WO2003038183A1 - Procede de teinture de toile tissee comprenant une fibre de polyamide - Google Patents

Procede de teinture de toile tissee comprenant une fibre de polyamide Download PDF

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Publication number
WO2003038183A1
WO2003038183A1 PCT/JP2002/011341 JP0211341W WO03038183A1 WO 2003038183 A1 WO2003038183 A1 WO 2003038183A1 JP 0211341 W JP0211341 W JP 0211341W WO 03038183 A1 WO03038183 A1 WO 03038183A1
Authority
WO
WIPO (PCT)
Prior art keywords
fabric
dyeing
antioxidant
fibers
polyamide
Prior art date
Application number
PCT/JP2002/011341
Other languages
English (en)
Japanese (ja)
Inventor
Yasuhiro Kawaguchi
Haruhiko Maeda
Gi Tsuda
Masahiro Saioka
Akihiro Kawahara
Original Assignee
Kanebo, Limited
Kanebo Gohsen Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanebo, Limited, Kanebo Gohsen Limited filed Critical Kanebo, Limited
Priority to JP2003540437A priority Critical patent/JPWO2003038183A1/ja
Publication of WO2003038183A1 publication Critical patent/WO2003038183A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2066—Thermic treatments of textile materials
    • D06P5/2072—Thermic treatments of textile materials before dyeing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/667—Organo-phosphorus compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/24—Polyamides; Polyurethanes

Definitions

  • the present invention relates to a cross-knitted fabric with a polyamide fiber-containing fabric, for example, a polyurethane fiber.
  • the present invention relates to a method of dyeing a textile or the like without causing dye spots.
  • JP-A-4-122477 discloses that a semicarbazide compound and a hindered phenol phosphite compound are applied when dyeing a fiber product comprising polyamide fiber Z polyurethane elastic fiber, It is disclosed to perform staining.
  • the present invention is intended to solve such a problem. It is an object of the present invention to improve and develop a method for improving dyeing spots on polyamide fibers by using an antioxidant, and to obtain an industrially stable, high-grade polyamide. It is to provide a dyed product. Disclosure of the invention
  • the present invention provides a method for dyeing after heat setting a fabric containing polyamide fibers, wherein the substantially dried fabric is immersed in an aqueous solution of a phenolic antioxidant, and then heated at a dry heat temperature of 170 or more.
  • This is a method for dyeing a polyamide fiber-containing fabric, which is characterized by dyeing after setting.
  • FIG. 1 is a schematic diagram showing an example of a part of the steps of the staining method of the present invention.
  • FIG. 2 is a schematic diagram showing an example of a part of the steps of the staining method of the present invention.
  • FIG. 3 is a schematic diagram showing an example of a part of the steps of the staining method of the present invention.
  • the fabric used in the present invention is not particularly limited as long as it contains a polyamide fiber, such as a woven fabric or a knitted fabric.
  • “contained” includes the use of composite yarn in addition to knitting and weaving with other fibers.
  • the present invention is significant when the polyamide fiber needs to be treated at a temperature higher than the normal heat setting temperature. Therefore, polyurethane-polyester elastic fibers and natural fibers such as polyester, polyacetate, and cotton are used. It is preferably a fabric mixed with other fibers. In this case, it is preferable that the polyamide fiber accounts for 10% by weight or more, more preferably 50% by weight or more of the whole fabric. This is because the effect of improving the above-mentioned stained spots becomes remarkable.
  • polyamide fibers examples include nylon 4, nylon 6, nylon 7, nylon 11, nylon 12, nylon 66, nylon 6,10, polymetaxyldecaneamide, and copolyamides containing these as components.
  • polyamide fiber it is preferable to use so-called Fuldal yarn containing lwt% or more of titanium oxide.
  • polyurethane fibers and polyester fibers are generally used as elastic fibers.
  • Such polyurethane fibers have a melting point of 200 to 300 ° C., and include those obtained by a dry heat spinning method or the like.
  • polyester-based elastic fibers include polybutylene terephthalate-based fibers.
  • the antioxidant used in the present invention is for preventing the progress of the radical chain reaction, and includes a phenol-based compound containing a phenol-based, monophenol-based, bisphenol-based, or polymer phenol-based as a main component. belongs to.
  • the amine-based materials and the like may cause discoloration in the processing step. It is particularly preferable to use a hindered phenol-based antioxidant, and for example, those having the following chemical structure are preferable.
  • the antioxidant it is important to uniformly apply these antioxidants.
  • the antioxidant can be treated with an aqueous system, and a water-soluble one is preferable.
  • antioxidants do not have good compatibility with water.
  • the compounds shown in (1) and (2) are relatively easy to make water soluble, and are preferred in the present invention. However, those containing chlorine or the like are preferably avoided because they may cause discoloration.
  • the greige fabric obtained by weaving using polyamide fibers is disintegrated (1), spontaneously shrunk (2), subjected to preliminary relaxation at room temperature (3), and subjected to wet heat relaxation. It is refined (4). Then, as shown in Fig. 2, through cooling and washing bath
  • the important step in the present invention is the step (8) of applying an antioxidant.
  • a drying treatment can include, but is not limited to, a dry heat treatment (7) using a chamber as shown in FIG.
  • a dry heat treatment at about 150 ° C. for several tens of seconds or more.
  • the treatment for applying the phenolic antioxidant is performed by immersion in an aqueous system. This is to provide the antioxidant uniformly. As described above, antioxidants are generally hardly soluble in water. For this reason, it is preferable to use the phenolic antioxidant as described above, but it is usually difficult to obtain a sufficient dissolved state by itself. Therefore, it is important to use both anionic and nonionic surfactants and to sufficiently dissolve the antioxidant before starting treatment. Specifically, it is necessary to dissolve the antioxidant in a small amount of hot water and then add it to the treatment bath.
  • the concentration of the antioxidant is preferably 0.1 g Zl or more, and more preferably 0.5 g Zl or more. However, when the concentration of the antioxidant is 20 g Z 1 or more, it is preferable to avoid dissolving and deteriorating the polyurethane elastic yarn, which may lower the product quality. Further, it is preferable to perform the treatment while maintaining the temperature of the immersion bath at about 25 to 35 ° C.
  • the so-called pad method in which the fabric is immersed in the treatment bath prepared as described above, and then squeezed and dewatered with a mangle or the like can be used for applying the antioxidant, provided that uniform treatment of the fabric is possible.
  • Other immersion methods may be used.
  • the pickup rate of the main component is preferably set to about 0.1 to 10%.
  • the fabric is subjected to heat setting to set polyamide fibers and the like.
  • the heat setting temperature of about 170 ° C. is sufficient for the polyamide fiber alone as described above, but there is little significance in adopting the method of the present invention.
  • the method of the present invention is significant when mixed with polyamide fibers and elastic fibers, particularly polyurethane fibers.
  • polyurethane fiber use polyurethane
  • the heat setting temperature may be set according to the characteristics of the tan fiber.
  • the treatment should be performed at a dry heat temperature of 205 ° C or less, more preferably 200 ° C or less. Is preferred.
  • Such heat setting can be performed using a normal tenter or the like.
  • the dyeing treatment may be appropriately selected according to the type of fiber to be used, and various methods such as finesse, zipper, beam, liquid jet dyeing machine and the like can be adopted. However, whichever method is employed, it is preferable that the treatment is such that the antioxidant provided in the previous step can be sufficiently removed. As described above, in the present invention, it is preferable that the above-described antioxidant is effectively present only during the heat setting of the polyamide fiber at a relatively high temperature.
  • Nylon 6 multifilament full-dull yarn 44 TZ10F titanium oxide content 1.7% by weight
  • polyurethane multifilament yarn 44TZ4F manufactured by Toray DuPont, set at a dry heat temperature of 150 ° C, 30%, with a melting point of 225
  • the antioxidant is a mixture of a hindered phenol-based antioxidant (20% by weight) having the following chemical structure, anionic and nonionic surfactants (70% by weight), and an aromatic ester (10% by weight).
  • the product (SF380: Takemoto Yushi) was completely dissolved in hot water 101 at 80 ° C and then added to the pad bath. In addition, the pickup rate of the pad treatment was set at 0.2%.
  • the purifying agent used was SAU Satsu ORL BL600 (manufactured by Nika Chemical Co., Ltd.).
  • the knitted fabric was dyed in an emerald green color using a phthalocyanine-based milling dye and evaluated.
  • Table 2 shows the results, including those without the antioxidant application step (8) and those with different concentrations of antioxidants.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)

Abstract

La présente invention concerne un procédé fondé sur l'amélioration et le progrès d'un procédé permettant de diminuer les points de teinture sur des fibres de polyamide avec un antioxydant et par lequel un article de polyamide teinté de haute qualité est produit industriellement de façon stable. Ce procédé par lequel une toile tissée comprenant des fibres de polyamide est thermiquement traitée puis séchée, consiste à immerger cette toile qui a été sensiblement séchée dans une solution aqueuse d'un antioxydant phénolique, à traiter thermiquement ensuite cette toile en atmosphère sèche à une température qui n'est pas inférieure à 1700 C, puis à sécher cette toile.
PCT/JP2002/011341 2001-10-31 2002-10-31 Procede de teinture de toile tissee comprenant une fibre de polyamide WO2003038183A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2003540437A JPWO2003038183A1 (ja) 2001-10-31 2002-10-31 ポリアミド繊維含有布帛の染色方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001/333804 2001-10-31
JP2001333804 2001-10-31

Publications (1)

Publication Number Publication Date
WO2003038183A1 true WO2003038183A1 (fr) 2003-05-08

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/011341 WO2003038183A1 (fr) 2001-10-31 2002-10-31 Procede de teinture de toile tissee comprenant une fibre de polyamide

Country Status (3)

Country Link
JP (1) JPWO2003038183A1 (fr)
CN (1) CN1578865A (fr)
WO (1) WO2003038183A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9290862B2 (en) 2007-07-03 2016-03-22 Swedish Biomimetics 3000 Limited Dual mobile phase apparatus and method
US9327262B2 (en) 2007-07-03 2016-05-03 Swedish Biomimetics 3000 Limited Solid phase reaction method and apparatus
CN111472125A (zh) * 2020-04-16 2020-07-31 晋江市七彩狐服装织造有限公司 一种弹力柔软锦纶面料的染整工艺
JP2022531561A (ja) * 2019-05-03 2022-07-07 ザ プロクター アンド ギャンブル カンパニー エラスタン含有布地を処理するための布地処理組成物において酸化防止剤を使用する方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000328357A (ja) * 1999-05-20 2000-11-28 Toyobo Co Ltd 耐熱性ポリアミド系繊維の製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000328357A (ja) * 1999-05-20 2000-11-28 Toyobo Co Ltd 耐熱性ポリアミド系繊維の製造方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9290862B2 (en) 2007-07-03 2016-03-22 Swedish Biomimetics 3000 Limited Dual mobile phase apparatus and method
US9327262B2 (en) 2007-07-03 2016-05-03 Swedish Biomimetics 3000 Limited Solid phase reaction method and apparatus
US10913047B2 (en) 2007-07-03 2021-02-09 Swedish Biomimetics 3000 Limited Dual mobile phase apparatus and method
JP2022531561A (ja) * 2019-05-03 2022-07-07 ザ プロクター アンド ギャンブル カンパニー エラスタン含有布地を処理するための布地処理組成物において酸化防止剤を使用する方法
JP7359865B2 (ja) 2019-05-03 2023-10-11 ザ プロクター アンド ギャンブル カンパニー エラスタン含有布地を処理するための布地処理組成物において酸化防止剤を使用する方法
CN111472125A (zh) * 2020-04-16 2020-07-31 晋江市七彩狐服装织造有限公司 一种弹力柔软锦纶面料的染整工艺

Also Published As

Publication number Publication date
CN1578865A (zh) 2005-02-09
JPWO2003038183A1 (ja) 2005-02-24

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