WO2003068358A1 - Procede et dispositif pour traiter des eaux usees - Google Patents

Procede et dispositif pour traiter des eaux usees Download PDF

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Publication number
WO2003068358A1
WO2003068358A1 PCT/DE2003/000388 DE0300388W WO03068358A1 WO 2003068358 A1 WO2003068358 A1 WO 2003068358A1 DE 0300388 W DE0300388 W DE 0300388W WO 03068358 A1 WO03068358 A1 WO 03068358A1
Authority
WO
WIPO (PCT)
Prior art keywords
water
wastewater
storage container
air
evaporated
Prior art date
Application number
PCT/DE2003/000388
Other languages
German (de)
English (en)
Inventor
Peter Wolf
Wolfgang Jaske
Original Assignee
Peter Wolf
Wolfgang Jaske
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Peter Wolf, Wolfgang Jaske filed Critical Peter Wolf
Priority to AU2003218608A priority Critical patent/AU2003218608A1/en
Priority to DE10390484T priority patent/DE10390484D2/de
Publication of WO2003068358A1 publication Critical patent/WO2003068358A1/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/34Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
    • B01D3/343Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances the substance being a gas
    • B01D3/346Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances the substance being a gas the gas being used for removing vapours, e.g. transport gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/16Evaporating by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0027Condensation of vapours; Recovering volatile solvents by condensation by direct contact between vapours or gases and the cooling medium

Definitions

  • the invention relates to a process for the treatment of water-containing liquid waste, in particular industrial waste water, in which the waste liquid is evaporated, wherein moist air is drawn off and solids contained in the evaporated waste water are returned and the moist air is fed to a heat exchanger and the water condensed there is collected ,
  • the invention further relates to a device for performing this method.
  • a method and a device of the type mentioned are known from DE 41 09 276 C2.
  • water is evaporated, fed to an evaporator of a refrigeration machine, condensed there and the cooled, dry gas is heated and then returned to the evaporation of the waste water in a closed circuit.
  • WO 99/65588 it is known to design a device for separating, for example, water-oil emulsion in such a way that a separation chamber is provided with a bed of solids, around a large surface of the emulsion which is passed over the solids and the latter wetted to achieve.
  • the separation chamber is subjected to a vacuum. This causes it to come close to the surface the wetted solids very quickly to a saturation of the suppressed gas in liquid.
  • GB 2323048 A discloses a device for separating emulsions which achieves the separation of the heated mixture by passing the mixture over a column filled with packing and passing air in countercurrent. In this device too, the air is quickly saturated with water by passing emulsions over a large surface and the water is removed from the emulsion.
  • the invention has for its object to provide a method and a device of the type mentioned, with which liquid waste can be processed in a simple method as cost-effective, easy to maintain and with low energy consumption.
  • Essential to the invention is in the process for the treatment of water-containing, liquid waste, in which the waste water is evaporated, the moist air is drawn off and solids contained in the evaporated waste water are returned and the moist air is fed to a heat exchanger and the water condensed there is collected, which the Air leaving the condenser is fed directly to the wastewater to be evaporated, ie the air leaving the heat exchanger is not heated in the meantime, that is to say is free of energy supply, but with unchanged Temperature is passed on and that in addition the air in the closed circuit is • saturated with moisture at all times, ie essentially 100% air humidity is given.
  • Such a method is also suitable for treating small amounts of water and is particularly inexpensive and can be carried out with little effort.
  • the waste water is preferably heated and sprayed, so that the waste water is sprayed to evaporate. Furthermore, it is preferred to bring the humid air in the condenser into contact with cooler condensate, which is finely distributed by spraying, since particularly good condensation is thereby achieved. In particular, the combination of spraying the waste water in the evaporation device and spraying a condensate in the condensation device is preferred.
  • the process according to the invention is further characterized in that external energy is supplied exclusively for heating the waste water to be evaporated.
  • the device according to the invention for the treatment of water-containing liquid waste for carrying out the method according to the invention described above has an evaporation device and a condensation device, the evaporation device having a storage container for the waste water and an evaporator for the waste water with a separation chamber and the condensation device having a condenser for condensing the evaporated water and a second reservoir.
  • the storage container for the waste water is arranged within the second storage container for the purified water.
  • this enables a particularly space-saving design and, on the other hand, a high safety standard is achieved in a particularly inexpensive manner, in which the storage container for the waste water is double-walled by the arrangement within the storage container for the purified water, so that in In the event of a leak within the storage tank for the waste water, this does not leak out, but is caught by the storage tank for the cleaned water.
  • the condensation device and the evaporation device are arranged within a common closed container.
  • a wall separating the condensation device and the evaporation device in particular a stainless steel sheet, is provided within the container, only a slot or a passage remaining in each of the upper and lower regions, which forms the channel for the air flowing around the container, the the upper opening forms the path from the evaporation device to the condensation device and the lower opening forms the path from the condensation device to the evaporation device.
  • the wall separating the evaporation device and the condensation device is movable, in particular pivotable about an axis, so that as a function of that during evaporation resulting gas volumes, the wall can be pivoted and moved in such a way that excess pressure and thus excessive flow velocities are prevented.
  • the position of the wall is preferably controlled by measuring the flow rate.
  • the evaporation device has a blower, the blower preferably being installed in such a way that the air flow is passed through the storage container for the waste water and is fed from there to the evaporator.
  • the evaporator preferably has a separating chamber, which can be filled with packing elements, within a column, into which the waste water to be treated can be introduced from above and which can be acted upon by an air stream from below.
  • the evaporator which is preferably arranged above the separation chamber, advantageously has a distributor for the wastewater to be treated, which distributes the wastewater evenly over the packed bed in the separation chamber in order to achieve a uniform wetting of the packed bed, so that the largest possible surface area of the to be treated Waste water is reached in the separation chamber.
  • the wastewater to be treated from the storage tank by means of a pump and a riser pipe through the distributor above the separation chamber into the evaporator, the pump being able to be designed as a submersible pump within the storage tank or in other designs.
  • the condensation device also preferably has a gas-liquid separator with which the separated water and air can be separated.
  • the cross-sectional area of the condenser within the condensation device preferably corresponds to the cross-sectional area of the evaporator of the evaporation device
  • a heat exchanger for condensing the water from the air stream is installed, which preferably has a surface of the same size or a larger surface than the packed bed of the evaporator.
  • Fig. 1 a schematic representation of a first
  • FIG. 2 shows a schematic representation of a second embodiment of a device according to the invention
  • FIG. 3 shows a schematic representation of a third embodiment of a device according to the invention.
  • Fig. 4 a perspective view of a first
  • FIG. 5 a top view of the illustration according to FIG. 4;
  • FIG. 6 shows a perspective view of a second variant of a storage container for the purified water with a storage container for waste water arranged therein;
  • the device consists of an evaporation device A and a condensation device B.
  • the condensation device has an evaporator 1 with a separation chamber 2 filled with packing elements, a storage container 3 for the waste water, a distribution system 8 for the waste water, a heat exchanger 11 and a pipeline 10 with pumps 9 , wherein the pump 9 is installed in the reservoir 3 and gives the waste water via the pipeline 10 in the heat exchanger 11.
  • the column for separating pure water in the form of water saturated with air is attached to the storage container 3.
  • the diameter of the storage container 3 has at least the size of the evaporator, in particular the separation chamber 2, in order to ensure the largest possible capacity.
  • the design of the shape of the storage container is based on the spatial conditions (e.g. container).
  • the evaporator 1 is preferably mounted on the storage container 3 in a cylindrical column.
  • the evaporator 1 has in the lower part an air inlet opening 4, the cross-sectional area of which preferably corresponds to the evaporator cross-sectional area, which is connected via a pipeline 5 to the outlet 6 of the gas-liquid separator 7 in order to achieve a closed air circuit for the transport of the water saturated air.
  • a distributor system 8 for the liquid waste conveyed from the storage container 3 by means of a pump 9 via the pipeline 10.
  • a heat exchanger 11 is installed, in which external heat z. B.
  • the wastewater can also be heated at any other point in the cycle.
  • the wastewater flows back into the reservoir 3 by gravity through the separation chamber 2 with packing.
  • the packing consist of a non-corrosive material, preferably plastic, V4A or glass.
  • the packing can also be made of corrosive material, such as z. B. steel chips consist of turning shops.
  • the height of the packing of the packing 2 in the evaporator preferably corresponds to 3 to 5 times the evaporator diameter. Other filling levels are also possible.
  • the liquid waste concentrated by water removal is removed from the storage container by means of a pump 12.
  • the air saturated with water is fed to the condensation device B via a pipeline 13.
  • the condensation device B has a condenser 14, in which water is extracted from the air saturated with water by cooling, a gas-liquid separator 7 and a second storage container 17.
  • the cross section of the condenser 14 is the same as or larger than the cross section of the separation chambers 2 with packing elements, in order to avoid compression effects of the air flowing through it. However, other cross sections are conceivable.
  • the condenser 14 has a heat exchanger 15 with a cooling circuit 16.
  • the cooling capacity of the heat exchanger 15 is designed such that it can absorb and dissipate the energy supplied to the evaporation device A via the heat exchanger 11. Energy absorbed by the cooling circuit 15 of the heat exchanger 16 can again be supplied to the energy source of the evaporation device A. from that the result is that the energy required for wastewater treatment is not consumed, but only transported.
  • the heat exchanger 15 is followed by a gas-liquid separator 7, in which the condensed water is separated from the air flow.
  • the separated water is fed to a second reservoir 17.
  • the water is pumped out of the reservoir with a pump 18 and can be fed back into the production process.
  • the cooled air flow is fed back to the first part of the device via a pipeline 5. It is also possible to supply the air flow to the storage container 3 for the water-containing liquid waste and thus to close the air circuit.
  • the blower 19 for transporting the air is located between the gas-liquid separator 7 and the air inlet opening 4 of the condensation device A, that is to say at the outlet of the condensation device, since here the temperature of the air in the air circuit is the lowest.
  • the lowest possible temperature of the medium to be pumped means the lowest possible wear on the fan.
  • the device is controlled via electronic logic modules. Float switches and encapsulated thermoswitches are used for data acquisition.
  • the liquid waste is heated directly or indirectly in the first step with the aid of the heat exchanger 11 in order to increase the vapor pressure and thereby obtain a large material flow.
  • Heating the wastewater increases the steam pressure of the water exponentially and promotes the evaporation line.
  • the water absorption capacity of air at 100% humidity is 50g water per m 3 air at 40 ° C and 350g water per m 3 air at 80 ° C.
  • the wastewater conveyed in the head of the separation chamber 2 flows back into the reservoir by gravity. Air flows in countercurrent over the packed bed conducted, whereby it warms up and enriched with water. By removing the water, the impurities remain in the reservoir of the system and can be pumped out there by the pump 12.
  • the water vapor in the air is condensed by means of a heat exchanger.
  • water is released from the air saturated with water by cooling.
  • the relative humidity is 100% even after cooling.
  • the condensed water is separated off via a gas-liquid separator and collected in another container.
  • the air is returned to the first process step. This means that the air cycle is closed, and the air humidity in the system is always in the 100% range. Only the water absorption capacity of the air changes due to the different air temperature.
  • the thermal energy used in the first process step is in the water vapor of the air and is released again by condensation on the heat exchanger in the second process step. It is essentially an energy transport. Essentially, energy is required to transport the media, as is thermal energy to compensate for heat radiation losses. Thermal radiation losses can, however, be kept low by insulation.
  • the evaporation device A is here on the left side, while the condensation device B is shown here on the right side of the figure.
  • a spray evaporator 20 with an injection nozzle 23 is used, which sprays the waste water heated in the heat exchanger 11.
  • the water vapor is removed by the countercurrent air from the evaporation device A and fed to an injection condenser 21 which has an injection nozzle 22 and which brings water-laden air into contact with cooler condensate finely distributed by spraying.
  • the vapor from the air condenses on the cooler drops of condensate.
  • the condensate is fed in and discharged in the same amount as the waste water.
  • the remaining energy of the discharged condensate is used to dry the residual materials.
  • the circulating air flow which has become colder in the injection condenser 21, is again fed with the aid of the blower 19 to the storage container 3 with the waste water and from there into the spray evaporator 20.
  • External heat is supplied to the heat exchanger 11 for heating the waste water here, as in the exemplary embodiment according to FIG.
  • water obtained from the second storage container 17 is additionally taken out with the aid of the pump 30 and fed to the heat exchanger 11, the waste water being heated with the thermal energy contained in the purified water and the water then cooled in the heat exchanger being returned and via the injection nozzle 22 in the injection capacitor 21 is used.
  • the waste water is fed with the aid of a pump 13 and a pipe 26 to an additionally connected heat exchanger 27 in which the waste water is already preheated and then fed to the reservoir 3 via a further pipe 28.
  • the heating in the heat exchanger 27 takes place with the aid of the pipe 29 supplied from the second reservoir 17 via the pipe 29 purified water, which is supplied to the condensate drain 31 in the heat exchanger 27 after its residual thermal energy has been released.
  • FIG. 3 shows a third embodiment of the device according to the invention.
  • This embodiment is characterized by a closed container 35, in which the evaporation device A and also the condensation device B are arranged.
  • the evaporation device A and the condensation device B are separated by a vertical wall 36.
  • the vertical wall 36 is movable, in particular pivotable about an axis 37 by means of a motor 38.
  • the gas volume increases. This increases the flow rate in the evaporation device A and leads to the fact that constituents of the waste water are carried along and the cleaning performance is thereby reduced. With variable energy supply, the regulation of the flow rate is difficult.
  • a sensor 40 is therefore used to measure the flow rate and the motor 38 is controlled accordingly with the aid of a control 39, so that the pressure in the evaporation device A can be compensated and the flow rate can be reduced.
  • the lower part 41 of the wall 36 is flexible in order to compensate for the varying distances from the base plate. With the help of the fan 19, the air is removed in the condensation device B and fed to the evaporation device A.
  • FIGS. 4 and 5 show a perspective view and a top view of a first embodiment of the arrangement of the storage container 3 for waste water within the second storage container 17 for purified water, namely the condensate.
  • the second reservoir 17 is designed such that its Side walls form the outer double wall for the reservoir 3 for the waste water.
  • the storage container 3 for the waste water is placed on an intermediate ceiling provided in the second storage container 17, an insulating layer preferably being provided between the two containers.
  • the storage container 3 is smaller than the storage container 17, so that there remains an area which is freely accessible from above and which is provided with a cover 45 which is equipped with supply and disposal lines and measuring devices.
  • On the storage container 3 for the waste water there is an opening 43 for the evaporator and an opening 44 for access for cleaning purposes.
  • the opening 44 is closed with a lid.
  • the supply and disposal device and the measuring technology can be installed on this cover.
  • FIGS. 6 and 7 show a perspective view and a top view of a second embodiment of a storage container 3 for waste water arranged in a second storage container 17.
  • the storage container 3 is trapezoidal in cross-section and rests with its upper side against the entire upper side and is formed with its underside running obliquely within the storage container 17.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

La présente invention concerne un procédé pour traiter des déchets liquides contenant de l'eau, notamment des eaux usées, les eaux usées étant chauffées et évaporées. Selon l'invention, de l'air humide est extrait et des substances solides contenues dans les eaux usées évaporées sont réduites, et l'air humide alimente un condensateur dans lequel l'eau se condense. Le procédé de l'invention se caractérise en ce que l'air quittant le condensateur est introduit directement dans les eaux usées à évaporer, et en ce que l'air circulant dans le circuit fermé est constamment saturé d'humidité. L'invention a également pour objet un dispositif pour mettre en oeuvre un procédé de ce type.
PCT/DE2003/000388 2002-02-11 2003-02-11 Procede et dispositif pour traiter des eaux usees WO2003068358A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2003218608A AU2003218608A1 (en) 2002-02-11 2003-02-11 Method and device for the treatment of waste water
DE10390484T DE10390484D2 (de) 2002-02-11 2003-02-11 Verfahren und Vorrichtung zur Aufbereitung von Abwässern

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10205528 2002-02-11
DE10205528.9 2002-02-11

Publications (1)

Publication Number Publication Date
WO2003068358A1 true WO2003068358A1 (fr) 2003-08-21

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AU (1) AU2003218608A1 (fr)
DE (1) DE10390484D2 (fr)
WO (1) WO2003068358A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004039274A1 (de) * 2004-08-13 2006-03-02 Wolf, Peter, Dr. Verfahren und Vorrichtung zur Behandlung von mit Schwebstoffen verunreinigtem Brauchwasser
EP1797935A1 (fr) 2005-12-13 2007-06-20 Peter Wolf Procédé et appareil de traitement d'eaux usées polluées par des matières en suspension
WO2009117777A1 (fr) * 2008-03-28 2009-10-01 Australian Creative Technologies Pty Ltd Dispositif et procédé d'utilisation du surplus de refroidissement d'eau dans une tour de refroidissement
WO2010116100A2 (fr) * 2009-04-09 2010-10-14 The Third Millenium Water Company Perfectionnements aux distillateurs reproduisant le cycle naturel de l'eau
WO2012140405A1 (fr) * 2011-04-15 2012-10-18 Mads Landrok Systèmes d'alimentation en eau
DE102013224351A1 (de) * 2013-11-28 2015-05-28 Reinhold Barth Vorrichtung zur Erzeugung von Brauchwasser
EP2248766A4 (fr) * 2008-01-18 2015-07-22 Electra Holdings Co Ltd Equipement de production d'eau douce économe en énergie
EP3348320A1 (fr) * 2017-01-13 2018-07-18 Siemens Aktiengesellschaft Procédé et dispositif de refroidissement d'une unité d'électrolyse et de traitement d'eau
EP3348319A1 (fr) * 2017-01-13 2018-07-18 Siemens Aktiengesellschaft Procédé et dispositif de refroidissement d'un écoulement de fluide d'une unité d'électrolyse et de production d'eau
DE102022109435A1 (de) 2022-04-19 2023-10-19 Oliver Kerschgens System zur wasseraufbereitung und entsalzung

Citations (4)

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Publication number Priority date Publication date Assignee Title
DE964504C (de) * 1955-02-18 1957-05-23 Paul Knuer Mit Waermepumpe arbeitendes Ausdampfverfahren und zu dessen Ausuebung dienende Einrichtung
US3311543A (en) * 1963-05-15 1967-03-28 Aqua Chem Inc Vapor compression still for distilling impure water
US4310382A (en) * 1979-01-25 1982-01-12 Schering Ag Method of and a device for vaporizing and recovering water from aqueous solutions
US5096543A (en) * 1990-09-27 1992-03-17 Kamyr, Inc. Carrier gas apparatus for evaporation and condensation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE964504C (de) * 1955-02-18 1957-05-23 Paul Knuer Mit Waermepumpe arbeitendes Ausdampfverfahren und zu dessen Ausuebung dienende Einrichtung
US3311543A (en) * 1963-05-15 1967-03-28 Aqua Chem Inc Vapor compression still for distilling impure water
US4310382A (en) * 1979-01-25 1982-01-12 Schering Ag Method of and a device for vaporizing and recovering water from aqueous solutions
US5096543A (en) * 1990-09-27 1992-03-17 Kamyr, Inc. Carrier gas apparatus for evaporation and condensation

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004039274B4 (de) * 2004-08-13 2006-12-28 Wolf, Peter, Dr. Verfahren und Vorrichtung zur Behandlung von mit Schwebstoffen verunreinigtem Brauchwasser
DE102004039274A1 (de) * 2004-08-13 2006-03-02 Wolf, Peter, Dr. Verfahren und Vorrichtung zur Behandlung von mit Schwebstoffen verunreinigtem Brauchwasser
EP1797935A1 (fr) 2005-12-13 2007-06-20 Peter Wolf Procédé et appareil de traitement d'eaux usées polluées par des matières en suspension
EP2248766A4 (fr) * 2008-01-18 2015-07-22 Electra Holdings Co Ltd Equipement de production d'eau douce économe en énergie
WO2009117777A1 (fr) * 2008-03-28 2009-10-01 Australian Creative Technologies Pty Ltd Dispositif et procédé d'utilisation du surplus de refroidissement d'eau dans une tour de refroidissement
US20110011107A1 (en) * 2008-03-28 2011-01-20 Creative Water Technology Ltd. Device and method for utilising surplus cooling of water in a cooling tower
AU2009227990B2 (en) * 2008-03-28 2013-01-31 Creative Water Technology Ltd A device and method for utilising surplus cooling of water in a cooling tower
WO2010116100A2 (fr) * 2009-04-09 2010-10-14 The Third Millenium Water Company Perfectionnements aux distillateurs reproduisant le cycle naturel de l'eau
FR2944277A1 (fr) * 2009-04-09 2010-10-15 Third Millenium Water Company Perfectionnements aux distilateurs reproduisant le cycle naturel de l'eau
WO2010116100A3 (fr) * 2009-04-09 2010-11-25 The Third Millenium Water Company Distillateurs par convention et recuperation de chaleur
GB2489989B (en) * 2011-04-15 2018-02-28 Landrok Mads Water supply systems
WO2012140405A1 (fr) * 2011-04-15 2012-10-18 Mads Landrok Systèmes d'alimentation en eau
DE102013224351A1 (de) * 2013-11-28 2015-05-28 Reinhold Barth Vorrichtung zur Erzeugung von Brauchwasser
DE102013224351B4 (de) 2013-11-28 2017-03-30 Reinhold Barth Vorrichtung zur Erzeugung von Brauchwasser
EP3348320A1 (fr) * 2017-01-13 2018-07-18 Siemens Aktiengesellschaft Procédé et dispositif de refroidissement d'une unité d'électrolyse et de traitement d'eau
EP3348319A1 (fr) * 2017-01-13 2018-07-18 Siemens Aktiengesellschaft Procédé et dispositif de refroidissement d'un écoulement de fluide d'une unité d'électrolyse et de production d'eau
WO2018130398A1 (fr) * 2017-01-13 2018-07-19 Siemens Aktiengesellschaft Procédé et dispositif de refroidissement d'un flux de fluide d'une unité d'électrolyse et de production d'eau
WO2018130385A1 (fr) * 2017-01-13 2018-07-19 Siemens Aktiengesellschaft Procédé et dispositif de refroidissement d'une unité d'électrolyse et de traitement d'eau
US10815649B2 (en) 2017-01-13 2020-10-27 Siemens Aktiengesellschaft Method and device for cooling a fluid stream of an electrolysis unit and for obtaining water
DE102022109435A1 (de) 2022-04-19 2023-10-19 Oliver Kerschgens System zur wasseraufbereitung und entsalzung
WO2023202980A1 (fr) * 2022-04-19 2023-10-26 Russwurm Heinz Georg Système de traitement et de dessalement de l'eau

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DE10390484D2 (de) 2005-05-12
AU2003218608A1 (en) 2003-09-04

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