WO2003084639A2 - Verwendung von polymerisaten, enthaltend thermoplastische polymere als filterhilfs- und/oder stabilisierungsmittel - Google Patents
Verwendung von polymerisaten, enthaltend thermoplastische polymere als filterhilfs- und/oder stabilisierungsmittel Download PDFInfo
- Publication number
- WO2003084639A2 WO2003084639A2 PCT/EP2003/003439 EP0303439W WO03084639A2 WO 2003084639 A2 WO2003084639 A2 WO 2003084639A2 EP 0303439 W EP0303439 W EP 0303439W WO 03084639 A2 WO03084639 A2 WO 03084639A2
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- WIPO (PCT)
- Prior art keywords
- polymers
- filtration
- diatomaceous earth
- group
- mixtures
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Classifications
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
- C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
- C12H1/02—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material
- C12H1/04—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/02—Loose filtering material, e.g. loose fibres
- B01D39/06—Inorganic material, e.g. asbestos fibres, glass beads or fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D37/00—Processes of filtration
- B01D37/02—Precoating the filter medium; Addition of filter aids to the liquid being filtered
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D37/00—Processes of filtration
- B01D37/04—Controlling the filtration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/02—Loose filtering material, e.g. loose fibres
- B01D39/04—Organic material, e.g. cellulose, cotton
Definitions
- thermoplastic polymers as filter aids and / or stabilizers
- the present invention relates to the use of polymers containing thermoplastic polymers as filter aids and / or stabilizers for the filtration or stabilization of aqueous liquids.
- filter aids means a series of products that are used in loose, powdery, granulated or fibrous form as precoat material in the filtration.
- Filter aids can be applied to the filter aids as a filter auxiliary layer (precoat filter) before the start of the filtration in order to achieve a loose cake build-up, or continuously added to the turbidity to be filtered.
- precoat filter a filter auxiliary layer
- Known filter additives are, for example, diatoms, natural products that result from the calcination of diatomite.
- the main components are amorphous Si0 2 modifications, accompanied by oxides of aluminum, iron and other elements as well as their silicate compounds.
- Perlite is an annealed, ground, selected expanded clay of volcanic origin (rhyolite). The structure is flake-like and can be described chemically as a sodium, potassium, aluminum silicate.
- Bentonites are clay minerals with a high swelling and absorption capacity.
- Filter aids should form a porous environment during the filtration, which absorbs the impurities to be removed and facilitates the outflow of the liquid phase.
- the additives should have an increased porosity and should not deform under pressure.
- the substances should be chemically inert and easily recoverable.
- kieselguhr precoat and layer filters are mainly used at present.
- precoat filtration a diatomaceous earth preliminary layer is washed onto a support surface (filter device) before the start of the filtration. After this precoat has been suspended, the beer to be filtered (unfiltrate) becomes a mixture of fine and coarse diatomaceous earth added.
- a kieselguhr consumption of 150 to 200 g / hl of beer is to be expected in beer production.
- Diatomaceous earth has proven particularly useful for precoat filtration because of its large pore volume, its low bulk density, its higher absorbency and its large specific surface area.
- a disadvantage of the use of diatomaceous earth is that after a number of filter operating hours it is used up due to retained solid material and must be removed from the support surfaces of the filter and replaced.
- turbidity-causing substances such as dissolved polyphenols or proteins
- the separation of turbidity-causing substances is also an important step in many beverage production processes because the removal of these substances leads to a longer shelf life of the beverage.
- Stabilization can be achieved by adding substances that bind, precipitate, or remove the turbidity-causing substances from the medium in some other suitable way.
- substances include e.g. the silica gel, which binds or falls, or polyvinylpyrrolidone, which binds polyphenols.
- EP 351 363 describes highly crosslinked polyvinylpolypyrrolidones (PVPP) as stabilizing and filtering aids.
- PVPP polyvinylpolypyrrolidones
- US 4344846 describes a method for precoat filtration with filter aids based on expanded polystyrene.
- WO 96/35497 describes regenerable filter aids for the filtration of a liquid medium, in particular beer, which comprise granules of synthetic or natural polymers which form a filter cake with a porosity between 0.3 and 0.5.
- the object of the present invention was to provide a filter aid or stabilizer which can be used instead of diatomaceous earth in the filtration or stabilization of aqueous liquids, in particular in the production of beer and beverages. It should be usable both as a filter aid and as a stabilizing agent, but also as well as for both functions. It should be insoluble and only slightly swellable, chemically inert and rich in surface area, and simple and easy to produce in acceptable reaction times. Furthermore, it should be possible to specifically adjust the adsorption and it should be regenerable.
- the invention relates to the use of polymers containing
- thermoplastic polymer (a) 20 to 95% by weight of at least one thermoplastic polymer
- thermoplastic polymer must not be polystyrene.
- Another object of the invention is a method for filtration and / or stabilization of an aqueous liquid, characterized in that a polymer as a filter aid or. Containing stabilizing agents
- thermoplastic polymer (a) 20 to 95% by weight of at least one thermoplastic polymer
- thermoplastic polymer 80 to 5% by weight of at least one further substance selected from the group of silicates, carbonates, oxides, silica gel, diatomaceous earth, diatomaceous earth, other polymers or mixtures thereof is used, with the proviso that the thermoplastic polymer must not be polystyrene.
- the method can be carried out in such a way that only one filtration or stabilization of the aqueous medium takes place, or that in addition to the filtration, a simultaneous stabilization takes place. In addition to the filtration, stabilization also preferably takes place.
- the precoat filtration technique is preferably used for the filtration.
- the adsorption of, for example, the constituents causing the clouding in beverages can be set in a targeted manner by the polymers according to the invention.
- Another advantage of using the polymers according to the invention is their regenerability.
- thermoplastic polymers mentioned under (a) are understood to mean amorphous uncrosslinked and partially crystalline uncrosslinked
- Polymers They are meltable and can be processed by extrusion, injection molding or spinning. They are often soluble in organic solvents. They contain both crystalline and amorphous areas. The macromolecule chains go through several areas and thus establish the cohesion of the polymer (see also Handbuch der Technischen Polymerchemie, A. Echte, 1st ed., 1993, VCM, Weinheim). These include, for example, polyolefins, vinyl polymers, polyamides, polyesters, polyacetates, polycarbonates or even polyurethanes and isomers.
- the semi-crystalline thermoplastics are preferably understood to be polyethylene, polyoxymethylene or polypropylene.
- the amorphous thermoplastics are preferably understood to mean polyvinyl chloride or polymethacrylate.
- thermoplastic polymers (a) are used in amounts of 20 to 95% by weight, preferably 40 to 90% by weight, particularly preferably 60 to 90% by weight, based on the total amount of the filter aid.
- the carbonates under (b) are understood to be alkali or alkaline earth carbonates, alkali or alkaline earth hydrogen carbonates, preferably calcium carbonate, sodium hydrogen carbonate or potassium hydrogen carbonate.
- the oxides are oxides or mixed oxides of sub-group 4 or main group 3, preferably titanium oxide or aluminum oxide.
- Silicates are understood to mean other natural and artificial silicates not expressly mentioned above; this also includes mixed silicates such as aluminosilicates or zeolites.
- Polyamide or crosslinked polyvinyllactam and / or polyvinylamine are preferably used as further polymers under (b).
- Preferred polyvinyllactam and / or polyvinylamine are: polyvinylpyrrolidone, polyvinylpiperidone, polyvinylcaprolactam, polyvinylimidazole, polyvinyl-2-methylimidazole, polyvinyl-4-methylimidazole, polyvinylformamide.
- Highly crosslinked poly vinylpolypyrrolidon is particularly preferred, for example that available under the trade name Divergan ® F used.
- Crosslinkers are compounds that contain at least two ethylenically unsaturated non-conjugated double bonds in the molecule.
- Preferred crosslinkers are divinylbenzene, N, N'-divinylethylene urea, N, N'-divinylpropylurea, alkylene bisacrylamides, alkylene glycol di (meth) acrylates.
- the end product of the "popcorn" polymerization is a foamy, crusty, granular polymer with a cauliflower-like structure. Because of their mostly strong crosslinking, popcorn polymers are generally insoluble and hardly swellable.
- the additives mentioned under (b) can be contained in the filter aid both alone and in mixtures.
- Crosslinked polyvinylpyrrolidone, Ti0 2 , KHC0 3 , NaHC0 3 , CaC0 3 , silica gel, diatomaceous earth, diatomaceous earth or bentonite are preferably used as additives alone.
- Mixtures of crosslinked polyvinylpolypyrrolidone (PVPP) with Ti0, NaHC0 3 , KHC0 3 , CaC0 3 , silica gel, diatomaceous earth, diatomaceous earth or bentonite or mixtures of NaHC0 3 or KHC0 3 with CaC0 3 , Ti0, silica gel are preferred,
- Crosslinked polyvinylpolypyrrolidone is particularly preferably used.
- thermoplastics used can be produced by processes known per se. Such methods are, for example, in A. Echte; Technical Polymer Chemistry Handbook; VCH, Weinheim, 1993.
- thermoplastic polymers and at least one further substance are compounded in an extruder.
- Compounding is generally understood to mean the mixing of a polymer with at least one additive ⁇ the twin-screw extruder: basic and application areas, ed. : VDI-Gesellschaft Kunststofftechnik. -Düsseldorf: VDI-Verlag, 1995, Chapter 7 and Processing of Polymers with Novel Properties, Ed. : VDI Society for Plastics Technology. -Düsseldorf: VDI-Verlag, 1995, p. 135ff.
- the preparation of polymers by filling and reinforcing is e.g. for polyolefins and polystyrene to improve the properties and reduce manufacturing costs.
- the fillers can be differentiated according to their particle geometry according to the so-called aspect ratio.
- the substance is a pure filler (extender), and a reinforcing effect is usually only achieved at higher values. This effect can be enhanced by the pronounced adhesive forces between the additive and the polymer.
- Frequently used fillers are calcium carbonate (chalk) and talc. Due to the food approval, polypropylene filled with calcium carbonate has also been widely used for food packaging (injection molding, deep drawing). Also described is the filling of polypropylene with wood flour for panels that are used in automobile construction. Glass (e.g. spherical), asbestos, silicates (e.g. wollastonite), mica, spade and graphite are also common. A common one
- the proportion of filler is 20-80% by mass, but can also be up to 95%.
- thermoplastic materials By reinforcing thermoplastic materials with fiber materials, the mechanical properties, especially the stiffness and hardness of the plastic, are increased. Glass fibers, carbon fibers, steel fibers and aramid fibers are usually used as fiber materials. Mixing at least two plastics, alloying, gives polymers with a different property profile. The mixtures can be homogeneous, heterogeneous or partially or with limited tolerance. In all cases, the use of extruders, in particular twin-screw extruders, is preferred. In addition, so-called kneaders also occur.
- Temperatures and pressures usually occur during extrusion, which, in addition to the purely physical mixture, involve chemical conversion, i.e. a chemical change in the components used.
- Implementation in the sense of the invention describes a process in which at least two substances are physically and / or chemically reacted with one another.
- the reaction can also take place by customary methods for thermoplastic processing, in particular mixing, dispersing, filling, reinforcing, alloying, degassing and reactive processing, by rolling, kneading, casting, sintering, pressing, compounding, calendering, extrusion or extrusion or Combination of these methods.
- the polymer powders are preferably compounded in an extruder.
- filtration is understood to mean the flow of a porous filter medium through a suspension (cloudy) consisting of a discontinuous phase (dispersed substances) and a continuous phase (dispersing medium). Solid particles are deposited on the filter medium and the filtered liquid (filtrate) leaves the filter medium clear. An applied pressure difference acts as an external force to overcome the flow resistance.
- precoat filters are used in various designs for beverage filtration (Kunze, Wolfgang, Technologie Brauer and Gurlzer, 7th edition, 1994, p. 372).
- filter aids the solids contained in the liquid to be filtered and also the deliberately added solids (filter aids) are retained by a filter medium, whereby a filter cake builds up. This is in the course of Filtration as well as to flow through the filter medium.
- Such a filtration is also known as precoat filtration.
- the liquids to be filtered and / or stabilized according to the invention mean fruit juices or fermentation beverages, such as wine or beer.
- the method according to the invention is used for the filtration and / or stabilization of beer.
- the filter aids or stabilizers provided according to the invention are notable for good wettability with water and a constant flow rate with a good filtering effect.
- the filter aids are comminuted by techniques of granulating the grinding and / or grinding, preferably by a sequence of granulation and grinding.
- water can remain in the end product.
- the powders obtained have an average grain size between 1 and 1000 ⁇ m, preferably between 2 and 200 ⁇ m. They have either a regular or irregular structure, which can be spheroid or non-spheroid. However, the powders obtained are preferably non-spheroid.
- thermoplastic polymer and at least one other substance are compounded in an extruder.
- the extrudate is cooled in a water bath and granulated.
- the granules obtained are crushed in a baffle plate mill and sieved using a vibrating sieve.
- thermoplastic polymer and corresponding additives (substance 1, possibly also substance 2) have been compounded.
- the sample identifier is given in brackets after the weight ratio.
- Polypropylene Novo1en, BASF
- Polyethylene Lupolen®, BASF
- Polyamide Ultramid®, BASF diatomaceous earth: diatomaceous earth, Merck, CAS no. 68855-54-9;
- CaC0 3 Calcium carbonate (precipitated, very pure), Merck, CAS no. 471-34-1;
- Ti0 2 titanium dioxide ( ⁇ 325 mesh, 99%), Aldrich, CAS no. 1317-70-0;
- PVPP Divergan F, BASF, CAS no. 9003-39-8;
- NaHC0 3 sodium bicarbonate (ultra pure), Merck, CAS no. 144-55-8;
- Silica gel Silica gel, Merck, CAS no. 63231-67-4;
- Bentonite Bentonite, Aldrich.
- the filtration effect is assessed in the precoat filtration on the basis of the clarification of a standard turbidity solution, ie a formazine solution with a defined turbidity, which is known to the person skilled in the art for the characterization of filter aids for the beverage industry.
- the criteria for a good test result are keeping the flow rate and the precoat pressure constant and the filtration effect, ie clarity of the filtrate: the precoat pressure before and after the filter has the same value with good flow, ie there is no clogging of the filter.
- the turbidity is determined according to a standard test according to EBC. A liquid is judged to be clear if the turbidity values are ⁇ 1 according to EBC.
- the milling fraction with a particle size smaller than 100 ⁇ is preferably used.
- the zero value i.e. the value of the standard turbidity solution is 20 EBC.
- the flow rate without filter aids is 40 1 h -1 .
- the measured value remains constant for the entire duration of the filtration.
- the precoat pressure of the pure liquid, ie without filter aids, is 1.5 bar.
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- Geology (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
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- General Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Food Science & Technology (AREA)
- Biochemistry (AREA)
- Zoology (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Filtering Materials (AREA)
- Filtration Of Liquid (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
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Abstract
Description
Claims
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
UA20041109073A UA81245C2 (en) | 2002-04-05 | 2003-02-04 | Polymer powder and method for filtering and/or stabilization of aqueous liquid |
DE50310282T DE50310282D1 (de) | 2002-04-05 | 2003-04-02 | Verwendung von polymerisaten, enthaltend thermoplastische polymere als filterhilfs- und/oder stabilisierungsmittel |
KR10-2004-7015743A KR20040111475A (ko) | 2002-04-05 | 2003-04-02 | 열가소성 중합체를 포함하는 중합체의 여과조제 및(또는)안정화제로서의 용도 |
US10/509,641 US10744434B2 (en) | 2002-04-05 | 2003-04-02 | Use of polymers comprising thermoplastic polymers as filtration aids and/or stabilising agent |
AU2003216913A AU2003216913B2 (en) | 2002-04-05 | 2003-04-02 | Use of polymers comprising thermoplastic polymers as filtration aids and/or stabilising agent |
NZ536027A NZ536027A (en) | 2002-04-05 | 2003-04-02 | Use of polymers comprising thermoplastic polymers as filtration aids and/or stabilising agent |
EP03712126A EP1495104B1 (de) | 2002-04-05 | 2003-04-02 | Verwendung von polymerisaten, enthaltend thermoplastische polymere als filterhilfs- und/oder stabilisierungsmittel |
BR0308823-5A BR0308823A (pt) | 2002-04-05 | 2003-04-02 | Uso de polìmeros, e, processo para filtrar e/ ou estabilizar um lìquido aquoso |
JP2003581872A JP2005527349A (ja) | 2002-04-05 | 2003-04-02 | 熱可塑性ポリマーを含むポリマーのろ過助剤および/または安定化剤としての使用 |
CA002480515A CA2480515A1 (en) | 2002-04-05 | 2003-04-02 | Use of polymers comprising thermoplastic polymers as filtration aids and/or stabilising agent |
DK03712126T DK1495104T3 (da) | 2002-04-05 | 2003-04-02 | Anvendelse af polymerer, der indholder termoplastiske polymerer som filtreringshjælpe- og/eller stabiliseringsmiddel |
MXPA04009187A MXPA04009187A (es) | 2002-04-05 | 2003-04-02 | Uso de polimeros que comprenden polimeros termoplasticos como auxiliares y / o estabilizadores de filtro. |
IL16405103A IL164051A0 (en) | 2002-04-05 | 2003-04-02 | Use of polymers comprising thermoplastic polymers as filtration aids and/or stabilisingagent |
NO20044446A NO20044446L (no) | 2002-04-05 | 2004-10-19 | Anvendelse av polymerer omfattende termoplastiske polymerer som filterhjelpemidler og/eller stabiliseringsmiddel |
HR20041033A HRP20041033A2 (en) | 2002-04-05 | 2004-11-03 | Use of polymers comprising thermoplastic polymers as filtration aids and/or stabilising agent |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10215147A DE10215147A1 (de) | 2002-04-05 | 2002-04-05 | Verwendung von Polymerisation, enthaltend thermoplastische Polymere als Filterhilfs- und/oder Stabilisierungsmittel |
DE10215147.4 | 2002-04-05 |
Publications (2)
Publication Number | Publication Date |
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WO2003084639A2 true WO2003084639A2 (de) | 2003-10-16 |
WO2003084639A3 WO2003084639A3 (de) | 2003-12-18 |
Family
ID=28051144
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2003/003439 WO2003084639A2 (de) | 2002-04-05 | 2003-04-02 | Verwendung von polymerisaten, enthaltend thermoplastische polymere als filterhilfs- und/oder stabilisierungsmittel |
Country Status (20)
Country | Link |
---|---|
US (1) | US10744434B2 (de) |
EP (1) | EP1495104B1 (de) |
JP (1) | JP2005527349A (de) |
KR (1) | KR20040111475A (de) |
CN (1) | CN100510047C (de) |
AT (1) | ATE403712T1 (de) |
AU (1) | AU2003216913B2 (de) |
BR (1) | BR0308823A (de) |
CA (1) | CA2480515A1 (de) |
DE (2) | DE10215147A1 (de) |
DK (1) | DK1495104T3 (de) |
HR (1) | HRP20041033A2 (de) |
IL (1) | IL164051A0 (de) |
MX (1) | MXPA04009187A (de) |
NO (1) | NO20044446L (de) |
NZ (1) | NZ536027A (de) |
PL (1) | PL372749A1 (de) |
RU (1) | RU2339689C2 (de) |
UA (1) | UA81245C2 (de) |
WO (1) | WO2003084639A2 (de) |
Cited By (4)
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EP1751266A1 (de) * | 2004-05-18 | 2007-02-14 | Inbev S.A. | Verfahren zur herstellung einer proteine zur anschliessenden trennung enthaltenden flüssigkeit unter verwendung eines oder mehrerer proteinkomplexierungsmittel |
EP1820555A1 (de) * | 2006-02-17 | 2007-08-22 | Millipore Corporation | Adsorbierende Filtermedien zur Entfernung biologischer Schadstoffe aus Prozessflüssigkeiten |
US7993533B2 (en) | 2006-09-29 | 2011-08-09 | Basf Se | Method for regenerating an auxiliary filtering agent |
US8394279B2 (en) | 2007-03-15 | 2013-03-12 | Basf Se | Method for regenerating a filter aid |
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JP2007268351A (ja) * | 2006-03-30 | 2007-10-18 | Kitakyushu Foundation For The Advancement Of Industry Science & Technology | フェノール類・カルボン酸類捕捉材及びそれを用いた分離具並びにそれを用いたフェノール類・カルボン酸類の分離方法 |
DK2006367T3 (da) * | 2007-06-15 | 2014-08-11 | Mondo Minerals B V | Filtrerings- og/eller flokkuleringsmidler til oprensning af flydende fødevarer |
JP5242430B2 (ja) * | 2008-01-23 | 2013-07-24 | 花王株式会社 | 歯磨き組成物 |
MX2012002465A (es) * | 2009-08-28 | 2012-06-01 | Green Mountain Coffee Roasters Inc | Cartucho para bebidas y metodo para la formacion de bebidas utilizando un coadyuvante de filtracion. |
US20110097464A1 (en) * | 2009-10-22 | 2011-04-28 | Ge Healthcare Bio-Sciences Ab | Method for liquid processing |
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WO2015080657A1 (en) * | 2013-11-28 | 2015-06-04 | Ge Healthcare Bio-Sciences Ab | Stabilization of fermented beverages |
WO2015100050A1 (en) * | 2013-12-26 | 2015-07-02 | Imerys Filtration Minerals, Inc. | Co-agglomerated composite materials, methods for making co-agglomerated composite materials, and methods for using co-agglomerated composite materials |
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- 2002-04-05 DE DE10215147A patent/DE10215147A1/de not_active Withdrawn
-
2003
- 2003-02-04 UA UA20041109073A patent/UA81245C2/uk unknown
- 2003-04-02 PL PL03372749A patent/PL372749A1/xx not_active Application Discontinuation
- 2003-04-02 AU AU2003216913A patent/AU2003216913B2/en not_active Ceased
- 2003-04-02 MX MXPA04009187A patent/MXPA04009187A/es active IP Right Grant
- 2003-04-02 NZ NZ536027A patent/NZ536027A/en unknown
- 2003-04-02 DK DK03712126T patent/DK1495104T3/da active
- 2003-04-02 KR KR10-2004-7015743A patent/KR20040111475A/ko not_active Application Discontinuation
- 2003-04-02 CA CA002480515A patent/CA2480515A1/en not_active Abandoned
- 2003-04-02 AT AT03712126T patent/ATE403712T1/de not_active IP Right Cessation
- 2003-04-02 US US10/509,641 patent/US10744434B2/en not_active Expired - Lifetime
- 2003-04-02 CN CNB038079739A patent/CN100510047C/zh not_active Expired - Lifetime
- 2003-04-02 WO PCT/EP2003/003439 patent/WO2003084639A2/de active IP Right Grant
- 2003-04-02 RU RU2004132223/04A patent/RU2339689C2/ru active
- 2003-04-02 DE DE50310282T patent/DE50310282D1/de not_active Expired - Lifetime
- 2003-04-02 BR BR0308823-5A patent/BR0308823A/pt not_active Application Discontinuation
- 2003-04-02 EP EP03712126A patent/EP1495104B1/de not_active Expired - Lifetime
- 2003-04-02 JP JP2003581872A patent/JP2005527349A/ja active Pending
- 2003-04-02 IL IL16405103A patent/IL164051A0/xx unknown
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2004
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- 2004-11-03 HR HR20041033A patent/HRP20041033A2/xx not_active Application Discontinuation
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1751266A1 (de) * | 2004-05-18 | 2007-02-14 | Inbev S.A. | Verfahren zur herstellung einer proteine zur anschliessenden trennung enthaltenden flüssigkeit unter verwendung eines oder mehrerer proteinkomplexierungsmittel |
EP1820555A1 (de) * | 2006-02-17 | 2007-08-22 | Millipore Corporation | Adsorbierende Filtermedien zur Entfernung biologischer Schadstoffe aus Prozessflüssigkeiten |
US7673757B2 (en) | 2006-02-17 | 2010-03-09 | Millipore Corporation | Adsorbent filter media for removal of biological contaminants in process liquids |
US8403153B2 (en) | 2006-02-17 | 2013-03-26 | Emd Millipore Corporation | Adsorbent filter media for removal of biological contaminants in process liquids |
US8562875B2 (en) | 2006-02-17 | 2013-10-22 | Emd Millipore Corporation | Adsorbent filter media for removal of biological contaminants in process liquids |
US8672144B2 (en) | 2006-02-17 | 2014-03-18 | Emd Millipore Corporation | Adsorbent filter media for removal of biological contaminants in process liquids |
US7993533B2 (en) | 2006-09-29 | 2011-08-09 | Basf Se | Method for regenerating an auxiliary filtering agent |
US8394279B2 (en) | 2007-03-15 | 2013-03-12 | Basf Se | Method for regenerating a filter aid |
Also Published As
Publication number | Publication date |
---|---|
PL372749A1 (en) | 2005-08-08 |
US20050145579A1 (en) | 2005-07-07 |
CN1646678A (zh) | 2005-07-27 |
JP2005527349A (ja) | 2005-09-15 |
NO20044446L (no) | 2004-10-22 |
MXPA04009187A (es) | 2004-11-26 |
HRP20041033A2 (en) | 2005-06-30 |
CN100510047C (zh) | 2009-07-08 |
ATE403712T1 (de) | 2008-08-15 |
DE50310282D1 (de) | 2008-09-18 |
RU2004132223A (ru) | 2005-05-27 |
EP1495104B1 (de) | 2008-08-06 |
KR20040111475A (ko) | 2004-12-31 |
IL164051A0 (en) | 2005-12-18 |
DK1495104T3 (da) | 2008-11-24 |
UA81245C2 (en) | 2007-12-25 |
AU2003216913A1 (en) | 2003-10-20 |
RU2339689C2 (ru) | 2008-11-27 |
US10744434B2 (en) | 2020-08-18 |
DE10215147A1 (de) | 2003-10-16 |
BR0308823A (pt) | 2005-01-18 |
WO2003084639A3 (de) | 2003-12-18 |
AU2003216913B2 (en) | 2008-08-07 |
EP1495104A2 (de) | 2005-01-12 |
CA2480515A1 (en) | 2003-10-16 |
NZ536027A (en) | 2006-08-31 |
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