WO2002062737A3 - Heterogene katalysierte gasphasenpartialoxidation von vorläuferverbindungen der (meth)acrylsäure - Google Patents

Heterogene katalysierte gasphasenpartialoxidation von vorläuferverbindungen der (meth)acrylsäure Download PDF

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Publication number
WO2002062737A3
WO2002062737A3 PCT/EP2002/000234 EP0200234W WO02062737A3 WO 2002062737 A3 WO2002062737 A3 WO 2002062737A3 EP 0200234 W EP0200234 W EP 0200234W WO 02062737 A3 WO02062737 A3 WO 02062737A3
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WO
WIPO (PCT)
Prior art keywords
meth
acrylic acid
partial oxidation
precursor compounds
phase partial
Prior art date
Application number
PCT/EP2002/000234
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English (en)
French (fr)
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WO2002062737A2 (de
Inventor
Raimund Felder
Signe Unverricht
Heiko Arnold
Jochen Petzoldt
Original Assignee
Basf Ag
Raimund Felder
Signe Unverricht
Heiko Arnold
Jochen Petzoldt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Raimund Felder, Signe Unverricht, Heiko Arnold, Jochen Petzoldt filed Critical Basf Ag
Priority to EP02714086A priority Critical patent/EP1353892A2/de
Priority to BR0206493-6A priority patent/BR0206493A/pt
Priority to KR10-2003-7009367A priority patent/KR20030070105A/ko
Priority to US10/466,244 priority patent/US7129195B2/en
Priority to JP2002562698A priority patent/JP2004517953A/ja
Priority to AU2002246034A priority patent/AU2002246034A1/en
Priority to DE10290375T priority patent/DE10290375D2/de
Publication of WO2002062737A2 publication Critical patent/WO2002062737A2/de
Publication of WO2002062737A3 publication Critical patent/WO2002062737A3/de
Priority to US11/443,135 priority patent/US20070032680A1/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30223—Cylinder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/302—Basic shape of the elements
    • B01J2219/30242—Star
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30475—Composition or microstructure of the elements comprising catalytically active material

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Ein Verfahren der heterogen katalysierten Gasphasenpartial-oxidation von Voläuferverbindungen der (Meth)acrylsäure an einem Katalysatorfestbett das als Katalysator eine zu einem geometrischen Körper geformte Mischoxidaktivmasse enthält, wobei der geometrische Körper ein geometrischer Grundkörper ist, in dessen Oberfläche ein Hohlraum eingearbeitet ist.
PCT/EP2002/000234 2001-01-15 2002-01-12 Heterogene katalysierte gasphasenpartialoxidation von vorläuferverbindungen der (meth)acrylsäure WO2002062737A2 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP02714086A EP1353892A2 (de) 2001-01-15 2002-01-12 Heterogene katalysierte gasphasenpartialoxidation von vorläuferverbindungen der (meth)acrylsäure
BR0206493-6A BR0206493A (pt) 2001-01-15 2002-01-12 Processo para a oxidação parcial em fase gasosa heterogeneamente catalisada de um composto precursor de ácido (met)acrìlico a (met)acroleìna e/ou ácido (met) acrìlico, material ativo de óxido misto moldado em um corpo geométrico, e, uso de um ácido (met)acrìlico
KR10-2003-7009367A KR20030070105A (ko) 2001-01-15 2002-01-12 (메트)아크릴산의 전구체 화합물의 불균일 촉매작용-기상부분 산화 방법
US10/466,244 US7129195B2 (en) 2001-01-15 2002-01-12 Heterogenically catalysed gas-phase partial oxidation method for precursor compounds of (meth)acrylic acid
JP2002562698A JP2004517953A (ja) 2001-01-15 2002-01-12 （メタ）アクリル酸の前駆物質化合物の不均一系触媒作用下での気相部分酸化法
AU2002246034A AU2002246034A1 (en) 2001-01-15 2002-01-12 Heterogenically catalysed gas-phase partial oxidation for precursor compounds of (meth)acrylic acid
DE10290375T DE10290375D2 (de) 2001-01-15 2002-01-12 Verfahren der heterogen katalysierten Gasphasenpartialoxidation von Vorläuferverbindungen der (Meth)acrylsäure
US11/443,135 US20070032680A1 (en) 2001-01-15 2006-05-31 Heterogeneously catalyzed gas-phase partial oxidation of precursor compounds of (meth)acrylic acid

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10101695.6 2001-01-15
DE10101695A DE10101695A1 (de) 2001-01-15 2001-01-15 Verfahren zur heterogen katalysierten Gasphasenpartialoxidation von Vorläuferverbindungen der (Meth)acrylsäure

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/443,135 Division US20070032680A1 (en) 2001-01-15 2006-05-31 Heterogeneously catalyzed gas-phase partial oxidation of precursor compounds of (meth)acrylic acid

Publications (2)

Publication Number Publication Date
WO2002062737A2 WO2002062737A2 (de) 2002-08-15
WO2002062737A3 true WO2002062737A3 (de) 2002-11-07

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PCT/EP2002/000234 WO2002062737A2 (de) 2001-01-15 2002-01-12 Heterogene katalysierte gasphasenpartialoxidation von vorläuferverbindungen der (meth)acrylsäure

Country Status (11)

Country Link
US (2) US7129195B2 (de)
EP (1) EP1353892A2 (de)
JP (1) JP2004517953A (de)
KR (1) KR20030070105A (de)
CN (1) CN1484628A (de)
AU (1) AU2002246034A1 (de)
BR (1) BR0206493A (de)
CZ (1) CZ20031943A3 (de)
DE (2) DE10101695A1 (de)
WO (1) WO2002062737A2 (de)
ZA (1) ZA200306312B (de)

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