WO2002100586A1 - Anvil for friction stir welding high temperature materials - Google Patents
Anvil for friction stir welding high temperature materials Download PDFInfo
- Publication number
- WO2002100586A1 WO2002100586A1 PCT/US2002/018774 US0218774W WO02100586A1 WO 2002100586 A1 WO2002100586 A1 WO 2002100586A1 US 0218774 W US0218774 W US 0218774W WO 02100586 A1 WO02100586 A1 WO 02100586A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- anvil
- friction stir
- recited
- stir welding
- materials
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K37/00—Auxiliary devices or processes, not specially adapted to a procedure covered by only one of the preceding main groups
- B23K37/06—Auxiliary devices or processes, not specially adapted to a procedure covered by only one of the preceding main groups for positioning the molten material, e.g. confining it to a desired area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/12—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating the heat being generated by friction; Friction welding
- B23K20/122—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating the heat being generated by friction; Friction welding using a non-consumable tool, e.g. friction stir welding
- B23K20/1245—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating the heat being generated by friction; Friction welding using a non-consumable tool, e.g. friction stir welding characterised by the apparatus
- B23K20/126—Workpiece support, i.e. backing or clamping
Definitions
- This invention relates to friction stir welding and, more particularly, to an anvil used in friction stir welding processes that is either coated with or manufactured from a substance capable of resisting anvil deformation and preventing diffusion bonding or mechanical bonding between the anvil and the friction stir welding tool or work piece when friction stir welding high temperature materials or work pieces.
- Friction welding has been used for years in the welding industry. For example, when the ends of two pipes are pressed together and simultaneously turned in opposite directions to one another heat is generated and causes the ends of the pipes to become plasticized and bonded. Rapidly stopping rotation of the pipes causes the two pipes to fuse together.
- Friction stir welding is a relatively new technique, and was first described in United States Patent No. 5,460,317, issued October 24, 1995. Friction stir welding involves pressing a non-consumable friction stir welding tool with a profiled probed end against two work pieces at the point where they come in contact with one another. Cyclical movement of the probed end of the tool generates heat as it presses against the two work pieces. The probed end of the tool enters or plunges into the two work pieces in a plasticized region created by the friction of the probed end. The probed end can then be slowly moved to a region where the two pieces abut each other, thereby enabling the area between the two pieces, which is beneath the probed end, to solidify together.
- Friction stir welding has traditionally been limited to welding of low melting temperature materials such as aluminum alloy, copper alloys, lead and magnesium alloys because of the wear on the probed end. These materials are effectively joined using standard steel backing supports or anvils.
- U.S. Pat. No. 6,168,066 incorporates a ceramic sensor plate for sensing magnetic fields and eddies to control the depth of the magnetic friction stir welding tool in softer non-magnetic materials.
- Some embodiments of the present invention provide a friction stir welding anvil that forms a diffusion barrier between the work pieces and the anvil when friction stir welding. Some embodiments of the present invention provide an improved friction stir welding anvil that allows for the welding of materials and work pieces normally considered 'rigid' and difficult to weld with conventional friction stir welding anvils.
- some embodiments of the present invention provide an improved friction stir welding anvil that allows for full penetration welding of materials currently difficult to friction stir weld with conventional friction stir welding anvils.
- Some embodiments of the present invention provide an improved friction stir welding anvil that resists the usual deformation attributable to the anvil when friction stir welding high temperature work pieces and materials.
- Some embodiments of the present invention provide a friction stir welding anvil that prevents diffusion bonding between the work pieces and the anvil when friction stir welding.
- some embodiments of the present invention provide a number of materials that can be used to coat an anvil or from which an anvil can be manufactured so as to enable superior performance than is available with current friction stir welding anvils.
- a system whereby a friction stir welding anvil is manufactured from a chemically inert material such as an Oxide, Nitride, Carbide or Silicate.
- the anvil is a generally flat plate or rotating wheel that supports the work pieces while friction stir welding.
- the chemically inert material is used to coat the anvil. The following are alternatives for the method of application or manufacturing of the anvil using the above referenced materials.
- the anvil is created by directly spray-coating the metallic anvil with the chemically inert material.
- the anvil is coated with the chemically inert material by chemical or vapor deposition.
- the anvil may also be coated with the chemically inert material through anodizing or may be coated with the chemically inert material through ion beam sintering. Further, the anvil may be a complete insert comprised of the chemically inert material or the anvil may be coated with a powdered form of the chemically inert material. Furthermore, the anvil may be coated with a powdered form of the chemically inert material by slurry. Alternatively, the anvil may be coated with the chemically inert material by creating and bonding the chemically inert material simultaneously by reaction or transformation.
- the anvil's geometry or shape can vary in order to accomplish more specific objectives, so long as the anvil is at least partially coated or comprised of the chemically inert material.
- any chemically inert coating that includes a metal combined with Oxygen, Nitrogen, Carbon or Silicon as a second or third component to respectively form an Oxide, a Nitride, a Carbide or a Silicate improves performance of the anvil in accordance with embodiments of the present invention.
- any chemically inert coating that includes a chemically inert material, such as but not limited to diamonds improves performance of the anvil in accordance with embodiments of the present invention.
- inventions of the present invention enable full penetration during friction stir welding of traditionally non-friction stir weldable materials, such as steels, titanium, and other high temperature materials because the tool does not stick to the anvil or work pieces and an enhanced weld is achieved.
- Figure 1 is a cross sectional view illustrating the face to be welded, wherein the illustration includes both the joint line of the work pieces and supporting anvil;
- Figure 2 is another cross-sectional illustration of the face to be welded and shows the friction stir welding tool operating within the work pieces;
- Figure 3 depicts a cross-sectional view of the face after welding with conventional anvils
- Figure 4 depicts a cross-sectional view of the face after welding with embodiments of the present invention as disclosed herein;
- Figure 5 illustrates a cross-sectional view depicting the face to be welded and further depicting a coated diffusion barrier on the anvil; and
- Figure 6 is yet another cross-sectional view illustrating the face to be welded and an anvil that is composed of an inert diffusion barrier.
- the term 'higher temperature materials' refers to those compositions or work pieces that are not easily friction stir welded using traditional friction stir welding tools. These compositions are exemplified by, but not limited to steels, stainless steels, nickel alloys and titanium alloys. When friction stir welding the aforementioned materials, temperatures exceeding 1300 degrees Celsius and pressures exceeding ten tons of force are typical.
- Figure 1 demonstrates a cross-sectional view through the face to be welded, showing two work pieces and a supporting anvil 14. The view shows welding plates
- Figure 2 shows a friction stir welding tool 22 and welding plates 10A and 10B.
- Pin 16 frictionally plasticizes the material and welds the plate.
- the state of the art is to avoid full penetration leaving an unjoined section 18.
- Such lack of penetration results in a weld having a cross section 24, as illustrated in Figure 3, where the bottom portion of the weld 18 is difficult upon simple examination to determine whether or not the weld is or is not complete.
- Figure 4 shows a cross section 24 of a weld that is joined in accordance with principles of embodiments of the present invention.
- a coated anvil 14 is illustrated that allows full penetration without the risk of diffusion or mechanical bonding the work pieces to the anvil.
- the anvil may be coated with an inert material that resists diffusion bonding.
- a flat rectangular anvil that is spray-coated is used.
- Figure 5 shows a cross-sectional view of such a coated anvil.
- the illustrated anvil includes a conventional steel core 28, which is sprayed with an inert coating 26 to resist diffusion bonding.
- chemical vapor deposition is an alternative method for depositing materials on the conventional steel core.
- materials include, for example and not by way of limitation, carbides, nitrides, oxides and silicates.
- the inert coating shown in Figure 5 may be applied to the conventional steel core through, for example, a powder-coating process. An inert powder is spread over the existing steel anvil before placing the work pieces in a position ready for friction stir welding. As the work pieces move across the anvil, the powder coats the bottom of the work pieces and resists bonding.
- the coating in Figure 5 may alternatively be applied through anodization. Accordingly, the anvil is suspended in an electrolyte bath as an anode, and a current is passed through it. This process produces oxygen at the anode surface that reacts with the metal to form an oxide layer.
- Figure 6 illustrates an anvil that consists completely of the inert material 26.
- Embodiments embrace the use of such an anvil as an insert.
- An alternative embodiment for an anvil includes, but is not limited, to a horizontal rotatable cylinder or roller. This and other geometries are intended to be included within the scope of embodiments of the present invention.
- the providing of an anvil that is covered with or includes inert chemicals teaches away from traditional techniques because of the high cost of friction stir welding bits and economic pressures, which do not allow many to try full penetration with high temperature materials.
- coating may not typically prevent deformation of the anvil when the anvil is comprised of all types of materials, a coating typically prevents diffusion bonding in anvils constructed of most types of materials.
- both the prevention of diffusion bonding and deformation occurs in anvils that are formed from materials that are highly resistant to heat deformation and that are coated according to the teachings of embodiments of the present invention.
- Subsequent welds on a deformed table or anvil typically causes severe problems with surface location, however, embodiments of the present invention include coated and non-coated solid anvil materials that maintain their elastic modulus at elevated temperatures and will not diffusion weld (i.e., above steels 30 million psi). Some of these materials are made from the diffusion barrier materials discussed above.
- Embodiments also include the use of marble and/or granite.
- Liquid cooling of the anvil or of the table on which the work pieces are situated regulate the flow of heat, which can be used as a control parameter for weld quality and to maintain table modulus during friction stir welding.
- Solid ceramic materials may be used in accordance with embodiments of the present invention to control heat flow based on their thermal conductivity. Solid ceramic materials may also be used as anvils and do not typically allow diffusion bonding or deformation.
- the embodiments of the present invention embrace friction stir welding and, more particularly, an anvil used in friction stir welding processes that is either coated with or manufactured from a substance capable of resisting anvil deformation and preventing diffusion bonding or mechanical bonding between the anvil and the friction stir welding tool or work piece when friction stir welding high temperature materials or work pieces.
- the present invention may be embodied in other specific forms without departing from its spirit or essential characteristics.
- the described embodiments are to be considered in all respects only as illustrative and not restrictive.
- the scope of the invention is, therefore, indicated by the appended claims rather than by the foregoing description. All changes that come within the meaning and range of equivalency of the claims are to be embraced within their scope.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020037016243A KR100865433B1 (en) | 2001-06-12 | 2002-06-12 | Anvil for friction stir welding high temperature materials |
CA2449972A CA2449972C (en) | 2001-06-12 | 2002-06-12 | Anvil for friction stir welding high temperature materials |
EP02778964A EP1399286A4 (en) | 2001-06-12 | 2002-06-12 | Anvil for friction stir welding high temperature materials |
MXPA03011424A MXPA03011424A (en) | 2001-06-12 | 2002-06-12 | Anvil for friction stir welding high temperature materials. |
JP2003503391A JP4322664B2 (en) | 2001-06-12 | 2002-06-12 | Anvil for friction stir welding of high temperature materials |
ZA2003/09639A ZA200309639B (en) | 2001-06-12 | 2003-12-11 | Anvil for friction stir wilding high temperature materials |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US29773801P | 2001-06-12 | 2001-06-12 | |
US60/297,738 | 2001-06-12 | ||
US10/161,295 | 2002-06-03 | ||
US10/161,295 US7210610B2 (en) | 2001-06-04 | 2002-06-03 | Apparatus and method for performing non-linear friction stir welds on either planar or non-planar surfaces |
US10/171,272 US6732901B2 (en) | 2001-06-12 | 2002-06-11 | Anvil for friction stir welding high temperature materials |
US10/171,272 | 2002-06-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002100586A1 true WO2002100586A1 (en) | 2002-12-19 |
Family
ID=27388591
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2002/018774 WO2002100586A1 (en) | 2001-06-12 | 2002-06-12 | Anvil for friction stir welding high temperature materials |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1399286A4 (en) |
JP (1) | JP4322664B2 (en) |
CN (1) | CN1304160C (en) |
CA (1) | CA2449972C (en) |
MX (1) | MXPA03011424A (en) |
WO (1) | WO2002100586A1 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004067218A2 (en) * | 2003-01-30 | 2004-08-12 | Smith International, Inc. | Out-of-position stir welding of high melting temperature alloys |
KR100742699B1 (en) * | 2003-09-26 | 2007-07-25 | 셀라네세 아세테이트 앨앨씨 | Method and apparatus for making an absorbent composite |
US7651018B2 (en) | 2004-10-05 | 2010-01-26 | Sii Megadiamond | Expandable mandrel for use in friction stir welding |
US7832613B2 (en) | 2009-01-15 | 2010-11-16 | General Electric Company | Friction stir welding system |
WO2010130271A1 (en) * | 2009-05-12 | 2010-11-18 | Rheinisch-Westfälische Technische Hochschule Aachen | Method for material bonding by means of friction welding using an adhesive |
US8056797B2 (en) | 2005-10-05 | 2011-11-15 | Megastir Technologies | Expandable mandrel for use in friction stir welding |
US8298480B2 (en) | 2005-03-16 | 2012-10-30 | Siemens Energy, Inc. | Manufacture of specialized alloys with specific properties |
US8550326B2 (en) | 2005-10-05 | 2013-10-08 | Megastir Technologies Llc | Expandable mandrel for use in friction stir welding |
US9242308B2 (en) | 2009-11-02 | 2016-01-26 | Megastir Technologies Llc | Out of position friction stir welding of casing and small diameter tubing or pipe |
EP4017676A4 (en) * | 2019-09-26 | 2023-10-11 | Worldwide Machinery, Ltd | Backing material for welding |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5193462B2 (en) * | 2006-12-26 | 2013-05-08 | 国立大学法人大阪大学 | Metal joining method |
US20090200359A1 (en) * | 2008-02-13 | 2009-08-13 | Gm Global Technology Operations, Inc. | Reducing sheet distortion in friction stir processing |
JP5074985B2 (en) * | 2008-03-31 | 2012-11-14 | 株式会社総合車両製作所 | Backing member for friction stir welding and friction stir welding method |
DE102008044763A1 (en) * | 2008-08-28 | 2010-03-04 | Hochschule Für Angewandte Wissenschaften - Fachhochschule Kempten | coating process |
CN102500911B (en) * | 2011-11-21 | 2014-02-12 | 哈尔滨工业大学 | Pre-friction aid device and method for implementing diffusion bonding by using same |
JP5540256B2 (en) * | 2012-11-06 | 2014-07-02 | 国立大学法人大阪大学 | Metal joining method |
CN109570737A (en) * | 2019-01-16 | 2019-04-05 | 苏州市哈工万洲自动化有限公司 | A kind of long weld seam agitating friction soldering equipment and friction stir welding method |
CN114190796B (en) * | 2021-12-17 | 2023-09-22 | 武汉苏泊尔炊具有限公司 | Cutting board and manufacturing method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5611479A (en) * | 1996-02-20 | 1997-03-18 | Rockwell International Corporation | Friction stir welding total penetration technique |
JP2000073164A (en) * | 1998-08-28 | 2000-03-07 | Showa Alum Corp | Backing plate for sputtering |
US6168066B1 (en) * | 1999-04-21 | 2001-01-02 | Lockheed Martin Corp. | Friction stir conduction controller |
US6199745B1 (en) * | 1998-07-09 | 2001-03-13 | Mts Systems Corporation | Welding head |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4049183A (en) * | 1976-05-24 | 1977-09-20 | General Dynamics Corporation | Welding back-up tape |
JPS59212169A (en) * | 1983-05-18 | 1984-12-01 | Ishihara Yakuhin Kk | Backing method for one-side welding |
GB9220273D0 (en) * | 1992-09-25 | 1992-11-11 | Welding Inst | Improvements relating to friction jointing and surfacing |
US5624067A (en) * | 1995-09-26 | 1997-04-29 | The Babcock & Wilcox Company | Method and apparatus for weld joining pipe sections |
JP3081804B2 (en) * | 1997-01-22 | 2000-08-28 | 昭和アルミニウム株式会社 | Friction stir welding |
-
2002
- 2002-06-12 CN CNB028118162A patent/CN1304160C/en not_active Expired - Fee Related
- 2002-06-12 JP JP2003503391A patent/JP4322664B2/en not_active Expired - Fee Related
- 2002-06-12 CA CA2449972A patent/CA2449972C/en not_active Expired - Fee Related
- 2002-06-12 WO PCT/US2002/018774 patent/WO2002100586A1/en active Application Filing
- 2002-06-12 EP EP02778964A patent/EP1399286A4/en not_active Withdrawn
- 2002-06-12 MX MXPA03011424A patent/MXPA03011424A/en active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5611479A (en) * | 1996-02-20 | 1997-03-18 | Rockwell International Corporation | Friction stir welding total penetration technique |
US6199745B1 (en) * | 1998-07-09 | 2001-03-13 | Mts Systems Corporation | Welding head |
JP2000073164A (en) * | 1998-08-28 | 2000-03-07 | Showa Alum Corp | Backing plate for sputtering |
US6168066B1 (en) * | 1999-04-21 | 2001-01-02 | Lockheed Martin Corp. | Friction stir conduction controller |
Non-Patent Citations (1)
Title |
---|
See also references of EP1399286A4 * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004067218A2 (en) * | 2003-01-30 | 2004-08-12 | Smith International, Inc. | Out-of-position stir welding of high melting temperature alloys |
WO2004067218A3 (en) * | 2003-01-30 | 2004-11-04 | Smith International | Out-of-position stir welding of high melting temperature alloys |
JP2006518671A (en) * | 2003-01-30 | 2006-08-17 | スミス インターナショナル、インコーポレテッド | Out-of-position friction stir welding of high melting point materials |
US7270257B2 (en) | 2003-01-30 | 2007-09-18 | Sii Megadiamond, Inc. | Out-of-position friction stir welding of high melting temperature alloys |
KR100742699B1 (en) * | 2003-09-26 | 2007-07-25 | 셀라네세 아세테이트 앨앨씨 | Method and apparatus for making an absorbent composite |
US7651018B2 (en) | 2004-10-05 | 2010-01-26 | Sii Megadiamond | Expandable mandrel for use in friction stir welding |
US8298480B2 (en) | 2005-03-16 | 2012-10-30 | Siemens Energy, Inc. | Manufacture of specialized alloys with specific properties |
US8056797B2 (en) | 2005-10-05 | 2011-11-15 | Megastir Technologies | Expandable mandrel for use in friction stir welding |
US8550326B2 (en) | 2005-10-05 | 2013-10-08 | Megastir Technologies Llc | Expandable mandrel for use in friction stir welding |
US7832613B2 (en) | 2009-01-15 | 2010-11-16 | General Electric Company | Friction stir welding system |
WO2010130271A1 (en) * | 2009-05-12 | 2010-11-18 | Rheinisch-Westfälische Technische Hochschule Aachen | Method for material bonding by means of friction welding using an adhesive |
US9242308B2 (en) | 2009-11-02 | 2016-01-26 | Megastir Technologies Llc | Out of position friction stir welding of casing and small diameter tubing or pipe |
EP4017676A4 (en) * | 2019-09-26 | 2023-10-11 | Worldwide Machinery, Ltd | Backing material for welding |
Also Published As
Publication number | Publication date |
---|---|
CA2449972C (en) | 2013-02-12 |
CN1516634A (en) | 2004-07-28 |
EP1399286A4 (en) | 2008-03-05 |
JP2004528990A (en) | 2004-09-24 |
CN1304160C (en) | 2007-03-14 |
CA2449972A1 (en) | 2002-12-19 |
JP4322664B2 (en) | 2009-09-02 |
EP1399286A1 (en) | 2004-03-24 |
MXPA03011424A (en) | 2005-04-19 |
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