WO2003035805A1 - Composition liquide a base d'hydrocarbure contenant de l'oxygene, procede d'elaboration, et procede d'elaboration de combustible liquide faiblement polluant - Google Patents

Composition liquide a base d'hydrocarbure contenant de l'oxygene, procede d'elaboration, et procede d'elaboration de combustible liquide faiblement polluant Download PDF

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Publication number
WO2003035805A1
WO2003035805A1 PCT/JP2002/010998 JP0210998W WO03035805A1 WO 2003035805 A1 WO2003035805 A1 WO 2003035805A1 JP 0210998 W JP0210998 W JP 0210998W WO 03035805 A1 WO03035805 A1 WO 03035805A1
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ether
hydrocarbon
oxygen
liquid composition
alcohol
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PCT/JP2002/010998
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English (en)
Japanese (ja)
Inventor
Wataru Murota
Kenji Yamazaki
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Wataru Murota
Kenji Yamazaki
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Publication of WO2003035805A1 publication Critical patent/WO2003035805A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only

Definitions

  • the present invention relates to a novel oxygen-containing hydrocarbon-containing liquid composition, a method for producing the same, and a method for producing a liquid fuel containing the oxygen-containing hydrocarbon-containing liquid composition. More specifically, the present invention can be used alone as a low-pollution liquid fuel for internal combustion engines (gasoline engines, diesel engines, jet engines, etc.) by replacing it with gasoline or light oil.
  • a novel oxygen-containing hydrocarbon-containing liquid composition that can also be used as a source, a method for producing the same, and a method for producing a low-pollution liquid fuel that can be used in an internal combustion engine containing the oxygen-containing hydrocarbon-containing liquid composition
  • Liquid fuels are mainly composed of liquid hydrocarbons, and are classified into gasoline, kerosene, light oil, heavy oil, etc., depending on the molecular weight of the hydrocarbons contained.
  • these liquid fuels are used as fuel for internal combustion engines, the generation of energy is due to the oxidation of these liquid hydrocarbons.
  • the theoretically emitted gases are carbon dioxide and water.
  • Methanol does not have much advantage compared with gasoline in terms of exhaust gas composition, it also has the power, the small heating value per unit volume, and the need to enlarge the fuel tank and the corrosion problem. Not very practical.
  • dimethyl ether has a high cetane number, generates a larger amount of heat than methanol, emits almost no PM, and can be stored and used as a liquid because it liquefies at about 5 atm at room temperature. It is known that it can be used as fuel for engines, but it has not yet been put to practical use.
  • methanol has a higher hydrogen content and lower reforming temperature than gasoline, but it has a lower hydrogen concentration than methane, and it has not been able to take full advantage of its toxicity due to its toxicity.
  • gasoline has been studied as a promising hydrogen source because it has the advantage of being able to use the same infrastructure as a conventional gas station, but it has a lower hydrogen content than methanol and has been modified. There is a problem that the quality temperature is high.
  • the present inventors have conducted various studies to solve the above-mentioned problems of the conventional technology, and as a result, when natural gas or hydrogen gas, which is a gaseous low-pollution fuel, is dissolved in a liquid hydrocarbon fuel, low-pollution fuel is obtained.
  • the low-pollution fuel of the prior invention has the following configuration.
  • a low-priced fuel manufactured by dissolving natural gas cooled to 10 to 30 atm and cooled to 110 to -30 ° C in liquid fuel for fuel cooled to 10 to 130 ° C. Harmful fuel.
  • Liquid fuel hydrocarbons cooled to between 10 ° C and 130 ° C, selected from olefin hydrocarbons, glycols and acetal cooled to between 110 ° C and 130 ° C.
  • a low-pollution fuel manufactured by dissolving natural gas that has been mixed with one type and then pressurized to 3 to 10 atmospheres and cooled to 110 to 130 ° C.
  • a low-pollution fuel manufactured by dissolving one or more of low molecular gaseous glycols, acetal, and esters and hydrogen gas at a pressure of 10 atmospheres and cooled to 110 to 130 degrees Celsius.
  • the above-mentioned prior invention is not a simple production method in which a gas mainly containing methane or hydrogen is mixed with fuel at room temperature, but a gas mainly containing methane or hydrogen is first dissolved in a liquid hydrocarbon for fuel.
  • the mixing of oxygenated hydrocarbons compensates for the lack of oxygen in the combustion chamber and contributes to the oxidation reaction, and promotes the oxidation of particulate carbon, so that the generation of PM in exhaust gas can also be suppressed. It is effective. Disclosure of the invention
  • the above-mentioned prior invention has an excellent effect from the viewpoint of reducing the pollution of hydrocarbons for fuel, it is economically unacceptable from the viewpoint of energy efficiency when producing the low-pollution fuel.
  • the amount of dissolved oxygen-containing hydrocarbons and natural gas or hydrogen gas is increased by cooling the fuel hydrocarbons to 110 ° C. to 130 ° C.
  • a large amount of energy is required to cool the fuel hydrocarbons, which are usually large components, and the obtained liquid fuel is ultimately used at room temperature. Even if heat can be recovered, the remaining heat energy will be wasted, and the amount of processing will be enormous in practical use, and the cooling and heat recovery means will require very large equipment. There was a point.
  • the present inventors have conducted various experiments to solve the problems of the prior invention, and as a result, it was found that methane-hydrogen dissolved in fuel hydrocarbon under low-temperature and high-pressure conditions easily vaporized when the temperature was returned to normal temperature and normal pressure. On the other hand, methane and hydrogen dissolved in oxygenated hydrocarbons under the same low-temperature and high-pressure conditions, even when returned to normal temperature and normal pressure or partially vaporized, have considerable amounts of methane and hydrogen. The inventors have found that hydrogen remains dissolved, and have completed the present invention.
  • an object of the present invention is to provide a novel oxygen-containing hydrocarbon-containing liquid composition, a method for producing the same, and a method for producing a low-pollution liquid fuel containing the composition. More specifically, the present invention can be used alone as a low-pollution liquid fuel for internal combustion engines (gasoline engine, diesel engine, jet engine, etc.) by replacing it with gasoline or light oil.
  • a novel oxygen-containing hydrocarbon-containing liquid composition that can also be used as a source, and a method for producing the same, and a low-pollution liquid that can be used in an internal combustion engine containing the oxygen-containing hydrocarbon-containing liquid composition It is an object to provide a method for producing a fuel.
  • the above object of the present invention is achieved by the following configurations.
  • an oxygenated hydrocarbon-containing liquid composition comprising an oxygenated hydrocarbon and at least one selected from methane and hydrogen and being liquid at ordinary temperature and pressure. Is done.
  • the oxygen-containing hydrocarbon cooled to + 10 ° C. to 180 ° C. is supplied with methane and + 80 ° C. to 180 ° C.
  • Oxygen-containing carbonization comprising dissolving at least one selected from gases mainly composed of hydrogen or hydrogen under the condition of 1 to 500 atmospheres, and then returning to normal temperature and normal pressure to remove the vaporized components.
  • a method for producing a hydrogen-containing liquid composition is provided.
  • the oxygen-containing hydrocarbon-containing liquid composition after producing the oxygen-containing hydrocarbon-containing liquid composition according to the second aspect, the oxygen-containing hydrocarbon-containing liquid composition and the liquid hydrocarbon for fuel are produced. And a method for producing a low-pollution liquid fuel.
  • the term "gas containing methane as a main component” refers to not only pure methane gas but also gas containing a large amount of methane gas even if it contains components other than methane such as natural gas.
  • the term “gas containing hydrogen as a main component” includes not only pure hydrogen gas but also gas containing a large amount of hydrogen gas even if other components are mixed.
  • the oxygenated hydrocarbon-containing liquid composition of the present invention has a greater amount of liquid composition even when placed under the same normal temperature and normal pressure than when methane gas or hydrogen gas is dissolved in the oxygenated hydrocarbon simply at normal temperature and normal pressure. This has the effect of dissolving methane gas and hydrogen gas. The exact reason for this effect is not always clear, Although it is necessary to wait for this, it is presumed to be due to the following reasons as suggested in the above specification of the prior invention.
  • oxygen-containing hydrocarbon at least one selected from alcohol-based hydrocarbons, ether-based hydrocarbons, and daryl alcohol-based hydrocarbons can be used, and preferably has a low coagulation temperature and normal temperature and normal pressure. It is desirable to use a liquid that exists.
  • the freezing point is in the range of 180 ° C or more, by appropriately selecting the temperature range in which the liquid exists within the temperature range of +10 ° C to 180 ° C, It can be suitably used by mixing with another oxygen-containing hydrocarbon and selecting an appropriate temperature range in which the liquid exists within a temperature range of + 10 ° C. to 180 ° C.
  • the temperature of the oxygen-containing hydrocarbon exceeds + 10 ° C, the amount of dissolved methane gas and hydrogen gas decreases, which is not preferable. If the temperature is lower than 180 ° C, most of the oxygen-containing hydrocarbon becomes solid. Not only is it undesirable, as it also makes it difficult to use, and wastes energy for cooling. Even if the oxygen-containing hydrocarbon contains a component that solidifies in a temperature range of + 10 ° C to 180 ° C, it can be formed into a sherbet by stirring or flowing. Can be used as well.
  • the preferred temperature range of the gas containing methane and Z or hydrogen as the main component dissolved in the oxygenated hydrocarbon varies depending on the temperature of the oxygenated hydrocarbon, but is preferably + 60 ° C.
  • a temperature of +60 ° C is typically cooling
  • the temperature of a methane gas cylinder or a hydrogen gas cylinder placed outside is often about +60 ° C, and methane or hydrogen at this temperature is the main component. If the temperature of the oxygen-containing hydrocarbon is low, the introduced methane gas or hydrogen gas is inevitably cooled and effectively dissolved in the oxygen-containing hydrocarbon. However, if the temperature exceeds + 60 ° C., the temperature rise of the oxygen-containing hydrocarbon increases, which is not preferable.
  • the lower limit temperature of the gas containing methane and / or hydrogen as a main component is set at 180 ° C.
  • the temperature of liquefied natural gas is maintained at about 162 ° C, but if it is lower than 180 ° C, liquefied natural gas itself may be solidified. This is because, even if cooled, the oxygen-containing hydrocarbon-containing liquid composition or low-pollution fuel of the present invention is used at normal temperature and normal pressure, and is wasteful in energy.
  • alcohol-based hydrocarbon methanol, ethanol, 1-propanol, isopropyl alcohol, 1-ptanol, isoptyl alcohol, 2-butanol, t-butyl alcohol, 1-pentanol, isoamino alcohol, s —Ami / Leanorecol, t-amyl alcohol, 1-hexanol,
  • At least one selected from hexanol nos, aryl alcohols, pronogilanols, ethylene glycol, propylene glycol, and trimethylene glycol can be appropriately selected and used.
  • the ether hydrocarbon may be dimethyl ether, dimethyl ether, methyl ethyl ethyl ether, methyl propinolate ether, or di-n-pro.
  • At least one selected from pill ether, diisopropyl ether, methyl tert-butyl ether, tamyl methyl ether, dibutynol ether, divinyl ether, ethylen vinyl ether, aryl ether, and polyoxyether They can be selected and used as appropriate.
  • glycol ether-based hydrocarbon ethylene dali cornole monomethinoleate ether, ethylene glycolone monoethylenate ethereene, ethylene glycol dimethyl ether, ethylene glycolone retinole ether, ethylene glycol diethylene dimethyl ether, At least one selected from dioxane and diethylene glycol can be appropriately selected and used.
  • the gas mainly containing methane used in the present invention includes not only pure methane gas, but also natural gas, liquefied natural gas, petroleum cracked gas, methane gas separated from methane hydrate, biogas, sewage sludge and waste.
  • natural gas is usually imported as liquefied natural gas (LNG) cooled to about 160 ° C. Since heat of vaporization can be used to cool the oxygen-containing hydrocarbon, LNG is preferable from the viewpoint of effective use of energy.
  • LNG liquefied natural gas
  • the hydrogen gas used in the present invention may be a known gas such as a hydrogen gas produced by reforming a natural gas or a hydrocarbon, or a hydrogen gas produced by electrolysis of water.
  • hydrogen gas used in the present invention is the main component. It is desirable to use those synthesized from natural gas and hydrocarbons as the gas and oxygen-containing hydrocarbon. By doing so, all raw materials can be synthesized from natural gas and hydrocarbons, eliminating the need to use multiple types of raw materials.
  • the oxygen-containing hydrocarbon-containing liquid composition In the production of the oxygen-containing hydrocarbon-containing liquid composition, a well-known gas-liquid contact device can be used, and a patch method or a continuous flow method can be appropriately selected and used. Furthermore, in the method for producing a low-pollution fuel according to the present invention, at least one selected from gasoline, kerosene, light oil and heavy oil can be used as the liquid hydrocarbon for fuel.
  • the amount of the hydrogen-containing liquid composition varies depending on the composition and the composition of the liquid hydrocarbon for fuel, but the total amount is 1 to 99 wt%, preferably 5 to 20 wt%, more preferably 10 to 15 wt%. Although it is added within the range, it is not preferable that the addition amount is too large because it is far from the properties of liquid hydrocarbons for fuel such as gasoline and light oil which are usually used.
  • oxygen-containing hydrocarbon-containing liquid composition of the present invention a method for producing the same, and a method for producing a low-pollution liquid fuel containing the composition will be described in detail with reference to Examples.
  • Example 1 the calorific value per unit weight when methane gas was dissolved in methanol was determined using methanol as an oxygenated hydrocarbon and methane gas in a commercially available cylinder as a gas mainly composed of methane.
  • methane gas at room temperature was dissolved in methanol cooled to 150 ° C in batchwise manner at 8.5 atm until it reached an equilibrium state.
  • methanol-methane composition was returned to normal temperature and pressure, a part of the composition was vaporized, but a methanol-methane composition having a methane content of about 9% by weight was obtained.
  • the calorific value of this composition was measured by the method described in JIS-K2279, and was found to be 42.11 MjZKg.
  • a methanol-methane composition was prepared in the same manner as in Example 1, except that the pressure of the methane gas was changed to 9 atm.
  • the calorific value of this composition was measured by the same method as in Example 1, and it was 46.31 MJ / Kg.
  • Example 3 the amount of heat generated per unit weight when a gas mainly containing methane was dissolved in methanol as oxygen-containing hydrocarbon first, and then a gas mainly containing hydrogen was dissolved. It was measured.
  • Commercially available cylinders of methane gas and hydrogen gas were used as the gas mainly containing methane and the gas mainly containing hydrogen.
  • Methane gas at room temperature was dissolved in methanol cooled to 50 ° C until the equilibrium state was reached by pressurizing it to 9 atm. In that state, the pressure was returned to normal pressure, and the methane gas was replaced with hydrogen gas at normal temperature.
  • the calorific value of the obtained methanol-methane-hydrogen composition was measured by the same method as in Example 1 and found to be 50.12 MJ / K.
  • Example 4 methanol was used as the oxygen-containing hydrocarbon, and a commercially available cylinder-containing hydrogen gas was used as the gas containing hydrogen as a main component. The heat generated per unit weight when the hydrogen gas was dissolved in methanol was used. The amount was determined. Hydrogen gas at room temperature was dissolved in methanol cooled to -50 ° C in batchwise manner to 9 atmospheres until it reached an equilibrium state. Thereafter, the obtained methanol-hydrogen composition was returned to normal temperature and normal pressure, and the calorific value of the obtained liquid composition was measured in the same manner as in Example 1. As a result, the calorific value was 47.75M jZKg.
  • Example 5 was performed under the same conditions as Example 3 except that the order of dissolution of methane gas and hydrogen gas was reversed.
  • the calorific value of the obtained methanol-hydrogen-methane composition was measured by the same method as in Example 1 and found to be 51.30 MJ / Kg.
  • Example 6 the oxygen-containing hydrocarbon was ethylene glycol monoethyl ether (EGE, trade name: Echilse Mouth Sorp (manufactured by Dow Chemical Co.)), and a commercially available cylinder-based gas containing methane as a main component was used.
  • EGE ethylene glycol monoethyl ether
  • a commercially available cylinder-based gas containing methane as a main component was used.
  • the calorific value per unit weight when methane gas was dissolved in EGE using methane gas was calculated.
  • methane gas at room temperature was patch-pressurized to 9 atm in EGE cooled to 50 ° C until it reached an equilibrium state. Thereafter, the obtained EGE-methane-based yarn composition was returned to normal temperature and normal pressure, and the calorific value of the obtained composition was measured in the same manner as in Example 1. As a result, the calorific value was 52.3 OMJ / Kg.
  • Example 7 In Example 7, the same EGE as used in Example 6 was used as the oxygen-containing hydrocarbon.First, a gas mainly containing methane was dissolved, and then a gas mainly containing hydrogen was dissolved. The calorific value per unit weight at that time was measured. Commercially available cylinders of methane gas and hydrogen gas were used as the gas mainly composed of methane and the gas mainly composed of hydrogen. At room temperature, methane gas was dissolved in EGE cooled to 50 ° C until the equilibrium state was reached by pressurizing it to 9 atm. In that state, the pressure was returned to normal pressure, methane gas was replaced with hydrogen gas at normal temperature, and the pressure was further increased to 9 atm to dissolve until equilibrium was reached. The calorific value of the obtained EGE-methane-hydrogen composition was measured by the same method as in Example 1 and found to be 60.40 MJ / Kg.
  • Example 6 The same EGE used in Example 6 was used as the oxygen-containing hydrocarbon, and hydrogen gas was dissolved in EGE using commercially available hydrogen gas in a cylinder as the gas mainly composed of hydrogen. The calorific value per unit weight at that time was determined. Hydrogen gas at room temperature was dissolved in EGE cooled to 50 ° C batchwise to 9 atmospheres until it reached an equilibrium state. Thereafter, the obtained EGE-hydrogen composition was returned to normal temperature and normal pressure, and the calorific value of the obtained liquid composition was measured in the same manner as in Example 1. The calorific value was 54.98 MJ / Kg. .
  • Example 9 was carried out under the same conditions as in Example 7, except that the dissolution order of EGE and hydrogen gas was reversed.
  • the calorific value of the obtained methanol-hydrogen-methane composition was measured by the same method as in Example 1 and found to be 62.58 MJ / Kg.
  • the measurement data of the calorific values of the above Examples 1 to 9 and reference examples such as methanol, methane, hydrogen, ethylene glycol monoethyl ether (EGE), synthetic gasoline (GTL), gasoline, diesel diesel oil and dimethyl ether (DME) Table 1 also summarizes the data on the calorific value of. ⁇ table 1 ⁇
  • EGE Ethylene Glyco / Remonoethyl / Reether
  • the calorific values of the oxygen-containing hydrocarbon-based compositions obtained in Examples 1 to 9 are all compared with the calorific value data shown in Table 1. Compared with the calorific value of the oxygen hydrocarbon compound alone, it was confirmed that the calorific value of the methanol-based composition was about twice and that of the EGE-based composition was about 1.5. The calorific value of these compositions is almost the same as or larger than that of gasoline / light oil, indicating that there is a possibility that they can be used as excellent low-pollution fuels for internal combustion engines.
  • low-pollution liquid fuels suitable as fuels for internal combustion engines were prepared using various compositions according to the present invention, and their exhaust gas characteristics were measured.
  • Methyl alcohol and ethyl ether were mixed at normal temperature and normal pressure so that the content ratio of each was 50 wt%.
  • This mixed solution was cooled to 124 ° C., and a natural gas at 124 ° C. was dissolved in a closed container by batching so as to have a concentration of 30 w%, and then returned to normal temperature and normal pressure. At this time, natural gas evaporation was 5 wt%.
  • This oxygenated hydrocarbon-containing liquid composition was added to light oil at normal temperature and normal pressure so as to have a concentration of 20 wt% to obtain a low-pollution fuel 1.
  • Table 3 shows nitrogen oxides, hydrocarbons (hydrocarbons), carbon monoxide and aldehydes. [Table 3]
  • Nitrogen oxides, hydrocarbons (hydrocarbons), carbon monoxide and aldehydes were as follows.
  • the unit is rp pmj except for -carbon oxide
  • Example 11 Ethylenedaricol and acetal were mixed at normal temperature and normal pressure so as to be 50 wt% each. This mixed solution was cooled to 124 ° C, and 25 wt% of natural gas at 24 ° C was applied by a patch method in a closed container. /. After dissolution, the pressure was returned to normal temperature and normal pressure. At this time, the natural gas evaporation was 5 wt%.
  • the low-pollution fuel 2 was obtained by adding the oxygen-containing hydrocarbon-containing liquid composition to light oil at normal temperature and pressure so as to be 20 wt%.
  • the low-emission fuel 2 was tested for exhaust gas using a 10-ton truck manufactured by Nissan Diesel. The results were as follows.
  • Nitrogen oxides, hydrocarbons (Hide mouth carbon), carbon monoxide and aldehydes were as follows.
  • the oxygen-containing hydrocarbon-containing liquid composition of the present invention is obtained by simply adding a gas containing methane or hydrogen as a main component to the oxygen-containing hydrocarbon at ordinary temperature and pressure. Unlike a dissolved composition, a large amount of methane gas or a large amount of methane gas even at normal temperature and normal pressure may be due to hydrogen bonds in methane or hydrogen atoms in hydrogen and oxygen atoms in oxygenated hydrocarbons. Hydrogen gas is dissolved and its calorific value is comparable to or larger than that of gasoline or light oil.
  • the oxygen-containing hydrocarbon-containing liquid composition itself may be a low-pollution fuel that can be converted into gasoline or light oil, and this oxygen-hydrocarbon-containing liquid composition may be added to conventional liquid hydrocarbons for fuel.
  • the low-pollution fuel of the present invention obtained by the above-described method is capable of simultaneously reducing NOX and particulate matter PM similarly to the preceding invention. It is clear that the cooling of liquid hydrocarbons for fuel is not required, so that it can be manufactured with a small-sized manufacturing equipment and energy-efficiently, and has an extremely large economic value.
  • the oxygen-containing hydrocarbon-containing liquid composition of the present invention since the oxygen-containing hydrocarbon-containing liquid composition of the present invention has a higher hydrogen content than the oxygen-containing hydrocarbon itself, it is promising as a raw material for producing hydrogen gas. It can also be used as a gas source.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

L'invention concerne un procédé relatif à l'élaboration d'une composition liquide à base d'hydrocarbure contenant de l'oxygène, qui consiste: à dissoudre au moins un type de gaz contenant du méthane et/ou de l'hydrogène comme constituant principal, à une température comprise entre +60° C et -180° C, dans un hydrocarbure qui renferme de l'oxygène, refroidi pour osciller en température entre +10° C et -80° C, sous une pression comprise entre 1 et 500 atmosphères; à maintenir le mélange résultant dans des conditions de température et de pression ordinaires. L'invention concerne également un combustible liquide faiblement polluant qui renferme un combustible hydrocarboné liquide, et une composition liquide élaborée selon le procédé décrit. Ledit procédé permet de produire une composition liquide renfermant un hydrocarbure à base d'oxygène, dont le rendement énergétique est satisfaisant et qui est rentable.
PCT/JP2002/010998 2001-10-23 2002-10-23 Composition liquide a base d'hydrocarbure contenant de l'oxygene, procede d'elaboration, et procede d'elaboration de combustible liquide faiblement polluant WO2003035805A1 (fr)

Applications Claiming Priority (8)

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JP2001-325718 2001-10-23
JP2001-325719 2001-10-23
JP2001325718 2001-10-23
JP2001325719 2001-10-23
JP2002121442 2002-03-20
JP2002-121442 2002-03-20
JP2002294409A JP4325907B2 (ja) 2001-10-23 2002-10-08 含酸素炭化水素含有液体組成物及びその製造方法並びに該組成物を含有する低公害液体燃料の製造方法。
JP2002-294409 2002-10-08

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CN102492498A (zh) * 2011-12-15 2012-06-13 黑龙江省科学院高技术研究院 燃料油助燃剂及其使用方法
CN102863992A (zh) * 2012-09-14 2013-01-09 青岛蔚蓝节能技术有限公司 一种新的合成液体燃料
CN103980956A (zh) * 2013-08-31 2014-08-13 张广舜 一种新燃料

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JP4573578B2 (ja) * 2004-06-16 2010-11-04 Ｊｘ日鉱日石エネルギー株式会社 ディーゼル機関用低粘性燃料油組成物
JPWO2007114277A1 (ja) * 2006-03-30 2009-08-20 新日鉄エンジニアリング株式会社 液体燃料合成システム
MX284139B (es) 2006-05-26 2011-02-18 Amyris Biotechnologies Inc Produccion de isoprenoides.
AU2007267914C1 (en) 2006-05-26 2012-06-07 Amyris, Inc. Fuel components, fuel compositions and methods of making and using same
TWI583782B (zh) * 2013-04-22 2017-05-21 碧氫科技開發股份有限公司 低碳液態燃料組合物

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JPH06263666A (ja) * 1993-03-12 1994-09-20 Agency Of Ind Science & Technol メタノールの製造方法
WO1996023755A1 (fr) * 1995-02-03 1996-08-08 Haldor Topsøe A/S Preparation d'ether dimethylique de qualite carburant
WO1999001526A1 (fr) * 1997-07-01 1999-01-14 Amoco Corporation COMBUSTIBLE A BASE DE DIMETHYLETHER ET PROCEDE DE PRODUCTION D'ENERGIE DANS UN SYSTEME DE COMBUSTION A SEC A FAIBLE EMISSION DE NO¿x?
EP1182185A2 (fr) * 2000-08-21 2002-02-27 Mitsubishi Heavy Industries, Ltd. Procédé de préparation de méthanol
JP2002180071A (ja) * 2000-12-12 2002-06-26 Ntd Kk 低公害燃料

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Publication number Priority date Publication date Assignee Title
EP0233076A2 (fr) * 1986-02-10 1987-08-19 Foster Wheeler Energy Limited Procédé de production de gaz de synthèse
JPH06263666A (ja) * 1993-03-12 1994-09-20 Agency Of Ind Science & Technol メタノールの製造方法
WO1996023755A1 (fr) * 1995-02-03 1996-08-08 Haldor Topsøe A/S Preparation d'ether dimethylique de qualite carburant
WO1999001526A1 (fr) * 1997-07-01 1999-01-14 Amoco Corporation COMBUSTIBLE A BASE DE DIMETHYLETHER ET PROCEDE DE PRODUCTION D'ENERGIE DANS UN SYSTEME DE COMBUSTION A SEC A FAIBLE EMISSION DE NO¿x?
EP1182185A2 (fr) * 2000-08-21 2002-02-27 Mitsubishi Heavy Industries, Ltd. Procédé de préparation de méthanol
JP2002180071A (ja) * 2000-12-12 2002-06-26 Ntd Kk 低公害燃料

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102492498A (zh) * 2011-12-15 2012-06-13 黑龙江省科学院高技术研究院 燃料油助燃剂及其使用方法
CN102863992A (zh) * 2012-09-14 2013-01-09 青岛蔚蓝节能技术有限公司 一种新的合成液体燃料
CN103980956A (zh) * 2013-08-31 2014-08-13 张广舜 一种新燃料

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