WO2003032932A1 - Liquide de regeneration capillaire comprenant de l'eau dispersee avec des particules ultrafines d'un metal du groupe titane par une decharge de plasma sous eau et procede et systeme de production - Google Patents
Liquide de regeneration capillaire comprenant de l'eau dispersee avec des particules ultrafines d'un metal du groupe titane par une decharge de plasma sous eau et procede et systeme de production Download PDFInfo
- Publication number
- WO2003032932A1 WO2003032932A1 PCT/JP2002/010523 JP0210523W WO03032932A1 WO 2003032932 A1 WO2003032932 A1 WO 2003032932A1 JP 0210523 W JP0210523 W JP 0210523W WO 03032932 A1 WO03032932 A1 WO 03032932A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- group metal
- titanium group
- titanium
- hair
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/24—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
- A61P17/16—Emollients or protectives, e.g. against radiation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q7/00—Preparations for affecting hair growth
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Definitions
- Patent application title Hair restoring solution comprising ultrafine dispersion water of ultrafine titanium group metal by plasma underwater discharge, and method and apparatus for producing the same
- the present invention relates to a hair restorative solution composed of highly functional water in which ultrafine particles of a titanium group metal are ultrafinely dispersed.
- the present invention also relates to a method and apparatus for producing a hair restorative solution comprising highly functional water in which ultrafine particles of a titanium group metal are ultrafinely dispersed.
- Titanium, zirconium, hafnium, and thorium titanium group metals are relatively new metal materials found in comparison to iron, copper, aluminum, etc., and utilize their light and high-temperature properties.
- hair treatment agents using titanium compounds have been proposed (for example, For example, JP-A-57-18606, JP-A-1-133133, JP-A-1
- JP-A-4-124241 JP-A-5-706635
- Japanese Patent Application No. 4-511,289 Japanese Patent Application No. 5-494989
- JP-A-11 JP-A-11
- Japanese Patent Application Laid-Open No. 60-67210 Japanese Patent Publication No. 5-45565, Japanese Patent No. 1850423, Japanese Patent Application Laid-Open No. 63-270620, Japanese Patent No. 2567861, Japanese Patent Application Laid-Open Japanese Patent No. 1-254617, Japanese Patent No. 2855205, Japanese Patent Application Laid-Open No. 3-141216, Japanese Patent No. 2837196 Japanese Patent Application Laid-Open No. 5-43431, Japanese Patent Application Laid-Open No. 10-291927, Japanese Patent Application Laid-Open No.
- titanium group metals such as titanium
- the present invention aims to utilize the usefulness of the titanium group metal, which is inferior in workability but can be said to be infinite, particularly in the fields of bioactive materials and health care products.
- the titanium-group metal ions generated by discharging the titanium-group metal in the water in the water storage tank collide with water to generate ultrafine titanium-group metal, which is contained in an ultrafinely dispersed state.
- An object of the present invention is to provide a hair restorative solution comprising functional water, a method for producing the same, and a device therefor.
- titanium group metal ultrafine dispersion water water containing ultrafine particles of micron to nanoscale of titanium group metal in ultrafine dispersion state in water.
- the basic feature of the present invention is to ionize titanium group metal in water by plasma water discharge in water to form a hair repairing solution composed of highly functional water in which ultrafine particles of titanium group metal are ultrafinely dispersed in water. Specifically, it is shown in the following (1) to (3).
- a hair repair solution characterized by the following:
- ultra-fine titanium-group metal particles are ultra-dispersed in water by using a high-pressure discharge generator having a titanium-group metal electrode and a counter electrode in water to discharge plasma water in water between the metal and the counter electrode.
- the titanium group metal precipitates and separates in a short time.
- the most important feature of ultra-dispersed water is that, because the titanium-group metal ionized by the plasma water discharge is ultra-finely dispersed in water, it does not cause segregation such as precipitation over a long period of time in ultra-fine particles, and is stable The point is to maintain the state.
- the ultrafinely dispersed water of the titanium group metal of the present invention has an unexpected and remarkable effect that the water molecule and the ultrafine particle titanium group metal are correlated to form a hair repair solution having a physiologically active action. Demonstrate.
- the case of using a hair restorative solution will be described.
- hair is rubbed, heat of sunlight, an external irritant such as a perm or a poor cut, malnutrition, nutritional state such as dieting.
- an external irritant such as a perm or a poor cut, malnutrition, nutritional state such as dieting.
- the hair is damaged from defects and the damaged hair has no self-healing power, so it was necessary to provide external protection to prevent further damage.
- Treatment agents are used for this purpose, but the most important ingredients for hair are water and oil, as well as skin. Moisture is taken into the cortex of the hair and gives the hair a moist, supple texture and the flexibility to swing as the body moves. In addition, the oil forms an oil film on the fur and gives it a gloss and luster to reduce friction and prevent damage to the fur, but the ultra-fine dispersion of the highly functional titanium group metal obtained by the present invention Water has been found to have excellent treatment effects that are not found in conventional commercial treatments, and damaged hair Has a remarkable restoring effect on
- the highly functional titanium-group metal ultra-dispersed water obtained by the present invention can be used not only for hair repair liquids, but also for health products such as motor function-enhancing creams, medical products such as antibacterial agents, UV cut products, and health drinks. It can be used as cosmetics such as water, health enhancers, cosmetics, food preservatives, food freshness preservatives, insect repellents or deodorants.
- the ultrafine dispersion water of the titanium group metal of the present invention is currently suitably used for the above-mentioned applications, but is an epoch-making bioactive material that can sufficiently respond to recent social health consciousness. It is expected to be.
- FIG. 1 is a flow chart for producing a hair restorative solution comprising ultrafine dispersion water of a titanium group metal of the present invention.
- FIG. 1 is a schematic view showing a hair repair liquid producing apparatus comprising ultrafine dispersion water of a titanium group metal according to the present invention.
- the hair repairing solution comprising the ultrafinely dispersed water of the titanium group metal of the present invention is a novel product which has not been produced conventionally.
- a method using heat melting, arc discharge or laser light irradiation which is a general means for dissolving a titanium group metal, is used for melting the titanium group metal for producing ultrafine dispersion water of the titanium group metal.
- the present invention discloses a new method and apparatus for producing a hair restorative solution composed of water containing titanium group metals, which are ionized by plasma discharge in water, in the form of ultrafine particles in water.
- the present inventors have studied the efficient and economical production of a hair restorative solution composed of ultrafine dispersion water of a titanium group metal and the use of the same for physiologically active uses.
- the titanium-group metal ions collide with water so that ultrafine particles of titanium-group metal are contained in water in an ultra-fine dispersion state.
- a device was devised to perform plasma discharge in the water storage tank.
- it is important to control the supply amount of the titanium group metal as a raw material.
- not only ultrafine titanium-group metal particles but also a small amount of fine metal oxide particles having a large particle diameter are generated in water, so that an appropriate filtration system needs to be used.
- the hair repairing solution comprising the ultrafine dispersion water of the titanium group metal of the present invention is treated with water as described above.
- the manufacturing method in the apparatus and the apparatus for implementing the method will be described with reference to the drawings.
- FIG. 1 is a flowchart for producing a hair restorative solution comprising ultra-fine dispersion water of a titanium group metal of the present invention
- FIG. 2 is a device for producing a hair restorative solution comprising ultra-fine dispersion water of a titanium group metal of the present invention. Is shown.
- the apparatus for producing ultrafine dispersed water of titanium group metal of the present invention in FIG. 2 is a water storage tank 3 for producing water in which titanium group metal ionized by underwater plasma discharge is ultrafinely dispersed in water.
- the basic structure of the plasma underwater discharge apparatus of the present invention is as follows: a water storage tank 3, a high-pressure discharge generator 1 including a titanium group metal electrode and its counter electrode, a water supply port 8, and discharging ultrafine dispersion water of a titanium group metal.
- This is a manufacturing device consisting of an outlet 9. It is provided with a filtration device 11 for ultrafine dispersion water of the generated titanium group metal as an additional component.
- the water storage tank of the present invention is made of a metal, preferably steel, tank.
- a water supply port 8 and a discharge port 9 are provided so that water to be processed can be continuously taken out. Like that.
- the titanium group metal electrode 6 is gradually sent out from the supply device 4 into the water storage tank according to the amount of dissolution. Titanium-group metal ions generated by plasma water discharge between the titanium-group metal electrode 6 and its counter electrode 7 come into contact with and dissolve in water to form ultra-fine particles. It is taken out from the discharge port 9 and is sequentially filtered by a suitable filtering device 11.
- metal ion vapor is generated from the electrode of the plasma discharge metal in water between the electrode of the titanium group metal and the counter electrode, and the aqueous dispersion in which ultrafine particles of the titanium group metal are ultrafinely dispersed by contact with water is produced. Generate.
- the electrode of the titanium group metal is inserted from the electrode supply device 4 in a fixed amount according to the amount of generated metal ion vapor.
- the titanium metal 12 ionized in the water storage tank 3 is released into the water from the electrode and collides with the water to generate ultrafine particles. At this time, it is considered that some of the titanium group metals take on a crystalline structure. As a result of the generation of ultrafine titanium group metal particles in water in this state, extremely hydrophobic titanium group metal particles are stable and ultrafinely dispersed in water. No precipitation occurs when the agent is used.
- a pure titanium metal electrode 6 is sequentially inserted and melted in a processing water storage tank 3 while vibrating or sliding.
- the ultrafine water of titanium group metal in which ultrafine particles of titanium group metal are finely dispersed in water, produced as described above, is appropriately purified to obtain a hair repair liquid or other health products.
- the power that is used as a raw material for cosmetics, foods, pharmaceuticals, quasi-drugs, etc., and the ultra-fine dispersion water of titanium group metal generated contains some titanium oxide fine particles with a relatively large particle size due to bonding with oxygen. Therefore, filtration and purification are necessary as needed.
- the filtration at this time is performed without using methods such as ion exchange or reverse osmosis membranes, and in order to prevent unnecessary removal of ultrafine particles of titanium metal, ultrafine dispersion of titanium metal suitable for the purpose.
- the use of the following filter device to make water is preferred.
- a hollow fiber membrane is suitable for the filter. If high-pressure water discharged from the high-pressure water storage tank is sequentially filtered, it is preferable in view of the properties of titanium ultra-fine dispersion water and the life of the filter. It can produce ultra finely dispersed water of titanium group metals that meet the standards of hygiene, cosmetics, and pharmaceuticals.
- FIG. 2 shows a production apparatus of the present invention.
- the manufacturing equipment includes a water storage tank 3, a titanium electrode 6 and a high-pressure discharge generator 1 having a titanium or carbon counter electrode 7, a water supply port 8, a processing water discharge port 9 and a discharge pump 10, electrode vibration or sliding.
- the device 5 is provided.
- Ultrafine dispersion water in which ultrafine titanium particles generated by collision of titanium group metal ions generated by plasma underwater discharge with water in the water storage tank 3 are ultrafinely dispersed is obtained.
- water is supplied into the water storage tank, and electricity is supplied to a high-pressure discharge generator having a titanium group metal electrode and a counter electrode to generate ion vapor of the titanium group metal by plasma underwater discharge.
- a high-pressure discharge generator having a titanium group metal electrode and a counter electrode to generate ion vapor of the titanium group metal by plasma underwater discharge.
- Contact and dissolution produces ultrafine particles.
- the supply amount of the titanium group metal is 0.5 kg / h
- 50 O kg of the ultrafine dispersion water of the generated titanium group metal is obtained.
- the obtained dispersion water is discharged from the outlet and sent to a filtration device.
- the filtration device filters 50, 25, 3, 3, 0.5 and 0.1 micron sequentially with a filter, and finally, ultrafine titanium particles and a very small amount of dissolved titanium Is obtained.
- a part of titanium takes a crystal structure, and titanium atoms rearrange in this, and it becomes almost spherical, and it is considered that the state becomes stable in terms of
- the water storage tank 3 only needs to be a pressure-resistant tank that can withstand the pressure generated when the plasma is discharged in water.By performing the pulsed plasma discharge, dissolved water of ultrafine titanium particles can be produced almost continuously.
- the equipment can be made compact, and it can be said that it is an efficient manufacturing method. Such a simple equipment does not require excessive withstand pressure, and therefore has excellent safety.
- titanium was used as the titanium metal as a raw material, but the same finely dispersed water was obtained even when zirconium was used.
- the hair was washed or coated with the ultrafine titanium dioxide water obtained in the present invention, and further, among those sprayed, the hair was recovered from damage, the hair properties were improved, or the skin on the head was improved.
- the hair repair solution comprising the titanium ultra-finely dispersed water of the present invention exerts a remarkable effect as a medical product or cosmetic product.
- FIG. 3 shows an enlarged photograph of the hair obtained by using the hair regenerating solution using the titanium ultra-fine dispersion water of the present invention used in the above test.
- Fig. 4 shows the case of treatment with ordinary water.
- the present invention is configured as described above, and provides a novel ultra-fine dispersion of titanium group metal, a hair repairing solution comprising water, and a method and apparatus for producing the same.
- a hair repairing solution composed of ultrafine water of a titanium group metal having a physiologically active function contained in water can be efficiently produced.
- the obtained hair repair solution consisting of ultra-fine dispersion water of titanium group metal has been subjected to a number of monitor tests to show that it can be used for health drinking water, health enhancers, cosmetics, food preservatives, food freshness preservatives, insect repellents or deodorants. It is also useful, and is expected to have significant industrial effects.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- Dermatology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Toxicology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MXPA04003264A MXPA04003264A (es) | 2001-10-12 | 2002-10-10 | Liquido para preparacion del cabello, que comprende particulas ultrafinas de metal del grupo titanio dispersa en agua, por decarga sub-acuatica de plasma y metodo y sistema para producir el mismo. |
US10/492,392 US20050019289A1 (en) | 2001-10-12 | 2002-10-10 | Hair repairing liquid comprising water dispersed with ultrafine particle titanium group metal by plasma underwater discharge and method and system for producing the same |
JP2003535738A JP3664442B2 (ja) | 2001-10-12 | 2002-10-10 | プラズマ水中放電による超微粒子チタン族金属の超微分散水よりなる毛髪修復液及びその製造方法と装置 |
BR0213153-6A BR0213153A (pt) | 2001-10-12 | 2002-10-10 | Lìquido de reparo capilar compreendendo água com metal do grupo do titânio em partìculas ultrafinas dispersadas por descarga de plasma subaquática e processo e sistema para sua produção |
HU0401942A HUP0401942A2 (hu) | 2001-10-12 | 2002-10-10 | A titáncsoportba tartozó fém víz alatti plazmakisülés során nyert ultrafinom részecskéinek vizes diszperzióját tartalmazó hajjavító folyadék, valamint eljárás és berendezés az előállítására |
CA002463460A CA2463460A1 (en) | 2001-10-12 | 2002-10-10 | Hair repairing liquid comprising water dispersed with ultrafine particle titanium group metal by plasma underwater discharge and method and system for producing the same |
EP02801526A EP1452166A4 (en) | 2001-10-12 | 2002-10-10 | HAIR REPAIR LIQUID CONTAINING WATER DISPERSED WITH ULTRAFINITE PARTICLES OF METAL OF TITANIUM GROUP BY UNDERWATER PLASMA DISCHARGE AND METHOD AND SYSTEM FOR ITS MANUFACTURE |
NO20041788A NO20041788L (no) | 2001-10-12 | 2004-04-30 | Harreparasjonsvaeske omfattende vann dispergert med ultrafine titangruppemetallpartikler ved plasma undervannsutladning og fremgangsmate og system for fremstilling av denne |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001-315337 | 2001-10-12 | ||
JP2001315337 | 2001-10-12 |
Publications (1)
Publication Number | Publication Date |
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WO2003032932A1 true WO2003032932A1 (fr) | 2003-04-24 |
Family
ID=19133521
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2002/010523 WO2003032932A1 (fr) | 2001-10-12 | 2002-10-10 | Liquide de regeneration capillaire comprenant de l'eau dispersee avec des particules ultrafines d'un metal du groupe titane par une decharge de plasma sous eau et procede et systeme de production |
Country Status (12)
Country | Link |
---|---|
US (1) | US20050019289A1 (ja) |
EP (1) | EP1452166A4 (ja) |
JP (1) | JP3664442B2 (ja) |
KR (1) | KR20050035130A (ja) |
CN (1) | CN1564674A (ja) |
BR (1) | BR0213153A (ja) |
CA (1) | CA2463460A1 (ja) |
HU (1) | HUP0401942A2 (ja) |
MX (1) | MXPA04003264A (ja) |
NO (1) | NO20041788L (ja) |
PL (1) | PL369636A1 (ja) |
WO (1) | WO2003032932A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006059808A1 (ja) * | 2004-12-03 | 2006-06-08 | Kabushiki Kaisha Toyota Jidoshokki | 液中プラズマ用電極、液中プラズマ発生装置および液中プラズマ発生方法 |
US7300672B2 (en) | 2001-10-12 | 2007-11-27 | Phild Co., Ltd. | Titanium-group metal containing high-performance water, and its producing method and apparatus |
US8128789B2 (en) | 2001-10-12 | 2012-03-06 | Phiten Co., Ltd. | Method for producing ultrafine dispersion water of noble metal ultrafine particles |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2465788A1 (en) * | 2001-11-06 | 2003-05-15 | Phild Co., Ltd. | Skin lotion comprising aqueous dispersion of ultra-fine titanium particles |
US7820147B2 (en) * | 2005-11-18 | 2010-10-26 | Mata Michael T | Hair restorative compositions and methods for treating damaged hair and safely chemically treating hair |
CN101785783A (zh) * | 2009-01-22 | 2010-07-28 | 朱晓颂 | 金属Ti微粒子在促进或增大皮肤外用抗菌或杀菌药物功效上的用途 |
KR101533727B1 (ko) * | 2015-03-31 | 2015-07-03 | 한국항공대학교산학협력단 | 백금-팔라듐 합금 나노입자를 활용한 원자력 발전소 배관재의 응력부식균열 억제방법 |
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JPS6389405A (ja) * | 1986-09-30 | 1988-04-20 | Riken Corp | 酸化物超微粒子の製造方法 |
US5553630A (en) * | 1991-06-04 | 1996-09-10 | L'oreal | Use of metal oxide nanopigments for protecting hair keratin against atmospheric attack, especially light, method of protecting hair and gel composition using these nanopigments |
JPH11228141A (ja) * | 1998-02-18 | 1999-08-24 | C I Kasei Co Ltd | 二酸化チタン微粒子水分散体およびその製造方法 |
JP2001314878A (ja) * | 2000-05-10 | 2001-11-13 | Fuairudo Kk | チタン含有高機能水及びその製造方法と装置 |
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JPH02166202A (ja) * | 1988-12-20 | 1990-06-26 | Ishikawajima Harima Heavy Ind Co Ltd | 金属粒の製造方法 |
JPH0693311A (ja) * | 1992-09-17 | 1994-04-05 | Matsushita Electric Ind Co Ltd | 超微粒子分散液状物の製造方法 |
FR2719218B1 (fr) * | 1994-04-28 | 1996-07-05 | Oreal | Utilisation d'une suspension colloïdale à base de charges minérales comme composition cosmétique permettant de former un film sur les cheveux, la peau et/ou les ongles. |
US5707419A (en) * | 1995-08-15 | 1998-01-13 | Pegasus Refractory Materials, Inc. | Method of production of metal and ceramic powders by plasma atomization |
CA2442727A1 (en) * | 2001-03-29 | 2002-10-10 | Phild Co., Ltd. | Hair-restoring liquid comprising aqueous dispersion of ultrafine titanium particles and process and apparatus for producing the same |
-
2002
- 2002-10-10 CN CNA028197003A patent/CN1564674A/zh active Pending
- 2002-10-10 MX MXPA04003264A patent/MXPA04003264A/es not_active Application Discontinuation
- 2002-10-10 KR KR1020047005219A patent/KR20050035130A/ko not_active Application Discontinuation
- 2002-10-10 JP JP2003535738A patent/JP3664442B2/ja not_active Expired - Fee Related
- 2002-10-10 EP EP02801526A patent/EP1452166A4/en not_active Withdrawn
- 2002-10-10 BR BR0213153-6A patent/BR0213153A/pt not_active Application Discontinuation
- 2002-10-10 PL PL02369636A patent/PL369636A1/xx not_active Application Discontinuation
- 2002-10-10 HU HU0401942A patent/HUP0401942A2/hu unknown
- 2002-10-10 WO PCT/JP2002/010523 patent/WO2003032932A1/ja not_active Application Discontinuation
- 2002-10-10 CA CA002463460A patent/CA2463460A1/en not_active Abandoned
- 2002-10-10 US US10/492,392 patent/US20050019289A1/en not_active Abandoned
-
2004
- 2004-04-30 NO NO20041788A patent/NO20041788L/no not_active Application Discontinuation
Patent Citations (4)
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JPS6389405A (ja) * | 1986-09-30 | 1988-04-20 | Riken Corp | 酸化物超微粒子の製造方法 |
US5553630A (en) * | 1991-06-04 | 1996-09-10 | L'oreal | Use of metal oxide nanopigments for protecting hair keratin against atmospheric attack, especially light, method of protecting hair and gel composition using these nanopigments |
JPH11228141A (ja) * | 1998-02-18 | 1999-08-24 | C I Kasei Co Ltd | 二酸化チタン微粒子水分散体およびその製造方法 |
JP2001314878A (ja) * | 2000-05-10 | 2001-11-13 | Fuairudo Kk | チタン含有高機能水及びその製造方法と装置 |
Non-Patent Citations (1)
Title |
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See also references of EP1452166A4 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7300672B2 (en) | 2001-10-12 | 2007-11-27 | Phild Co., Ltd. | Titanium-group metal containing high-performance water, and its producing method and apparatus |
US8128789B2 (en) | 2001-10-12 | 2012-03-06 | Phiten Co., Ltd. | Method for producing ultrafine dispersion water of noble metal ultrafine particles |
WO2006059808A1 (ja) * | 2004-12-03 | 2006-06-08 | Kabushiki Kaisha Toyota Jidoshokki | 液中プラズマ用電極、液中プラズマ発生装置および液中プラズマ発生方法 |
JPWO2006059808A1 (ja) * | 2004-12-03 | 2008-06-05 | 株式会社豊田自動織機 | 液中プラズマ用電極、液中プラズマ発生装置および液中プラズマ発生方法 |
JP4909741B2 (ja) * | 2004-12-03 | 2012-04-04 | 株式会社豊田自動織機 | 液中プラズマ用電極、液中プラズマ発生装置および液中プラズマ発生方法 |
US8653404B2 (en) | 2004-12-03 | 2014-02-18 | Kabushiki Kaisha Toyota Jidoshokki | In-liquid plasma electrode, in-liquid plasma generating apparatus and in-liquid plasma generating method |
Also Published As
Publication number | Publication date |
---|---|
CA2463460A1 (en) | 2003-04-24 |
EP1452166A4 (en) | 2005-03-16 |
US20050019289A1 (en) | 2005-01-27 |
BR0213153A (pt) | 2004-08-10 |
MXPA04003264A (es) | 2004-07-23 |
CN1564674A (zh) | 2005-01-12 |
PL369636A1 (en) | 2005-05-02 |
JP3664442B2 (ja) | 2005-06-29 |
JPWO2003032932A1 (ja) | 2005-02-03 |
EP1452166A1 (en) | 2004-09-01 |
NO20041788L (no) | 2004-04-30 |
KR20050035130A (ko) | 2005-04-15 |
HUP0401942A2 (hu) | 2005-09-28 |
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