheated and hot and cold rollers H and C are used to apply the heat and pressure.
  • hot and cold rollers H and C are used to apply the heat and pressure.
  • a heated belt can be used instead of the hot and cold rolls H illustrated in Figure 2.
  • heated rolls or belts can be used on both the top and bottom surfaces of the nonwoven padding material to produce a dual-walled product having increased density portions on the top and bottom of the padding material.
  • This padding material can be used in this manner to provide a padding material having two portions with an increased density.
  • the top and bottom surfaces of the gradient density padding material 3 will have increased density portions, while the middle of the material 3 does not have an increased density.
  • the top and bottom of the material 3 can be processed at different temperature and/or temperature in order to form three portions having a different density.
  • the above-described gradient density padding material which has two increased density portions can be cut in half in the machine direction of the padding material to form two padding materials having a single increased density portion.
  • each of the two padding materials will have an increased density portion and a less dense portion.
  • the padding materials can then be used in any of the applications mentioned in the present disclosure. By cutting the padding material having two increased density portions in half, the processing time and therefore the cost of production of the padding material can be substantially decreased.
  • the absorption coefficient vs. frequency has been plotted before and after the gradient density process of the present invention has been performed.
  • the padding material itself has good absorption properties in the high frequency range. However, in the low frequency range, the absorption is unsatisfactory for most applications.
  • the absorption properties of the padding material have been increased over the entire low frequency range. In addition, no high frequency degradation has occu ⁇ ed.
  • the gradient density padding material 3 of the present invention can be used in any interior or exterior acoustic applications for vehicles.
  • the gradient density padding material 3 of the present invention can be used for interior application, such as dash interior and under carpet applications, or exterior application, such as tunnel shields.
  • interior application such as dash interior and under carpet applications
  • exterior application such as tunnel shields.
  • the gradient density padding material 3 of the present invention can be used in any application that calls for high acoustic performance other than automotive.
  • the gradient density padding material 3 of the present invention can be molded after the initial processing into complex shapes to fit the necessary geometry in many different automotive and non-automotive applications. Accordingly the padding material 3 of the present invention can be used anywhere that fibrous or foamed acoustic products are being used today.
  • the gradient density padding material 3 of the present invention can be used in molded carpets, molded exterior, etc.
  • the gradient density padding material 3 of the present invention is illustrated in an under carpet application.
  • the gradient density padding material 3 of the present invention can be attached to a carpet 9 having a backing 11 during the molding process of the carpet 9. In view of this, it is unnecessary to use adhesives to attach the carpet 9 to the padding material 3.
  • Figure 5 illustrates the used of the padding material 3 of the present invention with a carpet
  • the applications are not limited to carpets.
  • other nonwoven, woven, films, foils and/or adhesive layers can be used in addition to, or in place of the carpet 2 of Figure 5.
  • the gradient density padding material 3 is illustrated as being constructed from a vertically lapped nonwoven material.
  • the vertically lapped nonwoven material can be the type described in International Publication No. WO 02/095111, published November 28, 2002, which is incorporated herein by reference.
  • the gradient density padding material of the present invention can be used in any of the applications described in the above-identified international application to obtain an improved acoustic product having all of the advantages of a vertically lapped material.
  • the gradient density padding material 3 includes an increased density portion 5 and a low density base portion 7.
  • the gradient density padding material 3 of the present invention can also be used to produce an aesthetic as well as an acoustic product.
  • the padding material 3 of the present invention can be processed with heat and pressure on both the top and bottom of the material.
  • the material can then be cut in half to obtain two separate products having the acoustic properties of the present invention.
  • Each of the two products can be used in conjunction with other functional or non-functional layers of material or can be used alone.
  • the fibers used in the making of the padding material be colored in order to increase the aesthetic appeal of the resulting product.
  • the padding material can be used as, for example, a carpet or headliner, which has increased acoustic performance without the necessity of additional layers of material.
  • the use of the above-mentioned vertically lapped material is particularly advantageous.
  • the fibers are fused together in the process of making the vertically lapped material. Accordingly, the carpet has increased wear characteristics.
  • the fibers are generally vertical, eliminating the necessity of a secondary process of straightening the fibers as in other nonwoven carpet processes.
  • the increased density portion of the padding material performs the dual function of increasing the acoustic performance of the carpet, as well as locking the fibers together. Accordingly, there is no need for a backing layer to secure the fibers.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Multimedia (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Nonwoven Fabrics (AREA)
  • Soundproofing, Sound Blocking, And Sound Damping (AREA)
  • Building Environments (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
PCT/US2003/012173 2002-04-22 2003-04-22 Gradient density padding material and method of making same Ceased WO2003089731A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
KR1020047017041A KR101002540B1 (ko) 2002-04-22 2003-04-22 밀도구배 패딩물질 및 그의 제조방법
AU2003231005A AU2003231005B2 (en) 2002-04-22 2003-04-22 Gradient density padding material and method of making same
JP2003586434A JP2005523196A (ja) 2002-04-22 2003-04-22 密度勾配型パッド材及びその製造方法
EP03724126A EP1501987B1 (en) 2002-04-22 2003-04-22 Gradient density padding material and method of making same
CA002483709A CA2483709C (en) 2002-04-22 2003-04-22 Gradient density padding material and method of making same
BRPI0309489-8B1A BR0309489B1 (pt) 2002-04-22 2003-04-22 material de acolchoamento de densidade gradiente e mÉtodo de produzir o mesmo
MXPA04010440A MXPA04010440A (es) 2002-04-22 2003-04-22 Material de relleno de densidad gradiente y metodo para hacer el mismo.
DE60317658T DE60317658T2 (de) 2002-04-22 2003-04-22 Polstermaterial mit dichtegradient und verfahren zu dessen herstellung

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2870160A1 (fr) * 2004-05-13 2005-11-18 Cera Systeme de protection acoustique a impedance variable
EP1798722A1 (en) * 2005-12-13 2007-06-20 Takehiro Co., Ltd. Ultra-light sound insulator
JP2007519556A (ja) * 2004-01-12 2007-07-19 ダウ グローバル テクノロジーズ インコーポレイティド 粘弾性発泡体を含む自動車ダッシュインシュレータ
US7320739B2 (en) 2003-01-02 2008-01-22 3M Innovative Properties Company Sound absorptive multilayer composite
EP1775714A4 (en) * 2004-08-04 2009-01-07 Toyo Boseki ACOUSTIC ISOLATION
US7500541B2 (en) 2004-09-30 2009-03-10 Kimberly-Clark Worldwide, Inc. Acoustic material with liquid repellency
EP1812264B1 (de) 2004-11-06 2016-06-08 Röchling Automotive SE & Co. KG Akustik-verkleidungsteil für ein fahrzeug

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6900145B2 (en) * 2001-08-24 2005-05-31 Owens Corning Fiberglas Technology, Inc. Trim panel insulator for a vehicle
US20040231914A1 (en) * 2003-01-02 2004-11-25 3M Innovative Properties Company Low thickness sound absorptive multilayer composite
US20040131836A1 (en) * 2003-01-02 2004-07-08 3M Innovative Properties Company Acoustic web
US7128561B2 (en) 2003-06-30 2006-10-31 Owens Corning Fiberglas Technology, Inc. Surface treatment for blanket of thermoplastic fibers
US7521386B2 (en) 2004-02-07 2009-04-21 Milliken & Company Moldable heat shield
US7696112B2 (en) 2005-05-17 2010-04-13 Milliken & Company Non-woven material with barrier skin
US7428803B2 (en) 2005-05-17 2008-09-30 Milliken & Company Ceiling panel system with non-woven panels having barrier skins
US7651964B2 (en) 2005-08-17 2010-01-26 Milliken & Company Fiber-containing composite and method for making the same
US7605097B2 (en) 2006-05-26 2009-10-20 Milliken & Company Fiber-containing composite and method for making the same
JP5022693B2 (ja) * 2005-12-13 2012-09-12 株式会社タケヒロ 超軽量な防音材
JP5008061B2 (ja) * 2006-10-11 2012-08-22 河西工業株式会社 車両の防音構造
US7825050B2 (en) 2006-12-22 2010-11-02 Milliken & Company VOC-absorbing nonwoven composites
JP2010535295A (ja) * 2007-07-30 2010-11-18 スリーエム イノベイティブ プロパティズ カンパニー 多孔質仕上げ材、音響減衰複合材、並びにそれらの製造方法及び使用法
US8461066B2 (en) * 2007-08-02 2013-06-11 Celanese Acetate Llc Nonwoven from bulked filament tow
MX338805B (es) * 2007-09-28 2016-05-02 Lydall Inc Un panel de vehiculo aislante acustico moldeado y formado y metodo de fabricacion del mismo.
KR100946521B1 (ko) * 2007-11-07 2010-03-11 현대자동차주식회사 차량용 카페트 및 그 제조방법
DE102009007891A1 (de) * 2009-02-07 2010-08-12 Willsingh Wilson Resonanz-Schallabsorber in mehrschichtiger Ausführung
ITMI20120148A1 (it) * 2012-02-03 2013-08-04 Eleda S R L Pannello fonoassorbente e relativo metodo di realizzazione
DE202013012568U1 (de) 2013-05-07 2017-07-17 Johann Borgers GmbH Hinterschäumbares Akustikelement eines Kraftfahrzeugkarosserieverkleidungsbauteils
WO2016115138A1 (en) * 2015-01-12 2016-07-21 Zephyros, Inc. Acoustic floor underlay system
WO2018075654A1 (en) * 2016-10-21 2018-04-26 Board Of Regents, The University Of Texas System Noise-absorbent and odor-adsorbent fabric cover systems for vehicle interiors
EP3425099A1 (de) * 2017-07-03 2019-01-09 Axel Nickel Meltblown-vliesstoff mit verbesserter stapelbarkeit und lagerbarkeit
EP4026937B1 (en) 2017-09-15 2024-10-30 3M Innovative Properties Company Non-woven fibrous web
US10946412B2 (en) * 2018-03-19 2021-03-16 Ronie Reuben Thermally insulating sheet formed from a down core structure and method of fabrication
US11185171B2 (en) * 2018-03-29 2021-11-30 Tiritona Piana US, Inc. Mattress top panel and mattress assemblies with improved airflow
DE102018111915A1 (de) * 2018-05-17 2019-11-21 J.H. Ziegler Gmbh Akustikabsorptionstextilverbundmaterial
EP3917370A1 (en) * 2019-01-29 2021-12-08 3M Innovative Properties Company Sustainable scouring pads
JP2022182264A (ja) * 2021-05-28 2022-12-08 林テレンプ株式会社 吸音パネル、及び、その製造方法
CA3166222A1 (en) * 2021-06-30 2022-12-30 Garland Industries, Inc. Material and method for providing insulation to a foundation wall
IT202200016836A1 (it) 2022-08-05 2024-02-05 O R V Mfg S P A Materiale fonoassorbente e metodo per realizzare tale materiale fonoassorbente
EP4316798A1 (en) 2022-08-05 2024-02-07 O.R.V. Manufacturing S.p.A. Sound-absorbing material and method of making such a sound-absorbing material

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2249138A1 (de) * 1972-10-06 1974-04-11 Giulini Gmbh Geb Neue versteifungsmaterialien
US5456872A (en) * 1991-11-15 1995-10-10 Eduard Kusters Maschinenfabrik Gmbh & Co. Kg Inherently rigid laminate material containing plastic trimmings and a method for producing same
US5824973A (en) * 1992-09-29 1998-10-20 Johns Manville International, Inc. Method of making sound absorbing laminates and laminates having maximized sound absorbing characteristics
WO1999044817A1 (de) * 1998-03-03 1999-09-10 Rieter Automotive (International) Ag Schallabsorbierendes dünnschichtlaminat
EP1154087A1 (en) * 2000-05-12 2001-11-14 Johns Manville International, Inc. Sound absorption system
US20010050139A1 (en) * 1998-12-24 2001-12-13 Johns Manville International, Inc. Meltblown fibrous acoustic insulation

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3660222A (en) * 1969-04-01 1972-05-02 Du Pont Filling material of polyester fibers
US3652377A (en) * 1969-07-03 1972-03-28 Johns Manville Method of forming fibrous bodies with dissimilar densities and apparatus therefor
US4131664A (en) * 1977-09-28 1978-12-26 Allen Industries, Inc. Method of making a multiple-density fibrous acoustical panel
US4196245A (en) * 1978-06-16 1980-04-01 Buckeye Cellulos Corporation Composite nonwoven fabric comprising adjacent microfine fibers in layers
US4213516A (en) * 1978-11-29 1980-07-22 American Seating Company Acoustical wall panel
US4474846A (en) * 1981-04-06 1984-10-02 Van Dresser Corporation Moldable fibrous mat and product molded therefrom
JPS59186750A (ja) 1983-04-07 1984-10-23 Nippon Tokushu Toryo Kk ボンネツトフ−ド用吸音板
US4568581A (en) * 1984-09-12 1986-02-04 Collins & Aikman Corporation Molded three dimensional fibrous surfaced article and method of producing same
US4661132A (en) * 1985-08-15 1987-04-28 Allied Corporation Themally formed gradient density filter
DE3701592A1 (de) * 1987-01-21 1988-08-04 Rockwool Mineralwolle Verfahren zur kontinuierlichen herstellung einer faserdaemmstoffbahn und vorrichtung zur durchfuehrung des verfahrens
DE3809980C2 (de) * 1988-03-24 1998-02-19 Stankiewicz Gmbh Aufbau zur Schallisolation, Verfahren zu seiner Herstellung und seine Verwendung
US5298694A (en) * 1993-01-21 1994-03-29 Minnesota Mining And Manufacturing Company Acoustical insulating web
US5418031A (en) * 1993-11-22 1995-05-23 The United States Of America As Represented By The Secretary Of Agriculture Combination cellulosic/thermoplastic batt insulation and a method of production for such insulation
EP0795916B1 (en) 1994-12-28 2010-02-24 Asahi Kasei Kabushiki Kaisha Wet type nonwoven fabric for cell separator, its production method and enclosed secondary cell
CA2224985A1 (en) * 1995-06-23 1997-01-09 Delton R. Thompson Method of attenuating sound, and acoustical insulation therefor
US5591289A (en) * 1995-06-29 1997-01-07 Davidson Textron Inc. Method of making a fibrous headliner by compression molding
US5759927A (en) * 1995-07-24 1998-06-02 Meeker; Brian L. Glass-fiber-containing non-woven polymer web, and process for preparing same
US5811178A (en) * 1995-08-02 1998-09-22 Kimberly-Clark Worldwide, Inc. High bulk nonwoven sorbent with fiber density gradient
WO1998018656A1 (de) * 1996-10-29 1998-05-07 Rieter Automotive (International) Ag Ultraleichter multifunktionaler, schallisolierender bausatz
JP3379565B2 (ja) 1997-01-21 2003-02-24 日産自動車株式会社 遮音構造体の製造方法
DE19708188C2 (de) * 1997-02-28 2001-05-10 Lohmann Gmbh & Co Kg Schallschutzmaterial
JP3213252B2 (ja) * 1997-03-03 2001-10-02 カネボウ株式会社 吸音材およびその製造方法
US6048809A (en) * 1997-06-03 2000-04-11 Lear Automotive Dearborn, Inc. Vehicle headliner formed of polyester fibers
ES2183545T3 (es) * 1998-05-12 2003-03-16 Rieter Automotive Int Ag Elemento de aislamiento acustico para vehiculos.
FI107129B (fi) * 1998-10-01 2001-06-15 Bki Holding Corp Menetelmä monikerroksisen suodatinmateriaalin valmistamiseksi ja monikerroksinen suodatinmateriaali
US6534145B1 (en) * 1998-10-28 2003-03-18 Lear Corporation Pleated nonwoven products and methods of constructing such products
US20020160682A1 (en) * 1999-12-29 2002-10-31 Qingyu Zeng Acoustical fibrous insulation product for use in a vehicle
EP1255663B1 (de) * 2000-02-10 2004-06-02 Rieter Automotive (International) Ag Akustisch wirksame hutablage
US6247691B1 (en) 2000-04-10 2001-06-19 Bell & Howell Mail & Messaging Technologies Company Positive drive mechanism for buckle folder and method
US6296075B1 (en) * 2000-06-02 2001-10-02 Lear Corporation Lightweight acoustical system
US6669265B2 (en) * 2000-06-30 2003-12-30 Owens Corning Fiberglas Technology, Inc. Multidensity liner/insulator
US6572723B1 (en) * 2000-06-30 2003-06-03 Owens Corning Fiberglas Technology, Inc. Process for forming a multilayer, multidensity composite insulator
AUPQ883000A0 (en) * 2000-07-19 2000-08-10 I.N.C. Corporation Pty Ltd A thermoformable acoustic sheet
WO2002020889A2 (en) * 2000-09-05 2002-03-14 Milliken & Company Nonwoven material and method of producing the same
PL362009A1 (en) * 2000-11-03 2004-10-18 Milliken & Company Nonwoven material and method of producing the same
US20030060113A1 (en) * 2001-09-20 2003-03-27 Christie Peter A. Thermo formable acoustical panel
US6797653B2 (en) * 2001-09-28 2004-09-28 Johns Manville International, Inc. Equipment and duct liner insulation and method
US6659223B2 (en) * 2001-10-05 2003-12-09 Collins & Aikman Products Co. Sound attenuating material for use within vehicles and methods of making same
US6726980B2 (en) * 2001-11-09 2004-04-27 Owens Corning Fiberglass Technology, Inc. Acoustic doorliner with integral water barrier
US6802389B2 (en) * 2001-12-07 2004-10-12 Collins & Aikman Products Co. Multi-density sound attenuating laminates and methods of making same
US6602581B2 (en) * 2001-12-12 2003-08-05 E. I. Du Pont De Nemours And Company Corrugated fiberfill structures for filling and insulation
US6631785B2 (en) * 2001-12-20 2003-10-14 Collins & Aikman Products Co. Sound attenuating composite articles incorporating scrim material and methods of making same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2249138A1 (de) * 1972-10-06 1974-04-11 Giulini Gmbh Geb Neue versteifungsmaterialien
US5456872A (en) * 1991-11-15 1995-10-10 Eduard Kusters Maschinenfabrik Gmbh & Co. Kg Inherently rigid laminate material containing plastic trimmings and a method for producing same
US5824973A (en) * 1992-09-29 1998-10-20 Johns Manville International, Inc. Method of making sound absorbing laminates and laminates having maximized sound absorbing characteristics
WO1999044817A1 (de) * 1998-03-03 1999-09-10 Rieter Automotive (International) Ag Schallabsorbierendes dünnschichtlaminat
US20010050139A1 (en) * 1998-12-24 2001-12-13 Johns Manville International, Inc. Meltblown fibrous acoustic insulation
EP1154087A1 (en) * 2000-05-12 2001-11-14 Johns Manville International, Inc. Sound absorption system

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7320739B2 (en) 2003-01-02 2008-01-22 3M Innovative Properties Company Sound absorptive multilayer composite
US7591346B2 (en) 2003-01-02 2009-09-22 3M Innovative Properties Company Sound absorptive multilayer composite
JP2007519556A (ja) * 2004-01-12 2007-07-19 ダウ グローバル テクノロジーズ インコーポレイティド 粘弾性発泡体を含む自動車ダッシュインシュレータ
FR2870160A1 (fr) * 2004-05-13 2005-11-18 Cera Systeme de protection acoustique a impedance variable
EP1775714A4 (en) * 2004-08-04 2009-01-07 Toyo Boseki ACOUSTIC ISOLATION
US7500541B2 (en) 2004-09-30 2009-03-10 Kimberly-Clark Worldwide, Inc. Acoustic material with liquid repellency
EP1812264B1 (de) 2004-11-06 2016-06-08 Röchling Automotive SE & Co. KG Akustik-verkleidungsteil für ein fahrzeug
EP1798722A1 (en) * 2005-12-13 2007-06-20 Takehiro Co., Ltd. Ultra-light sound insulator
US8194879B2 (en) 2005-12-13 2012-06-05 Takehiro Co., Ltd. Ultra-light sound insulator

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AU2003231005B2 (en) 2006-09-21
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US20030199216A1 (en) 2003-10-23
US8637414B2 (en) 2014-01-28
BR0309489A (pt) 2005-02-09
BR0309489B1 (pt) 2013-09-10
DE60317658T2 (de) 2008-10-30
CA2483709C (en) 2009-10-13
EP1501987A1 (en) 2005-02-02
DE60317658D1 (de) 2008-01-03
AU2003231005A1 (en) 2003-11-03
CA2483709A1 (en) 2003-10-30
MXPA04010440A (es) 2005-05-27
EP1501987B1 (en) 2007-11-21
KR20050018664A (ko) 2005-02-23
AU2003231005A2 (en) 2003-11-03

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